JP2001138503A - Electric field ejection head, electric field ejection control device and electric field ejection coating device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an electric field ejection head, an electric field ejection control device and an electric ejection coating device capable of enlarging a tolerance range of a gap between an ejection nozzle and an object to be coated and reducing an expansion range with respect to a diameter of the ejection nozzle when forming a stripe type coated pattern on the object to be coated. SOLUTION: This electric field ejection head comprises an introducing section for introducing a material to be ejected, an ejection section having a plurality of nozzles arranged in a line at predetermined intervals, a manifold to be a passage for temporarily storing the material to be ejected introduced from the introducing section and introducing it to the ejection section and an electrode (a voltage side electrode) provided in the manifold. The head is so constituted that at least the ejection section and manifold are electrically insulated from the electrode. There are disclosed an electric field ejection control device and an electric field ejection coating device adapted thereto.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention belongs to the field of coating technology. In particular, the present invention relates to an electric field discharge head, an electric field discharge control device, and an electric field discharge coating device suitable for forming a stripe-shaped precise coating pattern linearly arranged at predetermined intervals on an object to be coated.

[0002]

2. Description of the Related Art As a method of forming a stripe-shaped coating pattern on an object to be coated, a material to be discharged (coating material, ink) is discharged from discharge holes of a discharge head to form an object to be coated (web, substrate). There is known a method of coating. At this time,
A desired coating pattern can be obtained by moving the discharge head or the object to be coated such that the position of the discharge hole coincides with the position to be coated. Further, the amount of coating on the object to be coated can be controlled by adjusting the discharge amount and the moving distance per unit time.

[0003]

However, in such a method using a discharge head, after the substance to be discharged is discharged from the discharge hole at a predetermined initial speed, it is left to a process determined only by the action of surface tension and gravity. Do exercise. Therefore, there is a problem that the allowable range of the gap between the discharge hole and the object to be coated is narrow, and the discharge hole has a large spread with respect to the hole diameter.

The present invention has been made to solve such a problem, and an object of the present invention is to form a stripe-shaped coating pattern on an object to be coated. An electric field discharge head, which has a wide allowable range of the gap and can reduce the spread of the discharge hole with respect to the hole diameter.
An object of the present invention is to provide an electric field discharge control device and an electric field discharge coating device.

[0005]

The above object is achieved by the present invention described below. In other words, the electric field discharge head according to claim 1 of the present invention has an introduction section for introducing a substance to be ejected, an ejection section having a plurality of ejection holes linearly arranged at predetermined intervals, and the introduction section. A manifold serving as a passage for temporarily storing the introduced substance to be introduced and leading to the discharge unit, and an electrode (voltage-side electrode) disposed inside the manifold; at least the discharge unit is electrically connected to the electrode. It is designed to be electrically insulated. According to the present invention, after the substance to be discharged is discharged from the discharge hole at a predetermined initial velocity, the substance is subjected to not only the action of the surface tension and the gravity but also the action of the electric field, and performs a predetermined motion determined by the action. be able to. Therefore, there is provided an electric field discharge head capable of widening the allowable range of the gap between the discharge hole and the object to be coated, and reducing the spread of the discharge hole with respect to the hole diameter. Also, since the electrodes are placed inside the manifold,
The material to be ejected maintains electrical contact with the electrode, and the action of the electric field is stabilized.

According to a second aspect of the present invention, in the electric field discharge head according to the first aspect, at least the discharge portion is formed of an electrically insulating material. According to the present invention, the electrical insulation with respect to the electrode is ensured by the discharge portion formed of the electrically insulating material.

According to a third aspect of the present invention, in the electric field discharge head according to the first or second aspect, the electrodes extend linearly in a direction in which the linearly arranged discharge portions are arranged. Is provided.
ADVANTAGE OF THE INVENTION According to this invention, the effect | action of an electrode with respect to several discharge holes which are linearly arranged at the predetermined space | interval formed in the discharge part can be equalized.

According to a fourth aspect of the present invention, there is provided an electric field discharge head according to any one of the first to third aspects, wherein the electrode is disposed in the interior of the manifold immediately adjacent to an entrance of the discharge hole. It is something to do. According to the present invention, the discharge state of the discharge target substance is stabilized.

According to a fifth aspect of the present invention, there is provided an electric field discharge head according to any one of the first to fourth aspects, further comprising a pressurizing section for pressurizing the substance to be discharged inside the manifold. It is like that. According to the present invention, the material to be ejected is pressurized by the pressurizing portion of the electric field ejection head.

According to a sixth aspect of the present invention, there is provided an electric field ejection control apparatus applied to the electric field ejection head according to any one of the first to fifth aspects, wherein the electric field ejection control apparatus sets a form of an electric field to be generated. Electric field setting means for generating a setting electric field based on an input to be performed; and a synchronization input means for inputting a synchronization signal including a signal for obtaining synchronization between a discharge position in the electric field discharge head and a coating position on an object to be coated. Power generating means for generating a predetermined form of power based on the set electric field and the synchronization signal. According to the present invention, the set electric field is generated based on the input for setting the form of the electric field generated by the electric field setting means, and the synchronization input means synchronizes the discharge position of the electric field discharge head with the coating position of the object to be coated. A synchronization signal including a signal for obtaining the synchronization signal is input, and power of a predetermined form is generated by the power generation unit based on the set electric field and the synchronization signal. That is, after the material to be ejected is ejected from the ejection hole at a predetermined initial speed, it can be configured to perform not only the action of the surface tension and gravity but also the action of the electric field and perform a predetermined motion determined by the action. Therefore, there is provided an electric field discharge control device capable of widening the allowable range of the gap between the discharge hole and the object to be coated and reducing the spread of the discharge hole relative to the hole diameter.
Further, while synchronizing the discharge position of the electric field discharge head with the coating position of the object to be coated, a predetermined form of power determined based on the setting input is supplied to the electric field discharge head.

