JP2002516210A - Vehicle headliner made of thermoformable thermoplastic foam sheet - Google Patents
Vehicle headliner made of thermoformable thermoplastic foam sheetInfo
- Publication number
- JP2002516210A JP2002516210A JP2000550708A JP2000550708A JP2002516210A JP 2002516210 A JP2002516210 A JP 2002516210A JP 2000550708 A JP2000550708 A JP 2000550708A JP 2000550708 A JP2000550708 A JP 2000550708A JP 2002516210 A JP2002516210 A JP 2002516210A
- Authority
- JP
- Japan
- Prior art keywords
- foam
- vehicle
- headliner
- core layer
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 45
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- 239000004744 fabric Substances 0.000 claims abstract description 47
- 239000012792 core layer Substances 0.000 claims abstract description 46
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/05—Use of one or more blowing agents together
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Laminated Bodies (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
(57)【要約】 【課題】 現在の乗り物のヘッドライナーの不利な点は、高価なコンポーネントの物質及び複雑な製造方法により、コストが高く、有効なリサイクルが通常困難である。 【解決手段】 ヘッドライナーは熱成形された芯の層からなり、芯の層は、押し出された熱可塑性発泡体と所望により実質的に発泡していない熱可塑物の一つ以上の隣接する層からなるが、実質的に熱硬化性物質を含まず、好ましくはガラス/ガラス繊維のマット又はスクリムを含まない。芯の層は、乗り物に設置されるとき、実質的にたわみに抵抗し、そしてその形状を実質的に維持できる。修飾層例えばフェルト層又は布帛層は、好ましくは芯の層にラミネートされる。 The disadvantages of current vehicle headliners are that they are expensive and difficult to effectively recycle, due to expensive component materials and complicated manufacturing methods. The headliner comprises a thermoformed core layer, the core layer comprising one or more adjacent layers of extruded thermoplastic foam and optionally substantially non-foamed thermoplastic. But is substantially free of thermosetting materials, preferably free of glass / fiberglass mats or scrims. The core layer, when installed on a vehicle, substantially resists deflection and can substantially maintain its shape. A modifying layer, such as a felt or fabric layer, is preferably laminated to the core layer.
Description
【0001】[0001]
本発明は、熱可塑性発泡体からなる熱成形された芯の層を有する乗り物のヘッ
ドライナー(乗り物の天井の内張り)に関する。芯の層及びヘッドライナーは、
たとえ高温ででも乗り物に設置される場合、それらの形状及び輪郭を実質的に維
持できる。The present invention relates to a vehicle headliner (vehicle ceiling lining) having a thermoformed core layer of thermoplastic foam. The core layer and headliner are
Even when installed on vehicles, even at high temperatures, their shape and contour can be substantially maintained.
【0002】[0002]
ヘッドライナーは、乗り物の客室の屋根の下面に適用されるラミネートである
。ヘッドライナーは、衝撃吸収、美観、熱絶縁及び音響絶縁を含む種々の目的に
働く。 工業的に生産される乗り物に使用されるヘッドライナーは、ヘッドライナーが
曝される物理的な要求及び環境的な条件により、比較的複雑でありしかも高度の
技術を要する。ヘッドライナーは、重力によるたわみを防ぐのに十分な剛さを有
するが、製作及び/又は熱成形及び設置を行うのに十分に曲げやすくなくてはな
らない。ヘッドライナーは、また、客室の乗客による急激な接触の場合に或る程
度の衝撃吸収をもたらす全体の衝撃保護システムの一部であろう。ヘッドライナ
ーは、また、乗り物が太陽熱に曝されるときに生ずる高温に抵抗できなければな
らない。ヘッドライナーは、さらに、所望の形状、構造又は輪郭に成形できなけ
ればならない。The headliner is a laminate that is applied to the underside of the vehicle cabin roof. Headliners serve a variety of purposes, including shock absorption, aesthetics, thermal insulation and acoustic insulation. Headliners used in industrially produced vehicles are relatively complex and require high technology, depending on the physical requirements and environmental conditions to which the headliner is exposed. The headliner must have sufficient stiffness to prevent buckling due to gravity, but be flexible enough to be fabricated and / or thermoformed and installed. The headliner will also be part of an overall shock protection system that provides some shock absorption in the event of sudden contact by passengers in the cabin. The headliner must also be able to withstand the high temperatures that occur when the vehicle is exposed to solar heat. The headliner must also be capable of being shaped into a desired shape, structure or profile.
【0003】 現在工業的に使用されているヘッドライナーは、概して、ポリウレタン接着剤
により接着されそして所望の形状及び輪郭に加熱下ともにプレスされるポリウレ
タン発泡体及びガラス/ガラス繊維のマット又はスクリムの複数の層により成形
される。フェルト又は布帛は、概して、客室の内部に面することになる表面でヘ
ッドライナーに適用される。代表的なヘッドライナーは、米国特許第54608
70、5486256、5582906及び5670211号に開示されている
ものを含み、これらは、本明細書に参考として引用される。[0003] Headliners currently used in industry are generally comprised of a plurality of polyurethane foam and glass / glass fiber mats or scrims bonded together by a polyurethane adhesive and pressed together under heating to the desired shape and profile. Formed by the following layers. The felt or fabric is generally applied to the headliner on the surface that will face the interior of the cabin. A representative headliner is disclosed in US Pat.
Nos. 5,058,256, 5,582,906 and 5,670,211 which are incorporated herein by reference.
【0004】 現在の工業的なヘッドライナーの不利な点は多い。それらは、高価なコンポー
ネントの物質及び複雑な製造方法により、コストが高い。熱硬化性接着剤例えば
ポリウレタン接着剤は高価であり、複数の工程、時間のかかる適用及び硬化法を
要する。繊維状の形のガラス、ガラス繊維、炭素又は他の物質の補強用布帛又は
スクリム並びにポリウレタン発泡体シートは、また、熱硬化性接着剤とともに層
状の配列で散在していなければならない。これらの補強用物質は高価であり、熱
硬化性接着剤とともに製品中への複数の工程の組み込みを要する。さらに、コン
ポーネント物質及び最終のヘッドライナー製品は、不可能でないにしても、有効
なリサイクルが通常困難である。[0004] The disadvantages of current industrial headliners are numerous. They are costly due to expensive component materials and complicated manufacturing methods. Thermosetting adhesives, such as polyurethane adhesives, are expensive and require multiple steps, time consuming application and curing methods. Reinforcing fabrics or scrims of glass, fiberglass, carbon or other materials in fibrous form and polyurethane foam sheets must also be interspersed with the thermosetting adhesive in a layered arrangement. These reinforcing materials are expensive and require multiple steps to be incorporated into the product along with the thermosetting adhesive. Furthermore, component materials and final headliner products are usually difficult, if not impossible, to effectively recycle.
【0005】 より安価なコンポーネント物質からなりそしてより複雑でない安価な製造方法
により組立てのできるヘッドライナーを有することが望ましい。さらに、熱硬化
性物質と補強用布帛又はスクリムを使用するヘッドライナーによりもたらされる
ものと同様な性能の特徴及び特性を提供するヘッドライナーを有することも望ま
しい。また、ヘッドライナー及び/又はそのコンポーネント物質が容易にリサイ
クルできることも望ましい。It is desirable to have a headliner that is made of cheaper component materials and that can be assembled by less complex and less expensive manufacturing methods. Additionally, it is also desirable to have a headliner that provides performance characteristics and properties similar to those provided by a headliner using a thermoset and a reinforcing fabric or scrim. It is also desirable that the headliner and / or its component materials be easily recyclable.
【0006】[0006]
本発明によれば、改良されたヘッドライナーを有する乗り物がある。乗り物は
、そのなかに客室と客室の頭上に位置する屋根を有する。ヘッドライナーは、屋
根の下面に隣接して位置する。ヘッドライナーは熱成形された芯の層からなる。
芯の層は、押し出された熱可塑性発泡体と所望により実質的に発泡していない熱
可塑物の一つ以上の隣接する層からなる。芯の層は、実質的に熱硬化性物質を含
まず、好ましくはガラス/ガラス繊維のマット又はスクリムを含まない。芯の層
は、ヘッドライナーが乗り物に設置されるとき、実質的にたわみに抵抗し、そし
てその熱成形された形状を実質的に維持できる。修飾的な層例えばフェルト層又
は布帛層は、好ましくは芯の層にラミネートされる。According to the present invention, there is a vehicle having an improved headliner. The vehicle has a cabin therein and a roof located overhead of the cabin. The headliner is located adjacent to the lower surface of the roof. The headliner consists of a thermoformed core layer.
The core layer consists of an extruded thermoplastic foam and one or more adjacent layers of an optionally substantially unfoamed thermoplastic. The core layer is substantially free of thermosetting materials, preferably free of glass / fiberglass mats or scrims. The core layer substantially resists deflection when the headliner is installed in a vehicle and can substantially maintain its thermoformed shape. A decorative layer, such as a felt or fabric layer, is preferably laminated to the core layer.
【0007】 さらに本発明によれば、ヘッドライナーを組立て又は製造し、それを乗り物に
設置する方法がある。方法は、a)押し出された熱可塑性発泡体及び所望により
実質的に発泡していない熱可塑性樹脂の一つ以上の隣接する層からなる熱成形可
能な芯の層を設け、芯の層が実質的に熱硬化性物質を含まず、たわみに実質的に
抵抗しそして実質的にその形状を維持し;b)それに熱及び機械的な圧をかける
ことにより芯の層を熱成形してヘッドライナーを形成し;c)屋根の下面に隣接
してヘッドライナーを配置することを含む。好ましくは、装飾層は、客室の内部
に面することになる芯の層の表面にラミネートされる。装飾層は、芯の層の熱成
形前又は後の何れかで芯の層にラミネートできる。Further in accordance with the present invention, there is a method of assembling or manufacturing a headliner and installing it on a vehicle. The method comprises the steps of: a) providing a thermoformable core layer consisting of an extruded thermoplastic foam and optionally one or more adjacent layers of a substantially unfoamed thermoplastic resin, wherein the core layer is substantially B) thermoforming the core layer by applying heat and mechanical pressure thereto, wherein the headliner is substantially free of thermosetting materials and substantially resists deflection and substantially maintains its shape; C) disposing a headliner adjacent the lower surface of the roof. Preferably, the decorative layer is laminated to the surface of the core layer that will face the interior of the cabin. The decorative layer can be laminated to the core layer either before or after thermoforming the core layer.
【0008】 図1は、ヘッドライナーを有する乗り物の部分的な断面を有する断片的な透視
図である。 図2は、乗り物の屋根及びヘッドライナーが示される図1のカッタウエイ部分
の側面図である。 図3は、ヘッドライナーがカッタウエイで示されるヘッドライナーを有する乗
り物の屋根の断片的な透視図である。 図4は、ヘッドライナーがカッタウエイで示されるヘッドライナーを有する乗
り物の屋根の断片的な透視図である。 図5は、発泡された部分及び発泡されていない部分を有するヘッドライナーの
部分を示す。 図6−11は、ヘッドライナーアセンブリの部分のいくらかの構成を示す。FIG. 1 is a fragmentary perspective view with a partial cross section of a vehicle having a headliner. FIG. 2 is a side view of the cutterway portion of FIG. 1 showing the vehicle roof and headliner. FIG. 3 is a fragmentary perspective view of a vehicle roof having a headliner in which the headliner is indicated by a cutterway. FIG. 4 is a fragmentary perspective view of a vehicle roof having a headliner in which the headliner is indicated by a cutterway. FIG. 5 shows a portion of the headliner having a foamed portion and a non-foamed portion. Figures 6-11 show some configurations of parts of the headliner assembly.
【0009】 ヘッドライナーは、たった一つのヘッドライナーに関して当業者に知られてい
ない多くの利点をもたらす。これらの利点は、ヘッドライナーに存在する熱成形
可能な芯の層に多く関連する。これらの利点は、以下のものを含む。ヘッドライ
ナーが所望の形状、構成又は輪郭に容易に熱成形可能である;ヘッドライナーが
、熱い気候及び/又は日光の直射の条件で乗り物が通常遭遇する高温に曝された
ときですら、十分に剛くてたわみを防ぎそして実質的にその形状を維持する;ヘ
ッドライナーが好ましくは比較的安価なリサイクル可能な熱可塑物からなる。ヘ
ッドライナーは、頭がぶつかることに対して良好な緩衝性をもたらし、良好な音
響及び熱の吸収を示す。[0009] A headliner offers a number of advantages that are not known to those skilled in the art for only one headliner. These advantages are largely related to the thermoformable core layer present in the headliner. These advantages include the following. The headliner is easily thermoformable to the desired shape, configuration or contour; the headliner is sufficiently well-formed even when exposed to the high temperatures normally encountered by vehicles in conditions of hot weather and / or direct sunlight. Rigid to prevent deflection and substantially maintain its shape; the headliner preferably comprises a relatively inexpensive recyclable thermoplastic. The headliner provides good cushioning against head hits and exhibits good sound and heat absorption.
【0010】 本発明の熱可塑性発泡体からなる芯の層は、ヘッドライナーで有用であるとし
て従来技術で教示されている他の発泡体層に対して顕著な利点をもたらす。米国
特許第5670211号は、ポリウレタン接着剤により処理されヘッドライナー
に成形されるポリウレタン発泡体のたわむ又は半剛体の発泡体シートを有するヘ
ッドライナーを開示している。この特許は、また、PPO、膨脹したポリスチレ
ン及び膨脹したポリプロピレンの他の発泡シートがポリウレタン発泡体に変わり
うることを開示している。本発明の芯の層は、それが実質的に熱硬化性接着剤を
含まずそしてさらに容易にリサイクル出来る点で、この特許の教示より有利であ
る。押し出された熱可塑性発泡体からなる芯の層は、また、ポリウレタン発泡体
よりより容易に熱成形可能であり、概して膨脹された(ビーズ)発泡体より所定
の密度でより強く、ポリスチレン発泡体より高い熱歪み抵抗性を示す。米国特許
第3637458号は、ヘッドライナーとしての応用も含む応用の洗濯用のリス
トに有用であると記述された非常に薄い押し出されたポリプロピレン発泡体シー
トを開示している。この特許は、開示されたポリプロピレン発泡体シートはその
なかに有する機能又はこのヘッドライナーの構造に関する教示はない。発泡体は
、例えば構造及び機械的な性能をもたらすようなヘッドライナーにおける異なる
機能又は装飾的な布帛層に関する緩衝的な裏材として働くことができる。米国特
許第5536793号は、ヘッドライナーを含む多くの応用に有用であると記述
されているポリエステル発泡体を開示している。この特許の教示は、米国特許第
3637458号のものと同じ理由で不十分である。[0010] The core layer of the thermoplastic foam of the present invention offers significant advantages over other foam layers taught in the prior art as being useful in headliners. U.S. Pat. No. 5,670,211 discloses a headliner having a flexible or semi-rigid foam sheet of polyurethane foam which is treated with a polyurethane adhesive and molded into a headliner. The patent also discloses that other foam sheets of PPO, expanded polystyrene and expanded polypropylene can be converted to polyurethane foam. The core layer of the present invention is advantageous over the teachings of this patent in that it is substantially free of thermosetting adhesive and is more easily recyclable. A core layer of extruded thermoplastic foam is also more easily thermoformable than polyurethane foam, is generally stronger at a given density than expanded (bead) foam, and is more rigid than polystyrene foam. Shows high thermal strain resistance. U.S. Pat. No. 3,637,458 discloses a very thin extruded polypropylene foam sheet which has been described as being useful in a laundry list of applications, including applications as a headliner. This patent does not teach the function of the disclosed polypropylene foam sheet or the structure of this headliner. The foam can serve as a cushioning backing for different functions or decorative fabric layers in the headliner, for example, to provide structural and mechanical performance. U.S. Pat. No. 5,536,793 discloses polyester foams that are described as useful for many applications, including headliners. The teachings of this patent are inadequate for the same reasons as in US Pat. No. 3,637,458.
