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JP2000118163A - Unwoven fabric for heat sensitive stencil printing original paper - Google Patents

Unwoven fabric for heat sensitive stencil printing original paper

Info

Publication number
JP2000118163A
JP2000118163A JP10297069A JP29706998A JP2000118163A JP 2000118163 A JP2000118163 A JP 2000118163A JP 10297069 A JP10297069 A JP 10297069A JP 29706998 A JP29706998 A JP 29706998A JP 2000118163 A JP2000118163 A JP 2000118163A
Authority
JP
Japan
Prior art keywords
fiber
nonwoven fabric
constituting
stencil printing
base paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10297069A
Other languages
Japanese (ja)
Inventor
Kenji Kida
健次 喜田
Masakado Takahashi
正矩 高橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP10297069A priority Critical patent/JP2000118163A/en
Publication of JP2000118163A publication Critical patent/JP2000118163A/en
Pending legal-status Critical Current

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  • Printing Plates And Materials Therefor (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)

Abstract

PROBLEM TO BE SOLVED: To strengthen the nerve of a fabric and permit the restriction of generation of creasing even when the weight of the fabric is reduced while improving a printed image by a method wherein both of a principal fiber, constituting the part of a skeleton and the non-oriented fiber, constituting the part of binder, are formed of a polyester, whose principal constituent is polyethylene naphthalate. SOLUTION: An unwoven fabric is constituted of a principal fiber, constituting the part of a skeleton, and a non-oriented fiber, constituting the part of binder. Both of the principal fiber, constituting the part of a skeleton, and the non-oriented fiber, constituting the part of binder and low in the orientation of fibers, are constituted of a polyester, whose principal constituent is polyethylene naphthalate, and whose ethylene naphthalate unit is at least 80 mol% or more in a repeating unit. According to this method, the nerve of the fabrics can be strengthened and the fiber can be used even when the weight thereof is reduced whereby a printing press can be compacted.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、感熱孔版印刷原紙
用不織布に関する。更に詳しくは、感熱孔版印刷原紙を
構成する多孔性支持体に用いられる不織布に関し、特に
腰が強く、低目付化してもしわが発生しにくく、良好な
画像をもたらす感熱孔版印刷原紙用不織布に関するもの
である。
The present invention relates to a nonwoven fabric for heat-sensitive stencil printing base paper. More specifically, the present invention relates to a non-woven fabric for a heat-sensitive stencil printing paper, which is used for a porous support constituting the heat-sensitive stencil printing paper, and particularly has a strong stiffness, hardly generates wrinkles even when the basis weight is reduced, and provides a good image. is there.

【0002】[0002]

【従来の技術】従来、感熱孔版印刷原紙としては、塩化
ビニリデン−塩化ビニル共重合体フィルム、ポリプロピ
レンフィルムあるいはポリエステルフィルムのような熱
可塑性樹脂フィルムとマニラ麻などの天然繊維を抄紙し
た薄葉紙等の多孔性支持体とを接着剤で貼合せた構造の
ものがよく知られている(特公昭41−7623号公報
または特開昭51−2513号公報)。しかしながらマ
ニラ麻等の天然繊維を含む薄葉紙は、湿度の影響を受け
やすいため、特に梅雨時のような多湿時には、吸湿伸長
する。このため、熱可塑性樹脂フィルムと貼合せた原紙
は、カールしたり、寸法の変化が大きいという欠点があ
った。
2. Description of the Related Art Conventionally, as heat-sensitive stencil printing paper, porous paper such as thin paper made of a thermoplastic resin film such as vinylidene chloride-vinyl chloride copolymer film, polypropylene film or polyester film and natural fibers such as manila hemp has been used. A structure in which a support and a support are bonded together with an adhesive is well known (JP-B-41-7623 or JP-A-51-2513). However, tissue paper containing natural fibers such as Manila hemp is susceptible to humidity, so it absorbs and expands especially in humid conditions such as during the rainy season. For this reason, the base paper laminated with the thermoplastic resin film has a drawback that it is curled and changes in dimensions are large.

【0003】また、多孔性支持体として天然繊維に一部
化学繊維を混抄したものを用いたり(特公昭48−82
17号公報または特開昭60−217197号公報)、
多孔性支持体全体に合成樹脂を含浸させることが提案さ
れているが(特公昭55−47997号公報)、未だ満
足すべきものは得られていない。例えば、化学繊維を混
抄した多孔性支持体は、化学繊維が天然繊維との接着性
に劣るため湿潤時の寸法安定化に殆ど寄与しないし、多
孔性支持体全体に合成樹脂を含浸させた場合、印刷イン
クの透過不良に基づく印刷鮮明性低下が避けられない。
[0003] As a porous support, a mixture of natural fibers and some synthetic fibers may be used (Japanese Patent Publication No. 48-82).
No. 17 or JP-A-60-217197),
Although it has been proposed to impregnate the entire porous support with a synthetic resin (Japanese Patent Publication No. 55-47997), no satisfactory resin has yet been obtained. For example, a porous support mixed with a chemical fiber hardly contributes to dimensional stabilization when wet because the chemical fiber has poor adhesion to natural fibers, and a case where the entire porous support is impregnated with a synthetic resin. In addition, a reduction in print sharpness due to poor transmission of the printing ink is inevitable.

【0004】さらには、多孔性支持体としてポリエステ
ルのような疎水性繊維を100%用いた不織布も提案さ
れているが(特開昭59−2896号公報、特開昭60
−38193号公報、特開平2−67197号公報また
は特開平3−76894号公報等)、湿潤時の寸法安定
性という点では改善が見られるものの、製版時にサーマ
ルヘッドから受ける熱で収縮がおこる欠点のあることが
わかった。
Further, a nonwoven fabric using 100% of a hydrophobic fiber such as polyester as a porous support has been proposed (JP-A-59-2896 and JP-A-60-90).
JP-A-38193, JP-A-2-67197 or JP-A-3-76894), although the dimensional stability at the time of wetting is improved, but shrinkage occurs due to heat received from the thermal head during plate making. I found that there was.

【0005】また、印刷機内での原紙の供給が連続ロー
ル方式であり、印刷機のコンパクト化のために、原紙の
搬送を可能にするだけの剛性が、目付量ができるだけ小
さいところで達成される多孔性支持体が求められ、上記
のような従来の提案では未だ満足すべきものではなかっ
た。
[0005] In addition, a continuous roll system is used to supply the base paper in the printing press. In order to make the printing press compact, rigidity enough to allow the base paper to be conveyed has a rigidity that can be achieved in a place where the basis weight is as small as possible. However, conventional supports such as those described above have not been satisfactory.

【0006】[0006]

【発明が解決しようとする課題】本発明は、多孔性支持
体として用いられる不織布を構成する繊維を規定するこ
とで前記のような問題点を解決し、特に腰が強く、低目
付化してもしわの発生が抑制され、良好な画像をもたら
す不織布を提供しようとするものである。
SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems by defining the fibers constituting the non-woven fabric used as a porous support. An object of the present invention is to provide a nonwoven fabric which suppresses wrinkles and provides a good image.