According to a seventh aspect of the present invention, there is provided an electric field ejection control apparatus according to the sixth aspect, wherein
The pressure unit has a pressure input unit for inputting a pressure for pressurizing the substance to be ejected inside the manifold,
The electric field generating means generates the electric power based on the pressure. According to the present invention, the pressure in the pressurizing unit is reflected on the electric power generated by the electric field generating unit.

According to an eighth aspect of the present invention, in the electric field discharge control device according to the sixth or seventh aspect, the form of the generated electric field is such that the electric field discharge head performs continuous discharge. Is a rectangular wave. According to the present invention, the above-mentioned effects (such as claim 1) are remarkable due to the high-frequency component included in the rectangular wave.

According to a ninth aspect of the present invention, there is provided an electric field ejection control apparatus according to the eighth aspect, wherein
The rectangular wave is an AC waveform that does not include a DC component when integrated. According to the present invention, since the ionization of the material to be ejected does not occur, restrictions on the material to be ejected are small. Further, the above-mentioned effects are remarkable.

[0014] The field ejection control device according to claim 10 of the present invention, in a field discharge control apparatus according to claim 8 or 9, wherein the square wave voltage amplitude V _pp 100V~1
This is a rectangular wave having 0 kV and a frequency F of 1 Hz to 10 kHz. According to the present invention, the above-mentioned effects are particularly remarkable.

According to an eleventh aspect of the present invention, in the electric field emission control device according to the sixth or seventh aspect, the form of the generated electric field is such that the electric field ejection head performs intermittent ejection. Is a pulse. According to the present invention, intermittent ejection is performed by setting the form of the generated electric field as a pulse.

According to a twelfth aspect of the present invention, there is provided an electric field ejection control apparatus comprising the electric field ejection head according to any one of the first to fifth aspects and the electric field ejection control apparatus according to any one of the sixth to eleventh aspects. An electric field discharge coating apparatus, comprising: a supply unit that supplies the substance to be discharged to the introduction unit of the electric field discharge head; and a supply unit that supplies the substance to the introduction unit by operating the pressurizing unit of the electric field discharge head. Pressurized discharge control means for discharging a discharge substance from the discharge unit; electric field discharge control means for controlling a discharge state of the discharge target substance discharged by the electric field discharge head; and the electric field discharge means and / or the coating method It has a transfer means for transferring an object and outputting a synchronization signal indicating a transfer state, and a ground electrode disposed at a position facing the discharge section. According to the present invention, the material to be ejected is supplied to the introduction portion of the electric field discharge head by the supply means, and the material to be ejected supplied to the introduction portion is operated by operating the pressurizing portion of the electric field ejection head by the pressurization / discharge control means. The electric discharge control means controls the discharge state of the substance to be discharged, which is discharged by the electric field discharge head, and the transfer means transfers the electric field discharge means and / or the object to be coated and generates a synchronization signal indicating the transfer state. Output
The ground electrode is arranged at a position facing the discharge unit. That is, after the material to be ejected is ejected from the ejection hole at a predetermined initial speed, it can be configured to perform not only the action of the surface tension and gravity but also the action of the electric field and perform a predetermined motion determined by the action. Therefore, there is provided an electric field coating apparatus in which the allowable range of the gap between the discharge hole and the object to be coated is wide and the spread of the discharge hole with respect to the hole diameter is small.

[0017]

Next, an embodiment of the present invention will be described. FIG. 1 shows an example of the configuration of the electric field discharge head according to the present invention. FIG. 1A is a cross-sectional view of the central portion, and FIG.
(B) is a perspective view of the inside of which is seen through. In FIG.
1 is an introduction part, 2 is a discharge part, 3 is a manifold, 4 is an electrode, 5 is a pressure part, and 6 is a broken line indicating a boundary. As shown in FIG. 1, the electric field discharge head mainly includes a manifold 3
Has a structure in which each element part is provided in a main body part. The main body part is both a housing (container) and a support, and is distinguished from the manifold 3 in function. However, at least in the case of the example shown in FIG. 1, the manifold 3 is a main part of the main body, and it may not be meaningful to distinguish them. Therefore,
Here, unless otherwise described, the manifold 3 also means a main body portion. The boundary 6 means a “virtual boundary” when the discharge unit 2 and the manifold 3 are made of the same material and are integrated, and mean a “real boundary” when they are combined.

The introduction section 1 is provided for introducing a substance to be discharged. An introduction port is opened in the introduction section 1, and a pipe for feeding the substance to be ejected is provided therein. By applying pressure to the material to be ejected, the material to be ejected moves in the pipe.
The substance to be discharged is introduced into the inside of the manifold 3 from the introduction port.

The discharge section 2 is arranged at the tip of the main body (in other words, it constitutes the tip of the main body). A plurality of ejection holes are formed in the ejection unit 2, and the plurality of ejection holes are linearly arranged at predetermined intervals. Of course,
The size, shape, number, arrangement interval, and the like of the ejection holes are properties that are appropriately determined (designed) according to the purpose, conditions, and the like of coating with the electric field ejection head. The substance to be discharged introduced into the manifold 3 is discharged from the plurality of discharge holes when coating is performed.