【0011】 図は、本発明の態様を示す。図1では、乗り物10は、屋根12、客室14、
及びヘッドライナー16を有する。図1は、図2に見られる断面側面図に対応す
る円状の点線2−2に沿ったカッタウエイを示す。図2は、それに接着又は付着
したヘッドライナー16を有する屋根12を示す。ヘッドライナー16は、従来
の押し出された熱可塑性発泡体20、接着剤層22及び布帛層24からなる。図
3は、屋根/ヘッドライナーの組合せの別の態様を示す。図3では、乗り物の屋
根32に接着又は付着したヘッドライナー30がある。ヘッドライナー30は、
押し出され且つ合着したストランド熱可塑性発泡体34及び布帛層36からなる
。ヘッドライナー30では、ストランドは、ほぼ垂直でしかもほぼ屋根32の平
面にほぼ直角に配向されている。図4は、屋根/ヘッドライナーの組合せの別の
態様を示す。図4では、乗り物の屋根42に接着又は付着したヘッドライナー4
0がある。ヘッドライナー40は、押し出され且つ合着したストランド熱可塑性
発泡体44及び布帛層46からなる。ヘッドライナー40では、ストランドは、
ほぼ水平でしかも屋根42の平面にほぼ平行して配向されている。The figures illustrate aspects of the present invention. In FIG. 1, the vehicle 10 includes a roof 12, a cabin 14,
And a headliner 16. FIG. 1 shows a cutterway along a circular dotted line 2-2 corresponding to the cross-sectional side view seen in FIG. FIG. 2 shows a roof 12 having a headliner 16 adhered or adhered thereto. The headliner 16 comprises a conventional extruded thermoplastic foam 20, an adhesive layer 22, and a fabric layer 24. FIG. 3 illustrates another embodiment of a roof / headliner combination. In FIG. 3, there is a headliner 30 adhered or adhered to a vehicle roof 32. The headliner 30
Consists of extruded and coalesced strand thermoplastic foam 34 and fabric layer 36. In the headliner 30, the strands are oriented substantially perpendicularly and substantially perpendicular to the plane of the roof 32. FIG. 4 illustrates another embodiment of a roof / headliner combination. In FIG. 4, the headliner 4 adhered or adhered to the vehicle roof 42.
There is 0. The headliner 40 comprises an extruded and coalesced strand thermoplastic foam 44 and a fabric layer 46. In the headliner 40, the strand is
It is oriented substantially horizontal and substantially parallel to the plane of the roof 42.
【0012】 当業者に知られている接着剤は、ヘッドライナーの種々の層を互いに接着する
か又はヘッドライナーを自動車の屋根に接着するために使用できる。有用な接着
剤は、熱硬化性接着剤例えばポリウレタン樹脂及びエポキシ樹脂、並びに熱可塑
性接着剤例えばポリエチレン、ポリプロピレン、エチレンコポリマー;プロピレ
ンコポリマーなどを含む。有用な接着剤は、米国特許第5460870及び56
70211号に教示されている。接着剤は、当業者に周知の任意の手段、例えば
噴霧、コーティング又はフィルムの形により塗布できる。好ましい接着剤は、そ
れらの低いコスト及びリサイクル可能性のために熱可塑性樹脂である。接着剤の
存在は、本発明にとり必須ではない。発泡体は、独立気泡又は連続気泡である。
連続気泡含量は、ASTM D2856−Aにより測定される。独立気泡の発泡
体は、よりよい熱絶縁性及び弾性の利点をもたらし、そして連続気泡の発泡体は
、よりよい音響絶縁、寸法安定性及び熱成形中の熱移動の利点をもたらす。[0012] Adhesives known to those skilled in the art can be used to bond the various layers of the headliner together or to bond the headliner to the roof of an automobile. Useful adhesives include thermosetting adhesives such as polyurethane resins and epoxy resins, and thermoplastic adhesives such as polyethylene, polypropylene, ethylene copolymers; propylene copolymers and the like. Useful adhesives are described in U.S. Patent Nos. 5,460,870 and 56
No. 70211. The adhesive can be applied by any means known to those skilled in the art, for example, by spraying, coating or in the form of a film. Preferred adhesives are thermoplastics due to their low cost and recyclability. The presence of the adhesive is not essential to the invention. Foams are closed cells or open cells.
The open cell content is measured according to ASTM D2856-A. Closed cell foams offer the advantage of better thermal insulation and resilience, and open cell foams offer the advantage of better acoustic insulation, dimensional stability and heat transfer during thermoforming.
【0013】 熱可塑性発泡体は、好ましくは、1立方メートル当たり約16−約200そし
てさらに好ましくは約16−約80キログラムの熱成形前の密度を有する。発泡
体は、ASTM D3576により、好ましくは約0.1−約5.0そして好ま
しくは約0.2−約3.0ミリメートルの平均気泡サイズを有する。指示された
発泡体の密度及び気泡サイズの範囲は、熱可塑性発泡体について一般に存在して
いる。最も好ましい密度及び気泡サイズの範囲は、発泡体の組成及び望ましい物
理的性質に依存して変化するだろう。例えば、発泡体は、通常、密度又は気泡サ
イズの増加によりさらに剛くできる。 特に望ましい発泡体は、1立方メートル当たり約16−約160キログラムそ
して好ましくは1立方メートル当たり約24−約100キログラムの熱成形前の
密度を有するプロピレンポリマー、ポリエステル及びポリアミドのものである。The thermoplastic foam preferably has a density before thermoforming of about 16 to about 200 and more preferably about 16 to about 80 kilograms per cubic meter. The foam preferably has an average cell size of from about 0.1 to about 5.0 and preferably from about 0.2 to about 3.0 millimeters according to ASTM D3576. The indicated foam density and cell size ranges are generally present for thermoplastic foams. The most preferred density and cell size ranges will vary depending on the foam composition and the desired physical properties. For example, foams can typically be made more rigid by increasing density or cell size. Particularly desirable foams are those of propylene polymers, polyesters and polyamides having a density before thermoforming of about 16 to about 160 kilograms per cubic meter and preferably about 24 to about 100 kilograms per cubic meter.
【0014】 熱可塑性発泡体は、好ましくは、一体化した構造として押し出されるが、また
当業者に周知の任意の手段例えば熱ウエルディング又は接着層により、2枚以上
の比較的薄い熱可塑性発泡体シートをともにラミネートすることによって形成で
きる。 発泡体は、熱歪みに抵抗性がなければならず、そして日光の加熱により乗り物
の屋根で通常遭遇する高温で寸法的に安定でなければならない。発泡体は、好ま
しくは、SAE883に従って膨脹及び収縮の両者に関して約5%以下そしてさ
らに好ましくは約1%以下の寸法安定性を示す。 発泡体は、任意の断面のサイズ又は形態例えば発泡体のシート又は平板で作ら
れる。特に有用な発泡体は、1.5ミリメートル以上又はさらに好ましくは3ミ
リメートル以上の断面(厚さ)の小さいディメンジョンを有するものである。[0014] The thermoplastic foam is preferably extruded as an integral structure, but may also be extruded by any means known to those skilled in the art, such as a thermal welding or adhesive layer, to provide two or more relatively thin thermoplastic foams. It can be formed by laminating the sheets together. The foam must be resistant to thermal distortion and must be dimensionally stable at the high temperatures normally encountered on vehicle roofs due to sunlight heating. The foam preferably exhibits a dimensional stability of less than about 5% and more preferably less than about 1% with respect to both expansion and contraction according to SAE 883. The foam may be made of any cross-sectional size or form, such as a sheet or flat sheet of foam. Particularly useful foams are those having a small cross-section (thickness) dimension of 1.5 mm or more, or more preferably 3 mm or more.
【0015】 フェルト又は布帛のような装飾的な物質の一つ以上の層は、美観を呈するため
に、客室の内部又はインテリアキャビンに面するヘッドライナーの表面に適用さ
れる。層は、当業者に周知の任意のタイプのものである。工業的に最も代表的に
使用されるものは、フェルト又は織った布帛である。有用な布帛は、織ったポリ
エステル、ナイロン及びポリプロピレンの繊維のものを含む。好ましくは、フェ
ルト又は布帛の層は、当業者に周知の任意の手段、例えば熱ウエルディング、接
着フィルム又は接着用液体又はコーティングにより発泡体に接着できる。好まし
い修飾的な層は、接着剤の助けなしに芯の層に熱的にウエルディングされた熱可
塑性繊維の織った布帛である。熱ウエルディングは、繊維が粘着性になりそして
接着剤の助けなしに芯の層に接着出来る程度に布帛層を加熱することを意味する
。布帛層は、もし熱成形中に芯の層に適用されるか又は芯の層がそれ以外に高温
である場合には、芯の層に熱的にウエルディングできる。[0015] One or more layers of decorative material, such as felt or fabric, are applied to the interior of the cabin or to the surface of the headliner facing the interior cabin to provide an aesthetic appearance. The layers are of any type known to those skilled in the art. The most typically used in industry are felts or woven fabrics. Useful fabrics include those of woven polyester, nylon and polypropylene fibers. Preferably, the felt or fabric layer can be adhered to the foam by any means known to those skilled in the art, such as hot welding, an adhesive film or an adhesive liquid or coating. A preferred modifying layer is a woven fabric of thermoplastic fibers that is thermally welded to the core layer without the aid of an adhesive. Hot welding refers to heating the fabric layer to an extent that the fibers become tacky and can adhere to the core layer without the aid of an adhesive. The fabric layer can be applied to the core layer during thermoforming or can be thermally welded to the core layer if the core layer is otherwise hot.
【0016】 好ましいヘッドライナーは、リサイクル可能な物質だけからなる。有用なリサ
イクル可能な物質は、プロピレンポリマー例えばポリプロピレン;高密度ポリエ
チレン;ポリエステル例えばポリエチレンテレフタレート;及びポリカーボネー
トを含む。最も好ましいヘッドライナーは、それらがともにリサイクルできるよ
うな同様な組成のリサイクル可能な物質だけからなる。例えば、ヘッドライナー
は、以下のものの任意のものからなる。プロピレンポリマー発泡体と織ったポリ
プロピレン布帛層とのラミネート;ポリエチレンテレフタレート発泡体と織った
ポリエチレンテレフタレート布帛層とのラミネート;又はポリアミド(ナイロン
)発泡体とポリアミド布帛層。所望ならば、異なるリサイクル可能な物質は、以
下のようにともに使用できる。a)プロピレンポリマー発泡体とポリエステル又
はポリアミドの織った布帛層とのラミネート、及びb)ポリエステル発泡体とポ
リプロピレン又はポリアミドの織った布帛層とのラミネート。Preferred headliners consist solely of recyclable materials. Useful recyclable materials include propylene polymers such as polypropylene; high density polyethylene; polyesters such as polyethylene terephthalate; and polycarbonate. Most preferred headliners consist only of recyclable materials of similar composition such that they can be recycled together. For example, the headliner may be any of the following: A laminate of a propylene polymer foam and a woven polypropylene fabric layer; a laminate of a polyethylene terephthalate foam and a woven polyethylene terephthalate fabric layer; or a polyamide (nylon) foam and a polyamide fabric layer. If desired, different recyclable materials can be used together as follows. a) lamination of a propylene polymer foam with a woven fabric layer of polyester or polyamide, and b) lamination of a polyester foam with a woven fabric layer of polypropylene or polyamide.
【0017】 発泡体は、所望の形状、形態又は輪郭に容易に熱成形可能である。概して、発
泡体そしてヘッドライナーの残りのものは、ヘッドライナーが屋根の下方に位置
するために、乗り物の屋根と実質的に同じ形状、形態又は輪郭のものである。用
語「熱成形可能」は、発泡体が、異なる形状又は輪郭へ、当業者に周知の任意の
従来の手段により熱及び機械的な圧の下に熱成形されるか又はそれ以外に成形さ
れることを意味する。概して、発泡体は、実質的に平らなシート又は平板の形で
提供され、そして熱及び圧の下プレスされて、それがその下に位置する乗り物の
屋根と同様な形状及び輪郭のシートを形成する。所望ならば、修飾的な層例えば
織った熱可塑性繊維の布帛層は、熱成形工程中に発泡体に熱ウエルディングされ
る。The foam can be easily thermoformed into a desired shape, form or contour. In general, the foam and the rest of the headliner are of substantially the same shape, form or profile as the vehicle roof because the headliner is located below the roof. The term “thermoformable” means that the foam is thermoformed or otherwise shaped under different thermal or mechanical pressures by any conventional means well known to those skilled in the art. Means that. Generally, the foam is provided in the form of a substantially flat sheet or slab and is pressed under heat and pressure to form a sheet similar in shape and contour to the roof of the underlying vehicle. I do. If desired, a decorative layer, such as a fabric layer of woven thermoplastic fibers, is hot welded to the foam during the thermoforming process.