【0007】[0007]

【課題を解決するための手段】上述した目的を達成する
本発明は、骨格部分を構成する主体繊維およびバインダ
ー部分を構成する未延伸繊維のいずれもがポリエチレン
ナフタレートを主体とするポリエステルからなることを
特徴とする感熱孔版印刷用不織布である。
According to the present invention, which achieves the above-mentioned object, both the main fiber constituting the skeleton portion and the undrawn fiber constituting the binder portion are made of a polyester mainly composed of polyethylene naphthalate. A non-woven fabric for thermosensitive stencil printing characterized by the following.

【0008】[0008]

【発明の実施の形態】以下、さらに詳しく本発明につい
て説明をする。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail.

【0009】本発明における不織布は、骨格部分を構成
する主体繊維およびバインダー部分を構成する熱接着効
果を有する未延伸繊維からなるものである。
The nonwoven fabric according to the present invention comprises a main fiber constituting a skeleton portion and an undrawn fiber having a thermal bonding effect constituting a binder portion.

【0010】未延伸繊維を用いず接着剤などにより主体
繊維同士を接着したものは、接着剤がインキの透過を阻
害し、画像鮮明性が低下するため好ましくない。
[0010] Those in which the main fibers are bonded to each other with an adhesive or the like without using undrawn fibers are not preferable because the adhesive inhibits the transmission of ink and lowers the image clarity.

【0011】本発明において、骨格部分を構成する主体
繊維およびバインダー部分を構成する未延伸繊維のいず
れもがポリエチレンナフタレートを主体とするポリエス
テルからなる。
In the present invention, both the main fibers constituting the skeleton portion and the undrawn fibers constituting the binder portion are made of a polyester mainly composed of polyethylene naphthalate.

【0012】ポリエチレンナフタレートを主体とするポ
リエステルとは、繰り返し単位の少なくとも70モル%
をエチレンナフタレート単位とするポリエステルであ
る。好ましくは80モル%以上、さらに好ましくは85
モル%以上である。主体繊維を構成するポリエステルに
おいてエチレンナフタレート単位が70モル%未満であ
ると、剛性も低下するため好ましくない。また、未延伸
繊維を構成するポリエステルにおいてエチレンナフタレ
ート単位が70モル%未満であると、剛性も低下するば
かりか、製版時の収縮も大きくなり好ましくない。な
お、繰り返し単位の30モル%以下であれば以下の共重
合成分によって変性されたものであってもよい。
[0012] Polyester mainly composed of polyethylene naphthalate means at least 70 mol% of repeating units.
Is an ethylene naphthalate unit. Preferably it is 80 mol% or more, more preferably 85 mol% or more.
Mol% or more. If the content of the ethylene naphthalate unit in the polyester constituting the main fiber is less than 70 mol%, the rigidity is undesirably reduced. In addition, if the content of the ethylene naphthalate unit in the polyester constituting the undrawn fiber is less than 70 mol%, not only the rigidity is lowered but also the shrinkage during plate making is undesirably large. In addition, if it is 30 mol% or less of the repeating unit, it may be modified with the following copolymer component.

【0013】共重合成分として、ジカルボン酸成分やジ
オール成分などの2価のエステル形成性官能基を有する
成分を挙げることができ、さらに具体的には、テレフタ
ル酸、イソフタル酸、4,4’−ジフェニルジカルボン
酸、4,4’−ジフェニルエーテルジカルボン酸、4,
4’−ジフェニルスルホンジカルボン酸、5−ナトリウ
ムスルホイソフタル酸などの芳香族ジカルボン酸、コハ
ク酸、アジピン酸、スベリン酸、セバシン酸などの脂肪
族ジカルボン酸、1,4−シクロヘキサンジカルボン酸
などの脂環族ジカルボン酸、1,2−プロパンジオー
ル、1,3−プロパンジオール、ネオペンチルグリコー
ル、1,3−ブタンジオール、1,4−ブタンジオー
ル、1,5−ペンタンジオール、1,6−ヘキサンジオ
ール、1,4−シクロヘキサンジメタール、ジエチレン
グリコール、ポリアルキレングリコール、2,2’−ビ
ス(4’−β−ヒドロキシエトキシフェニル)プロパン
等のジオールを挙げることができる。これらは1種のみ
用いてもよく、2種以上併用してもよく、さらには、ヒ
ドロキシ安息香酸等のオキシ酸等を一部共重合してもよ
い。
Examples of the copolymer component include components having a divalent ester-forming functional group such as a dicarboxylic acid component and a diol component. More specifically, terephthalic acid, isophthalic acid, 4,4'- Diphenyl dicarboxylic acid, 4,4′-diphenyl ether dicarboxylic acid, 4,
Aromatic dicarboxylic acids such as 4'-diphenylsulfone dicarboxylic acid and 5-sodium sulfoisophthalic acid, aliphatic dicarboxylic acids such as succinic acid, adipic acid, suberic acid and sebacic acid, and alicyclic rings such as 1,4-cyclohexanedicarboxylic acid Aliphatic dicarboxylic acid, 1,2-propanediol, 1,3-propanediol, neopentyl glycol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, Examples thereof include diols such as 1,4-cyclohexanedimetal, diethylene glycol, polyalkylene glycol, and 2,2′-bis (4′-β-hydroxyethoxyphenyl) propane. These may be used alone or in combination of two or more, and further, an oxyacid such as hydroxybenzoic acid may be partially copolymerized.

【0014】本発明における主体繊維は、複屈折△nが
0.15〜0.25の高配向であることが好ましく、さ
らに好ましくは0.18〜0.25である。複屈折率が
0.15から0.25の範囲であれば、腰の強さが十分
であり好ましい。
The main fiber in the present invention preferably has a highly oriented birefringence Δn of 0.15 to 0.25, more preferably 0.18 to 0.25. When the birefringence is in the range of 0.15 to 0.25, the stiffness is sufficient, which is preferable.

【0015】本発明においてバインダー部分を構成する
未延伸繊維は、繊維の配向が低いものであり、Δnとし
ては0.12以下が好ましい。より好ましくは0.10
以下、さらに好ましくは0.08以下である。繊維の配
向が低いと主体繊維との接着力が向上し、繊維の脱落を
より引き起こしにくいため好ましい。△nが0.12以
下であれば十分な接着力を得ることができる。
In the present invention, the unstretched fiber constituting the binder portion has a low fiber orientation, and Δn is preferably 0.12 or less. More preferably 0.10
Or less, more preferably 0.08 or less. When the orientation of the fiber is low, the adhesive force with the main fiber is improved, and the fiber is less likely to fall off, which is preferable. If Δn is 0.12 or less, a sufficient adhesive strength can be obtained.

