[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

IN2015DN02232A - - Google Patents

Info

Publication number
IN2015DN02232A
IN2015DN02232A IN2232DEN2015A IN2015DN02232A IN 2015DN02232 A IN2015DN02232 A IN 2015DN02232A IN 2232DEN2015 A IN2232DEN2015 A IN 2232DEN2015A IN 2015DN02232 A IN2015DN02232 A IN 2015DN02232A
Authority
IN
India
Prior art keywords
elasticity
harmonic
storage modulus
measured
copolymer
Prior art date
Application number
Inventor
Chem Ltd Lg
Original Assignee
Lg Chemical Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020130075873A external-priority patent/KR101585204B1/en
Priority claimed from KR1020140047679A external-priority patent/KR101684648B1/en
Priority claimed from KR1020140080039A external-priority patent/KR101446685B1/en
Application filed by Lg Chemical Ltd filed Critical Lg Chemical Ltd
Publication of IN2015DN02232A publication Critical patent/IN2015DN02232A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/06Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene-diene terpolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/20Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/02Cp or analog bridged to a non-Cp X anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09Long chain branches
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The present invention relates to a ternary elastomeric copolymer having a long chain branch obtained in the presence of a group IV transition metal catalyst and capable of achieving both excellent processability and excellent elasticity (flexibility) and a method for preparing the same. The ternary elastomeric copolymer is a copolymer of ethylene an alpha olefin having 3 to 20 carbon atoms and a diene i) having a weight average molecular weight of 100 000 to 500 000 measured by GPC; and ii) capable of having a positive value on the LCB index which is the ratio of a first harmonic of the storage modulus of elasticity measured by a rubber process analyzer at 125°C using the Large Angles of Oscillation and high Strains (LAOS) method with respect to a fifth harmonic of the storage modulus of elasticity.
IN2232DEN2015 2013-06-28 2014-06-30 IN2015DN02232A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR1020130075873A KR101585204B1 (en) 2013-06-28 2013-06-28 Elastic diene terpolymer and preparation method thereof
KR20140040551 2014-04-04
KR1020140047679A KR101684648B1 (en) 2014-04-21 2014-04-21 Elastic diene terpolymer and preparation method thereof
KR1020140080039A KR101446685B1 (en) 2014-04-04 2014-06-27 Elastic diene terpolymer and preparation method thereof
PCT/KR2014/005811 WO2014209085A1 (en) 2013-06-28 2014-06-30 Ternary elastomeric copolymer comprising diene and method for preparing same

Publications (1)

Publication Number Publication Date
IN2015DN02232A true IN2015DN02232A (en) 2015-08-21

Family

ID=52142322

Family Applications (1)

Application Number Title Priority Date Filing Date
IN2232DEN2015 IN2015DN02232A (en) 2013-06-28 2014-06-30

Country Status (6)

