IL41933A - Disubstituted n-(aminomethylene)-thiolphosphoric and thiono-phosphoric acid ester amides their production and their use as insecticides and acaricides - Google Patents
Disubstituted n-(aminomethylene)-thiolphosphoric and thiono-phosphoric acid ester amides their production and their use as insecticides and acaricidesInfo
- Publication number
- IL41933A IL41933A IL41933A IL4193373A IL41933A IL 41933 A IL41933 A IL 41933A IL 41933 A IL41933 A IL 41933A IL 4193373 A IL4193373 A IL 4193373A IL 41933 A IL41933 A IL 41933A
- Authority
- IL
- Israel
- Prior art keywords
- alkyl
- compound
- carbon atoms
- formula
- alkenyl
- Prior art date
Links
- 230000000895 acaricidal effect Effects 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000002917 insecticide Substances 0.000 title description 3
- 239000000642 acaricide Substances 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 104
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 28
- -1 piperidino, morpholino Chemical group 0.000 claims abstract description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 9
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract description 4
- 125000006350 alkyl thio alkyl group Chemical group 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 26
- 239000002253 acid Substances 0.000 claims description 16
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- 230000006378 damage Effects 0.000 claims description 6
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- 239000007788 liquid Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 claims description 4
- 125000006295 amino methylene group Chemical group [H]N(*)C([H])([H])* 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
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- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
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- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 2
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 2
- 239000005864 Sulphur Chemical group 0.000 claims description 2
- 125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 1
- 125000004372 methylthioethyl group Chemical group [H]C([H])([H])SC([H])([H])C([H])([H])* 0.000 claims 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 abstract description 2
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- 125000004214 1-pyrrolidinyl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
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- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
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- QDKJWXBGYXJIOS-UHFFFAOYSA-N n-(dimethoxymethyl)-n-ethylethanamine Chemical compound CCN(CC)C(OC)OC QDKJWXBGYXJIOS-UHFFFAOYSA-N 0.000 description 1
- PXSXRABJBXYMFT-UHFFFAOYSA-N n-hexylhexan-1-amine Chemical compound CCCCCCNCCCCCC PXSXRABJBXYMFT-UHFFFAOYSA-N 0.000 description 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 208000007578 phototoxic dermatitis Diseases 0.000 description 1
- 231100000018 phototoxicity Toxicity 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/6533—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2454—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2458—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic of aliphatic amines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2216552A DE2216552C3 (de) | 1972-04-06 | 1972-04-06 | Disubstituierte N- [Aminomethyliden] - thiol-(thiono)-phosphorsäureesterimide, Verfahren zu ihrer Herstellung und ihre Verwendung als Insektizide und Akarizide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL41933A0 IL41933A0 (en) | 1973-06-29 |
| IL41933A true IL41933A (en) | 1977-10-31 |
Family
ID=5841151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL41933A IL41933A (en) | 1972-04-06 | 1973-04-03 | Disubstituted n-(aminomethylene)-thiolphosphoric and thiono-phosphoric acid ester amides their production and their use as insecticides and acaricides |
Country Status (21)
| Country | Link |
|---|---|
| JP (2) | JPS4913122A (tr) |
| AT (1) | AT322908B (tr) |
| BE (1) | BE797792A (tr) |
| BR (1) | BR7302379D0 (tr) |
| CH (1) | CH582994A5 (tr) |