【0016】本発明の不織布を構成する主体繊維の繊維
径は1〜12μmが好ましく、3〜8μmがより好まし
い。また、未延伸繊維の繊維径は4〜30μmが好まし
く、5〜20μmがより好ましい。繊維径が小さいほど
印刷画像は均一となり好ましいが、製造の容易性から上
記範囲が好ましい範囲となる。主体繊維、未延伸繊維と
も、断面形状はいかなるものでもよいが、未延伸繊維は
扁平なものが好ましく、その場合、断面の長径に相当す
る部分が上記繊維径の範囲であることが特に好ましい。
さらに主体繊維、未延伸繊維とも連続繊維であってもよ
いが、1〜15mm程度の短繊維であることがより好ま
しい。
The fiber diameter of the main fibers constituting the nonwoven fabric of the present invention is preferably 1 to 12 μm, more preferably 3 to 8 μm. Further, the fiber diameter of the undrawn fiber is preferably 4 to 30 μm, more preferably 5 to 20 μm. The smaller the fiber diameter is, the more uniform the printed image becomes, which is preferable. However, the above range is a preferable range from the viewpoint of ease of production. Both the main fiber and the unstretched fiber may have any cross-sectional shape, but the unstretched fiber is preferably flat. In this case, it is particularly preferable that the portion corresponding to the major axis of the cross section is within the above-mentioned fiber diameter.
Further, both the main fiber and the undrawn fiber may be continuous fibers, but more preferably short fibers of about 1 to 15 mm.

【0017】本発明において、主体繊維と、バインダー
部分を構成する未延伸繊維との混合比率は50:50〜
95:5の範囲が好ましく、70:30〜90:10の
範囲がより好ましい。主体繊維の混合比率が高いと、腰
の強さが増し、未延伸繊維の混合比率が増加すると繊維
の脱落を抑えることができ、上記範囲がバランスできる
好ましい範囲となる。
In the present invention, the mixing ratio of the main fiber and the undrawn fiber constituting the binder portion is 50:50 to 50:50.
A range of 95: 5 is preferred, and a range of 70:30 to 90:10 is more preferred. When the mixing ratio of the main fibers is high, the stiffness increases, and when the mixing ratio of the undrawn fibers increases, the falling off of the fibers can be suppressed, and the above range is a preferable range in which the above range can be balanced.

【0018】本発明の不織布の目付量は、好ましくは2
〜15g/m2 であり、より好ましくは3〜12g/m
2 である。目付量が2〜15g/m2 であると十分な強
度が得られる。また、目付量が3〜12g/m2 では、
さらに十分な強度とともに良好な画像が得られる。
The basis weight of the nonwoven fabric of the present invention is preferably 2
1515 g / m 2 , more preferably 3 to 12 g / m 2
2 If the basis weight is 2 to 15 g / m 2 , sufficient strength can be obtained. When the basis weight is 3 to 12 g / m 2 ,
Further, a good image can be obtained with sufficient strength.

【0019】本発明の不織布の厚さは、好ましくは15
〜70μm、より好ましくは25〜60μmである。厚
さが15〜70μmであると、インクの透過性が良好
で、画像性が良い。また、厚さが25〜60μmである
と、排版時のインクのロスも少ない。
The thickness of the nonwoven fabric of the present invention is preferably 15
To 70 μm, more preferably 25 to 60 μm. When the thickness is 15 to 70 μm, ink permeability is good and image quality is good. Further, when the thickness is 25 to 60 μm, loss of ink at the time of plate discharge is small.

【0020】本発明の不織布の引張弾性率は、好ましく
は0.15N/mm以上、より好ましくは0.18N/
mm以上である。引張弾性率が0.15N/mm以上で
あると、原紙として印刷機内で搬送されるときのしわの
発生がない。また、0.18N/mm以上であると、印
刷中の伸びが抑制される。
The tensile modulus of the nonwoven fabric of the present invention is preferably 0.15 N / mm or more, more preferably 0.18 N / mm.
mm or more. When the tensile modulus is 0.15 N / mm or more, no wrinkles occur when the base paper is conveyed in the printing press. When it is 0.18 N / mm or more, elongation during printing is suppressed.

【0021】本発明の不織布は、主としてポリエステル
からなる繊維を対象にしているが、不織布の剛性、イン
クの透過性、収縮性等その他基本性能を損なわない範囲
の第3成分を混合することは差し支えない。第3成分と
して、コウゾ、ミツマタ、マニラ麻等の天然繊維、ポリ
ビニルアルコール系、アクリル系あるいはアラミド等の
合成繊維を挙げることができる。
The nonwoven fabric of the present invention is mainly intended for fibers made of polyester. However, it is acceptable to mix a third component which does not impair the basic performance such as rigidity of the nonwoven fabric, ink permeability and shrinkage. Absent. Examples of the third component include natural fibers such as cucumber, honey bean, and manila hemp, and synthetic fibers such as polyvinyl alcohol, acrylic, and aramid.

【0022】次に本発明の不織布の製造方法を、以下に
説明する。
Next, the method for producing the nonwoven fabric of the present invention will be described below.

【0023】本発明においてポリエステルは、例えば、
ジカルボン酸成分をジオール成分と直接エステル化反応
させた後、この反応の生成物を減圧下で加熱して余剰の
ジオール成分を除去しつつ重縮合させることによって製
造する方法や、ジカルボン酸成分としてジアルキルエス
テルを用い、これとジオール成分とでエステル交換反応
させた後、上記と同様に重縮合させることによって製造
する方法等がある。この際、必要に応じて、反応触媒と
してアルカリ金属、アルカリ土類金属、マンガン、コバ
ルト、亜鉛、アンチモン、ゲルマニウム、チタン化合物
を用いることもできる。
In the present invention, the polyester is, for example,
After the dicarboxylic acid component is directly esterified with the diol component, the product of this reaction is heated under reduced pressure to remove the excess diol component and polycondensate the dicarboxylic acid component. There is a method of using an ester, performing a transesterification reaction between the ester and a diol component, and then performing polycondensation in the same manner as described above. At this time, if necessary, an alkali metal, an alkaline earth metal, manganese, cobalt, zinc, antimony, germanium, and a titanium compound can be used as a reaction catalyst.

【0024】本発明においてポリエステルには、必要に
応じて、難燃剤、熱安定剤、酸化防止剤、紫外線吸収
剤、帯電防止剤、顔料、脂肪酸エステル、ワックス等の
有機滑剤あるいはポリシロキサン等の消泡剤等を配合す
ることができる。
In the present invention, if necessary, the polyester may contain an organic lubricant such as a flame retardant, a heat stabilizer, an antioxidant, an ultraviolet absorber, an antistatic agent, a pigment, a fatty acid ester, a wax, or a polysiloxane. A foaming agent and the like can be blended.

【0025】未延伸繊維および主体繊維に用いるポリエ
ステルは、ポリエチレンナフタレートを主体とするもの
であればよく、共重合、添加物等により多少異なっても
よい。 次いで未延伸繊維は、ポリエチレンナフタレー
トを主体とするポリエステルを用いて溶融紡糸法によっ
て得ることができる。
The polyester used for the unstretched fiber and the main fiber may be one mainly composed of polyethylene naphthalate, and may slightly vary depending on copolymerization, additives and the like. Next, undrawn fibers can be obtained by a melt spinning method using a polyester mainly composed of polyethylene naphthalate.

【0026】また、主体繊維はポリエチレンナフタレー
トを主体とするポリエステルを用いて、溶融紡糸後延伸
することによって得ることができる。
The main fiber can be obtained by using a polyester mainly composed of polyethylene naphthalate and then subjecting it to melt spinning and then drawing.

【0027】主体繊維、未延伸繊維のそれぞれの繊維
は、所定の長さに切断し短繊維とすることが好ましい。
Each of the main fiber and the undrawn fiber is preferably cut into a predetermined length to be a short fiber.