【0018】 発泡体の物理的な性質及び熱抵抗性は、例えば発泡体へプラスチックフィルム
又はシートをラミネート化することにより、プラスチック樹脂によりそれをコー
ティングすることにより、そのガラス転移温度又は融点より高く発泡体の一つ以
上の表面を加熱して表面で気泡構造をこわすことにより、又はこれらの任意のも
のの組合せにより、発泡体上の実質的に発泡していない表面を形成することを導
入することにより増加できる。フィルム、シート又はコーティングは、任意の周
知の熱可塑性樹脂又は熱硬化性樹脂からなる。有用な熱可塑性樹脂は、発泡体を
形成するものに関して上述されたものを含み、有用な熱硬化性樹脂は、ポリウレ
タン及びエポキシ樹脂を含む。 ヘッドライナーは、当業者に周知の任意の手段、例えば接着により又は機械的
な手段による付着により、乗り物の屋根の下面に適用できる。機械的な手段は、
クリップ、サイドモールディング、及び頭上(ドーム)ライトアセンブリを含む
。[0018] The physical properties and thermal resistance of the foam can be measured by, for example, laminating a plastic film or sheet to the foam, coating it with a plastic resin, and foaming above its glass transition temperature or melting point. By heating one or more surfaces of the body to break the cellular structure at the surface, or by combining any of these, to form a substantially non-foamed surface on the foam Can increase. The film, sheet or coating may be made of any known thermoplastic or thermosetting resin. Useful thermoplastics include those described above for forming the foam, and useful thermosets include polyurethane and epoxy resins. The headliner can be applied to the underside of the vehicle roof by any means known to those skilled in the art, such as by gluing or by mechanical means. Mechanical means
Includes clips, side moldings, and overhead (dome) light assemblies.
【0019】 有用な熱可塑性発泡体は、プロピレンポリマー、ポリエステル、ポリアミド、
ポリカーボネート、高密度ポリエチレン、塩素化ポリエチレン、ポリフェニレン
オキシド、ポリフェニレンオキシドとポリスチレンとのブレンド、プロピレン/
エチレンコポリマー、熱可塑性ポリウレタン、EPDMとポリエチレンとのブレ
ンド、ポリプロピレンとEPDMとのブレンド、ポリプロピレンとエチレン/ス
チレンコポリマーとのブレンドを含むが、これらに限定されない。エチレン/ス
チレンコポリマー及びこれを含む発泡体は、米国特許第5460818号に教示
され、それは本明細書に参考として引用される。好ましい発泡体は、プロピレン
ポリマー発泡体及びポリエステル発泡体を含む。さらに好ましい発泡体は、ポリ
プロピレン発泡体、95/5−99.5/0.5のモノマー重量比のプロピレン
/エチレンコポリマーの発泡体、そしてポリエチレンテレフタレート発泡体を含
む。Useful thermoplastic foams are propylene polymers, polyesters, polyamides,
Polycarbonate, high density polyethylene, chlorinated polyethylene, polyphenylene oxide, blend of polyphenylene oxide and polystyrene, propylene /
Including, but not limited to, ethylene copolymers, thermoplastic polyurethanes, blends of EPDM and polyethylene, blends of polypropylene and EPDM, and blends of polypropylene and ethylene / styrene copolymer. Ethylene / styrene copolymers and foams containing same are taught in U.S. Pat. No. 5,460,818, which is incorporated herein by reference. Preferred foams include propylene polymer foams and polyester foams. More preferred foams include polypropylene foam, propylene / ethylene copolymer foam with a monomer weight ratio of 95 / 5-99.5 / 0.5, and polyethylene terephthalate foam.
【0020】 芯の層に最も好ましい発泡体は、押し出されたプロピレンポリマー発泡体であ
る。好適なプロピレンポリマー物質は、プロピレンホモポリマー(ポリプロピレ
ン)、及びプロピレンと共重合可能なエチレン性不飽和コモノマーとのコポリマ
ーを含む。プロピレンポリマー物質は、さらに非プロピレン性ポリマーを含むこ
とができる。プロピレンポリマー物質は、1種以上のプロピレンホモポリマー、
1種以上のプロピレンコポリマー、プロピレンホモポリマー及びコポリマーのそ
れぞれの1種以上のブレンド、又は前記のものの任意のものと非プロピレンポリ
マーとのブレンドだけからなることができる。組成に関係なく、プロピレンポリ
マー物質は、50重量%より多いそして好ましくは約70重量%以上のプロピレ
ンモノマー単位を含む。The most preferred foam for the core layer is an extruded propylene polymer foam. Suitable propylene polymer materials include propylene homopolymer (polypropylene), and copolymers of propylene with ethylenically unsaturated comonomers that are copolymerizable with propylene. The propylene polymer material can further include a non-propylene polymer. The propylene polymer material comprises one or more propylene homopolymers,
It may consist solely of one or more blends of one or more propylene copolymers, propylene homopolymers and copolymers, or a blend of any of the foregoing with a non-propylene polymer. Regardless of composition, the propylene polymer material contains more than 50% by weight and preferably more than about 70% by weight of propylene monomer units.
【0021】 好適なモノエチレン性不飽和コモノマーは、オレフィン、酢酸ビニル、アクリ
ル酸メチル、アクリル酸エチル、メチルメタクリレート、アクリル酸、イタコン
酸、マレイン酸、無水マレイン酸などを含む。プロピレンコポリマーは、好まし
くは、約45重量%以下のエチレン性不飽和コモノマーを含む。 プロピレンポリマー物質に配合可能な好適な非プロピレン性ポリマーは、高密
度、中密度、低密度そして線状のポリエチレン、ポリブテン−1、エチレン/ア
クリル酸コポリマー、エチレン/酢酸ビニルコポリマー、エチレン/プロピレン
コポリマー、スチレン/ブタジエンコポリマー、エチレン/スチレンコポリマー
、エチレン/アクリル酸エチルコポリマー、イオノマーなどを含む。[0021] Suitable monoethylenically unsaturated comonomers include olefins, vinyl acetate, methyl acrylate, ethyl acrylate, methyl methacrylate, acrylic acid, itaconic acid, maleic acid, maleic anhydride and the like. The propylene copolymer preferably contains up to about 45% by weight of the ethylenically unsaturated comonomer. Suitable non-propylene polymers that can be incorporated into the propylene polymer material include high density, medium density, low density and linear polyethylene, polybutene-1, ethylene / acrylic acid copolymer, ethylene / vinyl acetate copolymer, ethylene / propylene copolymer, Including styrene / butadiene copolymer, ethylene / styrene copolymer, ethylene / ethyl acrylate copolymer, ionomer and the like.
【0022】 特に有用なプロピレンコポリマーは、プロピレンと1種以上の非プロピレン性
オレフィンとのコポリマーである。プロピレンコポリマーは、プロピレンと、エ
チレン、C4−C101−オレフィン及びC4−C10ジエンからなる群から選
ばれるオレフィンとのランダム、ブロック及びグラフトコポリマーを含む。プロ
ピレンコポリマーは、また、プロピレンと、エチレン及びC4−C81−オレフ
ィンからなる群から選ばれる1−オレフィンとのランダムターポリマーを含む。
エチレンとC4−C81−オレフィンとの両者を有するターポリマーでは、エチ
レン含量は、好ましくは45重量%以下である。C4−C101−オレフィンは
、線状及び分枝鎖のC4−C101−オレフィン例えば1−ブテン、イソブチレ
ン、1−ペンテン、3−メチル−1−ブテン、1−ヘキセン、3、4−ジメチル
−1−ブテン、1−ヘプテン、3−メチル−1−ヘキセンなどを含む。C4−C 10 ジエンの例は、1、3−ブタジエン、1、4−ペンタジエン、イソプレン、
1、5−ヘキサジエン、2、3−ジメチル−1、3−ヘキサジエンなどを含む。 また、本明細書で使用されるとき、プロピレンポリマー物質は、ASTM D
1238条件Lに従って約0.05−50そして好ましくは0.1−20の溶融
流れ速度を有する。Particularly useful propylene copolymers are propylene and one or more non-propylene
It is a copolymer with an olefin. Propylene copolymers include propylene and
Tylene, C4-C101-olefin and C4-C10Choose from a group of diene
Includes random, block and graft copolymers with olefins. Professional
Pyrene copolymers also include propylene, ethylene and C4-C81-Oleph
And a random terpolymer with a 1-olefin selected from the group consisting of olefins.
Ethylene and C4-C8In terpolymers having both 1-olefins,
The len content is preferably not more than 45% by weight. C4-C101-olefins
, Linear and branched C4-C101-olefins such as 1-butene, isobutyle
1-pentene, 3-methyl-1-butene, 1-hexene, 3,4-dimethyl
-1-butene, 1-heptene, 3-methyl-1-hexene and the like. C4-C 10 Examples of dienes are 1,3-butadiene, 1,4-pentadiene, isoprene,
1,5-hexadiene, 2,3-dimethyl-1,3-hexadiene and the like. Also, as used herein, a propylene polymer material is an ASTM D
1238 Melt of about 0.05-50 and preferably 0.1-20 according to condition L
Has a flow velocity.
【0023】 好ましいプロピレンポリマー樹脂は、分枝鎖又はやや橋かけ結合したポリマー
物質であるプロピレン樹脂である。分枝鎖(又はやや橋かけ結合)は、当業者に
一般に周知の方法、例えば化学的又は照射枝分かれ化/光橋かけ化により得るこ
とができる。ポリプロピレン樹脂を使用して最終のポリプロピレン樹脂製品を製
造する前に枝分かれした/やや橋かけ結合したポリプロピレン樹脂として製造さ
れる樹脂の一つ、並びにこのポリプロピレン樹脂を製造する方法は、米国特許第
4916198号に記述され、それは本明細書に参考として引用される。分枝鎖
/やや橋かけ結合したポリプロピレン樹脂を製造する他の方法は、ポリプロピレ
ン樹脂とともに押し出し機中に化学的化合物を導入しそして押し出し機中で分枝
鎖/やや橋かけ結合反応を起こさせることである。米国特許第4714716号
は、この方法を説明しており、参考として引用される。A preferred propylene polymer resin is a propylene resin which is a branched or slightly crosslinked polymer material. Branched chains (or slightly cross-linked) can be obtained by methods generally known to those skilled in the art, for example, chemical or irradiation branching / photocrosslinking. One of the resins produced as a branched / semi-crosslinked polypropylene resin prior to producing the final polypropylene resin product using the polypropylene resin, as well as a method of producing this polypropylene resin, is disclosed in US Pat. No. 4,916,198. Which is incorporated herein by reference. Another method of producing a branched / semi-bridged polypropylene resin involves introducing a chemical compound into an extruder with the polypropylene resin and causing a branched / slightly cross-linked reaction in the extruder. It is. U.S. Pat. No. 4,714,716 describes this method and is incorporated by reference.
【0024】 有用な押し出されたプロピレンポリマー発泡体は、米国特許第5348795
、5527573及び5567742号に記載されており、それらは本明細書で
参考として引用される。 ポリエチレンテレフタレート(PET)発泡体を含む有用な押し出されたポリ
エステル発泡体は、米国特許第5000991、5234640及び55367
93号に記載されており、それらは本明細書で参考として引用される。 発泡体は、他の有用な熱可塑性樹脂、例えば高密度ポリエチレン、塩素化ポリ
エチレン、EPDMゴム(エチレン/プロピレン/ジアミンコポリマー)とポリ
エチレンとのTPO混合物から製造できる。[0024] Useful extruded propylene polymer foams are disclosed in US Pat. No. 5,348,795.
Nos. 5,527,573 and 5,567,742, which are incorporated herein by reference. Useful extruded polyester foams, including polyethylene terephthalate (PET) foams, are described in US Pat.
No. 93, which are incorporated herein by reference. Foams can be made from other useful thermoplastic resins, such as high density polyethylene, chlorinated polyethylene, TPO blends of EPDM rubber (ethylene / propylene / diamine copolymer) and polyethylene.
【0025】 有用な熱可塑性発泡体は、好ましくは非橋かけ結合のものであるが、やや橋か
け結合していてもよい。用語「橋かけ結合」は、しかし、橋かけ結合剤又は照射
の使用なしに自然に生ずる僅かな程度の橋かけ結合のものを含む。非橋かけ結合
発泡体は、ASTM D2765−84、方法Aに従って5%より少ないゲルを
含む。やや橋かけ結合した発泡体は、ASTM D2765−84、方法Aに従
って5−15%のゲルを含む。発泡剤は、有機及び/又は無機の組成の化学的発
泡剤及び物理的発泡剤のような当業者に周知の任意のものを含む。有用な好適な
無機の発泡剤は、二酸化炭素、窒素、アルゴン、水、空気、窒素及びヘリウムを
含む。好適な有機の発泡剤は、1−9個の炭素を有する脂肪族炭化水素及び1−
4個の炭素原子を有するハロゲン化脂肪族炭化水素を含む。脂肪族炭化水素は、
メタン、エタン、プロパン、n−ブタン、イソブタン、n−ペンタン、イソペン
タン、ネオペンタンなどを含む。また、アルコール例えばエタノール、メタノー
ル及びプロパノールも含まれる。ハロゲン化炭化水素のなかで、フッ素化炭化水
素が好ましい。フッ素化炭化水素の例は、フッ化メチル、ペルフルオロメタン、
フッ化エチル、1、1−ジフルオロエタン、1、1、1−トリフルオロエタン(
HFC−143a)、1、1、1、2−テトラフルオロエタン(HFC−134
a)、ペンタフルオロエタン、ペルフルオロエタン、2、2−ジフルオロプロパ
ン、1、1、1−トリフルオロプロパン、ペルフルオロプロパン、ペルフルオロ
ブタン、ペルフルオロシクロブタンを含む。本発明に使用される部分的にハロゲ
ン化されたクロロカーボン及びクロロフルオロカーボンは、塩化メチル、塩化メ
チレン、塩化エチル、1、1、1−トリクロロエタン、1、1−ジクロロ−1−
フルオロエタン(HCFC−141b)、1−クロロ−1、1−ジフルオロエタ
ン(HCFC−142b)、1、1−ジクロロ−2、2、2−トリフルオロエタ
ン(HCFC−141b)、1−クロロ−1、1−ジフルオロエタン(HCFC
−142b)、1、1−ジクロロ−2、2、2−トリフルオロエタン(HCFC
−123)及び1−クロロ−1、2、2、2−テトラフルオロエタン(HCFC
−124)を含む。完全にハロゲン化したクロロフルオロカーボンは、トリクロ
ロモノフルオロメタン(CFC−11)、ジクロロジフルオロメタン(CFC−
12)、トリクロロトリフルオロエタン(CFC−113)、ジクロロテトラフ
ルオロエタン(CFC−114)、クロロヘプタフルオロプロパン、及びジクロ
ロヘキサフルオロプロパンを含む。完全にハロゲン化されたクロロフルオロカー
ボンは、それらのオゾン消耗の潜在性のため好ましくない。化学的発泡剤は、ア
ゾジカーボンアミド、アゾジイソブチロニトリル、ベンゼンスルホンヒドラジド
、4、4−オキシベンゼンスルホニルセミカルバジド、p−トルエンスルホニル
セミカルバジド、バリウムアゾジカルボキシレート、N、N´−ジメチル−N、
N´−ジニトロソテレフタルアミド、及びトリヒドラジノトリアジンを含む。 ポリマー溶融物中に配合して発泡体形成ポリマーゲルを製造する発泡剤の量は
、ポリマーの1キログラム当たり約0.2−約4.0、好ましくは約0.3−約
3.0そして最も好ましくは約0.5−2.50モルである。Useful thermoplastic foams are preferably non-crosslinked, but may be slightly crosslinked. The term "crosslinking", however, includes those of a slight degree of crosslinking which occur naturally without the use of crosslinking agents or irradiation. The non-crosslinked foam contains less than 5% gel according to ASTM D2765-84, Method A. The slightly crosslinked foam contains 5-15% gel according to ASTM D2765-84, Method A. Blowing agents include any known to those skilled in the art, such as chemical and physical blowing agents of organic and / or inorganic composition. Useful suitable inorganic blowing agents include carbon dioxide, nitrogen, argon, water, air, nitrogen and helium. Suitable organic blowing agents are aliphatic hydrocarbons having 1-9 carbons and 1-
Includes halogenated aliphatic hydrocarbons having 4 carbon atoms. Aliphatic hydrocarbons are
Includes methane, ethane, propane, n-butane, isobutane, n-pentane, isopentane, neopentane and the like. Also included are alcohols such as ethanol, methanol and propanol. Of the halogenated hydrocarbons, fluorinated hydrocarbons are preferred. Examples of fluorinated hydrocarbons are methyl fluoride, perfluoromethane,
Ethyl fluoride, 1,1-difluoroethane, 1,1,1-trifluoroethane (
HFC-143a), 1,1,1,2-tetrafluoroethane (HFC-134
a), pentafluoroethane, perfluoroethane, 2,2-difluoropropane, 1,1,1-trifluoropropane, perfluoropropane, perfluorobutane, perfluorocyclobutane. The partially halogenated chlorocarbons and chlorofluorocarbons used in the present invention are methyl chloride, methylene chloride, ethyl chloride, 1,1,1-trichloroethane, 1,1-dichloro-1-.
