JP2001328398A - Hydraulic transfer sheet and manufacturing method therefor - Google Patents
Hydraulic transfer sheet and manufacturing method thereforInfo
- Publication number
- JP2001328398A JP2001328398A JP2000146473A JP2000146473A JP2001328398A JP 2001328398 A JP2001328398 A JP 2001328398A JP 2000146473 A JP2000146473 A JP 2000146473A JP 2000146473 A JP2000146473 A JP 2000146473A JP 2001328398 A JP2001328398 A JP 2001328398A
- Authority
- JP
- Japan
- Prior art keywords
- transparent resin
- layer
- resin layer
- transfer sheet
- hydraulic transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Decoration By Transfer Pictures (AREA)
Abstract
Description
【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION
【０００１】[0001]
【発明の属する技術分野】本発明は、曲面又は凹凸面を
有する家具・建具、車両等の部品の表面化粧に使用され
る水圧転写シート及びその製造方法に関し、特に、転写
物に安定したホログラム効果をもたらす水圧転写シート
及びその製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hydraulic transfer sheet used for surface decoration of parts such as furniture, fittings and vehicles having a curved surface or an uneven surface, and a method of manufacturing the same. And a method for producing the same.
【０００２】[0002]
【従来の技術】水圧転写技術は、特公昭５２−４４１６
８２号公報に示されているように、薄膜（フィルム）に
パターンを印刷し、この薄膜を、印刷面を上にして液体
表面上に浮かべ、前記印刷面上に物体を押圧しつつその
全部又は一部を液中に沈め、液体の圧力により上記パタ
ーンを物体表面に転写し、その後薄膜を物体表面から除
去する印刷技術として知られている。また、特公昭５７
−５０５４７号公報に示されているように、薄膜を水溶
性とする印刷方法も知られている。2. Description of the Related Art The hydraulic transfer technology is disclosed in Japanese Patent Publication No. 52-4416.
No. 82, a pattern is printed on a thin film (film), and the thin film is floated on a liquid surface with the printed surface up, and all or all of the object is pressed while pressing the object on the printed surface. It is known as a printing technique in which a part is immersed in a liquid, the pattern is transferred to the surface of the object by the pressure of the liquid, and then the thin film is removed from the surface of the object. In addition,
As disclosed in JP-A-50547, a printing method for making a thin film water-soluble is also known.
【０００３】従来のいずれの水圧転写シートも曲面又は
凹凸面のような複雑な外形形状を有する物体表面の化粧
に適している。前記の水溶性の薄膜（フィルム）を含む
水圧転写シートにおいて、その水溶性フィルムは転写中
に水に溶けて消失し、透明な樹脂層と蒸着金属層とによ
るシートが転写物の表面を覆って化粧効果を発揮する。
その化粧効果は、透明樹脂層に施したエンボスとこの透
明樹脂層に隣接する蒸着金属層とによるホログラム効
果、または透明樹脂層とこれに隣接する蒸着金属層に施
したエンボスとによるホログラム効果である。このホロ
グラム効果のほか、印刷層があるときはもちろん絵柄模
様の印刷による装飾効果が付加される。[0003] Any conventional hydraulic transfer sheet is suitable for the makeup of the surface of an object having a complicated external shape such as a curved surface or an uneven surface. In the hydraulic transfer sheet containing the water-soluble thin film (film), the water-soluble film dissolves in water during the transfer and disappears, and the sheet of the transparent resin layer and the vapor-deposited metal layer covers the surface of the transferred material. Exhibits a cosmetic effect.
The cosmetic effect is a hologram effect by the emboss applied to the transparent resin layer and the deposited metal layer adjacent to the transparent resin layer, or a hologram effect by the transparent resin layer and the emboss applied to the deposited metal layer adjacent to the transparent resin layer. . In addition to this hologram effect, if there is a print layer, a decorative effect by printing a picture pattern is of course added.