The manifold 3 serves as a passage for temporarily storing the substance to be discharged introduced from the introduction section 1 and guiding the substance to the discharge section 2. The passage is simplified in FIG. The actual passage has a shape such that a predetermined discharge amount is obtained in all of the plurality of discharge holes formed in the discharge portion 2 and the discharge passage is not imbalanced.

The electrodes 4 are arranged inside the manifold 3 and have a shape extending linearly in the direction in which the discharge units 2 are arranged linearly. In the example shown in FIG.
Is a rectangular plate electrode, and has a structure in which the lead terminals appear outside the main body from near the center of the plate electrode.
Power supply for generating an electric field in the electric field ejection head is as follows.
It is performed from the lead terminal.

The electrode 4 is disposed inside the manifold 3 immediately near the entrance of the discharge hole 2. By disposing as close to the discharge hole 2 as possible, the discharge state of the material to be discharged is stabilized as compared with the case where the discharge target is disposed away from the discharge hole 2 (see FIGS. 3 and 4).

The pressurizing section 5 pressurizes the material to be ejected introduced into the manifold 3. The upper surface of the substance to be ejected introduced from the introduction unit 1 moves up and down inside the manifold 3 in balance with the supply amount and the ejection amount. Normally, control is performed such that the vertical movement range is in a range above the upper side portion of the electrode 4 and below the pressing unit 5. In one example shown in FIG. 1, compressed air is introduced into the pressurizing section 5. The compressed air pressurizes the upper surface of the material to be discharged. By controlling the pressure of the compressed air, the discharge amount can be controlled.

In the above-described configuration of the electric field discharge head, at least the discharge section 2 is electrically insulated from the electrode 4. Further, it is preferable that not only the discharge unit 2 but also the manifold 3 be electrically insulated from the electrode 4. Here, being electrically insulated, that is, the definition means that no current (direct current) flows in a static state. Even if a current (displacement current) flows in a dynamic state, if the above definition is satisfied, it is regarded as electrically insulated here.

In order to realize this electrically insulated state, for example, an electric insulator may be interposed between the electrode 4 and the manifold 3. However, it is more preferable to form the discharge unit 2 and the manifold 3 from an electrically insulating material, since the generated electric field is almost determined by the characteristics and shape of the electrodes. As the material, for example, a plastic or ceramic material can be applied.

The substance to be ejected will be described in detail later.
The material to be ejected is not electrically insulative and does not have good electrical conductivity like metal.
In the present invention, in the electric field discharge head, the electrode 4
Is configured such that current can flow out from the electrode 4 to the material to be ejected at a portion that contacts the material to be ejected. On the other hand, it is necessary to prevent current sneaking and leakage using the material to be ejected as a medium. Therefore, in a case where the discharge unit 2 and the manifold 3 are made of a material having electrical conductivity, at least the discharge unit 2, preferably the inner surface of the discharge unit 2 and the manifold 3 is required to obtain electrical insulation with respect to the electrode 4. On the other hand, it is necessary to provide an insulating coating.

Next, the electric field discharge control device will be described. FIG. 2 is a block diagram showing the configuration of the electric field discharge coating device, and the configuration of the electric field discharge control device is shown at 20 in FIG. 2, reference numeral 20 denotes an electric field discharge device, 21 denotes an electric field setting means, 22 denotes a pressure input means,
3 is a synchronization input means, 24 is a power generation means, and 25 is a monitor. The electric field discharge control device 20 is a device that supplies controlled electric power to the electric field discharge head.

The electric field setting means 21 generates a set electric field (data) based on an input for setting the form of the generated electric field. The form of the generated electric field includes direct current and alternating current. Also, as the AC waveform, a sine wave, a triangular wave, a rectangular wave,
There are no particular restrictions, including pulses and other waveforms. Here, a rectangular wave is a pulse train having a predetermined pulse width and a predetermined period, and a pulse is a waveform whose amplitude changes from a steady state and lasts for a finite time and returns to the original state. . The setting items of the form of the generated electric field include not only the types of the above-described waveforms but also frequencies, amplitude values, start conditions, end conditions, and the like. From the start to the end, the frequency, amplitude value, type of waveform,
Can be set to change in a predetermined pattern.

A plurality of such electric fields are stored in a storage device as preset data. The setting is performed by selecting preset data that matches the coating conditions from among the plurality of preset data. This selection is made in one of a mode performed by an operator's operation and a mode performed by inputting instruction data from the outside. The electric field setting means 21 generates a set electric field (data) based on the input.

The pressure input means 22 inputs the pressure applied by the pressurizing section 5 to the substance to be ejected introduced into the inside of the manifold 3. This pressure is generated by the electric field discharge control device 20.
It is used as data referred to when the electric field generating means 24 generates the set electric field.

The synchronization input means 23 inputs a synchronization signal including a signal for obtaining synchronization between the discharge position of the electric field discharge head and the coating position of the object to be coated. In the electric field ejection head, ejection holes are linearly and one-dimensionally arranged.
When coating is performed on a three-dimensional surface, it is necessary to scan an object to be coated with an electric field discharge head. Relative movement is performed in the scanning, and the movement may be, of course, either the electric field discharge head or the object to be coated, or both. In this scanning, the synchronization input means 23 inputs, as a synchronization signal, a signal indicating a position at which ejection is started, a signal indicating a position at which ejection is completed, a signal indicating a scanning speed, and the like.