Fluoroethane (HCFC-141b), 1-chloro-1,1-difluoroethane (HCFC-142b), 1,1-dichloro-2,2,2-trifluoroethane (HCFC-141b), 1-chloro-1, 1-difluoroethane (HCFC
-142b) 1,1-Dichloro-2,2,2-trifluoroethane (HCFC
-123) and 1-chloro-1,2,2,2-tetrafluoroethane (HCFC
-124). Completely halogenated chlorofluorocarbons include trichloromonofluoromethane (CFC-11) and dichlorodifluoromethane (CFC-
12), trichlorotrifluoroethane (CFC-113), dichlorotetrafluoroethane (CFC-114), chloroheptafluoropropane, and dichlorohexafluoropropane. Fully halogenated chlorofluorocarbons are not preferred because of their ozone depletion potential. Chemical blowing agents include azodicarbonamide, azodiisobutyronitrile, benzenesulfonhydrazide, 4,4-oxybenzenesulfonylsemicarbazide, p-toluenesulfonylsemicarbazide, barium azodicarboxylate, N, N′-dimethyl-N,
Including N'-dinitrosoterephthalamide and trihydrazinotriazine. The amount of blowing agent incorporated into the polymer melt to produce a foam-forming polymer gel can range from about 0.2 to about 4.0, preferably from about 0.3 to about 3.0 and most per kilogram of polymer. Preferably it is about 0.5-2.50 mol.
【0026】 熱可塑性発泡体は、一般に、熱可塑性樹脂を加熱して可塑化された又は溶融さ
れたポリマー物質を形成し、そのなかに物理的発泡剤を配合して発泡可能なゲル
を形成し、そしてダイを通してゲルを押し出して発泡体製品を形成することによ
り、押し出し工程で製造される。発泡剤は、当業者に周知の任意の手段、例えば
押し出し機、ミキサー、ブレンダーなどによりプラスチック溶融物中に配合又は
混合できる。発泡剤との混合前に、プラスチック物質は、プラスチック物質のガ
ラス転移温度又は融点以上の温度に加熱される。発泡剤は、溶融物の実質的な膨
脹を防ぎそして溶融物内に発泡剤を均一に一般に分散するのに十分な高圧でプラ
スチック溶融物と混合される。所望により、核形成剤がポリマー溶融物にブレン
ドされる。発泡剤及び核形成剤の供給速度は、比較的低密度の発泡体及び小さい
気泡サイズを達成するように調節され、それは薄い気泡壁を有する発泡体を生ず
る。[0026] Thermoplastic foams are generally formed by heating a thermoplastic resin to form a plasticized or molten polymer material, into which a physical blowing agent is incorporated to form a foamable gel. It is manufactured in an extrusion process by extruding the gel through a die to form a foam product. The blowing agent can be compounded or mixed into the plastic melt by any means known to those skilled in the art, such as an extruder, mixer, blender, and the like. Prior to mixing with the blowing agent, the plastic material is heated to a temperature above the glass transition temperature or melting point of the plastic material. The blowing agent is mixed with the plastic melt at a high pressure sufficient to prevent substantial expansion of the melt and to evenly and generally disperse the blowing agent within the melt. If desired, a nucleating agent is blended into the polymer melt. The blowing agent and nucleating agent feed rates are adjusted to achieve a relatively low density foam and small cell size, which results in a foam with thin cell walls.
【0027】 発泡剤の配合後、発泡可能なゲルは、発泡体製品の物理的特徴を最適にする低
い温度に概して冷却される。ゲルは、次に所望の形状のダイを通して低い圧力の
ゾーンに押し出されて発泡体製品を形成する。もし化学的発泡剤が使用されるな
らば、それは溶融されたポリマー物質中に配合されそして高温のゾーンに押し出
されるか又は運ばれて、剤は分解して気体通常二酸化炭素を形成する。溶融ポリ
マー物質/気体混合物は膨脹して発泡体を形成する。After incorporation of the blowing agent, the foamable gel is generally cooled to a low temperature that optimizes the physical characteristics of the foam product. The gel is then extruded through a die of desired shape into a zone of low pressure to form a foam product. If a chemical blowing agent is used, it is incorporated into the molten polymer material and extruded or conveyed to the hot zone, where the agent decomposes to form gaseous carbon dioxide. The molten polymer material / gas mixture expands to form a foam.
【0028】 熱可塑性発泡体を製造する他の好適な方法は、米国特許第4824720、5
348795、5527573、5567742号及びWO88/06094号
に記載されている合着した発泡体の方法がある。これらの特許は、複数のオリフ
ィスを含むダイを利用して複数の合着した押し出されたストランド又はプロフィ
ルからなる開放又は独立気泡ポリオレフィン発泡体を製造する方法に関する。オ
リフィスは、溶融した押し出された物の隣接する流れ間の接触が発泡工程中に生
じそして接触する表面が一体の構造を生ずるのに十分な接着により互いに接着す
るように準備される。合着した発泡体の個々のストランドは、一体の構造に接着
したままであり、製造、成形及び発泡体の利用に遭遇するストレス下のストラン
ドの剥離化を防ぐ。Another suitable method for making thermoplastic foams is disclosed in US Pat.
There are methods for coalescing foams described in US Pat. Nos. 3,487,955, 5,527,573, 5,677,742 and WO 88/06094. These patents relate to a method of making an open or closed cell polyolefin foam consisting of a plurality of coalesced extruded strands or profiles utilizing a die containing a plurality of orifices. The orifices are arranged so that contact between adjacent streams of molten extruded material occurs during the foaming process and the contacting surfaces adhere to each other with sufficient adhesion to produce a unitary structure. The individual strands of the coalesced foam remain adhered to the unitary structure, preventing the strands from delaminating under the stresses encountered in manufacturing, molding and using the foam.
【0029】 押し出され且つ合着したストランド発泡体は、異方性の物理的性質の利点をも
たらす。これらの発泡体は、横又は水平の方向よりも押し出し方向に比較的大き
な圧縮強さ及び衝撃抵抗性を示す。ストランドが図3のヘッドライナーにおける
ように水平に配向されるとき、頭のぶつかりに対するより大きな衝撃抵抗性が、
従来のスリットダイを通して押し出される一体の構造の従来の熱可塑性発泡体に
比較して所定の密度の発泡体について観察される。Extruded and coalesced strand foam offers the advantage of anisotropic physical properties. These foams exhibit relatively greater compressive strength and impact resistance in the extrusion direction than in the transverse or horizontal direction. When the strands are oriented horizontally, as in the headliner of FIG. 3, greater impact resistance to head impact is
Observed for a foam of a given density compared to a one-piece conventional thermoplastic foam extruded through a conventional slit die.
【0030】 WO88/06094号は、合着したストランド発泡体の押し出し方法に関し
、複数のオリフィス押し出しダイ内のあるオリフィスがブロック又は密封されて
、比較的大きな直径又はディメンジョンの連続し且つ縦方向のチャンネルを有す
る合着したストランドが製造できる。このような比較的大きなチャンネルを有す
る合着したストランド発泡体は、図4に示されるやり方でヘッドライナーに使用
されて、所望ならば、配線又は排気、冷却又は加熱の空気用のダクトが客室の前
部からその客室の後部又は背後に導かれる。WO 88/06094 relates to a method of extruding a coalesced strand foam wherein certain orifices in a plurality of orifice extrusion dies are blocked or sealed to provide continuous and longitudinal channels of relatively large diameter or dimension. Can be produced. A coalesced strand foam having such relatively large channels may be used in a headliner in the manner shown in FIG. 4 to provide wiring or ducts for exhaust, cooling or heating air, if desired, in the cabin. It is led from the front to the back or behind the cabin.
【0031】 米国特許第4323528号は、本明細書で参考として引用されるが、蓄積す
る押し出し工程を経てポリオレフィン発泡体を製造することに関する。方法は、
1)熱可塑性樹脂質及び発泡剤を混合してポリマーゲルを形成する工程、2)混
合物を発泡させない温度及び圧力に維持した保持ゾーン中にゲルを押し出す工程
(保持ゾーンは、ゲルが発泡するより低い圧力のゾーン中にオリフィスの開口を
画成するダイ並びにダイのオリフィスを閉じる開くことのできるゲートを有する
)、3)周期的にゲートを開ける工程、4)ゲルに移動可能なラムにより機械的
な圧力を実質的に同時に適用して、より低い圧力のゾーン中にダイのオリフィス
を通って保持ゾーンからそれを放出する工程、そして5)射出されたゲルを膨脹
させて発泡体を形成する工程からなる。US Pat. No. 4,323,528, which is hereby incorporated by reference, relates to making polyolefin foams through an accumulating extrusion process. The method is
1) a step of mixing a thermoplastic resin and a foaming agent to form a polymer gel; 2) a step of extruding the gel into a holding zone that is maintained at a temperature and pressure that does not cause the mixture to foam (the holding zone is used to form the polymer gel) Having a die defining an orifice opening in the zone of low pressure and an openable gate closing the orifice of the die), 3) periodically opening the gate, 4) mechanically by a ram movable to the gel. Applying substantially the same pressure substantially simultaneously to release it from the holding zone through the orifice of the die into the lower pressure zone, and 5) expanding the injected gel to form a foam. Consists of
【0032】 発泡体の強さは、ヘッドライナーの発泡体の部分中に比較的薄い実質的に発泡
していないプレート又はプロフィルを配合することにより増大できる。これは、
任意の好適な方法、例えば発泡体を有する又は有しない押し出し物又はプラスチ
ック溶融物を使用して所望のプレート/プロフィルの組合せを直接押し出すこと
により達成でき、それは、押し出しダイ内の異なるオリフィスを通って運ばれそ
して合着させられて、発泡した樹脂プロフィルと発泡しない樹脂プロフィルの両
者を有するプレート/プロフィル及び発泡体の組合せを形成する。他の方法は、
それが押し出しによりプレート又はプロフィルと接触するような条件下で発泡体
を押し出し、それにより所望の組合せを形成する方法である。発泡体の押し出し
断面では、発泡していない樹脂プレート又はプロフィルは、規則的又は不規則的
なパターンをとることができる。プレート又はプロフィルは、相互に交差するか
又は交差しない。発泡体内の発泡していないプロフィル又はプレートの可能な断
面のパターンは、ハチの巣状、円形、長方形又は対角の格子のパターンを含む。
図5は、発泡した部分51と発泡していない部分52とを有する長方形の格子の
パターンを有するプレート/プロフィルと発泡体との組合せを示す。発泡体を加
熱ワイヤにより切断しそして次にそれらがともに熱ウエルディングされるように
いくつかの発泡体の片を再結合又は合着させることにより発泡した部分と発泡し
ない部分とを有する押し出された構造体を製造することもできる。好ましくは、
熱ウエルディングは、発泡体が加熱ワイヤにより切断された直後に行う。発泡体
への熱の適用は、ワイヤに隣接する発泡体の気泡構造を壊し、そしていくつかの
発泡体の片が合着した後に、発泡体内に発泡していないプレート又はプロフィル
を生成する。The strength of the foam can be increased by incorporating a relatively thin, substantially non-foamed plate or profile into the foam portion of the headliner. this is,
It can be achieved by any suitable method, for example by extruding the desired plate / profile combination directly using an extrudate or plastic melt with or without foam, through different orifices in an extrusion die. Conveyed and coalesced to form a plate / profile and foam combination having both a foamed resin profile and a non-foamed resin profile. Another way is
This is a method of extruding the foam under conditions such that it comes into contact with the plate or profile by extrusion, thereby forming the desired combination. In the extruded cross section of the foam, the unfoamed resin plate or profile can take a regular or irregular pattern. The plates or profiles may or may not intersect each other. Possible cross-sectional patterns of unfoamed profiles or plates within the foam include honeycomb, circular, rectangular or diagonal grid patterns.
FIG. 5 shows a foam / plate combination with a plate / profile having a rectangular grid pattern with foamed portions 51 and non-foamed portions 52. The foam was cut by a heating wire and then extruded with foamed and non-foamed parts by recombining or coalescing several pieces of foam so that they were hot welded together Structures can also be manufactured. Preferably,
Hot welding is performed immediately after the foam is cut by the heating wire. Application of heat to the foam breaks the foam structure of the foam adjacent to the wire and, after several pieces of foam have coalesced, creates an unfoamed plate or profile within the foam.
【0033】 発泡したそして発泡していないプロフィル又は層を互いに代わる代わるラミネ
ートして一体の構造を形成することにより、発泡したそして発泡していない部分
を有する構造体を製造することも可能である。これらのプロフィル又は層は、熱
ウエルディング又は接着によりともにラミネートできた。It is also possible to produce structures having expanded and non-expanded parts by alternately laminating expanded and non-expanded profiles or layers to form a unitary structure. These profiles or layers could be laminated together by hot welding or bonding.