【０００４】ところで、ホログラム効果を安定して得る
ためには、蒸着装置における一定の真空度の下で金属材
料の蒸着が行われることが必要である。しかし、水圧転
写シートにとって不可欠の要素である水溶性フィルムは
高い吸水性を有し、蒸着装置における真空度は、該水溶
性フィルムに含まれる水分のためにしばしば変化し、蒸
着にムラが生じるという問題がある。この蒸着ムラを生
じたとき、所望のホログラム効果を得ることはできな
い。By the way, in order to stably obtain the hologram effect, it is necessary to deposit a metal material under a certain degree of vacuum in a deposition apparatus. However, the water-soluble film, which is an essential element for the hydraulic transfer sheet, has high water absorption, and the degree of vacuum in the vapor deposition device often changes due to the moisture contained in the water-soluble film, resulting in uneven vapor deposition. There's a problem. When this deposition unevenness occurs, a desired hologram effect cannot be obtained.
【０００５】[0005]
【発明が解決しようとする課題】本発明の目的は、水圧
転写シートの製造過程における上記の問題に解決を与え
ることにあり、水溶性フィルムに含まれる水分を調整し
て、蒸着装置における真空度の変化最小限にし、蒸着の
安定化をはかってホログラム効果を確保することにあ
る。SUMMARY OF THE INVENTION An object of the present invention is to provide a solution to the above-mentioned problems in the process of manufacturing a hydraulic transfer sheet. Of the hologram effect by minimizing the variation of the hologram and stabilizing the vapor deposition.
【０００６】[0006]
【課題を解決するための手段】本発明は、上記の目的を
達成するために、水圧転写シートを構成する水溶性フィ
ルムの含水率を一定値以下にすることを基本構想とする
ものであり、本発明らの知見によれば、その含水率を７
％以下にすることにより、水圧転写シートによるホログ
ラム効果を安定的に確保することができる。SUMMARY OF THE INVENTION In order to achieve the above-mentioned object, the present invention has a basic concept of reducing the water content of a water-soluble film constituting a hydraulic transfer sheet to a certain value or less. According to the findings of the present inventors, the water content is 7
%, The hologram effect of the hydraulic transfer sheet can be stably ensured.
【０００７】したがって、本発明に係る水圧転写シート
は、含水率が７％以下である水溶性フィルムと、該水溶
性フィルム上の透明樹脂層と、該透明樹脂層上の蒸着金
属層とからなり、該蒸着金属層と前記透明樹脂層との間
で該透明樹脂層にエンボスが施されている。前記水溶性
フィルムと前記透明樹脂層との間に印刷層を備えること
ができる。また、本発明に係る水圧転写シートは、含水
率が７％以下である水溶性フィルムと、該水溶性フィル
ム上の透明樹脂層と、該透明樹脂層上の蒸着金属層とか
らなり、該蒸着金属層の表面にエンボスが施されてい
る。水圧転写シート。前記水溶性フィルムと前記透明樹
脂層との間に印刷層を備えることができる。Therefore, the hydraulic transfer sheet according to the present invention comprises a water-soluble film having a water content of 7% or less, a transparent resin layer on the water-soluble film, and a vapor-deposited metal layer on the transparent resin layer. The transparent resin layer is embossed between the vapor-deposited metal layer and the transparent resin layer. A printing layer may be provided between the water-soluble film and the transparent resin layer. The hydraulic transfer sheet according to the present invention comprises a water-soluble film having a water content of 7% or less, a transparent resin layer on the water-soluble film, and a vapor-deposited metal layer on the transparent resin layer. The surface of the metal layer is embossed. Hydraulic transfer sheet. A printing layer may be provided between the water-soluble film and the transparent resin layer.
