IE45870B1 - Artificial straw for making stable litters - Google Patents
Artificial straw for making stable littersInfo
- Publication number
- IE45870B1 IE45870B1 IE1859/77A IE185977A IE45870B1 IE 45870 B1 IE45870 B1 IE 45870B1 IE 1859/77 A IE1859/77 A IE 1859/77A IE 185977 A IE185977 A IE 185977A IE 45870 B1 IE45870 B1 IE 45870B1
- Authority
- IE
- Ireland
- Prior art keywords
- strips
- extrudate
- strip
- shaping
- straw
- Prior art date
Links
- 239000010902 straw Substances 0.000 title claims abstract description 79
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 11
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 8
- 238000007493 shaping process Methods 0.000 claims description 66
- 239000000126 substance Substances 0.000 claims description 39
- 238000005520 cutting process Methods 0.000 claims description 20
- 239000000945 filler Substances 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- -1 polyethylene Polymers 0.000 claims description 14
- 238000001125 extrusion Methods 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
- 239000005977 Ethylene Substances 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 235000006708 antioxidants Nutrition 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001748 polybutylene Polymers 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 235000012222 talc Nutrition 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229920001567 vinyl ester resin Polymers 0.000 claims 1
- 241001465754 Metazoa Species 0.000 description 21
- 235000013339 cereals Nutrition 0.000 description 8
- 241000283086 Equidae Species 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000007794 irritation Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 241000283690 Bos taurus Species 0.000 description 2
- 240000005979 Hordeum vulgare Species 0.000 description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 210000000003 hoof Anatomy 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229940063583 high-density polyethylene Drugs 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229940100630 metacresol Drugs 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
- A01K1/0152—Litter
- A01K1/0155—Litter comprising organic material
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
- A01K1/0152—Litter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B26—HAND CUTTING TOOLS; CUTTING; SEVERING
- B26D—CUTTING; DETAILS COMMON TO MACHINES FOR PERFORATING, PUNCHING, CUTTING-OUT, STAMPING-OUT OR SEVERING
- B26D1/00—Cutting through work characterised by the nature or movement of the cutting member or particular materials not otherwise provided for; Apparatus or machines therefor; Cutting members therefor
- B26D1/01—Cutting through work characterised by the nature or movement of the cutting member or particular materials not otherwise provided for; Apparatus or machines therefor; Cutting members therefor involving a cutting member which does not travel with the work
- B26D1/12—Cutting through work characterised by the nature or movement of the cutting member or particular materials not otherwise provided for; Apparatus or machines therefor; Cutting members therefor involving a cutting member which does not travel with the work having a cutting member moving about an axis
- B26D1/25—Cutting through work characterised by the nature or movement of the cutting member or particular materials not otherwise provided for; Apparatus or machines therefor; Cutting members therefor involving a cutting member which does not travel with the work having a cutting member moving about an axis with a non-circular cutting member
- B26D1/34—Cutting through work characterised by the nature or movement of the cutting member or particular materials not otherwise provided for; Apparatus or machines therefor; Cutting members therefor involving a cutting member which does not travel with the work having a cutting member moving about an axis with a non-circular cutting member moving about an axis parallel to the line of cut
- B26D1/38—Cutting through work characterised by the nature or movement of the cutting member or particular materials not otherwise provided for; Apparatus or machines therefor; Cutting members therefor involving a cutting member which does not travel with the work having a cutting member moving about an axis with a non-circular cutting member moving about an axis parallel to the line of cut and coacting with a fixed blade or other fixed member
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Forests & Forestry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Cultivation Of Plants (AREA)
- Housing For Livestock And Birds (AREA)
Abstract
The invention provides artificial straw adapted to be used instead of natural straw for stable litter or the like. This artificial straw is constituted of chips made of a crystalline thermoplastic alimentary polymer having an elongation at rupture of at least 50%, said chips having, when in a flat and stretched condition, a shape and dimensions such that each chip is inscribable in a parallelepiped having a length comprised between 30 and 800 mm, a width comprised between 1 and 20 mm and a height comprised between 0.06 and 12 mm, the thickness of said chips being comprised between 0.06 and 0.8 mm.
Description
The present invention relates to artificial straw
I 1 for use as stable litter for animals such as horses and cattle. The invention is also related to a method for manufacturing sueh artificial straw, as well as to apparatus for carrying out the method. The invention is related furthermore to stable litter constituted partially or entirely by the abovementioned artificial straw.