The power generating means 24 generates a predetermined form of power based on the set electric field (data) and the synchronization signal. The power generation unit 24 basically generates the electric field in the form of the electric field determined by the set electric field as power, but at that time, synchronizes based on the synchronization signal. For example, when the discharge is started, during the discharge, or when the discharge is ended, the power control suitable for the discharge is controlled.

The electric field generating means 24 has a function of changing the form of the generated electric field so as to conform to the coating conditions. For example, the discharge amount of the discharge target substance discharged from the electric field discharge head is determined by the pressure inside the manifold 3. However, the ejection amount is affected by the set electric field, which will not be determined solely but will be described later in detail. Therefore, for example, the amplitude value, which is one of the parameters of the preset data, is changed to match the internal pressure of the manifold 3, which is one of the parameters of the coating condition.

The monitor 25 displays the waveform of the power output from the power generation means 24. The electric field set by the electric field setting means 21 is displayed, the pressure input by the pressure input means 22 is displayed, and the synchronization input means 23 is displayed by an input synchronization signal. These displays are used by the operator to operate the electric field discharge control device 20 and to confirm the state.

Next, the operation of the electric field discharge control device 20 in the above configuration will be described. First, the case of continuous coating will be described as an example (part 1) of the operation of the electric field discharge control device 20. In the electric field setting means 21, the voltage amplitude V
A rectangular wave having a _pp of 1 kV and a frequency F of 1 kHz is set, and the set electric field is generated. The power generation means 24 inputs the set electric field. On the other hand, the synchronization input means 22 keeps inputting a synchronization signal in scanning the object to be coated by the electric field discharge head. The electric field generating means 24 also receives the synchronization signal.

The electric field generating means 24 generates electric power (voltage waveform) based on the above-mentioned set electric field and supplies the electric power to the electric field discharge head at or just before the scanning timing when the discharge is started. During the ejection, the electric field generating means 24 maintains the electric power. Then, at or shortly after the scan timing when the ejection is completed, the electric field generation unit 24 stops supplying power to the electric field ejection head.

In the continuous coating as described above, the conditions under which the allowable range of the gap between the discharge hole and the object to be coated is wide and the spread of the discharge hole with respect to the hole diameter will be described. As a form of the electric field, a rectangular wave is more suitable than a sine wave or a triangular wave. Although the exact reason is not clear, it is presumed to be related to the fact that the rectangle contains many harmonic components.

The rectangular wave has a voltage amplitude V _pp of 10
It is appropriate that the voltage F ranges from 0 V to 10 kV and the frequency F ranges from 1 Hz to 10 kHz. From the viewpoint of ejection stability and ease of voltage control, it is more preferable to be in the range of 1 to 7 kV. Also, depending on the viscosity and material composition of the material to be ejected, the optimum frequency changes when the electric conductivity differs. In many cases, the optimum frequency increases with increasing electrical conductivity. If the frequency is low, deposition on the electrode or the like is likely to occur, which is not preferable. In addition, when the frequency is high, there is a problem that control becomes difficult due to the performance of the power supply. A preferred frequency range is 1 Hz to 10 kHz. From the viewpoints of ejection continuity and voltage control, the frequency is more preferably 100 Hz to 4 kHz.

Further, not only AC but also DC can be applied. In the case of direct current, it is appropriate that the range is 100 V to 10 kV. Regardless of the polarity in the case of direct current, there is no particular problem.

Next, the case of intermittent coating will be described as an example (part 2) of the operation of the electric field discharge control device 20. In the electric field setting means 21, a pulse having an absolute value Va of 1 kV and a width of 1 msec of external synchronous oscillation is set, and the set electric field is generated. The power generation means 24 inputs the set electric field. On the other hand, the synchronization input means 22 inputs a synchronization signal in scanning the object to be coated by the electric field discharge head, and the pressure input means 22 keeps inputting the pressure inside the manifold 3 by the pressurizing section 5. The electric field generating means 24 also inputs the synchronization signal and the pressure.

The electric field generating means 24 generates electric power (voltage waveform) based on the above-mentioned set electric field and supplies it to the electric field discharge head in accordance with the scanning timing at which the discharge is started. At that time, 1 kV of the absolute value Va of the voltage is corrected according to the above-mentioned pressure. As described above, the discharge amount is affected by the set electric field. The discharge of the discharge target substance in the electric field discharge head is related not only to the pressure applied to the discharge target substance inside the manifold 3 but also to the intensity of the electric field. In the electric field discharge head, it is necessary to apply a pressure exceeding a predetermined pressure in order to discharge the substance to be discharged. The substance to be ejected is ejected when a predetermined electric field is applied at a pressure that does not reach the threshold value but is close to the pressure.

When the application of the electric field is stopped, there are a case where the discharge is continued and a case where the discharge is stopped depending on the condition at that time. Here, it is assumed that the discharge is stopped (in this example). In that case, since the set electric field is a pulse,
The material to be ejected is intermittently ejected in response to the pulse. Thereby, intermittent coating can be performed. The electric field at the time of performing such an ejection operation is similar to the pressure, and it is necessary to apply an electric field exceeding the threshold electric field. The correction of the absolute value Va of the voltage in accordance with the pressure in the electric field generating means 24 is performed so as to generate electric power that applies an appropriate electric field exceeding the threshold electric field.

During discharge, the electric field generating means 24 generates electric power based on the above-mentioned set electric field and pressure and supplies it to the electric field discharge head in synchronization with the scanning timing for performing intermittent discharge. Then, the electric field generation unit 24 stops supplying electric power to the electric field ejection head in accordance with the scan timing at which the ejection ends.