【０００８】他方、本発明に係る水圧転写シートの製造
方法は、含水率が７％以下である水溶性フィルム上に透
明樹脂を塗布して透明樹脂層を形成し、該透明樹脂層の
表面にエンボスを施し、該エンボスを施した透明樹脂層
上に金属材料を蒸着して蒸着金属層を形成することを特
徴とする。水圧転写シートに印刷層を設けるときは、含
水率が７％以下である水溶性フィルム上に印刷を施して
印刷層を形成し、該印刷層上に透明樹脂を塗布して透明
樹脂層を形成し、該透明樹脂層の表面にエンボスを施
し、該エンボスを施した透明樹脂層上に金属材料を蒸着
して蒸着金属層を形成する。また、本発明に係る水圧転
写シートの製造方法は、含水率が７％以下である水溶性
フィルム上に透明樹脂を塗布して透明樹脂層を形成し、
該透明樹脂層上に金属材料を蒸着して蒸着金属層を形成
し、該蒸着金属層の表面にエンボスを施すことを特徴と
する。また、水圧転写シートに印刷層を設けるときは、
含水率が７％以下である水溶性フィルム上に印刷を施し
て印刷層を形成し、該印刷層上に透明樹脂を塗布して透
明樹脂層を形成し、該透明樹脂層上に金属材料を蒸着し
て蒸着金属層を形成し、該蒸着金属層の表面にエンボス
を施す。On the other hand, the method for producing a hydraulic transfer sheet according to the present invention comprises applying a transparent resin on a water-soluble film having a water content of 7% or less to form a transparent resin layer, and forming a transparent resin layer on the surface of the transparent resin layer. The method is characterized in that embossing is performed and a metal material is vapor-deposited on the embossed transparent resin layer to form a vapor-deposited metal layer. When a printing layer is provided on a hydraulic transfer sheet, printing is performed on a water-soluble film having a water content of 7% or less to form a printing layer, and a transparent resin is applied on the printing layer to form a transparent resin layer. Then, embossing is performed on the surface of the transparent resin layer, and a metal material is vapor-deposited on the embossed transparent resin layer to form a vapor-deposited metal layer. Further, in the method for producing a hydraulic transfer sheet according to the present invention, a transparent resin is applied on a water-soluble film having a water content of 7% or less to form a transparent resin layer,
A metal material is deposited on the transparent resin layer to form a deposited metal layer, and the surface of the deposited metal layer is embossed. When providing a printing layer on the hydraulic transfer sheet,
Printing is performed on a water-soluble film having a water content of 7% or less to form a printing layer, a transparent resin is applied on the printing layer to form a transparent resin layer, and a metal material is coated on the transparent resin layer. The metal layer is formed by vapor deposition, and the surface of the metal layer is embossed.
【０００９】[0009]
【実施の形態】図１に示すように、本発明に係る水圧転
写シート１０は、含水率が７％以下である水溶性フィル
ム１２と、該水溶性フィルム上の透明樹脂層１４と、該
透明樹脂層上の蒸着金属層１６とからなり、該蒸着金属
層と前記透明樹脂層との間で該透明樹脂層にエンボス１
８が施されている。図２に示す水圧転写シート１０で
は、水溶性フィルム１２と透明樹脂層１４との間に印刷
層２０が形成されている。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS As shown in FIG. 1, a hydraulic transfer sheet 10 according to the present invention comprises a water-soluble film 12 having a water content of 7% or less, a transparent resin layer 14 on the water-soluble film, A metal layer 16 on the resin layer, wherein the transparent resin layer has an embossed layer 1 between the metal layer and the transparent resin layer.
8 is given. In the hydraulic transfer sheet 10 shown in FIG. 2, a printing layer 20 is formed between the water-soluble film 12 and the transparent resin layer 14.
【００１０】水圧転写シート１０の製造に際しては、含
水率が７％以下である水溶性フィルム１２上に透明樹脂
を塗布して透明樹脂層１４を形成し、該透明樹脂層の表
面にエンボス１８を施し、該エンボスを施した透明樹脂
層上に金属材料を蒸着して蒸着金属層１６を形成する。
図２に示すように、印刷層２０を設ける際は、前記水溶
性フィルム１２上に印刷を施して印刷層２０を形成し、
該印刷層上に透明樹脂を塗布して透明樹脂層１４を形成
し、該透明樹脂層の表面にエンボス１８を施し、該エン
ボスを施した透明樹脂層上に金属材料を蒸着して蒸着金
属層１６を形成する。In manufacturing the hydraulic transfer sheet 10, a transparent resin is applied on a water-soluble film 12 having a water content of 7% or less to form a transparent resin layer 14, and an emboss 18 is formed on the surface of the transparent resin layer. Then, a metal material is deposited on the embossed transparent resin layer to form a deposited metal layer 16.
As shown in FIG. 2, when providing the printing layer 20, printing is performed on the water-soluble film 12 to form the printing layer 20,
A transparent resin is applied on the printing layer to form a transparent resin layer 14, an emboss 18 is applied to the surface of the transparent resin layer, and a metal material is deposited on the embossed transparent resin layer by vapor deposition. 16 are formed.