【0028】得られたそれぞれの繊維を、所定の割合と
なるように水中にパルパーあるいはビーターで混合分散
させた後、円網、短網あるいは長網抄紙機で抄造し、次
いで熱カレンダー圧着することで原綿が得られる。
Each of the obtained fibers is mixed and dispersed in water with a pulper or a beater so as to have a predetermined ratio, and then formed with a circular, short or long net paper machine, and then subjected to hot calender pressing. The raw cotton is obtained.

【0029】本発明の不織布は、カレンダー条件とし
て、例えば、抄紙ドライヤー温度110〜150℃で抄
造された抄上げシートを、主体繊維、未延伸繊維それぞ
れのポリエステルの融解温度のうち低い方の温度以下の
温度、例えば180〜240℃で圧着して得られる。
For the nonwoven fabric of the present invention, the calendering conditions are as follows. For example, the papermaking sheet formed at a papermaking dryer temperature of 110 to 150 ° C. is heated to a temperature lower than the lower one of the melting temperatures of the polyesters of the main fiber and the undrawn fiber. At a temperature of, for example, 180 to 240 ° C.

【0030】カレンダー加工方法としては、一段法でも
多段法でも使用することができる。
As the calendering method, either a single-stage method or a multi-stage method can be used.

【0031】また、必要に応じて、不織布を構成する原
綿あるいは不織布本体に帯電防止加工をほどこしてもよ
いし、また不織布のインク透過性を挙げるために親水化
処理を行うことも可能である。
If necessary, antistatic treatment may be applied to the raw cotton or the nonwoven fabric constituting the nonwoven fabric, or a hydrophilic treatment may be performed to increase the ink permeability of the nonwoven fabric.

【0032】本発明の不織布を用いて感熱孔版原紙とす
るため、熱可塑性樹脂フィルムと接着するには、例え
ば、フィルム側または不織布側にアクリル系、塩化ビニ
ル系、ポリエステル系、酢酸ビニル系、ウレタン系等の
接着剤を乾燥塗布量が0.1〜1g/m2 になるように
塗布し、重ね合わせて圧着、加熱、乾燥もしくは紫外線
等を照射することにより可能である。さらに、サーマル
ヘッドとの融着を防止するため、フッ素系、シリコーン
系や界面活性剤などの離型剤をフィルムの不織布面側と
反対面に設けることもできる。
In order to form a heat-sensitive stencil sheet using the nonwoven fabric of the present invention, for example, an acrylic, vinyl chloride, polyester, vinyl acetate, urethane, etc. It is possible to apply an adhesive of a system or the like so that the dry application amount is 0.1 to 1 g / m 2 , and to superimpose and press, heat, dry, or irradiate with ultraviolet rays or the like. Further, in order to prevent fusion with the thermal head, a release agent such as a fluorine-based, silicone-based, or surfactant may be provided on the surface of the film opposite to the nonwoven fabric side.

【0033】[0033]

【特性の測定方法】(1)平均繊維径:平均繊維径は、
不織布の任意の10箇所を電子顕微鏡で倍率2000倍
で10枚の写真撮影を行い、1枚の写真につき任意の1
5本の繊維の直径を測定しこれを10枚の写真について
行い、合計150本の繊維径を測定してその平均値を表
したものである。
[Method of measuring characteristics] (1) Average fiber diameter: The average fiber diameter is
Ten photographs were taken of arbitrary 10 places of the non-woven fabric with an electron microscope at a magnification of 2000 times, and arbitrary 1 was taken per photograph.
The diameters of five fibers were measured, and the measurement was performed on ten photographs. The diameters of a total of 150 fibers were measured, and the average value was shown.

【0034】(2)複屈折(Δn):偏光顕微鏡によっ
て光源にナトリウムランプを用い、試料をα−ブロムナ
フタリン浸漬下Berekコンペンセーター法でレター
デーションを求めて算出した。
(2) Birefringence (Δn): A birefringence (Δn) was calculated by using a sodium lamp as a light source with a polarizing microscope and determining the retardation of the sample by the Berk compensator method while immersing the sample in α-bromonaphthalene.

【0035】(3)目付量:不織布を20×20cmに
切り取りその重量を測定して1平方メートル当たりの重
量に換算した値を用いた。
(3) Weight per unit area: A nonwoven fabric was cut into a size of 20 × 20 cm, the weight was measured, and the value converted to the weight per square meter was used.

【0036】(4)引張弾性率:原紙を長さ方向または
幅方向に、20mm×150mm切り取り、“テンシロ
ン”引張試験機(東洋測器(株)製)のエアチャックに
把持して弾性率を測定した。測定条件は、チャック間隔
50mm、引張速度50mm/分とし、荷重−伸び線図
(S−Sカーブ)を記録した。S−Sカーブの初期の立
ち上がり勾配から、伸度1%における引張荷重をサンプ
ル幅で除して算出した。
(4) Tensile elastic modulus: A base paper was cut in a length direction or a width direction by 20 mm × 150 mm and gripped by an air chuck of a “Tensilon” tensile tester (manufactured by Toyo Sokki Co., Ltd.) to determine the elastic modulus. It was measured. The measurement conditions were a chuck interval of 50 mm and a tensile speed of 50 mm / min, and a load-elongation diagram (SS curve) was recorded. It was calculated by dividing the tensile load at an elongation of 1% by the sample width from the initial rising slope of the SS curve.

【0037】(5)着版じわ:原紙を理想科学工業
(株)製“RISOGRAPH”GR375に供給し
て、無地のものを原稿として製版動作を行った。製版動
作後、版胴に巻き付いた原紙の状態を目視観察した。こ
れを5回繰り返し、次の基準で判定した。
(5) Plate formation wrinkle: The base paper was supplied to "RISOGRAPH" GR375 manufactured by Riso Kagaku Kogyo Co., Ltd., and a plate making operation was performed using a plain paper as an original. After the plate making operation, the state of the base paper wound around the plate cylinder was visually observed. This was repeated five times and judged according to the following criteria.

【0038】しわの発生が、全くないものを、「○」 しわが、端部にわずかに見られたのが5回中2回以内で
あるものを、「△」 5回中3回以上しわが、見られたものを、「×」 「○」または「△」が、実用上使用できるレベルであ
る。
When no wrinkles were generated, the result was evaluated as “○”. When wrinkles were slightly observed at the end within 2 times out of 5 times, “△” was performed 3 times or more out of 5 times. In the case of what I saw, "x", "o" or "△" is a practically usable level.

【0039】(6)印刷じわ:原紙を理想科学工業
(株)製“RISOGRAPH”GR375に供給し
て、黒ベタのものを原稿として製版、印刷を行った。1
00枚の印刷を行った後、版胴に巻き付いた原紙の状態
を目視観察し、次の基準で判定した。
(6) Print wrinkle: The base paper was supplied to RISOGRAPH GR375 manufactured by Riso Kagaku Kogyo Co., Ltd., and plate making and printing were performed using a black solid document as an original. 1
After printing 00 sheets, the state of the base paper wrapped around the plate cylinder was visually observed and judged according to the following criteria.

【0040】しわの発生が、全くないものを、「○」 しわが、端部にわずかに見られたのものを、「△」 しわが、複数または中央部に見られたものを、「×」 「○」または「△」が、実用上使用できるレベルであ
る。
[0040] Wrinkles were not observed at all. "O". Wrinkles were slightly observed at the edges. "△". Wrinkles were observed at a plurality or at the center. “○” or “△” is a practically usable level.