【0034】 さらに、核形成剤は、発泡体の気泡のサイズをコントロールするために、発泡
工程で添加できる。好ましい核形成剤は、無機物質、例えば炭酸カルシウム、タ
ルク、粘土、二酸化チタン、シリカ、硫酸バリウム、ステアリン酸カルシウム、
ステアリン酸バリウム、珪藻土、そしてクエン酸と重炭酸ナトリウムとの混合物
などを含む。使用される核形成剤の量は、ポリマー樹脂の100重量部当たり約
0.01−約5重量部に及ぶことができる。好ましい範囲は、0.1−約3重量
部である。 発泡体及び発泡工程で、顔料、抗酸化剤、酸スカベンジャー、紫外線吸収剤、
難燃剤、加工助剤、押し出し助剤などのような種々の添加物を添加することも可
能である。In addition, a nucleating agent can be added in the foaming step to control the size of the cells of the foam. Preferred nucleating agents are inorganic substances such as calcium carbonate, talc, clay, titanium dioxide, silica, barium sulfate, calcium stearate,
Includes barium stearate, diatomaceous earth, and mixtures of citric acid and sodium bicarbonate. The amount of nucleating agent used can range from about 0.01 to about 5 parts by weight per 100 parts by weight of the polymer resin. A preferred range is 0.1 to about 3 parts by weight. In the foam and foaming process, pigments, antioxidants, acid scavengers, UV absorbers,
Various additives such as flame retardants, processing aids, extrusion aids and the like can also be added.
【0035】 発泡体の物理的性質及び熱抵抗性は、充填剤の形の有機又は無機の物質の粒状
物又は繊維を添加することにより増加できる。これらの粒状物又は繊維は、製造
中発泡形成組成物に添加できる。有用な物質は、カーボンブラック粒状物、粘土
粒状物、カーボン又はグラファイトの繊維、ポリプロピレン繊維、ポリエステル
繊維、及びナイロン繊維、ガラス繊維、及びアクリロニトリル繊維を含む。発泡
体の物理的性質及び熱抵抗性は、また、これらの粒状物及び/又は繊維を含む発
泡していないフィルム/シートの層又はコーティングを発泡体にラミネートする
ことにより、増大できる。繊維は、短くても(フィブリル)長くても、任意の長
さのものでよい。それらは、布帛又はプレプレグの性質で、ランダムに分散され
るか又は織られるか、又は一緒に置かれる。The physical properties and thermal resistance of the foam can be increased by adding particulates or fibers of organic or inorganic substances in the form of a filler. These granules or fibers can be added to the foam-forming composition during manufacture. Useful materials include carbon black granules, clay granules, carbon or graphite fibers, polypropylene fibers, polyester fibers, and nylon fibers, glass fibers, and acrylonitrile fibers. The physical properties and thermal resistance of the foam can also be increased by laminating an unfoamed film / sheet layer or coating containing these granules and / or fibers to the foam. The fibers can be short (fibril) long or of any length. They are randomly dispersed or woven, or put together, in the nature of a fabric or prepreg.
【0036】 当業者に周知の接着剤は、ヘッドライナーの種々の層を互いに接着するか又は
自動車の屋根にヘッドライナーを接着するのに使用できる。有用な接着剤は、熱
硬化性接着剤、例えばポリウレタン樹脂及びエポキシ樹脂、並びに熱可塑性接着
剤、例えばポリエチレン、ポリプロピレン、エチレンコポリマー;プロピレンコ
ポリマーなどを含む。有用な接着剤は、米国特許第5460870及び5670
211号に教示されている。接着剤は、当業者に周知の任意の手段、例えば噴霧
、コーティング又はフィルムの形により適用できる。好ましい接着剤は、それら
の低コスト及びリサイクル可能性の理由で、熱可塑性樹脂である。接着剤の存在
は、本発明にとり必須ではない。[0036] Adhesives known to those skilled in the art can be used to adhere the various layers of the headliner to one another or to adhere the headliner to the roof of an automobile. Useful adhesives include thermosetting adhesives, such as polyurethane and epoxy resins, and thermoplastic adhesives, such as polyethylene, polypropylene, ethylene copolymers; propylene copolymers, and the like. Useful adhesives are disclosed in U.S. Patent Nos. 5,460,870 and 5,670.
No. 211 is taught. The adhesive can be applied by any means known to those skilled in the art, for example, in the form of a spray, coating or film. Preferred adhesives are thermoplastics because of their low cost and recyclability. The presence of the adhesive is not essential to the invention.
【0037】 装飾的な物質例えばフェルト又は布帛の一つ以上の層は、美観のために、客室
の内部又はインテリアキャビンに面するヘッドライナーの表面に適用できる。層
は、当業者に周知の任意のタイプのものである。工業的に最も典型的に使用され
るものは、フェルト又は織った繊維である。有用な布帛は、織ったポリエステル
、ナイロン及びポリプロピレン繊維のものを含む。好ましくは、フェルト又は布
帛の層は、発泡体と同じ又は類似のポリマー性物質からなる。フェルト又は布帛
の層は、当業者に周知の任意の手段、例えば熱ウエルディング、接着フィルム又
は接着液体又はコーティングにより発泡体に接着できる。好ましい装飾層は、接
着剤の助けによらず芯の層に熱ウエルディングされた熱可塑性繊維の織った布帛
である。熱ウエルディングは、繊維が粘着性になりそして接着剤の助けなしに芯
の層に接着できるような程度に布帛層を加熱することを意味する。布帛層は、ま
た、もし熱成形中に芯の層に適用されるか又は芯の層が高温にあるとき、芯の層
に熱ウエルディングできる。[0037] One or more layers of decorative material, such as felt or fabric, can be applied to the interior of the cabin or the surface of the headliner facing the interior cabin for aesthetics. The layers are of any type known to those skilled in the art. The most typically used in the industry are felts or woven fibers. Useful fabrics include those of woven polyester, nylon and polypropylene fibers. Preferably, the felt or fabric layer is composed of the same or similar polymeric material as the foam. The layer of felt or fabric can be adhered to the foam by any means known to those skilled in the art, such as hot welding, an adhesive film or an adhesive liquid or coating. A preferred decorative layer is a woven fabric of thermoplastic fibers that is hot welded to the core layer without the aid of an adhesive. Hot welding refers to heating the fabric layer to such an extent that the fibers become tacky and can adhere to the core layer without the aid of an adhesive. The fabric layer can also be heat welded to the core layer if it is applied to the core layer during thermoforming or the core layer is at an elevated temperature.
【0038】 好ましいヘッドライナーは、リサイクル可能な物質のみからなる。有用なリサ
イクル可能な物質は、プロピレンポリマー例えばポリプロピレン;高密度ポリエ
チレン;ポリエステル例えばポリエチレンテレフタレート;及びポリカーボネー
トを含む。最も好ましいヘッドライナーは、それらがともにリサイクル出来るよ
うに類似の組成のリサイクル可能な物質だけからなる。例えば、ヘッドライナー
は、以下のものの任意のものからなる。プロピレンポリマー発泡体と織ったポリ
プロピレン布帛層とのラミネート;ポリエチレンテレフタレート発泡体と織った
ポリエチレンテレフタレート布帛層とのラミネート;又はポリアミド(ナイロン
)発泡体とポリアミド布帛層。所望ならば、異なるリサイクル可能な物質は、以
下のようにともに使用できる。a)プロピレンポリマー発泡体とポリエステル又
はポリアミドの織った布帛層とのラミネート、及びb)ポリエステル発泡体とポ
リプロピレン又はポリアミドの織った布帛層とのラミネート。Preferred headliners consist solely of recyclable materials. Useful recyclable materials include propylene polymers such as polypropylene; high density polyethylene; polyesters such as polyethylene terephthalate; and polycarbonate. Most preferred headliners consist only of recyclable materials of similar composition so that they can be recycled together. For example, the headliner may be any of the following: A laminate of a propylene polymer foam and a woven polypropylene fabric layer; a laminate of a polyethylene terephthalate foam and a woven polyethylene terephthalate fabric layer; or a polyamide (nylon) foam and a polyamide fabric layer. If desired, different recyclable materials can be used together as follows. a) lamination of a propylene polymer foam with a woven fabric layer of polyester or polyamide, and b) lamination of a polyester foam with a woven fabric layer of polypropylene or polyamide.
【0039】 発泡体は、所望の形状、形態又は輪郭に容易に熱成形可能である。概して、発
泡体そしてヘッドライナーの残りのものは、ヘッドライナーが屋根の下方に位置
するために、乗り物の屋根と実質的に同じ形状、形態又は輪郭のものである。用
語「熱成形可能」は、発泡体が、異なる形状又は輪郭へ、当業者に周知の任意の
従来の手段により熱及び機械的な圧の下に熱成形されるか又はそれ以外に成形さ
れることを意味する。概して、発泡体は、実質的に平らなシート又は平板の形で
提供され、そして熱及び圧の下プレスされて、それがその下に位置する乗り物の
屋根と同様な形状及び輪郭のシートを形成する。所望ならば、修飾的な層例えば
織った熱可塑性繊維の布帛層は、熱成形工程中に発泡体に熱ウエルディングされ
る。The foam can be easily thermoformed into a desired shape, form or contour. In general, the foam and the rest of the headliner are of substantially the same shape, form or profile as the vehicle roof because the headliner is located below the roof. The term “thermoformable” means that the foam is thermoformed or otherwise shaped under different thermal or mechanical pressures by any conventional means well known to those skilled in the art. Means that. Generally, the foam is provided in the form of a substantially flat sheet or slab and is pressed under heat and pressure to form a sheet similar in shape and contour to the roof of the underlying vehicle. I do. If desired, a decorative layer, such as a fabric layer of woven thermoplastic fibers, is hot welded to the foam during the thermoforming process.
【0040】 発泡体の物理的な性質及び熱抵抗性は、例えば発泡体へプラスチックフィルム
又はシートをラミネート化することにより、プラスチック樹脂によりそれをコー
ティングすることにより、そのガラス転移温度又は融点より高く発泡体の一つ以
上の表面を加熱して表面で気泡構造をこわすことにより、又はこれらの任意のも
のの組合せにより、発泡体上の実質的に発泡していない表面を形成することを導
入することにより増加できる。フィルム、シート又はコーティングは、任意の周
知の熱可塑性樹脂又は熱硬化性樹脂からなる。有用な熱可塑性樹脂は、発泡体を
形成するものに関して上述されたものを含み、有用な熱硬化性樹脂は、ポリウレ
タン及びエポキシ樹脂を含む。The physical properties and thermal resistance of a foam can be measured by, for example, laminating a plastic film or sheet to the foam, coating it with a plastic resin, and expanding it above its glass transition temperature or melting point. By heating one or more surfaces of the body to break the cellular structure at the surface, or by combining any of these, to form a substantially non-foamed surface on the foam Can increase. The film, sheet or coating may be made of any known thermoplastic or thermosetting resin. Useful thermoplastics include those described above for forming the foam, and useful thermosets include polyurethane and epoxy resins.
【0041】 ヘッドライナーは、当業者に周知の任意の手段、例えば接着により又は機械的
な手段による付着により、乗り物の屋根の下面に適用できる。機械的な手段は、
クリップ、サイドモールディング、及び頭上(ドーム)ライトアセンブリを含む
。 用語「乗り物」は、当業者に周知のもの例えば自動車、トラック、リクリエー
ショナル・ビークル(RV)、スポーツ・ユーティリティ・ビークル、航空機、
トレーン及びボートを含む。The headliner can be applied to the underside of the vehicle roof by any means known to those skilled in the art, such as by gluing or by mechanical means. Mechanical means
Includes clips, side moldings, and overhead (dome) light assemblies. The term “vehicle” is well known to those skilled in the art, such as a car, truck, recreational vehicle (RV), sports utility vehicle, aircraft,
Includes trains and boats.
【0042】 図6−10は、いくつかの異なるヘッドライナーの形態の部分を示す。図6は
、垂直の配向を有する発泡体ストランドからなる2枚の発泡体シート66及び6
7、発泡体裏打ちファプリックシート63、及び接着フィルム64及び65の層
を示す。好ましい態様では、例えば乗客ドアに最も近いヘッドライナーの側面に
沿うような追加のエネルギー吸収能力が望ましいが、これらの他の場所ではヘッ
ドライナーの厚さを最小にするために単一の発泡体シートからなる場合、ヘッド
ライナーは、ヘッドライナーのある場所でのみ第二の発泡体シート67を含む。
接着フィルム層64及び65は、布帛と発泡体層66及び67とを接着しそして
ヘッドライナーの全体のかたさを増大させるために使用できる。所望ならば、フ
ィルム層は、省くことができ、そして布帛と発泡体とは、任意の他の好適な手段
、例えば発泡体の層をともに熱ウエルディングすることにより互いに接着させ、
そして液体布帛接着剤を使用してそれに隣接する発泡体層に接着させる。FIGS. 6-10 illustrate portions of several different headliner configurations. FIG. 6 shows two foam sheets 66 and 6 made of foam strands having a vertical orientation.
7, the foam-backed facsimile sheet 63 and the layers of adhesive films 64 and 65 are shown. In a preferred embodiment, additional energy absorption capacity is desirable, e.g., along the side of the headliner closest to the passenger door, but at these other locations a single foam sheet to minimize headliner thickness , The headliner includes the second foam sheet 67 only at the location of the headliner.
Adhesive film layers 64 and 65 can be used to adhere the fabric and foam layers 66 and 67 and increase the overall hardness of the headliner. If desired, the film layer can be omitted, and the fabric and foam are adhered to each other by any other suitable means, such as hot welding the layers of foam together,
A liquid fabric adhesive is then used to adhere to the adjacent foam layer.
【0043】 図7−9は、発泡体の二つの層がヘッドライナー内で配向されているいくらか
のやり方を示す。これらの形態における頂部の発泡体の層71、81及び91は
、ストランド発泡体からなり、それはストランドが乗り物の屋根に関して垂直に
なるように位置し、そのため最大のエネルギー吸収が達成される。底部の発泡体
の層は、屋根に垂直なストランドを有するストランド発泡体層72、非ストラン
ド発泡体82、及び乗り物92の屋根に関してストランドが垂直になるように位
置するストランド発泡体として示される。これらの態様では、発泡体の層は、好
適な手段、例えば接着剤、接着フィルムを使用することにより、又はそれらをと
もに熱ウエルディングすることにより、互いに接着できる。FIGS. 7-9 show some ways in which the two layers of foam are oriented in the headliner. The top foam layers 71, 81 and 91 in these configurations consist of strand foam, which is positioned so that the strands are perpendicular to the vehicle roof, so that maximum energy absorption is achieved. The bottom foam layer is shown as a strand foam layer 72 having strands perpendicular to the roof, a non-strand foam 82, and a strand foam with the strands positioned perpendicular to the vehicle 92 roof. In these embodiments, the foam layers can be adhered to each other by any suitable means, such as by using an adhesive, an adhesive film, or by hot welding them together.