【００１１】水溶性フィルム１２の材料として、ポリビ
ニルアルコール（ＰＶＡ）を使用することができる。ま
た、透明樹脂層１４の材料として、熱可塑性樹脂、熱硬
化性樹脂又はラジカル重合樹脂を使用することができ
る。さらに、蒸着金属層１６の材料としては、銅、クロ
ム等の重金属を使用することができ、また酸化アルミニ
ウム、二酸化ケイ素等の酸化金属を使用することがで
き、さらにアルミニウムを使用することもできる。蒸着
金属層１６の厚さは１５０〜８００Åとすることができ
る。またエンボス１８の深さは０．５〜２μとすること
ができる。As a material of the water-soluble film 12, polyvinyl alcohol (PVA) can be used. Further, as a material of the transparent resin layer 14, a thermoplastic resin, a thermosetting resin, or a radical polymerizable resin can be used. Further, as a material of the vapor deposition metal layer 16, a heavy metal such as copper or chromium can be used, a metal oxide such as aluminum oxide or silicon dioxide can be used, and further, aluminum can be used. The thickness of the vapor-deposited metal layer 16 can be 150 to 800 °. Further, the depth of the emboss 18 can be set to 0.5 to 2 μm.
【００１２】次に、図３，４に示す例にでは、エンボス
１８は蒸着金属層１６に施されている。すなわち、図３
に示す水圧転写シート１０は、含水率が７％以下である
水溶性フィルム１０と、該水溶性フィルム上の透明樹脂
層１４と、該透明樹脂層上の蒸着金属層１６とからな
り、該蒸着金属層の表面にエンボス１８が施されてい
る。図４に示す水圧転写シート１０は、前記の水溶性フ
ィルム１０と透明樹脂層１４との間に印刷層２０を有す
る。Next, in the examples shown in FIGS. 3 and 4, the embossment 18 is applied to the vapor-deposited metal layer 16. That is, FIG.
Is composed of a water-soluble film 10 having a water content of 7% or less, a transparent resin layer 14 on the water-soluble film, and a vapor-deposited metal layer 16 on the transparent resin layer. An emboss 18 is provided on the surface of the metal layer. The hydraulic transfer sheet 10 shown in FIG. 4 has a printing layer 20 between the water-soluble film 10 and the transparent resin layer 14.
【００１３】製造に際して、含水率が７％以下である水
溶性フィルム１０上に透明樹脂を塗布して透明樹脂層１
４を形成し、該透明樹脂層上に金属材料を蒸着して蒸着
金属層１６を形成し、該蒸着金属層の表面にエンボス１
８を施す。印刷層２０を設ける際は、前記の水溶性フィ
ルム１０上に印刷を施して印刷層２０を形成し、該印刷
層上に透明樹脂を塗布して透明樹脂層１４を形成し、該
透明樹脂層上に金属材料を蒸着して蒸着金属層１６を形
成し、該蒸着金属層の表面にエンボス１８を施す。At the time of production, a transparent resin is applied on a water-soluble film 10 having a water content of 7% or less to form a transparent resin layer 1.
4 is formed, and a metal material is vapor-deposited on the transparent resin layer to form a vapor-deposited metal layer 16.
Apply 8. When providing the printing layer 20, printing is performed on the water-soluble film 10 to form the printing layer 20, and a transparent resin is applied on the printing layer to form the transparent resin layer 14, and the transparent resin layer 14 is formed. A metal material is vapor-deposited thereon to form a vapor-deposited metal layer 16, and an emboss 18 is applied to the surface of the vapor-deposited metal layer.
【００１４】図３，４に示す実施例においても、水溶性
フィルム１２の材料として、ポリビニルアルコール（Ｐ
ＶＡ）を使用することができ、透明樹脂層１４の材料と
して、熱可塑性樹脂、熱硬化性樹脂又はラジカル重合樹
脂を使用することができ、さらに、銅、クロム等の重金
属を使用することができ、また酸化アルミニウム、二酸
化ケイ素等の酸化金属を使用することができ、さらにア
ルミニウムを使用することもできる。蒸着金属層１６の
厚さは１５０〜８００Åとすることができる。またエン
ボス１８の深さは０．５〜２μとすることができる。Also in the embodiment shown in FIGS. 3 and 4, the water-soluble film 12 is made of polyvinyl alcohol (P
VA) can be used, and as the material of the transparent resin layer 14, a thermoplastic resin, a thermosetting resin, or a radical polymerization resin can be used, and further, a heavy metal such as copper or chromium can be used. Further, metal oxides such as aluminum oxide and silicon dioxide can be used, and aluminum can also be used. The thickness of the vapor-deposited metal layer 16 can be 150 to 800 °. Further, the depth of the emboss 18 can be set to 0.5 to 2 μm.