| CS (2) | CS183697B2 (tr) |
| DD (1) | DD107934A5 (tr) |
| DE (1) | DE2216552C3 (tr) |
| DK (1) | DK134320C (tr) |
| EG (1) | EG10754A (tr) |
| ES (2) | ES413374A1 (tr) |
| FR (1) | FR2179214B1 (tr) |
| GB (1) | GB1377329A (tr) |
| HU (1) | HU168160B (tr) |
| IL (1) | IL41933A (tr) |
| IT (1) | IT981879B (tr) |
| NL (1) | NL7304849A (tr) |
| PL (1) | PL86814B1 (tr) |
| RO (2) | RO62884A (tr) |
| TR (1) | TR17151A (tr) |
| ZA (1) | ZA732384B (tr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RO65820A (ro) * | 1974-09-12 | 1980-06-15 | Bayer A.G.,De | Procedeu de preparare a unor noi esteri fosforici |
| JPS5423479U (tr) * | 1977-07-19 | 1979-02-15 | ||
| DE2737403A1 (de) * | 1977-08-19 | 1979-02-22 | Bayer Ag | N-(aminomethylen)-(mono- bzw. dithio) -phosphorsaeurediesteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide, akarizide und nematizide |
| LU85892A1 (fr) * | 1985-05-10 | 1986-12-05 | Wurth Paul Sa | Procede de controle du chargement d'un four a cuve |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3121084A (en) * | 1962-09-17 | 1964-02-11 | Du Pont | Selected n, n, n'-trisubstituted amidines and their preparation by reaction of compounds with-nh2 groups with amide acetals |
| DE2118469C3 (de) * | 1971-04-16 | 1980-02-14 | Bayer Ag, 5090 Leverkusen | N-(Dimenthylaminomethyliden)-thiol(thiono)phosphorsäureesterimide, Verfahren zu ihrer Herstellung sowie ihre Verwendung als Insektizide und Akarizide |
| BE792901A (fr) * | 1971-12-17 | 1973-06-18 | Ciba Geigy | Amidines phosphorees et produits pesticides qui en contiennent |
-
1972
- 1972-04-06 DE DE2216552A patent/DE2216552C3/de not_active Expired
-
1973
- 1973-03-21 DD DD169627A patent/DD107934A5/xx unknown
- 1973-03-28 CS CS7600006200A patent/CS183697B2/cs unknown
- 1973-03-28 CS CS7300002271A patent/CS183687B2/cs unknown
- 1973-03-29 RO RO7300074333A patent/RO62884A/ro unknown
- 1973-03-29 RO RO7383028A patent/RO65819A/ro unknown
- 1973-04-03 JP JP48037482A patent/JPS4913122A/ja active Pending
- 1973-04-03 IL IL41933A patent/IL41933A/en unknown
- 1973-04-03 BR BR732379A patent/BR7302379D0/pt unknown
- 1973-04-03 JP JP48037483A patent/JPS4913336A/ja active Pending
- 1973-04-03 TR TR17151A patent/TR17151A/tr unknown
- 1973-04-04 CH CH484073A patent/CH582994A5/xx not_active IP Right Cessation
- 1973-04-04 PL PL1973161700A patent/PL86814B1/pl unknown
- 1973-04-04 EG EG126/73A patent/EG10754A/xx active
- 1973-04-04 IT IT22593/73A patent/IT981879B/it active
- 1973-04-05 BE BE129657A patent/BE797792A/xx unknown
- 1973-04-05 DK DK184873A patent/DK134320C/da active
- 1973-04-05 GB GB1635273A patent/GB1377329A/en not_active Expired
- 1973-04-05 ES ES413374A patent/ES413374A1/es not_active Expired
- 1973-04-05 AT AT299073A patent/AT322908B/de not_active IP Right Cessation
- 1973-04-05 ZA ZA732384A patent/ZA732384B/xx unknown
- 1973-04-06 HU HUBA2903A patent/HU168160B/hu unknown
- 1973-04-06 NL NL7304849A patent/NL7304849A/xx not_active Application Discontinuation
- 1973-04-06 FR FR7312444A patent/FR2179214B1/fr not_active Expired
-
1975
- 1975-08-14 ES ES440270A patent/ES440270A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1377329A (en) | 1974-12-11 |
| IL41933A0 (en) | 1973-06-29 |
| ES440270A1 (es) | 1977-03-16 |
| PL86814B1 (tr) | 1976-06-30 |
| RO65819A (ro) | 1981-07-30 |
| AU5422973A (en) | 1974-10-10 |
| EG10754A (en) | 1976-11-30 |
| IT981879B (it) | 1974-10-10 |
| HU168160B (tr) | 1976-03-28 |
| JPS4913336A (tr) | 1974-02-05 |
| CH582994A5 (tr) | 1976-12-31 |
| ZA732384B (en) | 1974-01-30 |
| ES413374A1 (es) | 1976-06-16 |
| DK134320C (da) | 1977-04-12 |
| RO62884A (fr) | 1978-01-15 |
| DE2216552B2 (de) | 1980-03-06 |
| DK134320B (da) | 1976-10-18 |
| CS183687B2 (en) | 1978-07-31 |
| DE2216552C3 (de) | 1980-10-30 |
| FR2179214B1 (tr) | 1977-02-04 |
| DD107934A5 (tr) | 1974-08-20 |
| BR7302379D0 (pt) | 1974-02-07 |
| FR2179214A1 (tr) | 1973-11-16 |
| BE797792A (fr) | 1973-10-05 |
| JPS4913122A (tr) | 1974-02-05 |
| TR17151A (tr) | 1974-04-25 |
| NL7304849A (tr) | 1973-10-09 |
| CS183697B2 (en) | 1978-07-31 |
| DE2216552A1 (de) | 1973-10-11 |
| AT322908B (de) | 1975-06-10 |
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