As described above, the discharge amount can be controlled by the voltage intensity by utilizing the fact that the discharge occurs when the absolute value Va of the voltage is equal to or higher than the threshold voltage Vt. In this continuous coating, the allowable range of the gap between the discharge hole and the object to be coated is wide,
The conditions under which the spread of the discharge holes with respect to the hole diameter can be reduced will be described. The magnitude of the threshold voltage Vt depends on the material to be ejected and the arrangement of the electrodes, but is appropriately set in the range of 100 V to 3 kV. The ejection voltage is 1 as in the case of continuous ejection.
It is appropriate that it is 00 to 10 kV, and it is more preferable that it is in the range of 1 to 7 kV.

Next, an electric field discharge coating apparatus will be described. FIG. 2 is a block diagram showing the configuration of the electric field discharge coating apparatus. In FIG. 2, reference numeral 20 denotes an electric field discharge device, 21 denotes an electric field setting unit, 22 denotes a pressure input unit, 23 denotes a synchronous input unit,
24 is a power generation means, 25 is a monitor, 31a, 31
b, 31c and 31d are electric field discharge heads, 32 is a linear moving mechanism, 33 is supply means, and 34 is pressurized discharge control means. Of the components constituting the electric field discharge coating apparatus, the electric field discharge heads 31a, 31b, 31c, 31d and the electric field discharge control device 20 are the same as those described above, and therefore the description is omitted here.

The electric field discharge heads 31a, 31b, 31c,
31d is attached to the support of the linear movement mechanism 32. In FIG. 2, this portion is a top view, and the electric field discharge heads 31a and 31c are provided on one side of the support, and the electric field discharge heads 31b and 31d are provided on the other side of the support. It is impossible to form ejection holes on the side surface of the electric field ejection head. As described above, by providing the electric field discharge heads every other, an arrangement of the discharge holes having the entire length which cannot be realized by one electric field discharge head is realized.

The linear moving mechanism 32 includes a support, a linear guide (not shown) for guiding the movement of the support in a direction perpendicular to the longitudinal direction of the support, and a drive unit (for moving the support). (Not shown). The drive unit includes a control device that controls a moving distance from the origin, a moving speed, and the like. The control device of the drive unit controls the movement of the support at the time of coating, and outputs a signal relating to the position and the moving speed of the support. This signal is a synchronization signal input by the synchronization input means 23 described above.

Although not shown in FIG. 2, the linear moving mechanism 32
Below is provided a flat stage on which a plate-shaped object to be coated is placed. The stage has a configuration for positioning and fixing the object to be coated. For the positioning, for example, an abutting mechanism that determines the position by bringing a plate-shaped object to be abutted on its side is applied. For the fixing, for example, a vacuum suction mechanism is used in which the back surface of the plate-shaped object to be coated is vacuumed and fixed on the stage by suction. In addition, a ground-side electrode is arranged at the position of the stage facing the discharge section of the electric field head or on the entire surface of the stage.

The supply means 33 supplies the substance to be discharged to the introduction portions of the electric field discharge heads 31a, 31b, 31c, 31d. Usually, fine bubbles are not completely removed from the substance to be ejected because air bubbles are buried in the manufacturing process. The supply means 33 includes a defoaming device for removing the air bubbles. Further, the supply means 33 includes a pump, and the material to be discharged after defoaming is supplied to the electric field discharge heads 31a, 31b, 31 through a pipe by the pump.
c, 31d.

The pressurizing / discharging control means 34
The material to be ejected supplied to the introduction section is ejected from the ejection section by operating the pressurizing section 5 of 1a, 31b, 31c, 31d. That is, compressed air is sent into the manifold 3 to pressurize and discharge the material to be discharged, and the compressed air is released to release the pressure of the material to be discharged and stop discharging. Further, the pressurized discharge control means 34 outputs the air pressure inside the manifold 3 as a pressure signal. This pressure signal corresponds to the pressure input by the pressure input means 22 described above.

In the above configuration of the electric field discharge coating apparatus,
Next, an example of the operation of the electric field discharge coating apparatus will be described. First, a case where a phosphor is continuously coated on a substrate (object to be coated) of a plasma display panel on which partition walls are formed will be described. Usually, a glass substrate is used as the substrate. A partition having a glass material as a main component is formed on the glass substrate. The partition walls have a size of, for example, 50 μm in width, 150 μm in height, and 300 μm in pitch, and are formed in plural (many) in parallel with the surface of the glass substrate.

The substance to be ejected in this coating is an ink containing a phosphor in the composition (phosphor ink). The phosphor ink is applied between adjacent partitions and dried (fired) to form a phosphor layer between the partitions. Usually, the phosphor emits light of R,
G and B colors are used. Here, three coatings are performed, and the phosphor layers of the emission colors are sequentially formed. Assuming that the pitch of the partition walls is 300 μm, the pitch of the phosphor layer of a specific color is 900 μm. Therefore, the arrangement pitch of the ejection holes of the electric field ejection head is 900 μmm.

The substrate of the plasma display panel, on which the partition walls are formed, is placed on the stage of the electric field discharge coating apparatus in advance, aligned, vacuum-adsorbed and fixed. A predetermined gap is secured between the tip of the discharge section of the electric field discharge head and its substrate. Further, the phosphor ink is supplied to the introduction portion 1 of the electric field discharge head through the pipe by the supply means 33. The phosphor ink is introduced into the inside of the manifold 3, and when the upper surface of the phosphor ink reaches between the electrode 4 and the pressure unit 5, the supply of the phosphor ink is stopped. Also, the support of the moving mechanism of the electric field discharge coating device is returned to the origin position. This origin position is a position slightly before the position to be coated with respect to the moving direction of the support.

