IT1254861B - Processo di produzione di gomma butile - Google Patents
Processo di produzione di gomma butileInfo
- Publication number
- IT1254861B IT1254861B ITMI920914A ITMI920914A IT1254861B IT 1254861 B IT1254861 B IT 1254861B IT MI920914 A ITMI920914 A IT MI920914A IT MI920914 A ITMI920914 A IT MI920914A IT 1254861 B IT1254861 B IT 1254861B
- Authority
- IT
- Italy
- Prior art keywords
- reactor
- phase
- liquid
- polymerization
- iir
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 229920005549 butyl rubber Polymers 0.000 title abstract 4
- 238000010092 rubber production Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000012071 phase Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
- C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La presente invenzione si riferisce ad un nuovo processo continuo in sospensione per la produzione di Gomma Butile (IIR) ed ai dispositivi atti a realizzarlo. Il nuovo processo permette sostanziali risparmi d'energia e d'investimento rispetto ai processi noti. Nel nuovo processo la polimerizzazlone avviene a -5OC° anziché a -1OOC°, mediante impiego di speciali catalizzatori. I1 calore di polimerizzazione viene dissipato mediante ebollizione del mezzo di reazione, anziché per scambio termico attraverso le pareti del reattore di polimerizzazione. Quest'ultimo è un reattore tri-fasico, contenente una fase polimerica, una liquida ed una vapore, disegnato in modo da: l)omogeneizzare la fase liquida in ogni punto del reattore, 2)convogliare (scremare) il polimero formato verso lo scarico del reattore, 3)separare la fase vapore verso il cielo del reattore. Il polimero scaricato dal reattore viene torchiato, facendo rifluire il liquido nel reattore. Mediante la combinazione di tutte le caratteristiche critiche sopraddette, l'energia di produzione della IIR può essere abbattuta di oltre il 20% e l'investimento di oltre il 30%. Lo schema del processo è mostrato nella fig.1.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI920914A IT1254861B (it) | 1992-04-15 | 1992-04-15 | Processo di produzione di gomma butile |
PCT/IT1993/000033 WO1993021241A1 (en) | 1992-04-15 | 1993-04-13 | New process for butyl rubber production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI920914A IT1254861B (it) | 1992-04-15 | 1992-04-15 | Processo di produzione di gomma butile |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI920914A0 ITMI920914A0 (it) | 1992-04-15 |
ITMI920914A1 ITMI920914A1 (it) | 1993-10-15 |
IT1254861B true IT1254861B (it) | 1995-10-11 |
Family
ID=11362946
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITMI920914A IT1254861B (it) | 1992-04-15 | 1992-04-15 | Processo di produzione di gomma butile |
Country Status (2)
Country | Link |
---|---|
IT (1) | IT1254861B (it) |
WO (1) | WO1993021241A1 (it) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6858690B2 (en) | 1999-11-15 | 2005-02-22 | Exxonmobil Chemical Patents Inc. | Process for polymerizing cationically polymerizable monomers |
KR20020054344A (ko) | 1999-11-15 | 2002-07-06 | 엑손 케미칼 패턴츠 인코포레이티드 | 이소부틸렌 공중합체의 제조법 |
JP5328001B2 (ja) * | 2000-12-20 | 2013-10-30 | エクソンモービル・ケミカル・パテンツ・インク | カチオン重合性モノマーの重合方法 |
CA2510856C (en) * | 2002-12-20 | 2013-01-08 | Exxonmobil Chemical Patents Inc. | Polymerization processes using hydrofluorocarbon(s)(hfc`s) |
CA2458750C (en) | 2004-02-23 | 2012-02-07 | Bayer Inc. | Isoolefin-diolefin production process and apparatus therefor |
US9896525B2 (en) | 2015-04-29 | 2018-02-20 | Exxonmobil Chemical Patents Inc. | Homogeneous polymerization process using evaporative cooling |
JP6596172B2 (ja) | 2016-01-29 | 2019-10-23 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 官能性オレフィンベースのポリマーの生成のためのシステム及び方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB561324A (en) * | 1940-12-07 | 1944-05-15 | Standard Oil Dev Co | Improved low temperature polymerisation process and apparatus therefor |
GB8515254D0 (en) * | 1985-06-17 | 1985-07-17 | Enichem Elastomers | Butyl rubber |
-
1992
- 1992-04-15 IT ITMI920914A patent/IT1254861B/it active IP Right Grant
-
1993
- 1993-04-13 WO PCT/IT1993/000033 patent/WO1993021241A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
ITMI920914A0 (it) | 1992-04-15 |
ITMI920914A1 (it) | 1993-10-15 |
WO1993021241A1 (en) | 1993-10-28 |
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