【００１５】（実施例）３０μ厚のＰＶＡフィルムから
なる水溶性フィルムに硝化綿・アルキッド系インキを用
いて絵柄を印刷して印刷層を形成した。この印刷層上に
硝化綿・アルキッド系の透明な樹脂を３μの厚さで塗布
して透明樹脂層を形成した。この透明樹脂層の表面に深
さが１μのエンボスをエンボスローラを用いて形成し
た。さらにその透明樹脂層上にアルミニウムを蒸着して
３５０Å厚の蒸着金属層を形成し、これにより図２に示
す構成の水圧転写シートを得た。この水圧転写シートを
使用してＡＢＳの成形品に水圧転写を行ったところ、印
刷模様とホログラム効果とが相互に作用した、干渉色の
強いホログラム模様を観察することができた。(Example) A print layer was formed by printing a pattern on a water-soluble film made of a PVA film having a thickness of 30 μm using nitrified cotton / alkyd ink. A transparent resin of nitrified cotton / alkyd was applied in a thickness of 3 μ on the printed layer to form a transparent resin layer. An emboss having a depth of 1 μm was formed on the surface of the transparent resin layer using an emboss roller. Further, aluminum was vapor-deposited on the transparent resin layer to form a vapor-deposited metal layer having a thickness of 350 °, thereby obtaining a hydraulic transfer sheet having the structure shown in FIG. When hydraulic transfer was performed to an ABS molded product using this hydraulic transfer sheet, a hologram pattern having a strong interference color, in which the print pattern and the hologram effect interacted, could be observed.
【図１】本発明の１実施例に係る水圧転写シートの部分
横断面図。FIG. 1 is a partial cross-sectional view of a hydraulic transfer sheet according to one embodiment of the present invention.
【図２】本発明の他の実施例に係る水圧転写シートの部
分横断面図。FIG. 2 is a partial cross-sectional view of a hydraulic transfer sheet according to another embodiment of the present invention.
【図３】本発明の他の実施例に係る水圧転写シートの部
分横断面図。FIG. 3 is a partial cross-sectional view of a hydraulic transfer sheet according to another embodiment of the present invention.
【図４】本発明のさらに他の実施例に係る水圧転写シー
トの部分横断面図。FIG. 4 is a partial cross-sectional view of a hydraulic transfer sheet according to still another embodiment of the present invention.
１０ 水圧転写シート １２ 水溶性シート １４ 透明樹脂シート １６ 蒸着金属層 １８ エンボス ２０ 印刷層 DESCRIPTION OF SYMBOLS 10 Hydraulic transfer sheet 12 Water-soluble sheet 14 Transparent resin sheet 16 Metallized metal layer 18 Emboss 20 Printing layer
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 3B005 EA06 EA12 EB01 EB03 FA03 FA08 FA12 FA17 FA18 FB42 FB44 FB53 FG02X GA24 GA28 GB01 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 3B005 EA06 EA12 EB01 EB03 FA03 FA08 FA12 FA17 FA18 FB42 FB44 FB53 FG02X GA24 GA28 GB01
Claims (12)
と、該水溶性フィルム上の透明樹脂層と、該透明樹脂層
上の蒸着金属層とからなり、該蒸着金属層と前記透明樹
脂層との間で該透明樹脂層にエンボスが施されている、
水圧転写シート。1. A water-soluble film having a water content of 7% or less, a transparent resin layer on the water-soluble film, and a deposited metal layer on the transparent resin layer, wherein the deposited metal layer and the transparent resin The transparent resin layer is embossed between the layers.
Hydraulic transfer sheet.
の間に印刷層を有する、請求項１に記載の水圧転写シー
ト。2. The hydraulic transfer sheet according to claim 1, further comprising a printing layer between the water-soluble film and the transparent resin layer.