Next, based on the input of the coating start instruction, the moving mechanism of the electric field discharge coating apparatus operates to start moving the support on which the electric field discharge head is mounted. When it has moved to just before the position to be coated, the pressurizing / discharging control means 34 supplies compressed air to the pressurizing unit 5 to pressurize the inside of the manifold 3. At this time, the pressure inside the manifold 3 is a pressure at which the phosphor ink is ejected from the ejection unit 2. Simultaneously with the pressurization, the electric field discharge control device 20 outputs electric power based on a preset electric field (see the above description of the electric field discharge control device 20). The electric power is supplied to the electrode 4 of the electric field discharge head.

The electric field discharge head discharges the phosphor ink,
The phosphor ink flows down between the partition walls, and the coating is performed. Since the electric field discharge head and the substrate of the plasma display panel on which the partition walls are formed are relatively moving, a stripe-shaped coating film is formed so as to fill between the partition walls. At this time, due to the effect of the electric field, the allowable range of the gap between the ejection hole and the object to be coated is wide, and the spread of the ejection hole with respect to the hole diameter can be reduced. Therefore, highly accurate coating can be stably performed.

When the pressurizing / discharging control means 34 has moved to just before the position where the coating is completed, the supply of the compressed air to the pressurizing section 5 is stopped, and the compressed air inside the manifold 3 is released. At this time, the pressure inside the manifold 3 decreases, and becomes a pressure at which the phosphor ink is not discharged from the discharge unit 2. At the same time as the pressure reduction, the output of electric power from the electric field discharge control device 20 is stopped. Therefore, power is not supplied to the electrode 4 of the electric field discharge head. Next, when the movement stop position is reached, the moving mechanism of the electric field discharge coating apparatus stops moving the support on which the electric field discharge head is mounted.

With reference to FIGS. 3 and 4, the form of a coating apparatus that is appropriate when a stripe-shaped coating is accurately performed on an extremely narrow area of about 300 μm as in the above-described coating will be described. Details will be described. FIG. 3 shows the cross-sectional shape of the electric field discharge head and the arrangement of the object to be coated. 3, reference numeral 2 denotes a discharge unit, 3 denotes a manifold, 4a and 4b denote electrodes, 41 denotes a discharge hole, 42 denotes an object to be coated, and 43 denotes an object to be coated. G indicates a gap between the discharge unit 2 and the object 42 to be coated, and P indicates a position of the electrodes 4a and 4b. The material to be discharged is discharged from the inside of the manifold 3 through the discharge holes 41 into the air, and is transferred to the object to be coated 42, thereby performing coating.

As shown in FIG. 3, the electrode 4a is an electrode disposed in the manifold immediately adjacent to the inlet of the discharge hole 41. The electrode 4b is an electrode arranged at a distance. As described above, in the electric field discharge head, the electrodes are arranged inside the manifold 3 immediately near the entrance of the discharge hole 41. That is, the electrode 4 in FIG.
It is arranged at the position of a. Thus, the allowable range of the size of the gap G between the discharge hole and the object to be coated is wide, and the discharge state of the discharge target material is stabilized. At this time, the size of the gap G is 300 μm or more. This stabilizes the ejection state of the ejection target material.

The form of the electric field generated in the electric field discharge control device is a rectangular wave. The rectangular wave is an AC waveform that does not include a DC component when integrated. Then, the square wave voltage amplitude V _pp 100V~10k
V and the frequency F are rectangular waves of 1 kHz to 10 kHz. Thereby, the stability of the ejection state of the substance to be ejected is particularly remarkable.

This value is a value obtained by experience or experiment. FIG. 4 shows an example of experimental data on the form of the electric field coating apparatus and the ejection stability. In FIG. 4, the horizontal axis represents the value of the gap G between the discharge hole and the object to be coated, and the vertical axis represents the frequency F of the rectangular wave. 0 m for electrode position P
For the two cases of m and 7 mm, the boundary values (points) at which the stability of the discharge state of the substance to be discharged is obtained and the boundary areas (lines) connecting the boundary values are indicated by curves. Frequency F at the boundary
Is the region where the discharge state of the discharge substance is stable.

In the example shown in FIG.
The area where 0 mm is more stable than 7 mm is wider. The gap G has a local maximum value near 300 μm and a local minimum value near 400 μm, but a stable region is wide when the gap G is approximately 300 μm or more.

Next, the substance to be ejected will be described. The material to be ejected is a material that is liquid at the operating temperature and has conductivity. Preferably, the viscosity is 1000 to 1,000,000 cp
s and the electric conductivity is 10 ⁻¹⁰ to 10 ⁻⁴ Ω ⁻¹ c
It is a substance in the range of m- ¹ . The composition of the material to be ejected is basically composed of an organic or inorganic liquid, a binder, and a component (target substance) to be patterned which is determined depending on the application. Also, in its composition, if necessary, a dispersant,
Various additives such as an antifoaming agent and a thixotropic agent are mixed.

Examples of the liquid that can be used as the material to be ejected include water, COCl ₂ , and inorganic liquids.
HBr, HNO ₃ , H ₃ PO ₄ , H ₂ SO ₄ , SOCl ₂ , S
O ₂ Cl ₂ , FSO ₃ H and the like can be mentioned.