【0041】(7)画像性:原紙を理想科学工業(株)
製“RISOGRAPH”GR375に供給して、黒ベ
タのものを原稿として、製版、印刷を行った。20枚の
印刷を行い、20枚目の印刷画像の白抜けと濃淡ムラの
状態を目視により、次の基準で判定した。
(7) Image quality: base paper is Riso Kagaku Kogyo Co., Ltd.
The plate was supplied to "RISOGRAPH" GR375, and plate making and printing were performed using a black solid document as a document. Twenty sheets were printed, and the state of white spots and density unevenness of the twentieth printed image was visually determined based on the following criteria.

【0042】<白抜け> 白抜けが、全くないものを、「○」 白抜けが、わずかに見られるものを、「△」 白抜けが、目立つものを、「×」 <濃淡むら> むらが、全くないものを、「○」 むらが、わずかに見られるものを、「△」 むらが、目立つものを、「×」 「○」または「△」が、実用上使用できるレベルであ
る。
<White spots> No white spots, “O” White spots slightly observed, “△” White spots, conspicuous spots, “×” <Light / shade unevenness> There are no samples at all, “○” unevenness is slightly observed, “も の” unevenness is noticeable, and “×” “○” or “△” is a practically usable level.

【0043】[0043]

【実施例】以下、本発明を実施例により説明するが、本
発明はこれらに限定されるものではない。
The present invention will be described below with reference to examples, but the present invention is not limited to these examples.

【0044】実施例1 [主体繊維の製造]ポリエチレンナフタレートチップを
295℃で溶融し、孔数が900の口金を通して290
℃で吐出し、1000m/分の速度で巻き取った。次に
この未延伸糸を3.8倍の倍率で110℃の雰囲気中で
延伸し、200℃で緊張熱処理、さらに140℃で弛緩
熱処理した後、5mmに切断し、平均繊維径5μmで複
屈折が0.18の主体繊維Aを得た。
Example 1 [Preparation of main fiber] A polyethylene naphthalate chip was melted at 295 ° C.
C. and discharged at a speed of 1000 m / min. Next, the undrawn yarn is drawn at a magnification of 3.8 times in an atmosphere of 110 ° C., subjected to a tension heat treatment at 200 ° C., a relaxation heat treatment at 140 ° C., cut into 5 mm, and birefringent at an average fiber diameter of 5 μm. Was 0.18.

【0045】[未延伸繊維の製造]他方、ポリエチレン
ナフタレートチップを295℃で溶融し、孔数が900
の口金を通して290℃で吐出し、5mmに切断し、平
均繊維径8μmで複屈折が0.05の未延伸繊維aを得
た。
[Production of Undrawn Fiber] On the other hand, a polyethylene naphthalate chip was melted at 295 ° C.
At 290 ° C. and cut into 5 mm to obtain undrawn fiber a having an average fiber diameter of 8 μm and a birefringence of 0.05.

【0046】[抄紙]主体繊維Aと未延伸繊維aとを8
0:20の重量比率でパルパー中で十分混合分散せしめ
た後、円網抄紙機で速度10m/分、ヤンキードライヤ
ー表面温度130℃で加熱乾燥した。抄上げ目付量は8
g/m2 であった。
[Paper making] The main fiber A and the undrawn fiber a
After thoroughly mixing and dispersing in a pulper at a weight ratio of 0:20, the mixture was heated and dried at a speed of 10 m / min and a surface temperature of a Yankee dryer of 130 ° C. using a circular paper machine. Estimated basis weight is 8
g / m 2 .

【0047】次いで、金属/弾性ロール系カレンダー加
工機で金属ロール表面温度215℃、線圧20kg/c
mの条件下圧着することにより、厚さ25μmの不織布
を得た。
Then, the metal roll surface temperature was 215 ° C., and the linear pressure was 20 kg / c using a metal / elastic roll calendering machine.
By pressing under a condition of m, a nonwoven fabric having a thickness of 25 μm was obtained.

【0048】[原紙の製造]エチレンテレフタレートと
エチレンイソフタレートとの共重合体(イソフタル酸共
重合量15モル%)からなる厚さ2μmの2軸延伸フィ
ルムに、酢酸ビニル系の接着材を用いて上記不織布を接
着し、フィルムの不織布側の反対面にシリコーン系離型
材を塗布して原紙を得た。
[Production of base paper] A 2 μm-thick biaxially stretched film made of a copolymer of ethylene terephthalate and ethylene isophthalate (isophthalic acid copolymerization amount: 15 mol%) was prepared by using a vinyl acetate adhesive. The above nonwoven fabric was adhered, and a silicone release material was applied to the opposite surface of the film from the nonwoven fabric side to obtain a base paper.

【0049】[評価]得られた原紙の特性を表1に示し
たが、製版時の寸法安定性に優れ、画像性も良好である
ことがわかる。
[Evaluation] The properties of the obtained base paper are shown in Table 1. It can be seen that the base paper has excellent dimensional stability during plate making and has good image quality.

【0050】比較例1 [主体繊維の製造]ポリエチレンテレフタレートチップ
を290℃で溶融し、孔数が900の口金を通して28
5℃で吐出し、1000m/分の速度で巻き取った。次
に、この未延伸糸を3.8倍の倍率で80℃の温水中で
延伸し、200℃で緊張熱処理、さらに125℃で弛緩
熱処理した後、5mmに切断し、平均繊維径5μmで複
屈折が0.20の主体繊維Bを得た。
Comparative Example 1 [Production of Main Fiber] A polyethylene terephthalate chip was melted at 290 ° C., and was passed through a die having 900 holes.
It was discharged at 5 ° C. and wound up at a speed of 1000 m / min. Next, the undrawn yarn is drawn at a magnification of 3.8 times in warm water at 80 ° C., subjected to a tension heat treatment at 200 ° C., a relaxation heat treatment at 125 ° C., cut into 5 mm, and cut into a fiber having an average fiber diameter of 5 μm. A main fiber B having a refraction of 0.20 was obtained.

【0051】[未延伸繊維の製造]他方、ポリエチレン
テレフタレートチップを290℃で溶融し、孔数が90
0の口金を通して285℃で吐出し、5mmに切断し、
平均繊維径8μmで複屈折が0.05の未延伸繊維bを
得た。
[Production of Undrawn Fiber] On the other hand, a polyethylene terephthalate chip was melted at 290 ° C.
Discharge at 285 ° C through the base of No. 0, cut to 5mm,
An undrawn fiber b having an average fiber diameter of 8 μm and a birefringence of 0.05 was obtained.

【0052】[抄紙]主体繊維Bと未延伸繊維bとを8
0:20の重量比率でパルパー中で十分混合分散せしめ
た後、円網抄紙機で速度10m/分、ヤンキードライヤ
ー表面温度130℃で加熱乾燥した。抄上げ目付量は8
g/m2 であった。
[Paper making] The main fiber B and the undrawn fiber b
After thoroughly mixing and dispersing in a pulper at a weight ratio of 0:20, the mixture was heated and dried at a speed of 10 m / min and a surface temperature of a Yankee dryer of 130 ° C. using a circular paper machine. Estimated basis weight is 8
g / m 2 .