Country Link
US (1) US9493593B2 (en)
EP (1) EP2883891A4 (en)
JP (1) JP2015532362A (en)
CN (1) CN104768986A (en)
IN (1) IN2015DN02232A (en)
WO (1) WO2014209085A1 (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101585204B1 (en) * 2013-06-28 2016-01-13 주식회사 엘지화학 Elastic diene terpolymer and preparation method thereof
JP2015532361A (en) 2013-06-28 2015-11-09 エルジー・ケム・リミテッド Ternary elastic copolymer containing diene and method for producing the same
CN104768986A (en) 2013-06-28 2015-07-08 株式会社Lg化学 Ternary elastomeric copolymer comprising diene and method for preparing same
KR101585206B1 (en) 2013-07-22 2016-01-13 주식회사 엘지화학 Elastic diene terpolymer and preparation method thereof
JP2015536368A (en) 2013-06-28 2015-12-21 エルジー・ケム・リミテッド Ternary elastic copolymer containing diene and method for producing the same
CN105899557B (en) 2013-12-06 2018-10-26 株式会社Lg化学 Block copolymer
US10239980B2 (en) 2013-12-06 2019-03-26 Lg Chem, Ltd. Block copolymer
EP3078685B1 (en) 2013-12-06 2020-09-09 LG Chem, Ltd. Block copolymer
WO2015084124A1 (en) 2013-12-06 2015-06-11 주식회사 엘지화학 Block copolymer
CN105916904B (en) 2013-12-06 2018-11-09 株式会社Lg化学 Block copolymer
JP6483693B2 (en) 2013-12-06 2019-03-13 エルジー・ケム・リミテッド Block copolymer
EP3078689B1 (en) 2013-12-06 2020-12-02 LG Chem, Ltd. Block copolymer
EP3078692B1 (en) 2013-12-06 2021-01-27 LG Chem, Ltd. Block copolymer
US10227438B2 (en) 2013-12-06 2019-03-12 Lg Chem, Ltd. Block copolymer
JP6483694B2 (en) 2013-12-06 2019-03-13 エルジー・ケム・リミテッド Monomers and block copolymers
CN105899559B (en) 2013-12-06 2018-05-25 株式会社Lg化学 Block copolymer
CN105934456B (en) 2013-12-06 2018-09-28 株式会社Lg化学 Block copolymer
CN107075050B (en) 2014-09-30 2019-08-13 株式会社Lg化学 Block copolymer
WO2016052999A1 (en) 2014-09-30 2016-04-07 주식회사 엘지화학 Block copolymer
CN107075052B (en) 2014-09-30 2020-05-29 株式会社Lg化学 Block copolymer
US10287430B2 (en) 2014-09-30 2019-05-14 Lg Chem, Ltd. Method of manufacturing patterned substrate
US10377894B2 (en) * 2014-09-30 2019-08-13 Lg Chem, Ltd. Block copolymer
CN107075028B (en) 2014-09-30 2020-04-03 株式会社Lg化学 Block copolymer
CN107077066B9 (en) 2014-09-30 2021-05-14 株式会社Lg化学 Method of manufacturing patterned substrate
EP3214102B1 (en) 2014-09-30 2022-01-05 LG Chem, Ltd. Block copolymer
WO2016053001A1 (en) 2014-09-30 2016-04-07 주식회사 엘지화학 Block copolymer
WO2016052994A1 (en) 2014-09-30 2016-04-07 주식회사 엘지화학 Block copolymer