【0044】 図10は、薄い部分及び熱い部分を有する望ましい形状に切断又は成形されて
いるストランド発泡体の単一の片としてヘッドライナー発泡体の部分を示し、厚
い部分は、乗客のサイドドアに最も近いヘッドライナーの側面に沿って位置する
。図11は、ストランド発泡体96、97及び98の三つの層を有するヘッドラ
イナーの部分を示し、第三の層は、特別なエネルギー吸収能力をもたらす。FIG. 10 shows the portion of the headliner foam as a single piece of strand foam that has been cut or formed into a desired shape having a thin portion and a hot portion, with the thick portion being attached to the passenger side door. Located along the side of the nearest headliner. FIG. 11 shows a portion of a headliner having three layers of strand foams 96, 97 and 98, with the third layer providing extra energy absorption capability.
【0045】[0045]
乗り物への設置に適したヘッドライナーを形成するように熱成形できそして構
築できた発泡体は、以下の実施例で製造された。 実施例 1 押し出されたポリプロピレン発泡体を製造した。 発泡体を製造する装置は、一連の押し出し機、ミキサー、クーラー及び環状の
押し出しダイからなった。ポリマーは、粒状の形で押し出し機に供給され、それ
は添加物と混合されてポリマー溶融物を形成した。ポリマー溶融物は、ミキサー
に運ばれ、発泡剤は加圧下そのなかに配合されて発泡可能なゲルを形成した。発
泡可能なゲルはダイに運ばれ、それは、マンドレルの回りの環状のオリフィスの
外に膨脹されて管状の発泡体シート製品を形成した。管状のシートは、次に裂け
されて平らなシートを形成した。 プロピレンポリマー樹脂は、98/2ポリプロピレン(ホモポリマー)樹脂(
Montell HMS樹脂PF−814)であった。発泡剤は、8pphのイ
ソブタン(ポリマー重量に基づいて100部当たりの部)であった。使用した添
加物は、0.2pphのタルク(核形成剤)、0.1pphのIrganox
1010(抗酸化剤)、及び0.1pphのUltranox 626(抗酸化
剤)であった。 発泡体は、5ミリメートル(mm)の厚さ、及び1600mmの幅、1.6%
の連続気泡含量、1立方フィート当たり2.7ポンドの密度(pcf)(1立方
メートル当たり43.2キログラム(kgm))、及び1.7mmの平均気泡サ
イズを有した。発泡体は、5.3の発泡可能指数値(米国特許第5527573
号により記述)を有した。発泡体は、比較的剛く、それ自身の重量を支持すると
きたわむことなく、そして熱成形可能であった。発泡体は、乗り物のヘッドライ
ナーの望ましいプロフィルに切断且つ成形され、そして修飾布帛の層がそれに接
着された。ヘッドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され
、そして好適な接着剤によりそれに付着された。Foams that could be thermoformed and built to form a headliner suitable for vehicle installation were made in the following examples. Example 1 An extruded polypropylene foam was produced. The apparatus for producing the foam consisted of a series of extruders, mixers, coolers and annular extrusion dies. The polymer was fed to the extruder in granular form, which was mixed with the additives to form a polymer melt. The polymer melt was conveyed to a mixer and the blowing agent was compounded therein under pressure to form a foamable gel. The foamable gel was conveyed to a die, which was expanded out of an annular orifice around the mandrel to form a tubular foam sheet product. The tubular sheet was then split to form a flat sheet. Propylene polymer resin is a 98/2 polypropylene (homopolymer) resin (
Montell HMS resin PF-814). The blowing agent was 8 pph isobutane (parts per hundred based on polymer weight). The additives used were 0.2 pph talc (nucleating agent), 0.1 pph Irganox.
1010 (antioxidant) and 0.1 pph of Ultranox 626 (antioxidant). The foam has a thickness of 5 millimeters (mm) and a width of 1600 mm, 1.6%
Has an open cell content of 2.7 pounds per cubic foot (pcf) (43.2 kilograms per cubic meter (kgm)) and an average cell size of 1.7 mm. The foam has a foamable index value of 5.3 (US Pat. No. 5,527,573).
No.). The foam was relatively stiff, without flexing to support its own weight, and was thermoformable. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0046】 実施例 2 他の押し出されたポリプロピレン発泡体シートは、実施例1に開示された装置
を用い、そして実施例1と実質的に同じ処理条件及び同じ発泡剤の含量及び装入
物で製造されたが、より大きなダイのギャップ及びより遅い取り出し延伸速度で
製造された。 発泡体は、9mmの厚さ及び1600mmの幅、2%より小さい連続気泡含量
、2.41pcf(38kgm)の密度、及び1.7mmの平均気泡サイズを有
した。発泡体は、4.7の発泡可能指数値(米国特許第5527573号により
記述)を有した。発泡体は、比較的剛く、それ自身の重量を支持するときたわむ
ことがなかった。発泡体は、乗り物のヘッドライナーの望ましいプロフィルに切
断且つ成形され、そして修飾布帛の層がそれに接着された。ヘッドライナーを、
乗り物の屋根の下面に隣接して乗り物に設置され、そして好適な接着剤によりそ
れに付着された。Example 2 Another extruded polypropylene foam sheet was prepared using the equipment disclosed in Example 1 and with substantially the same processing conditions and the same blowing agent content and charge as Example 1. Manufactured, but with larger die gap and slower take-out draw rates. The foam had a thickness of 9 mm and a width of 1600 mm, an open cell content of less than 2%, a density of 2.41 pcf (38 kgm), and an average cell size of 1.7 mm. The foam had a foamable index value of 4.7 (described by US Pat. No. 5,527,573). The foam was relatively stiff and did not flex to support its own weight. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. Headliner,
Mounted on the vehicle adjacent the underside of the vehicle roof and attached to it with a suitable adhesive.
【0047】 実施例 3 他の押し出されたプロピレンコポリマー発泡体シートは、実施例1に開示され
た装置を用い、そして実施例1と実質的に同じ処理条件及び同じ発泡剤の含量及
び装入物で製造された。 発泡体は、7mmの厚さ及び1600mmの幅、19%の連続気泡含量、2.
9pcf(46.1kgm)の密度、及び1.75mmの平均気泡サイズを有し
た。発泡体は、5.8の発泡可能指数値(米国特許第5527573号により記
述)を有した。発泡体は、比較的剛く、それ自身の重量を支持するときたわむこ
とがなく、熱成形可能であった。発泡体は、乗り物のヘッドライナーの望ましい
プロフィルに切断且つ成形され、そして修飾布帛の層がそれに接着された。ヘッ
ドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され、そして好適な
接着剤によりそれに付着された。Example 3 Another extruded propylene copolymer foam sheet uses the equipment disclosed in Example 1 and has substantially the same processing conditions and the same blowing agent content and charge as Example 1. Manufactured in. The foam has a thickness of 7 mm and a width of 1600 mm, an open cell content of 19%, 2.
It had a density of 9 pcf (46.1 kgm) and an average cell size of 1.75 mm. The foam had a foamable index value of 5.8 (described by US Pat. No. 5,527,573). The foam was relatively stiff, did not flex to support its own weight, and was thermoformable. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0048】 実施例 4 押し出されたプロピレンコポリマー発泡体シートは、実施例1に開示された装
置を用い、そして同じ発泡剤及び添加物プラス追加の核形成化のためのステアリ
ン酸カルシウム粉末の添加で製造された。ポリプロピレンポリマーは、0.42
pphのタルク、0.3pphのUltranox(商標)815P安定剤(G
E Specialty Chemicals)、0.3pphのステアリン酸
カルシウムとともに、990Lb/時(449kg/時)で押し出し機に供給さ
れた。可塑化されたゲル混合物は、次に加圧下3.9pphのイソブタンと混合
され、161℃に冷却され、そして環状ダイに運ばれ、そこでそれを圧力の低い
領域中に膨脹させ、直径16インチの冷却マンドレル上で延伸して管状の発泡体
シート製品を形成した。管状のシートを次に裂いて平らなシートを形成した。 発泡体は、7mmの厚さ及び1290mmの幅、20.4%の連続気泡含量、
3.3pcf(52.9kgm)の密度、及び3.6mmの平均気泡サイズを有
した。発泡体は、比較的剛く、それ自身の重量を支持するときたわむことがなく
、熱成形可能であった。発泡体は、SAE J949に記載された方法によりテ
ストされると175psi(1.21Mpa)の破壊値での曲げ強さ、そして1
3.6の発泡可能ファクターを有した。発泡体は、乗り物のヘッドライナーの望
ましいプロフィルに切断且つ成形され、そして修飾布帛の層がそれに接着された
。ヘッドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され、そして
好適な接着剤によりそれに付着された。Example 4 Extruded propylene copolymer foam sheets were made using the equipment disclosed in Example 1 and with the same blowing agents and additives plus the addition of calcium stearate powder for additional nucleation. Was done. 0.42 polypropylene polymer
pph talc, 0.3 pph Ultranox ™ 815P stabilizer (G
E Specialty Chemicals, with 0.3 pph calcium stearate, was fed to the extruder at 990 Lb / hr (449 kg / hr). The plasticized gel mixture is then mixed under pressure with 3.9 pph of isobutane, cooled to 161 ° C., and conveyed to an annular die where it is expanded into a low pressure zone, where it has a diameter of 16 inches. Stretched on a cooling mandrel to form a tubular foam sheet product. The tubular sheet was then split to form a flat sheet. The foam has a thickness of 7 mm and a width of 1290 mm, an open cell content of 20.4%,
It had a density of 3.3 pcf (52.9 kgm) and an average cell size of 3.6 mm. The foam was relatively stiff, did not flex to support its own weight, and was thermoformable. The foam has a flexural strength at a breaking value of 175 psi (1.21 Mpa) when tested according to the method described in SAE J949, and a 1
It had a foamable factor of 3.6. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0049】 実施例 5 押し出されたプロピレンコポリマー発泡体シートは、実施例1に開示された装
置を用い、そして同じ発泡剤及び添加物プラス追加の核形成化のためのステアリ
ン酸カルシウム粉末の添加で製造された。ポリプロピレンポリマーを、0.30
pphのタルク、0.21pphのUltranox(商標)815P安定剤(
GE Specialty Chemicalsから)、0.3pphのステア
リン酸カルシウムとともに、1380Lb/時(626kg/時)で押し出し機
に供給された。可塑化されたゲル混合物を次に加圧下3.9pphのイソブタン
と混合し、161.5℃に冷却し、そして環状のダイに運び、そこでそれを圧力
の低い領域中に膨脹させ、直径20インチの冷却マンドレル上で延伸して管状の
発泡体シート製品を形成した。管状のシートを次に裂いて平らなシートを形成し
た。 発泡体は、10.9mmの厚さ及び1600mmの幅、2.2%の連続気泡含
量、3.4pcf(54.5kgm)の密度、及び5.2mmの平均気泡サイズ
を有した。発泡体は、比較的剛く、それ自身の重量を支持するときたわむことが
なく、熱成形可能であった。発泡体は、SAE J949に記載された方法によ
りテストされると141psi(1Mpa)の破壊値での曲げ強さ、そして20
.3の発泡可能ファクターを有した。発泡体は、乗り物のヘッドライナーの望ま
しいプロフィルに切断且つ成形され、そして修飾布帛の層がそれに接着された。
ヘッドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され、そして好
適な接着剤によりそれに付着された。Example 5 Extruded propylene copolymer foam sheets were prepared using the equipment disclosed in Example 1 and with the same blowing agents and additives plus the addition of calcium stearate powder for additional nucleation. Was done. 0.30 polypropylene polymer
pph talc, 0.21 pph Ultranox® 815P stabilizer (
GE Specialty Chemicals), and 0.3 pph of calcium stearate, were fed to the extruder at 1380 Lb / hr (626 kg / hr). The plasticized gel mixture is then mixed under pressure with 3.9 pph of isobutane, cooled to 161.5 ° C., and conveyed to an annular die where it is expanded into a low pressure zone where it has a diameter of 20 inches. And stretched on a cooling mandrel to form a tubular foam sheet product. The tubular sheet was then split to form a flat sheet. The foam had a thickness of 10.9 mm and a width of 1600 mm, an open cell content of 2.2%, a density of 3.4 pcf (54.5 kgm), and an average cell size of 5.2 mm. The foam was relatively stiff, did not flex to support its own weight, and was thermoformable. The foam has a flexural strength at a breaking value of 141 psi (1 Mpa) when tested by the method described in SAE J949, and 20
. It had a foamable factor of 3. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it.
A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0050】 実施例 6 押し出された発泡体シートを、75%のMontellからのポリプロピレン
PF−814と25%のThe Dow Chemical Companyか
らのAFFINITY(商標)PL−1880ポリエチレンとのブレンドから製
造し、1.0dg/分の溶融指数、0.9020g/ccの密度及び9.0の|
10/|2を有した。発泡体シートを実施例1に記述した装置で製造した。ポリ
マーブレンドを、0.4pphのタルク及び0.3pphのUltranox(
商標)815P安定剤(GE Specialty Chemicalsから)
とともに1000Lb/時(454kg/時)で押し出し機に供給した。可塑化
したゲル混合物を次に加圧下6.0pphのイソブタンと混合し、157℃に冷
却し、環状のダイに運び、そこでそれを圧力の低い領域中に膨脹させ、直径20
インチの冷却マンドレル上で延伸して管状の発泡体シート製品を形成した。管状
のシートを次に裂いて平らなシートを形成した。 発泡体は、7mmの厚さ及び1600mmの幅、14.4%の連続気泡含量、
3.6pcf(57.7kgm)の密度、及び3.4mmの平均気泡サイズを有
した。発泡体は、比較的剛く、それ自身の重量を支持するときたわむことがなく
、熱成形可能であった。発泡体は、SAE J949に記載された方法によりテ
ストされると72psi(0.5Mpa)の破壊値での曲げ強さ、そして14.
0の発泡可能ファクターを有した。発泡体は、乗り物のヘッドライナーの望まし
いプロフィルに切断且つ成形され、そして修飾布帛の層がそれに接着された。ヘ
ッドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され、そして好適
な接着剤によりそれに付着された。Example 6 Extruded foam sheets were prepared from a blend of 75% polypropylene PF-814 from Montell and 25% AFFINITY ™ PL-1880 polyethylene from The Dow Chemical Company. A melting index of 0.0 dg / min, a density of 0.9020 g / cc and a | of 9.0
10 / | 2. A foam sheet was produced with the equipment described in Example 1. The polymer blend was combined with 0.4 pph of talc and 0.3 pph of Ultranox (
Trademark) 815P stabilizer (from GE Specialty Chemicals)
Together with the extruder at 1000 Lb / hr (454 kg / hr). The plasticized gel mixture is then mixed with 6.0 pph isobutane under pressure, cooled to 157 ° C., and conveyed to an annular die where it is expanded into a low pressure zone where it has a diameter of 20 μm.