【0053】次いで、金属/弾性ロール系カレンダー加
工機で金属ロール表面温度210℃、線圧15kg/c
mの条件下で圧着することにより、厚さ25μmの不織
布を得た。
Next, the metal roll surface temperature was 210 ° C., and the linear pressure was 15 kg / c using a metal / elastic roll calendering machine.
By pressing under a condition of m, a nonwoven fabric having a thickness of 25 μm was obtained.

【0054】[原紙の製造]エチレンテレフタレートと
エチレンイソフタレートとの共重合体(イソフタル酸共
重合量15モル%)からなる厚さ2μmの2軸延伸フィ
ルムに、酢酸ビニル系の接着材を用いて上記不織布を接
着し、フィルムの不織布側の反対面にシリコーン系離型
材を塗布して原紙を得た。
[Production of base paper] A 2 μm-thick biaxially stretched film made of a copolymer of ethylene terephthalate and ethylene isophthalate (isophthalic acid copolymerization amount: 15 mol%) was prepared by using a vinyl acetate adhesive. The above nonwoven fabric was adhered, and a silicone release material was applied to the opposite surface of the film from the nonwoven fabric side to obtain a base paper.

【0055】[評価]得られた原紙の特性を表1に示し
たが、着版時および印刷を繰り返すとしわが発生し、画
像が不良となるものであった。
[Evaluation] The properties of the obtained base paper are shown in Table 1. As shown in Table 1, wrinkles occurred when the plate was formed and the printing was repeated, and the image was defective.

【0056】比較例2 [抄紙]主体繊維Aと未延伸繊維bとを80:20の重
量比率でパルパー中で十分混合分散せしめた後、円網抄
紙機で速度10m/分、ヤンキードライヤー表面温度1
30℃で加熱乾燥した。抄上げ目付量は8g/m2 であ
った。
Comparative Example 2 [Papermaking] The main fiber A and the undrawn fiber b were thoroughly mixed and dispersed in a pulper at a weight ratio of 80:20. 1
It was dried by heating at 30 ° C. The weight per unit area was 8 g / m 2 .

【0057】次いで金属/弾性ロール系カレンダー加工
機で金属ロール表面温度210℃、線圧15kg/cm
の条件下圧着することにより、厚さ25μmの不織布を
得た。
Then, using a metal / elastic roll calendering machine, the metal roll surface temperature was 210 ° C., and the linear pressure was 15 kg / cm.
Under the following conditions to obtain a nonwoven fabric having a thickness of 25 μm.

【0058】[原紙の製造]エチレンテレフタレートと
エチレンイソフタレートとの共重合体(イソフタル酸共
重合量15モル%)からなる厚さ2μmの2軸延伸フィ
ルムに、酢酸ビニル系の接着材を用いて上記不織布を接
着し、フィルムの不織布側の反対面にシリコーン系離型
材を塗布して原紙を得た。
[Production of base paper] A 2-μm-thick biaxially stretched film made of a copolymer of ethylene terephthalate and ethylene isophthalate (isophthalic acid copolymerization amount: 15 mol%) was prepared by using a vinyl acetate adhesive. The above nonwoven fabric was adhered, and a silicone release material was applied to the opposite surface of the film from the nonwoven fabric side to obtain a base paper.

【0059】[評価]得られた原紙の特性を表1に示し
たが、しわが発生しやすく、画像も不十分なものであっ
た。
[Evaluation] The properties of the obtained base paper are shown in Table 1. As a result, wrinkles were easily generated and the image was insufficient.

【0060】実施例2 [主体繊維の製造]ポリエチレンナフタレートチップを
295℃で溶融し、孔数が900の口金を通して290
℃で吐出し、1000m/分の速度で巻き取った。次
に、この未延伸糸を3.2倍の倍率で110℃の雰囲気
中で延伸し、200℃で緊張熱処理、さらに140℃で
弛緩熱処理した後、5mmに切断し、平均繊維径5μm
で複屈折が0.15の主体繊維Bを得た。
Example 2 [Production of Main Fiber] A polyethylene naphthalate chip was melted at 295 ° C.
C. and discharged at a speed of 1000 m / min. Next, this undrawn yarn is drawn at a magnification of 3.2 times in an atmosphere of 110 ° C., subjected to a tension heat treatment at 200 ° C., and further subjected to a relaxation heat treatment at 140 ° C., and then cut into 5 mm to have an average fiber diameter of 5 μm.
As a result, a main fiber B having a birefringence of 0.15 was obtained.

【0061】[抄紙]主体繊維Bと未延伸繊維aとを8
0:20の重量比率でパルパー中で十分混合分散せしめ
た後、円網抄紙機で速度10m/分、ヤンキードライヤ
ー表面温度130℃で加熱乾燥した。抄上げ目付量は8
g/m2 であった。
[Paper making] The main fiber B and the undrawn fiber a
After thoroughly mixing and dispersing in a pulper at a weight ratio of 0:20, the mixture was heated and dried at a speed of 10 m / min and a surface temperature of a Yankee dryer of 130 ° C. using a circular paper machine. Estimated basis weight is 8
g / m 2 .

【0062】次いで、金属/弾性ロール系カレンダー加
工機で金属ロール表面温度215℃、線圧20kg/c
mの条件下圧着することにより、厚さ25μmの不織布
を得た。
Then, using a metal / elastic roll calendering machine, the metal roll surface temperature is 215 ° C., and the linear pressure is 20 kg / c.
By pressing under a condition of m, a nonwoven fabric having a thickness of 25 μm was obtained.

【0063】[原紙の製造]エチレンテレフタレートと
エチレンイソフタレートとの共重合体(イソフタル酸共
重合量15モル%)からなる厚さ2μmの2軸延伸フィ
ルムに、酢酸ビニル系の接着材を用いて上記不織布を接
着し、フィルムの不織布側の反対面にシリコーン系離型
材を塗布して原紙を得た。
[Production of base paper] A 2-μm-thick biaxially stretched film made of a copolymer of ethylene terephthalate and ethylene isophthalate (isophthalic acid copolymerization amount: 15 mol%) was prepared by using a vinyl acetate adhesive. The above nonwoven fabric was adhered, and a silicone release material was applied to the opposite surface of the film from the nonwoven fabric side to obtain a base paper.

【0064】[評価]得られた原紙の特性を表1に示し
たが、しわの発生が少なく、画像性も良好であることが
わかる。
[Evaluation] The characteristics of the obtained base paper are shown in Table 1. It can be seen that wrinkles are less generated and the image quality is good.

【0065】実施例3 [主体繊維の製造]ポリエチレンナフタレートチップを
295℃で溶融し、孔数が900の口金を通して290
℃で吐出し、1000m/分の速度で巻き取った。次に
この未延伸糸を4.5倍の倍率で110℃の温水中で延
伸し、200℃で緊張熱処理、さらに140℃で弛緩熱
処理した後、5mmに切断し、平均繊維径5μmで複屈
折が0.22の主体繊維Cを得た。
Example 3 Production of Main Fibers A polyethylene naphthalate chip was melted at 295 ° C.
C. and discharged at a speed of 1000 m / min. Next, this undrawn yarn is drawn at a magnification of 4.5 times in hot water at 110 ° C., subjected to a tension heat treatment at 200 ° C., a relaxation heat treatment at 140 ° C., cut into 5 mm, and birefringent at an average fiber diameter of 5 μm. Was 0.22.