As the organic liquid, methanol, n-propanol, isopropanol, n-butanol, 2-methyl-1-propanol, tert-butanol, 4-
Methyl-2-pentanol, benzyl alcohol, α-
Alcohols such as terpineol, ethylene glycol, glycerin, diethylene glycol, and triethylene glycol; phenols such as phenol, o-cresol, m-cresol, and p-cresol; dioxane, furfural, ethylene glycol dimethyl ether, methylcellosolve, and ethyl Ethers such as cellosolve, butyl cellosolve, ethyl carbitol, butyl carbitol, butyl carbitol acetate, epichlorohydrin; ketones such as acetone, methyl ethyl ketone, 2-methyl-4-pentanone, acetophenone; formic acid Acetic acid, dichloroacetic acid, trichloroacetic acid, and other fatty acids; methyl formate, ethyl formate, methyl acetate, ethyl acetate, n-butyl acetate, isobutyl acetate, acetic acid-3
-Methoxybutyl, n-pentyl acetate, ethyl propionate, ethyl lactate, methyl benzoate, diethyl malonate, dimethyl phthalate, diethyl phthalate, diethyl carbonate, ethylene carbonate, ethylene propylene carbonate, cellosolve acetate, butyl carbitol acetate , Ethyl acetoacetate, methyl cyanoacetate, ethyl cyanoacetate, etc .; nitromethane, nitrobenzene, acetonitrile, propionitrile, succinonitrile, valeronitrile, benzonitrile, ethylamine, diethylamine, ethylenediamine, aniline, N-methylaniline , N, N-dimethylaniline, o-toluidine, p-
Toluidine, piperidine, pyridine, α-picoline,
2,6-lutidine, quinoline, propylenediamine, formamide, N-methylformamide, N, N-dimethylformamide, N, N-diethylformamide, acetamide, N-methylacetamide, N-methylpropionamide, N, N, N ', N'-tetramethylurea,
Nitrogen-containing compounds such as N-methylpyrrolidone; sulfur-containing compounds such as dimethyl sulfoxide and sulfolane; hydrocarbons such as benzene, p-cymene, naphthalene, cyclohexylbenzene, cyclohexane; and 1,1-dichloroethane; 2-dichloroethane, 1,1,1-trichloroethane, 1,1,1,2-tetrachloroethane,
1,1,2,2-tetrachloroethane, pentachloroethane, 1,2-dichloroethylene (cis-), tetrachloroethylene, 2-chlorobutane, 1-chloro-2-
Methylpropane, 2-chloro-2-methylpropane, bromomethane, tribromomethane, 1-bromopropane,
And the like, and halogenated hydrocarbons.

Of the above substances, those which are solid at room temperature are:
What is necessary is just to supply the liquid to the head after heating it to a temperature higher than its melting point. Such a method is, for example, a general method of a hot-melt type ink jet recording method.However, since a recording device needs to be provided with a heater section and warm-up takes time, quick drying is required. It is not used for anything other than a special purpose.

The boiling point of the liquid is important because it affects the degree of clogging at the opening. The preferred boiling point range is 105
C. to 300 C., more preferably 180 C. to 25 C.
0 ° C. If the temperature is lower than 150 ° C., clogging due to drying is apt to occur. Such a high-boiling liquid preferably accounts for 50% by mass or more of the total liquid in the substance to be ejected, more preferably 70% by mass or more.

The target substance to be dissolved or dispersed in the liquid described above is not particularly limited, except for coarse particles that may cause clogging at the nozzle. For example, conventionally known organic or inorganic coloring pigments, phosphors, dyes, magnetic substances, glitter pigments,
Matt pigments, conductive substances, ceramics and precursors thereof, and the like can be given.

It is preferable to add various binders in order to firmly adhere the target substance to the recording medium. Examples of the binder used include cellulose such as ethyl cellulose and derivatives thereof; alkyd resins; (meth) acrylic resins such as polymethacrylic acid and metal salts thereof; poly (meth) acrylamide resins such as poly N-isopropylacrylamide; Styrene resins such as polystyrene; various saturated and unsaturated polyester resins; polyolefin resins such as polypropylene; vinyl resins such as vinyl chloride / vinyl acetate copolymer; polycarbonate resins; epoxy resins; polyurethane resins; Amide resins such as benzoguanamine; urea resins; melamine resins; polyvinyl alcohol resins and their anionic cation modified; polyvinyl pyrrolidone and its copolymers; natural or semi-synthetic trees such as gelatin and soybean proteins; Or the like can be used. These resins may be used alone or as a mixture of two or more kinds in a compatible range.

[0069]