Stretched on an inch cooling mandrel to form a tubular foam sheet product. The tubular sheet was then split to form a flat sheet. The foam has a thickness of 7 mm and a width of 1600 mm, an open cell content of 14.4%,
It had a density of 3.6 pcf (57.7 kgm) and an average cell size of 3.4 mm. The foam was relatively stiff, did not flex to support its own weight, and was thermoformable. 13. The foam has a flexural strength at a breaking value of 72 psi (0.5 Mpa) when tested according to the method described in SAE J949.
It had a foamable factor of 0. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0051】 実施例 7 押し出された発泡体シートを、75%のMontellからのポリプロピレン
PF−814と25%のThe Dow Chemical Companyか
らのAFFINITY(商標)PL−1880ポリエチレン(1.0dg/分の
溶融指数、0.9020g/ccの密度及び9.0の|10/|2を有する)と
のブレンドから製造した。発泡体シートを実施例1に記述した装置で製造した。
ポリマーブレンドを、0.4pphのタルク及び0.3pphのUltrano
x(商標)815P安定剤(GE Specialty Chemicalsか
ら)とともに1000Lb/時(454kg/時)で押し出し機に供給した。可
塑化したゲル混合物を次に加圧下6.0pphのイソブタンと混合し、157℃
に冷却し、環状のダイに運び、そこでそれを圧力の低い領域中に膨脹させ、直径
20インチの冷却マンドレル上で延伸して管状の発泡体シート製品を形成した。
管状のシートを次に裂いて平らなシートを形成した。 発泡体は、9.8mmの厚さ及び1600mmの幅、5.8%の連続気泡含量
、2.7pcf(43.3kgm)の密度、及び4.5mmの平均気泡サイズを
有した。発泡体は、比較的剛く、それ自身の重量を支持するときたわむことがな
く、熱成形可能であった。発泡体は、SAE J949に記載された方法により
テストされると70psi(0.5Mpa)の破壊値での曲げ強さ、そして13
.0の発泡可能ファクターを有した。発泡体は、乗り物のヘッドライナーの望ま
しいプロフィルに切断且つ成形され、そして修飾布帛の層がそれに接着された。
ヘッドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され、そして好
適な接着剤によりそれに付着された。Example 7 Extruded foam sheets were cured with 75% polypropylene PF-814 from Montell and 25% AFFINITY ™ PL-1880 polyethylene from The Dow Chemical Company (1.0 dg / min melt). Index, a density of 0.9020 g / cc and a | 10 / | 2 of 9.0). A foam sheet was produced with the equipment described in Example 1.
The polymer blend was mixed with 0.4 pph of talc and 0.3 pph of Ultrano
x (R) 815P stabilizer (from GE Specialty Chemicals) was fed to the extruder at 1000 Lb / hr (454 kg / hr). The plasticized gel mixture is then mixed with 6.0 pph isobutane under pressure and
And transferred to an annular die where it was expanded into a low pressure area and stretched over a 20 inch diameter cooling mandrel to form a tubular foam sheet product.
The tubular sheet was then split to form a flat sheet. The foam had a thickness of 9.8 mm and a width of 1600 mm, an open cell content of 5.8%, a density of 2.7 pcf (43.3 kgm), and an average cell size of 4.5 mm. The foam was relatively stiff, did not flex to support its own weight, and was thermoformable. The foam has a flexural strength at a breaking value of 70 psi (0.5 Mpa) when tested by the method described in SAE J949, and 13
. It had a foamable factor of 0. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it.
A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0052】 実施例 8 押し出された発泡体シートを、75%のMontellからのポリプロピレン
PF−814と25%のThe Dow Chemical Companyか
らのAFFINITY(商標)PL−1880ポリエチレン(1.0dg/分の
溶融指数、0.9020g/ccの密度及び9.0の|10/|2を有する)と
のブレンドから製造した。発泡体シートを実施例1に記述した装置で製造した。
ポリマーブレンドを、0.4pphのタルク及び0.3pphのUltrano
x(商標)815P安定剤(GE Specialty Chemicalsか
ら)とともに1200Lb/時(545kg/時)で押し出し機に供給した。可
塑化したゲル混合物を次に加圧下6.0pphのイソブタンと混合し、156℃
に冷却し、環状のダイに運び、そこでそれを圧力の低い領域中に膨脹させ、直径
20インチの冷却マンドレル上で延伸して管状の発泡体シート製品を形成した。
管状のシートを次に裂いて平らなシートを形成した。 発泡体は、14.6mmの厚さ及び1600mmの幅、3.3%の連続気泡含
量、2.6pcf(41.7kgm)の密度、及び3.2mmの平均気泡サイズ
を有した。発泡体は、比較的剛く、それ自身の重量を支持するときたわむことが
なく、熱成形可能であった。発泡体は、SAE J949に記載された方法によ
りテストされると58psi(0.4Mpa)の破壊値での曲げ強さ、そして9
.5の発泡可能ファクターを有した。発泡体は、乗り物のヘッドライナーの望ま
しいプロフィルに切断且つ成形され、そして修飾布帛の層がそれに接着された。
ヘッドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され、そして好
適な接着剤によりそれに付着された。Example 8 Extruded foam sheets were melted with 75% polypropylene PF-814 from Montell and 25% AFFINITY ™ PL-1880 polyethylene from The Dow Chemical Company (1.0 dg / min melt). Index, a density of 0.9020 g / cc and a | 10 / | 2 of 9.0). A foam sheet was produced with the equipment described in Example 1.
The polymer blend was mixed with 0.4 pph of talc and 0.3 pph of Ultrano
Feeded to the extruder at 1200 Lb / hr (545 kg / hr) with x ™ 815P stabilizer (from GE Specialty Chemicals). The plasticized gel mixture was then mixed under pressure with 6.0 pph of isobutane,
And transferred to an annular die where it was expanded into a low pressure area and stretched over a 20 inch diameter cooling mandrel to form a tubular foam sheet product.
The tubular sheet was then split to form a flat sheet. The foam had a thickness of 14.6 mm and a width of 1600 mm, an open cell content of 3.3%, a density of 2.6 pcf (41.7 kgm), and an average cell size of 3.2 mm. The foam was relatively stiff, did not flex to support its own weight, and was thermoformable. The foam has a flexural strength at a failure value of 58 psi (0.4 Mpa) when tested by the method described in SAE J949, and a 9
. It had a foamable factor of 5. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it.
A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0053】 実施例 9 実施例8の発泡体シートを、厚さ1.6ミル(0.04mm)の多層フィルム
とラミネートした。フィルムは2層からなり、a)はエチレンアクリル酸コポリ
マー/線状低密度ポリエチレンブレンド(60/40);b)はホモポリマーポ
リプロピレンであった。接着層a)は、フィルムの厚さのXX%からなった。フ
ィルムを発泡体の1面にラミネートした。ラミネーション後、フィルム/発泡体
構造物を、3インチ×12インチの部分に切断し、SAEテストJ949におけ
るように、曲げ強さについてテストした。得られた構造物は、1インチ(25.
4mm)曲げるのに25ニュートンより大きいニュートンを要した。発泡体は、
9.5の発泡可能ファクターを有する。発泡体は、乗り物のヘッドライナーの望
ましいプロフィルに切断且つ成形され、そして修飾布帛の層がそれに接着された
。ヘッドライナーを、乗り物の屋根の下面に隣接して乗り物に設置され、そして
好適な接着剤によりそれに付着された。Example 9 The foam sheet of Example 8 was laminated to a 1.6 mil (0.04 mm) thick multilayer film. The film consisted of two layers, a) an ethylene acrylic acid copolymer / linear low density polyethylene blend (60/40); b) a homopolymer polypropylene. The adhesive layer a) consisted of XX% of the thickness of the film. The film was laminated to one side of the foam. After lamination, the film / foam structure was cut into 3 inch x 12 inch sections and tested for flexural strength as in SAE test J949. The resulting structure is 1 inch (25.
4 mm) It took more than 25 Newtons to bend. The foam is
It has a foamable factor of 9.5. The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0054】 実施例 10 実施例5の発泡体シートを、実施例9に記載したように厚さ1.6ミル(0.
04mm)の多層フィルムとラミネートした。フィルムを発泡体の1面にラミネ
ートした。ラミネーション後、フィルム/発泡体構造体を3インチ×12インチ
の部分に切断しそしてSAEテストJ949におけるように曲げ強さについてテ
ストした。発泡体は20.3の発泡可能ファクターを有する。得られる構造体は
、1インチ(2.54mm)曲げるのに45ニュートンより大きいニュートンを
要した。実施例5の発泡体は、1インチ(2.54mm)曲げるのに20ニュー
トンを要した。発泡体は、乗り物のヘッドライナーの望ましいプロフィルに切断
且つ成形され、そして修飾布帛の層がそれに接着された。ヘッドライナーを、乗
り物の屋根の下面に隣接して乗り物に設置され、そして好適な接着剤によりそれ
に付着された。Example 10 The foam sheet of Example 5 was prepared as described in Example 9 with a thickness of 1.6 mils (0.
04 mm). The film was laminated to one side of the foam. After lamination, the film / foam structure was cut into 3 inch × 12 inch sections and tested for flexural strength as in SAE test J949. The foam has a foamable factor of 20.3. The resulting structure required more than 45 Newtons to bend one inch (2.54 mm). The foam of Example 5 required 20 Newtons to bend one inch (2.54 mm). The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【0055】 実施例 11 実施例7の発泡体シートを、実施例9に記載したように厚さ1.6ミル(0.
04mm)の多層フィルムとラミネートした。フィルムを発泡体の1面にラミネ
ートした。ラミネーション後、フィルム/発泡体構造体を3インチ×12インチ
の部分に切断しそしてSAEテストJ949におけるように曲げ強さについてテ
ストした。発泡体は13.0の発泡可能ファクターを有する。得られる構造体は
、1インチ(2.54mm)曲げるのに14ニュートンより大きいニュートンを
要した。発泡体は、乗り物のヘッドライナーの望ましいプロフィルに切断且つ成
形され、そして修飾布帛の層がそれに接着された。ヘッドライナーを、乗り物の
屋根の下面に隣接して乗り物に設置され、そして好適な接着剤によりそれに付着
された。Example 11 The foam sheet of Example 7 was prepared as described in Example 9 to a thickness of 1.6 mils (0.
04 mm). The film was laminated to one side of the foam. After lamination, the film / foam structure was cut into 3 inch × 12 inch sections and tested for flexural strength as in SAE test J949. The foam has a foamable factor of 13.0. The resulting structure required more than 14 Newtons to bend one inch (2.54 mm). The foam was cut and molded into the desired profile of the vehicle headliner and a layer of the modified fabric was adhered to it. A headliner was placed on the vehicle adjacent to the underside of the vehicle roof and attached to it with a suitable adhesive.
【図1】 ヘッドライナーを有する乗り物の部分的な断面を有する断片的な透視図である
。FIG. 1 is a fragmentary perspective view with a partial cross section of a vehicle having a headliner.
【図2】 乗り物の屋根及びヘッドライナーが示される図1の表面切断部分の側面図であ
る。FIG. 2 is a side view of the surface cutaway portion of FIG. 1 showing the vehicle roof and headliner.
【図3】 ヘッドライナーが表面を切断して示されるヘッドライナーを有する乗り物の屋
根の断片的な透視図である。FIG. 3 is a fragmentary perspective view of a vehicle roof having a headliner with the headliner shown cut through the surface.
【図4】 ヘッドライナーが表面を切断して示されるヘッドライナーを有する乗り物の屋
根の断片的な透視図である。FIG. 4 is a fragmentary perspective view of a vehicle roof having a headliner with the headliner shown cut away.
【図5】 発泡された部分及び発泡されていない部分を有するヘッドライナーの部分を示
す。FIG. 5 shows a portion of a headliner having a foamed portion and a non-foamed portion.
【図6】 ヘッドライナーアセンブリの部分のいくらかの構成を示す。FIG. 6 illustrates some configurations of parts of a headliner assembly.
【図7】 ヘッドライナーアセンブリの部分のいくらかの構成を示す。FIG. 7 illustrates some configurations of parts of a headliner assembly.
【図8】 ヘッドライナーアセンブリの部分のいくらかの構成を示す。FIG. 8 illustrates some configurations of parts of a headliner assembly.
【図9】 ヘッドライナーアセンブリの部分のいくらかの構成を示す。FIG. 9 illustrates some configurations of portions of a headliner assembly.
【図10】 ヘッドライナーアセンブリの部分のいくらかの構成を示す。FIG. 10 illustrates some configurations of portions of a headliner assembly.
【図11】 ヘッドライナーアセンブリの部分のいくらかの構成を示す。FIG. 11 illustrates some configurations of parts of a headliner assembly.