【0066】[抄紙]主体繊維Cと未延伸繊維aとを8
0:20の重量比率でパルパー中で十分混合分散せしめ
た後、円網抄紙機で速度10m/分、ヤンキードライヤ
ー表面温度130℃で加熱乾燥した。抄上げ目付量は8
g/m2 であった。
[Paper making] The main fiber C and the undrawn fiber a
After thoroughly mixing and dispersing in a pulper at a weight ratio of 0:20, the mixture was heated and dried at a speed of 10 m / min and a surface temperature of a Yankee dryer of 130 ° C. using a circular paper machine. Estimated basis weight is 8
g / m 2 .

【0067】次いで金属/弾性ロール系カレンダー加工
機で金属ロール表面温度215℃、線圧20kg/cm
の条件下圧着することにより、厚さ25μmの不織布を
得た。
Then, using a metal / elastic roll calendering machine, the metal roll surface temperature was 215 ° C., and the linear pressure was 20 kg / cm.
Under the following conditions to obtain a nonwoven fabric having a thickness of 25 μm.

【0068】[原紙の製造]エチレンテレフタレートと
エチレンイソフタレートとの共重合体(イソフタル酸共
重合量15モル%)からなる厚さ2μmの2軸延伸フィ
ルムに、酢酸ビニル系の接着材を用いて上記不織布を接
着し、フィルムの不織布側の反対面にシリコーン系離型
材を塗布して原紙を得た。
[Production of base paper] A 2-μm-thick biaxially stretched film made of a copolymer of ethylene terephthalate and ethylene isophthalate (isophthalic acid copolymerization amount: 15 mol%) was prepared by using a vinyl acetate adhesive. The above nonwoven fabric was adhered, and a silicone release material was applied to the opposite surface of the film from the nonwoven fabric side to obtain a base paper.

【0069】[評価]得られた原紙の特性を表1に示し
たが、製版時の収縮率が小さく、画像性も良好であるこ
とがわかる。
[Evaluation] The characteristics of the obtained base paper are shown in Table 1. It can be seen that the shrinkage during plate making is small and the image quality is good.

【0070】実施例4 [未延伸繊維の製造]他方、ポリエチレンナフタレート
チップを290℃で溶融し、孔数が900の口金を通し
て280℃で吐出し、5mmに切断し、平均繊維径5μ
mで複屈折が0.12の未延伸繊維bを得た。
Example 4 [Production of undrawn fiber] On the other hand, a polyethylene naphthalate chip was melted at 290 ° C, discharged at 280 ° C through a die having 900 holes, cut into 5 mm, and cut to an average fiber diameter of 5 µm.
As a result, an undrawn fiber b having a birefringence of 0.12 was obtained.

【0071】[抄紙]主体繊維Aと未延伸繊維bとを8
0:20の重量比率でパルパー中で十分混合分散せしめ
た後、円網抄紙機で速度10m/分、ヤンキードライヤ
ー表面温度130℃で加熱乾燥した。抄上げ目付量は8
g/m2 であった。
[Paper making] The main fiber A and the undrawn fiber b
After thoroughly mixing and dispersing in a pulper at a weight ratio of 0:20, the mixture was heated and dried at a speed of 10 m / min and a surface temperature of a Yankee dryer of 130 ° C. using a circular paper machine. Estimated basis weight is 8
g / m 2 .

【0072】次いで、金属/弾性ロール系カレンダー加
工機で金属ロール表面温度210℃、線圧15kg/c
mの条件下圧着することにより、厚さ25μmの不織布
を得た。
Then, the metal roll surface temperature was 210 ° C. and the linear pressure was 15 kg / c using a metal / elastic roll calendering machine.
By pressing under a condition of m, a nonwoven fabric having a thickness of 25 μm was obtained.

【0073】[原紙の製造]エチレンテレフタレートと
エチレンイソフタレートとの共重合体(イソフタル酸共
重合量15モル%)からなる厚さ2μmの2軸延伸フィ
ルムに、酢酸ビニル系の接着材を用いて上記不織布を接
着し、フィルムの不織布側の反対面にシリコーン系離型
材を塗布して原紙を得た。
[Production of base paper] A 2-μm-thick biaxially stretched film made of a copolymer of ethylene terephthalate and ethylene isophthalate (isophthalic acid copolymerization amount: 15 mol%) was prepared by using a vinyl acetate adhesive. The above nonwoven fabric was adhered, and a silicone release material was applied to the opposite surface of the film from the nonwoven fabric side to obtain a base paper.

【0074】[評価]得られた原紙の特性を表1に示し
たが、製版時の収縮率が小さく、また、画像性は良好で
あった。
[Evaluation] The properties of the obtained base paper are shown in Table 1. The shrinkage during plate making was small and the image quality was good.

【0075】実施例5 [抄紙]主体繊維Bと未延伸繊維bとを80:20の重
量比率でパルパー中で十分混合分散せしめた後、円網抄
紙機で速度10m/分、ヤンキードライヤー表面温度1
30℃で加熱乾燥した。抄上げ目付量は8g/m2 であ
った。
Example 5 [Paper making] After sufficiently mixing and dispersing the main fiber B and the undrawn fiber b at a weight ratio of 80:20 in a pulper, the speed was 10 m / min using a circular paper machine, and the surface temperature of a Yankee dryer. 1
It was dried by heating at 30 ° C. The weight per unit area was 8 g / m 2 .

【0076】次いで、金属/弾性ロール系カレンダー加
工機で金属ロール表面温度210℃、線圧15kg/c
mの条件下圧着することにより、厚さ25μmの不織布
を得た。
Then, the metal roll surface temperature was 210 ° C. and the linear pressure was 15 kg / c using a metal / elastic roll calendering machine.
By pressing under a condition of m, a nonwoven fabric having a thickness of 25 μm was obtained.

【0077】[原紙の製造]エチレンテレフタレートと
エチレンイソフタレートとの共重合体(イソフタル酸共
重合量15モル%)からなる厚さ2μmの2軸延伸フィ
ルムに、酢酸ビニル系の接着材を用いて上記不織布を接
着し、フィルムの不織布側の反対面にシリコーン系離型
材を塗布して原紙を得た。
[Production of base paper] A 2-μm-thick biaxially stretched film made of a copolymer of ethylene terephthalate and ethylene isophthalate (isophthalic acid copolymerization amount: 15 mol%) was prepared by using a vinyl acetate adhesive. The above nonwoven fabric was adhered, and a silicone release material was applied to the opposite surface of the film from the nonwoven fabric side to obtain a base paper.

【0078】[評価]得られた原紙の特性を表1に示し
たが、製版時の収縮率が小さく、また、画像性も使用可
能のものであった。
[Evaluation] The properties of the obtained base paper are shown in Table 1. The shrinkage during plate making was small, and the image quality was usable.