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
DE4236218C2 (en) 1991-12-19 2001-08-16 Degussa Vulcanizable EPDM rubber compounds
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
NL9400758A (en) * 1994-05-06 1995-12-01 Dsm Nv Process for the preparation of a high molecular weight polymer from ethylene, alpha olefin and optionally diene.
US5571883A (en) 1995-06-14 1996-11-05 Exxon Chemical Patents Inc. Elastomeric vehicle vibration damping devices
CN1224433A (en) 1996-05-03 1999-07-28 Dsm有限公司 Process for preparing terpolymers of ethylene, alpha-olefins and diolefins
CA2287963A1 (en) 1997-04-30 1998-11-05 Debra J. Mangold Ethylene/alpha-olefin/diene interpolymers and their preparation
CN1254350A (en) 1997-04-30 2000-05-24 唐化学原料公司 Ethylene/alpha-olefin/diene interpolymers and their preparation
US6521306B1 (en) 1997-08-27 2003-02-18 Dow Global Technologies Inc. Rheology modification of low density polyethylene
US5942587A (en) 1997-11-21 1999-08-24 Exxon Chemical Patents Inc. Ethylene polymers with a norbornene comonomer for LLDPE like resins of improved toughness and processibility for film production
WO2000026268A1 (en) 1998-11-02 2000-05-11 Du Pont Dow Elastomers L.L.C. SHEAR THINNING ETHYLENE/α-OLEFIN INTERPOLYMERS AND THEIR PREPARATION
KR100581761B1 (en) 1999-01-30 2006-05-22 주식회사 엘지화학 Olefin copolymer for rotomolding
US6369176B1 (en) 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
US6403520B1 (en) 1999-09-17 2002-06-11 Saudi Basic Industries Corporation Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
US6977287B2 (en) 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
CN1234740C (en) 1999-12-10 2006-01-04 埃克森化学专利公司 Articles formed from propylene diene copolymers
CA2292387A1 (en) 1999-12-17 2001-06-17 Bayer Inc. Process for producing olefin polymer with long chain branching
US6509431B1 (en) 2000-01-18 2003-01-21 Exxonmobil Oil Corporation Terpolymers
DE60124243T2 (en) 2000-05-10 2007-05-31 Exxonmobil Chemical Patents Inc., Baytown Polyolefin masses with improved low-temperature toughness and method
DE60331815D1 (en) * 2002-02-08 2010-05-06 Exxonmobil Chem Patents Inc MULTIMODAL ETHYLENE, ALPHA-OLEFIN AND DIEN POLYMERS, METHOD OF PREPARING THEM AND APPARATUS CONTAINING SUCH COMPOSITIONS
JP4945080B2 (en) 2002-06-19 2012-06-06 エクソンモービル・ケミカル・パテンツ・インク Ethylene, higher α-olefin comonomers and dienes, especially vinyl norbornene, and polymers produced using such methods
EP2261269B1 (en) 2003-07-09 2016-11-09 Arlanxeo Netherlands B.V. Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
CN101466752B (en) 2005-03-17 2012-09-26 陶氏环球技术有限责任公司 Compositions of ethylene/alpha-olefin multi-block interpolymer suitable for films
JP5227162B2 (en) 2005-03-17 2013-07-03 ダウ グローバル テクノロジーズ エルエルシー Polymer blend derived from ethylene / α-olefin copolymer and flexible molded article produced therefrom
KR100820542B1 (en) 2006-03-24 2008-04-08 주식회사 엘지화학 Transition metal complexes, catalysts composition containing the same and olefin polymerization theirwith
EP2787013A1 (en) 2006-05-17 2014-10-08 Dow Global Technologies LLC Polyolefin solution polymerization process and polymer
KR100976131B1 (en) 2007-01-10 2010-08-16 주식회사 엘지화학 Method for preparing transition metal complexes, Transition metal complexes prepared using the mathod, Catalysts composition containing the complexes
EP2115018B1 (en) 2007-02-08 2011-11-02 Lanxess Elastomers B.V. Elastomeric compound
US20120172548A1 (en) * 2007-05-02 2012-07-05 Lg Chem, Ltd. Polyolefin and preparation method thereof
KR100994252B1 (en) * 2007-05-09 2010-11-12 주식회사 엘지화학 Ethylene alpha-olefin copolymer
KR101066969B1 (en) 2007-05-18 2011-09-22 주식회사 엘지화학 Method for preparing olefin polymer using transition metal catalyst having better copolymerization
TW200932770A (en) 2007-10-22 2009-08-01 Univation Tech Llc Metallocene catalysts and their use in polymerization processes
WO2009072503A1 (en) 2007-12-05 2009-06-11 Mitsui Chemicals, Inc. Copolymer rubber, rubber composition, and molded rubber
KR101084677B1 (en) * 2008-05-14 2011-11-22 주식회사 엘지화학 Process for preparation of olefin polymers
KR101149755B1 (en) 2009-01-06 2012-06-01 에스케이종합화학 주식회사 The Manufacture of Ethylene-Propylene-Diene Copolymer
KR101262305B1 (en) * 2009-07-01 2013-05-08 주식회사 엘지화학 Process for preparation of elastomeric polymer using transition catalyst
KR101206166B1 (en) 2009-08-13 2012-11-28 주식회사 엘지화학 Catalyst composition comprising metallocene catalyst
WO2011056020A2 (en) * 2009-11-06 2011-05-12 주식회사 엘지화학 Mixed metallocene catalyst composition and method for preparing a polyolefin using same
EP2501758B1 (en) 2009-11-20 2018-08-08 Dow Global Technologies LLC Thermoplastic elastomer for cold and wet applications
KR101367402B1 (en) 2009-11-27 2014-02-25 주식회사 엘지화학 Process for preparation of elastomeric polymer having high diene-based monomer content and high molecular weight
KR101339391B1 (en) 2010-08-16 2013-12-09 주식회사 엘지화학 Olefin-based copolymer and method for preparation of the same
KR101889978B1 (en) 2012-01-30 2018-08-21 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 new transition metal complex with annulated ring substituted arylphenoxy ligand, catalyst composition containing the same for olefin copolymerization and methods for preparing copolymers of ethylene and α-olefins or copolymers of ethylene and olefin-diene using the same
KR101587189B1 (en) 2012-02-06 2016-02-02 주식회사 엘지화학 Polyolefin-based terpolymer and method for preparation of the same
EP2867293A4 (en) 2012-06-28 2015-12-02 Dow Global Technologies Llc Crosslinked foams having high hardness and low compression set
KR101391692B1 (en) * 2012-11-14 2014-05-07 주식회사 엘지화학 Elastic terpolymer and preparation method thereof
KR20140144076A (en) 2013-06-10 2014-12-18 주식회사 엘지화학 Preparation method of elastic terpolymer
CN104768986A (en) 2013-06-28 2015-07-08 株式会社Lg化学 Ternary elastomeric copolymer comprising diene and method for preparing same
KR101585206B1 (en) * 2013-07-22 2016-01-13 주식회사 엘지화학 Elastic diene terpolymer and preparation method thereof
JP2015532361A (en) * 2013-06-28 2015-11-09 エルジー・ケム・リミテッド Ternary elastic copolymer containing diene and method for producing the same