10 乗り物 12 屋根 14 客室 16 ヘッドライナー 20 熱可塑性発泡体層 22 接着層 24 布帛層 30 ヘッドライナー 32 屋根 34 熱可塑性発泡体 36 布帛層 40 ヘッドライナー 42 屋根 44 熱可塑性発泡体 46 布帛層 51 発泡した部分 52 発泡していない部分 63 布帛層 64 接着フィルム 65 接着フィルム 66 発泡体層 67 発泡体層 71 ストランド発泡体層 72 ストランド発泡体層 81 ストランド発泡体層 82 非ストランド発泡体 91 ストランド発泡体層 92 屋根 96 ストランド発泡体層 97 ストランド発泡体層 98 ストランド発泡体層 DESCRIPTION OF SYMBOLS 10 Vehicle 12 Roof 14 Guest room 16 Headliner 20 Thermoplastic foam layer 22 Adhesive layer 24 Fabric layer 30 Headliner 32 Roof 34 Thermoplastic foam 36 Fabric layer 40 Headliner 42 Roof 44 Thermoplastic foam 46 Fabric layer 51 Foamed Part 52 Non-foamed part 63 Fabric layer 64 Adhesive film 65 Adhesive film 66 Foam layer 67 Foam layer 71 Strand foam layer 72 Strand foam layer 81 Strand foam layer 82 Non-strand foam 91 Strand foam layer 92 Roof 96 Strand foam layer 97 Strand foam layer 98 Strand foam layer
───────────────────────────────────────────────────── フロントページの続き (81)指定国 EP(AT,BE,CH,CY, DE,DK,ES,FI,FR,GB,GR,IE,I T,LU,MC,NL,PT,SE),OA(BF,BJ ,CF,CG,CI,CM,GA,GN,GW,ML, MR,NE,SN,TD,TG),AP(GH,GM,K E,LS,MW,SD,SL,SZ,UG,ZW),E A(AM,AZ,BY,KG,KZ,MD,RU,TJ ,TM),AE,AL,AM,AT,AU,AZ,BA ,BB,BG,BR,BY,CA,CH,CN,CU, CZ,DE,DK,EE,ES,FI,GB,GE,G H,GM,HR,HU,ID,IL,IN,IS,JP ,KE,KG,KP,KR,KZ,LC,LK,LR, LS,LT,LU,LV,MD,MG,MK,MN,M W,MX,NO,NZ,PL,PT,RO,RU,SD ,SE,SG,SI,SK,SL,TJ,TM,TR, TT,UA,UG,US,UZ,VN,YU,ZA,Z W (72)発明者 ロレンゾ,ルイス アメリカ合衆国ミシガン州 48640−2568 ミドランド ランブル レーン 1908 (72)発明者 クリステンソン,クリストファー ピー アメリカ合衆国ミシガン州 48612 ビー バートン サウス ハンター ロード 5255 (72)発明者 シャファー,ウイリアム ジェイ アメリカ合衆国ミシガン州 48609−9547 サジナウ ショート ロード 1860 (72)発明者 スー,キュング ダブリュー アメリカ合衆国ミシガン州 48640 ミド ランド エバグリーン コート 6204 (72)発明者 ガンジー,ガジャナン ブイ アメリカ合衆国ミシガン州 48083 トロ イ ラウンドツリー ドライブ 2764 (72)発明者 マッギー,ロバート エル アメリカ合衆国ミシガン州 48642 ミド ランド メリー ジェーン ドライブ 3606 (72)発明者 パーク,チュン ピー ドイツ国 ディ−76532 バーデン−バー デン シュルストラッセ 10エイ Fターム(参考) 3D023 BA01 BB03 BC01 BD01 BE04 BE06 BE31 ──────────────────────────────────────────────────続 き Continuation of front page (81) Designated country EP (AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE ), OA (BF, BJ, CF, CG, CI, CM, GA, GN, GW, ML, MR, NE, SN, TD, TG), AP (GH, GM, KE, LS, MW, SD, SL, SZ, UG, ZW), EA (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), AE, AL, AM, AT, AU, AZ, BA, BB, BG, BR , BY, CA, CH, CN, CU, CZ, DE, DK, EE, ES, FI, GB, GE, GH, GM, HR, HU, ID, IL, IN, IS, JP , KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MD, MG, MK, MN, MW, MX, NO, NZ, PL, PT, RO, RU, SD, SE, SG, SI, SK, SL, TJ, TM, TR, TT, UA, UG, US, UZ, VN, YU, ZA, ZW (72) Inventor Lorenzo, Lewis Michigan 48640-2568 Midland Rumble Lane 1908 (72) Inventor Christenson, Christopherpie 48612 Bee Barton South Hunter Road, Michigan, USA 5255 (72) Inventor Shafar, William Jay, Michigan, USA 48609-9547 Saginaw Short Road 1860 (72) Inventor, Sue, Kung W, Michigan 48640 Midland Evergreen Court 6204 (72) Inventor Gee, Gajanan Buoy 48083 Troy Roundtree Drive, Michigan, United States of America 48083 Troy Roundtree Drive 2764 (72) Inventor McGee, Robert El. 48642 Midland, Maryland, United States of America 48642 Midland Mary Jane Drive 3606 (72) Inventor Park, Chumpie, Germany -76532 Baden-Bar Den-sur-Strasse 10A F-term (reference) 3D023 BA01 BB03 BC01 BD01 BE04 BE06 BE31
Claims (32)
に隣接して位置するヘッドライナーを有する乗り物であって、ヘッドライナーは
、熱成形された芯の層をもち、芯の層は、押し出された熱可塑性発泡体及び所望
により実質的に発泡していない熱可塑性樹脂の一つ以上の隣接した層からなり、
熱硬化性物質を実質的に含まず、さらに実質的にたるみに抵抗性であり且つ実質
的にその形を維持することができる乗り物。1. A vehicle having a cabin and a roof positioned over the head of the cabin and further having a headliner positioned adjacent a lower surface of the roof, the headliner having a thermoformed core layer. The core layer comprises one or more adjacent layers of extruded thermoplastic foam and optionally substantially unfoamed thermoplastic;
A vehicle that is substantially free of thermosetting materials, is substantially resistant to sag, and is capable of substantially maintaining its shape.
る請求項1の乗り物。2. The vehicle of claim 1 wherein the core layer has a decorative layer laminated to one of its major surfaces.
求項2の乗り物。3. The vehicle of claim 2, wherein the decorative layer is selected from the group consisting of a felt layer and a fabric layer.
質的に含まない請求項1の乗り物。4. The vehicle of claim 1 wherein the core layer is substantially free of a mat of fibers of a thermoset or thermoplastic material.
ヘッドライナーが、芯の層の主な表面にラミネートされた装飾層をさらに有する
請求項1の乗り物。5. The core layer consists essentially of extruded thermoplastic foam,
The vehicle of claim 1 wherein the headliner further comprises a decorative layer laminated to a major surface of the core layer.
いない熱可塑性樹脂の1以上の層から本質的になる請求項1の乗り物。6. The vehicle of claim 1, wherein the core layer consists essentially of one or more layers of extruded thermoplastic foam and substantially unfoamed thermoplastic.
6−約160キログラムの密度を有する請求項1の乗り物。7. The method of claim 1, wherein the foam is formed at about 1 cubic meter prior to fabrication or thermoforming.
6-The vehicle of claim 1 having a density of about 160 kilograms.
6−約80キログラムの密度を有する請求項1の乗り物。8. The method of claim 1 wherein the foam is formed at about 1 cubic meter prior to fabrication or thermoforming.
6-The vehicle of claim 1 having a density of about 80 kilograms.
て50重量%より多いプロピレンモノマー単位を含む請求項1の乗り物。9. The vehicle of claim 1, wherein the thermoplastic resin comprises greater than 50% by weight propylene monomer units based on the total weight of the propylene polymer material.
いて70重量%より多いプロピレンモノマー単位を含む請求項1の乗り物。10. The vehicle of claim 1 wherein the thermoplastic resin comprises greater than 70% by weight propylene monomer units based on the total weight of the propylene polymer material.
。12. The vehicle of claim 1, wherein the foam is a polycarbonate foam.
求項1の乗り物。14. The vehicle of claim 1, wherein the foam has a cross-sectional thickness of 1.5 millimeters or more.
1の乗り物。15. The vehicle of claim 1, wherein the foam has a cross-sectional thickness of no less than 3 millimeters.
ている請求項1の乗り物。16. The vehicle of claim 1, wherein the foam is made from two or more laminated sheets.
体である請求項9の乗り物。17. The vehicle of claim 9, wherein the foam is an extruded foam in the form of a coalesced strand.
項1の乗り物。18. The vehicle of claim 1, wherein the foam has a filler in the form of particles and / or fibers.
熱可塑性樹脂が、プロピレンポリマー物質の全重量に基づいて50重量%より多
いプロピレンモノマー単位を含み、発泡体が、製作又は熱成形前に1立方メート
ル当たり約16−約160キログラムの密度を有する請求項1の乗り物。19. The foam has a cross-sectional thickness of at least 1.5 millimeters,
The thermoplastic resin comprises more than 50% by weight propylene monomer units based on the total weight of the propylene polymer material, and the foam has a density of about 16 to about 160 kilograms per cubic meter prior to fabrication or thermoforming. One vehicle.
塑性樹脂が、プロピレンポリマー物質の全重量に基づいて70重量%より多いプ
ロピレンモノマー単位を含み、発泡体が、製作又は熱成形前に1立方メートル当
たり約16−約80キログラムの密度を有する請求項1の乗り物。20. A foam having a cross-sectional thickness of 3 millimeters or more, wherein the thermoplastic resin comprises greater than 70% by weight propylene monomer units based on the total weight of the propylene polymer material, wherein the foam comprises: The vehicle of claim 1 having a density of about 16 to about 80 kilograms per cubic meter prior to fabrication or thermoforming.
又はプロフィルを有する請求項1の乗り物。21. The vehicle of claim 1, wherein the foam has one or more unfoamed plates or profiles therein.
てヘッドライナーを組立てそしてそれを設置する方法であって、a)押し出され
た熱可塑性発泡体及び所望により実質的に発泡していない熱可塑性樹脂の一つ以
上の隣接する層からなる熱成形可能な芯の層を用意し、ここで芯の層は熱硬化性
物質を実質的に含まず、たわみに実質的に抵抗しそして実質的にその形状を維持
するものであり;b)この芯の層に熱及び機械的な圧力をかけることにより芯の
層を熱成形してヘッドライナーを形成し;c)屋根の下面に隣接してこのヘッド
ライナーを配置することからなる方法。22. A method of assembling and installing a headliner in a vehicle having a cabin and a roof located overhead of the cabin, comprising: a) extruded thermoplastic foam and optionally substantially expanded foam. Providing a thermoformable core layer comprising one or more adjacent layers of non-thermoplastic resin, wherein the core layer is substantially free of thermosetting material and substantially resists deflection. And substantially maintaining its shape; b) thermoforming the wick layer by applying heat and mechanical pressure to the wick layer to form a headliner; c) on the underside of the roof A method comprising positioning the headliner adjacent.
にラミネートされ、装飾層は、芯の層を熱成形する前又はその後の何れかで芯の
層にラミネートされる請求項22の方法。23. A decorative layer is placed adjacent to and parallel to the core layer and laminated thereto, the decorative layer being laminated to the core layer either before or after thermoforming the core layer. The method of claim 22.
熱可塑性樹脂が、プロピレンポリマー物質の全重量に基づいて50重量%より多
いプロピレンモノマー単位を含み、発泡体が、製作又は熱成形前に1立方メート
ル当たり約16−約160キログラムの密度を有する請求項22の方法。24. The foam has a cross-sectional thickness of at least 1.5 millimeters,
The thermoplastic resin comprises more than 50% by weight propylene monomer units based on the total weight of the propylene polymer material, and the foam has a density of about 16 to about 160 kilograms per cubic meter prior to fabrication or thermoforming. Method 22.
塑性樹脂が、プロピレンポリマー物質の全重量に基づいて70重量%より多いプ
ロピレンモノマー単位を含み、発泡体が、製作又は熱成形前に1立方メートル当
たり約16−約80キログラムの密度を有する請求項22の方法。25. A foam having a cross-sectional thickness of 3 millimeters or more, wherein the thermoplastic resin comprises greater than 70% by weight propylene monomer units based on the total weight of the propylene polymer material, wherein the foam comprises: 23. The method of claim 22, having a density of about 16 to about 80 kilograms per cubic meter prior to fabrication or thermoforming.
又はプロフィルを有する請求項22の方法。26. The method of claim 22, wherein the foam has one or more unfoamed plates or profiles therein.
。28. The method of claim 22, wherein the foam is a polycarbonate foam.
又はプロフィルを有する請求項1の方法。30. The method of claim 1, wherein the foam has one or more unfoamed plates or profiles therein.
された芯の層を有する乗り物のヘッドライナーであって、芯の層が、10%より
低いゲル含量を有し、そして熱成形前に50%より低い連続気泡含量、1立方メ
ートル当たり16−200キログラムの範囲の密度、少なくとも12インチの幅
、そして1.0−5.5mmの範囲の平均気泡サイズを有する押し出された熱可
塑性発泡体からなる乗り物のヘッドライナー。31. A vehicle headliner having at least one thermoformed core layer having a thickness of 1.5-25 mm, wherein the core layer has a gel content of less than 10%, And extruded prior to thermoforming having an open cell content of less than 50%, a density in the range of 16-200 kilograms per cubic meter, a width of at least 12 inches, and an average cell size in the range of 1.0-5.5 mm. Vehicle headliner made of thermoplastic foam.
る請求項30のヘッドライナー。32. The headliner of claim 30, wherein the thermoplastic foam has a foamable index greater than 2.0.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8694498P | 1998-05-27 | 1998-05-27 | |
US8905898P | 1998-06-12 | 1998-06-12 | |
US60/086,944 | 1998-06-12 | ||
US60/089,058 | 1998-06-12 | ||
PCT/US1999/009304 WO1999061283A1 (en) | 1998-05-27 | 1999-04-29 | Vehicle headliner comprised of a thermoformable thermoplastic foam sheet |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2002516210A true JP2002516210A (en) | 2002-06-04 |
Family
ID=26775339
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000550708A Pending JP2002516210A (en) | 1998-05-27 | 1999-04-29 | Vehicle headliner made of thermoformable thermoplastic foam sheet |
JP2000550916A Pending JP2002516370A (en) | 1998-05-27 | 1999-04-30 | Heat-expandable polypropylene foam sheet |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000550916A Pending JP2002516370A (en) | 1998-05-27 | 1999-04-30 | Heat-expandable polypropylene foam sheet |
Country Status (18)
Country | Link |
---|---|
US (1) | US6251319B1 (en) |
EP (2) | EP1082236A1 (en) |
JP (2) | JP2002516210A (en) |
KR (2) | KR20010043812A (en) |
CN (2) | CN1303337A (en) |
AT (1) | ATE263203T1 (en) |
AU (2) | AU3967699A (en) |
BR (2) | BR9910334A (en) |
CA (2) | CA2328974A1 (en) |
DE (1) | DE69916052T2 (en) |
ES (1) | ES2219016T3 (en) |
HU (1) | HUP0101966A3 (en) |
IL (2) | IL139579A0 (en) |
NO (1) | NO324390B1 (en) |
RU (1) | RU2219198C2 (en) |
TR (1) | TR200003492T2 (en) |
TW (2) | TW453950B (en) |
WO (2) | WO1999061283A1 (en) |
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- 1999-04-29 AU AU39676/99A patent/AU3967699A/en not_active Abandoned
- 1999-04-29 BR BR9910334-6A patent/BR9910334A/en not_active Application Discontinuation
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- 1999-04-29 EP EP99922751A patent/EP1082236A1/en not_active Withdrawn
- 1999-04-29 CA CA002328974A patent/CA2328974A1/en not_active Abandoned
- 1999-04-29 CN CN99806608A patent/CN1303337A/en active Pending
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- 1999-04-30 HU HU0101966A patent/HUP0101966A3/en unknown
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- 1999-04-30 RU RU2000132718/04A patent/RU2219198C2/en active
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- 1999-04-30 CA CA002330922A patent/CA2330922C/en not_active Expired - Fee Related
- 1999-04-30 EP EP99921556A patent/EP1082381B1/en not_active Expired - Lifetime
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- 1999-04-30 IL IL13958099A patent/IL139580A0/en unknown
- 1999-04-30 CN CN99806607A patent/CN1118507C/en not_active Expired - Fee Related
- 1999-04-30 KR KR1020007013262A patent/KR20010043823A/en not_active Application Discontinuation
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JP2017535635A (en) * | 2014-10-23 | 2017-11-30 | スリーエム イノベイティブ プロパティズ カンパニー | Side-blown foam slab |
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