【0079】実施例6〜8および比較例3 主体繊維Aと未延伸繊維aとの重量比率を表1のように
変更したこと以外は実施例1と同様にして、原紙を得
た。
Examples 6 to 8 and Comparative Example 3 A base paper was obtained in the same manner as in Example 1 except that the weight ratio between the main fiber A and the undrawn fiber a was changed as shown in Table 1.

【0080】[評価]得られた原紙の特性を表1に示し
たが、本発明の不織布は、製版時の寸法安定性に優れ、
画像性も良好であることがわかる。
[Evaluation] The properties of the obtained base paper are shown in Table 1. The nonwoven fabric of the present invention has excellent dimensional stability during plate making.
It can be seen that the image quality is also good.

【0081】実施例5、6 抄上げ目付量を6および10g/m2 に変更したこと以
外は実施例1と同様にして、原紙を得た。
Examples 5 and 6 Base papers were obtained in the same manner as in Example 1 except that the basis weight of the paper was changed to 6 and 10 g / m 2 .

【0082】[評価]得られた原紙の特性を表1に示し
たが、本発明の不織布は、製版時の寸法安定性に優れ、
画像性も良好であることがわかる。
[Evaluation] The properties of the obtained base paper are shown in Table 1. The nonwoven fabric of the present invention has excellent dimensional stability during plate making.
It can be seen that the image quality is also good.

【0083】[0083]

【表1】 [Table 1]

【0084】[0084]

【発明の効果】本発明の不織布は、腰が強く、特に感熱
孔版印刷用原紙に適した支持体を提供することができ
る。また。目付を小さくしても使用できるため、印刷機
をコンパクト化でき、白抜けなどの印刷時の欠点も抑制
できる。
The nonwoven fabric of the present invention has a strong stiffness and can provide a support particularly suitable for heat-sensitive stencil printing base paper. Also. Since the printer can be used even if the basis weight is reduced, the printing machine can be made compact and defects such as white spots during printing can be suppressed.

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 2H114 AB23 DA56 EA04 EA06 FA02 FA10 4F100 AK22G AK42B AK79D AS00A BA02 BA04 BA07 BA10A BA10D DG01A DG15A EJ37A GB90 JK04 JK07A JL04 JL14C JN18A YY00A 4L055 AF33 EA04 EA07 EA34 FA13 FA15 GA08 GA12 GA39  ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 2H114 AB23 DA56 EA04 EA06 FA02 FA10 4F100 AK22G AK42B AK79D AS00A BA02 BA04 BA07 BA10A BA10D DG01A DG15A EJ37A GB90 JK04 JK07A JL04 JL14C JN18 FA13GA4 GA4

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】骨格部分を構成する主体繊維およびバイン
ダー部分を構成する未延伸繊維のいずれもがポリエチレ
ンナフタレートを主体とするポリエステルからなること
を特徴とする感熱孔版印刷原紙用不織布。
1. A non-woven fabric for heat-sensitive stencil printing paper, wherein both the main fiber constituting the skeleton portion and the unstretched fiber constituting the binder portion are made of polyester mainly composed of polyethylene naphthalate.
【請求項2】主体繊維の複屈折が0.15〜0.25で
あることを特徴とする請求項1記載の感熱孔版印刷原紙
用不織布。
2. The nonwoven fabric for heat-sensitive stencil printing paper according to claim 1, wherein the birefringence of the main fiber is 0.15 to 0.25.
【請求項3】未延伸繊維の複屈折が0.12以下である
ことを特徴とする請求項1または2記載の感熱孔版印刷
原紙用不織布。
3. The nonwoven fabric for heat-sensitive stencil printing paper according to claim 1, wherein the birefringence of the undrawn fiber is 0.12 or less.
【請求項4】主体繊維と、バインダー部分を構成する未
延伸繊維との混合比率が50:50〜95:5の範囲で
あることを特徴とする請求項1〜3のいずれかに記載の
感熱孔版印刷原紙用不織布。
4. The heat-sensitive material according to claim 1, wherein the mixing ratio of the main fiber and the undrawn fiber constituting the binder portion is in the range of 50:50 to 95: 5. Non-woven fabric for stencil printing paper.
【請求項5】引張弾性率が0.15N/mm以上である
ことを特徴とする請求項1〜4のいずれかに記載の感熱
孔版印刷用不織布。
5. The non-woven fabric for heat-sensitive stencil printing according to claim 1, wherein the tensile elastic modulus is 0.15 N / mm or more.
JP10297069A 1998-10-19 1998-10-19 Unwoven fabric for heat sensitive stencil printing original paper Pending JP2000118163A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10297069A JP2000118163A (en) 1998-10-19 1998-10-19 Unwoven fabric for heat sensitive stencil printing original paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10297069A JP2000118163A (en) 1998-10-19 1998-10-19 Unwoven fabric for heat sensitive stencil printing original paper

Publications (1)

Publication Number Publication Date
JP2000118163A true JP2000118163A (en) 2000-04-25

Family

ID=17841817

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2000118163A (en)

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* Cited by examiner, † Cited by third party
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JP2006207085A (en) * 2005-01-31 2006-08-10 Teijin Techno Products Ltd Nonwoven fabric
JP2008156789A (en) * 2006-12-25 2008-07-10 Teijin Ltd Polyethylene naphthalate staple fiber nonwoven fabric and method for producing the same
JP2008163484A (en) * 2006-12-27 2008-07-17 Teijin Fibers Ltd Binder fiber for nonwoven fabric and method for producing the same
JP2008291404A (en) * 2007-05-28 2008-12-04 Teijin Fibers Ltd Heat resistant nonwoven fabric
JP2008297639A (en) * 2007-05-29 2008-12-11 Teijin Fibers Ltd Heat-resistant nonwoven fabric
JP2010100963A (en) * 2008-10-23 2010-05-06 Teijin Fibers Ltd Method for producing polyethylene naphthalate fiber
JP2012112079A (en) * 2010-11-26 2012-06-14 Teijin Fibers Ltd Polyethylene naphthalate fiber and staple fiber nonwoven fabric therefrom
JP2013122101A (en) * 2011-12-12 2013-06-20 Teijin Ltd Wet nonwoven fabric

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006207085A (en) * 2005-01-31 2006-08-10 Teijin Techno Products Ltd Nonwoven fabric
JP4616658B2 (en) * 2005-01-31 2011-01-19 帝人ファイバー株式会社 Non-woven
JP2008156789A (en) * 2006-12-25 2008-07-10 Teijin Ltd Polyethylene naphthalate staple fiber nonwoven fabric and method for producing the same
JP2008163484A (en) * 2006-12-27 2008-07-17 Teijin Fibers Ltd Binder fiber for nonwoven fabric and method for producing the same
JP2008291404A (en) * 2007-05-28 2008-12-04 Teijin Fibers Ltd Heat resistant nonwoven fabric
JP2008297639A (en) * 2007-05-29 2008-12-11 Teijin Fibers Ltd Heat-resistant nonwoven fabric
JP2010100963A (en) * 2008-10-23 2010-05-06 Teijin Fibers Ltd Method for producing polyethylene naphthalate fiber
JP2012112079A (en) * 2010-11-26 2012-06-14 Teijin Fibers Ltd Polyethylene naphthalate fiber and staple fiber nonwoven fabric therefrom
JP2013122101A (en) * 2011-12-12 2013-06-20 Teijin Ltd Wet nonwoven fabric

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