Also Published As

Publication number Publication date
US9493593B2 (en) 2016-11-15
EP2883891A4 (en) 2016-06-01
EP2883891A1 (en) 2015-06-17
CN104768986A (en) 2015-07-08
WO2014209085A1 (en) 2014-12-31
JP2015532362A (en) 2015-11-09
US20160280823A1 (en) 2016-09-29

Similar Documents

Publication Publication Date Title
IN2015DN02232A (en)
MX2016010394A (en) Producing polyethylene products with improved stiffness, toughness, and processability.
BR112015022786A2 (en) polymer films having improved heat sealing properties
BR112015006803A2 (en) composition comprising an ethylene-based polymer and article
RU2016124211A (en) METHODS FOR REGULATING POLYMER PROPERTIES
SG159475A1 (en) Conjugated diene polymer and conjugated diene polymer composition
EA201301155A1 (en) UHMWE-FIBER AND METHOD FOR ITS OBTAINING
GB201113196D0 (en) Thermoset resin compositions with increased toughness
WO2012004676A3 (en) Process for producing high molecular weight polyethylene
BR112015010241A2 (en) low density polyolefin resins and films made of the same
MX2016008016A (en) Catalyst system for polymerisation of an olefin.
MX2022001538A (en) Long chain branched polymers and methods of making same.
TW200704651A (en) Process for production of propylene copolymers
BR112013025617A2 (en) polymer composition for use in blow molding
MX360854B (en) Ethylene-based polymers with improved melt strength and processes for the same.
WO2012092491A3 (en) Compositions, methods of making the same, and articles prepared from the same
EA201800018A1 (en) METHOD OF OBTAINING A POLYETHYLENE COMPOSITION
MX2015002703A (en) Ethylene-based polymers and articles made therefrom.
MY181025A (en) Latex composition for dip forming and dip-formed article prepared therefrom
BR112017010838A2 (en) high density polyethylene (hdpe)
MX2016004602A (en) Enhanced escr bimodal rotomolding resin.
WO2013048848A3 (en) Dynamic modulation of metallocene catalysts
BR112013009340A2 (en) method of producing ethylene-based polymer particles and stretched molded article obtained from ethylene-based polymer particles
BR112014006802A2 (en) composition and article
AR094327A1 (en) POLYMERS BASED ON ETHYLENE AND PROCESSES TO MANUFACTURE THEM