As described above, according to the electric field discharge head according to the first aspect of the present invention, the allowable range of the gap between the discharge hole and the object to be coated is wide, and the spread of the discharge hole with respect to the hole diameter is reduced. An electric field discharge head capable of performing the above-described operations is provided. Further, since the electrodes are arranged inside the manifold, the material to be ejected maintains electrical contact with the electrodes, and the action of the electric field is stabilized. Further, according to the electric field discharge head of the second aspect of the present invention, electrical insulation with respect to the electrodes is ensured by the discharge portion and the manifold formed of the electrically insulating material. Further, according to the electric field discharge head of the third aspect of the present invention, it is possible to equalize the action of the electrodes on the plurality of discharge holes formed in the discharge section and arranged linearly at predetermined intervals. Further, according to the electric field discharge head according to claim 4 of the present invention, the discharge state of the discharge target substance is stabilized. Also,
According to the electric field ejection head according to claim 5 of the present invention, the substance to be ejected is pressurized by the pressurizing portion of the electric field ejection head. According to the electric field discharge control device according to claim 6 of the present invention, the allowable range of the gap between the discharge hole and the object to be coated is wide, and the spread of the discharge hole with respect to the hole diameter can be reduced. Is provided. In addition, while synchronizing the discharge position of the electric field discharge head with the coating position of the object to be coated, it is possible to supply the electric field discharge head with a predetermined form of power determined based on the setting input. Further, according to the electric field discharge control device according to claim 7 of the present invention, the pressure in the pressurizing section can be reflected on the electric power generated by the electric field generating means. Further, claim 8 of the present invention
According to the electric field discharge control device according to (1), the above-mentioned effects (such as claim 5) are remarkable due to the high frequency component included in the rectangular wave. Further, according to the electric field discharge control device of the ninth aspect of the present invention, since the ionization of the discharge target substance does not occur, the restriction on the discharge target substance is small. Further, the above-mentioned effects are remarkable. Further, according to the electric field discharge control device of the tenth aspect of the present invention, the above-mentioned effects are particularly remarkable. According to the eleventh aspect of the present invention, it is possible to perform intermittent ejection by setting the form of the generated electric field to a pulse. Further, according to the electric field discharge control device according to the twelfth aspect of the present invention, the electric field coating apparatus can have a wide allowable range of the gap between the discharge hole and the object to be coated, and can reduce the spread of the discharge hole with respect to the hole diameter. Is provided.

[Brief description of the drawings]

FIG. 1 is a diagram illustrating an example of a configuration of an electric field discharge head according to the present invention.

FIG. 2 is a block diagram showing a configuration of an electric field discharge coating apparatus.

FIG. 3 is a diagram showing an arrangement of an object to be coated together with a sectional shape of an electric field discharge head.

FIG. 4 is a diagram showing an example of experimental data relating to the form of an electric field coating apparatus and ejection stability.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Introducing part 2 Discharge part 3 Manifold 4 Electrode 5 Pressurization part 20 Electric field discharge device 21 Electric field setting means 22 Pressure input means 23 Synchronization input means 24 Power generation means 25 Monitor 31a, 31b, 31c, 31d Electric field discharge head 32 Linear movement mechanism 33 supply means 34 pressurized discharge control means

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI theme coat ゛ (reference) B05D 1/04 B41J 3/04 101Z 101Y F term (reference) 2C056 EA04 EC07 EC32 EC38 FB01 4D075 AA09 AA35 DA06 4F034 AA04 BA07 BB15 4F035 AA04 BA02 BB03 CD03 4F041 AA02 AB01 BA04 BA13 BA21 BA38

Claims (12)

[Claims] 1. An introduction section for introducing a substance to be ejected,
A discharge unit formed with a plurality of discharge holes arranged linearly at predetermined intervals, and a manifold serving as a passage for temporarily storing the substance to be discharged introduced from the introduction unit and leading to the discharge unit,
Electrode (voltage side electrode) arranged inside the manifold
Wherein the at least the discharge unit is electrically insulated from the electrode. 2. The electric field ejection head according to claim 1, wherein at least the ejection section is formed of an electrically insulating material. 3. The electric field discharge head according to claim 1, wherein the electrodes have a shape extending linearly in the direction in which the linearly arranged discharge portions are arranged. 4. The electric field discharge head according to claim 1, wherein the electrode is arranged in the inside of the manifold immediately adjacent to an entrance of the discharge hole. 5. The electric field ejection head according to claim 1, further comprising a pressurizing section for pressurizing the material to be ejected inside the manifold. 6. An electric field discharge control device applied to the electric field discharge head according to claim 1, wherein the electric field setting means generates a set electric field based on an input for setting a form of the generated electric field. Synchronization input means for inputting a synchronization signal including a signal for obtaining synchronization between the ejection position of the electric field ejection head and the coating position on the object to be coated, and a predetermined input based on the set electric field and the synchronization signal. An electric field discharge control device, comprising: a power generation unit that generates electric power in a form. 7. The electric field discharge control device according to claim 6, further comprising pressure input means for inputting a pressure for pressurizing the substance to be ejected inside the manifold in the pressurizing section, wherein the electric field generating means includes: An electric field discharge control device for generating the electric power based on pressure. 8. The electric field discharge control device according to claim 6, wherein the form of the generated electric field is a rectangular wave when continuous discharge is performed in the electric field discharge head. apparatus. 9. The electric field discharge control device according to claim 8, wherein the rectangular wave has an AC waveform that does not include a DC component when integrated. 10. The electric field discharge control device according to claim 8, wherein the rectangular wave has a voltage amplitude V _pp of 100V.
An electric field discharge control device characterized by being a rectangular wave having a frequency of 1 to 10 kV and a frequency F of 1 to 10 kHz. 11. The electric field ejection control device according to claim 6, wherein the form of the generated electric field is a pulse when intermittent ejection is performed in the electric field ejection head. . 12. An electric field discharge coating apparatus comprising: the electric field discharge head according to claim 1; and the electric field discharge control device according to claim 6; Supply means for supplying a substance to the introduction section of the electric field discharge head, and pressurized discharge for discharging the substance to be discharged supplied to the introduction section by operating the pressurizing section of the electric field discharge head from the discharge section. Control means, electric field discharge control means for controlling a discharge state of the substance to be discharged, which is discharged by the electric field discharge head, and a synchronous signal indicating the transfer state while transferring the electric field discharge means and / or the object to be coated. An electric field discharge coating apparatus comprising: a transfer means for outputting; and a ground-side electrode arranged at a position facing the discharge section.