脂、熱硬化性樹脂又はラジカル重合樹脂である、請求項
１又は２に記載の水圧転写シート。3. The hydraulic transfer sheet according to claim 1, wherein the material of the transparent resin layer is a thermoplastic resin, a thermosetting resin, or a radical polymerized resin.
の重金属、酸化アルミニウム、二酸化ケイ素等の酸化金
属又はアルミニウムである、請求項１又は２に記載の水
圧転写シート。4. The hydraulic transfer sheet according to claim 1, wherein the material of the vapor-deposited metal layer is a heavy metal such as copper or chromium, a metal oxide such as aluminum oxide or silicon dioxide, or aluminum.
Åである、請求項１、２又は５に記載の水圧転写シー
ト。5. The thickness of the deposited metal layer is 150 to 800.
The hydraulic transfer sheet according to claim 1, 2 or 5, wherein Å.
る、請求項１又は２に記載の水圧転写シート。6. The hydraulic transfer sheet according to claim 1, wherein the emboss depth is 0.5 to 2 μm.
上に透明樹脂を塗布して透明樹脂層を形成し、該透明樹
脂層の表面にエンボスを施し、該エンボスを施した透明
樹脂層上に金属材料を蒸着して蒸着金属層を形成する、
水圧転写シートの製造方法。7. A transparent resin layer is formed by applying a transparent resin on a water-soluble film having a water content of 7% or less, forming a transparent resin layer, embossing the surface of the transparent resin layer, and embossing the transparent resin layer. Depositing a metal material on top to form a deposited metal layer,
A method for manufacturing a hydraulic transfer sheet.
上に印刷を施して印刷層を形成し、該印刷層上に透明樹
脂を塗布して透明樹脂層を形成し、該透明樹脂層の表面
にエンボスを施し、該エンボスを施した透明樹脂層上に
金属材料を蒸着して蒸着金属層を形成する、水圧転写シ
ートの製造方法。8. Printing is performed on a water-soluble film having a water content of 7% or less to form a printed layer, and a transparent resin is applied on the printed layer to form a transparent resin layer. A method for producing a hydraulic transfer sheet, comprising embossing a surface of a transparent resin layer and vapor-depositing a metal material on the embossed transparent resin layer to form a vapor-deposited metal layer.
と、該水溶性フィルム上の透明樹脂層と、該透明樹脂層
上の蒸着金属層とからなり、該蒸着金属層の表面にエン
ボスが施されている、水圧転写シート。9. A water-soluble film having a water content of 7% or less, a transparent resin layer on the water-soluble film, and a vapor-deposited metal layer on the transparent resin layer, wherein the surface of the vapor-deposited metal layer is embossed. , A hydraulic transfer sheet.
との間に印刷層を有する、請求項９に記載の水圧転写シ
ート。10. The hydraulic transfer sheet according to claim 9, further comprising a printing layer between the water-soluble film and the transparent resin layer.
ム上に透明樹脂を塗布して透明樹脂層を形成し、該透明
樹脂層上に金属材料を蒸着して蒸着金属層を形成し、該
蒸着金属層の表面にエンボスを施す、水圧転写シートの
製造方法。11. A transparent resin layer is formed by applying a transparent resin on a water-soluble film having a water content of 7% or less, and a metal material is vapor-deposited on the transparent resin layer to form a vapor-deposited metal layer. A method for producing a hydraulic transfer sheet, wherein embossing is performed on the surface of the deposited metal layer.
ム上に印刷を施して印刷層を形成し、該印刷層上に透明
樹脂を塗布して透明樹脂層を形成し、該透明樹脂層上に
金属材料を蒸着して蒸着金属層を形成し、該蒸着金属層
の表面にエンボスを施す、水圧転写シートの製造方法。12. A printed layer is formed by printing on a water-soluble film having a water content of 7% or less, and a transparent resin layer is formed by applying a transparent resin on the printed layer. A method for producing a hydraulic transfer sheet, comprising forming a vapor-deposited metal layer by vapor-depositing a metal material thereon, and embossing the surface of the vapor-deposited metal layer.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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|---|---|---|---|
| JP2009176396A Division JP5075887B2 (en) | 2009-07-29 | 2009-07-29 | Hydraulic transfer sheet and manufacturing method thereof |
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| JP4382964B2 JP4382964B2 (en) | 2009-12-16 |
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