Numerous types of stable litter are known; in most cases these are constituted by cereal straw, especially corn straw, wheat straw, oat straw, rice straw, or barley straw. These known stable-litters do not efficiently absorb the liquid excreted by the animals, and this poor absorption results in fermentation of the litter, and these liquids, so that malodorous and dangerous ammoniacal gases are formed. Furthermore, oat straw is easily crushed, while barley straw contains pointed husks or chaffs which may irritate the skin of the animals. Apart from cereal straw, it has also been proposed to use sawdust, peat, moss and even dried leaves as stable litter. However, materials of this kind have considerable drawbacks in that they can undergo acid reactions which may result in a softening of the hooves of the animals, especially the hooves of horses, Furthermore, when the above-mentioned sorts of litter are placed in the stable, they produce considerable quantities of dust which can be harmful to the animals, especially
- 2 4 S a '70 horses, as well as to the personnel introducing the litter.
Amongst the main advantages of the artificial straw according to the invention are (i) that it has a soft feel and is light in weight; it cannot rot, it does not absorb the excreta of the animals, indeed the liquid excretions flow into a channel or groove provided, the artificial straw may easily be cleaned by means of water, for instance by a water-jet or in a washing machine, the thus cleaned or washed straw being re-usable several times over. Furthermore, this artificial straw can be handled by means of a fork in the same manner as cereal straw and, unlike the latter, it does not produce any dust or other particles harmful to the animals or personnel. The artificial straw may also be bundled or trussed by means of machines of the type currently used for cereal straw or hay. Also, due to the fact that the novel artificial straw is easy to handle and that it is necessary to replace only the soiled part of the straw to obtain clean stable litter, the litter in animal enclosures, especially for horses, can be prepared more rapidly than litter constituted by conventional straw.
According to the invention, we provide artificial straw for stable litters comprising strips of a crystalline thermoplastic alimentary polymer (as herein defined) having an elongation at rupture of at least 50%, and
5870 having, when in the flat and stretched state (as herein defined), a shape and dimensions such that each strip can be contained within a parallelepiped having a length from 30 to 800 mm, a width from 1 to 20 mm, and a height from 0.06 to 12 mm, the thickness of the strips being from 0.06 to 0.8 mm.
The term alimentary polymer or alimentary plastics material means a plastics material which can be used for wrapping food.
Xn one embodiment of the present invention the above-mentioned strips have, when in the flat and stretched state, such shapes and dimensions that they can be contained within parallelepipeds, the length of which are from 100 to 600 mm, the widths are from 2 to 15 mm and the heights are from 0.1 to 8 mm, said strips having a thickness from 0.1 to 0.6 mm.
When the artificial straw is to be used for making stable litter for horses or cattle or similar animals» said strips have preferably shapes and dimensions such that they can be contained within parallelepipeds each having a length from 150 to 400 mm, a width from 2.5 to 8 mm, and a height from 0.15 to 6 mm, said chips having a thickness from 0.15 to 0.5 mm.
The expression in the flat and stretched state as used with reference to the strips means the state of a
- 4 4 5 8 7 0 strip when one of its large surfaces is placed on a planar surface while the strip is not submitted to any tensile stress, fhe longitudinal direction of the strips being substantially rectilinear.
Furthermore, the thickness of a strip is defined as being the smallest dimension of the rectangle in which the surface resulting from the section of the strip in the flat and stretched state with a plane perpendicular to the longitudinal axis of said strip can be inscribed.
In the artificial straw according to the present invention the strips are randomly distributed and are not interconnected. These strips may have regular or irregular shapes. However, it is necessary that they do not have substantial protuberances which might hurt the animals.
The above-mentioned strips may have the shape of substantially rectilinear or spiral ribbons, having, in the flat and stretched state, substantially rectangular oval or semi-oval longitudinal and transverse cross-sections, and said transverse or longitudinal cross-sections may have, as the case may be, substantially constant dimensions from one zone to the other of any individual strip, as is the case, for instance of a substantially parallelepipedic ribbon, or the abovementioned longitudinal or transverse sections may have variable dimensions.
The strips may also have the form of substantially rectilinear or spiral ribbons, and they may be corrugated or waved over a part of their length or over their entire length, said ribbons having longitudinal cross-sections corresponding schematically to broken or wave-shaped lines and sections, in the direction of the waves or undulations, which are substantially rectangular, oval or semi-oval, said longitudinal section or sections in the direction of the corrugations or undulations having constant or variable dimensions.
When the strips constituting the artificial straw are waved or1 undulated, the amplitude and the periodicity of the undulations or waves may vary within comparatively broad limits. Advantageously the amplitude of the undulations or waves is comprised between 0.5 and 10 mm, preferably between 1 and 6 mm. As far as the periodicity of the undulations or waves is concerned, this should be selected in such a manner that there are 1 to 10 undulations or waves per 10 mm. In a preferred embodiment of the invention the direction of said undulations or said waves is inclined under an angle larger than 45°, preferably under an angle comprised between 60 to 80° with respect to the longitudinal direction of the strips.
As indicated hereinabove the polymeric substance from which the strips are made is selected from the group comprising the alimentary crystalline thermoplastic polymeric
- 6 4 5 8 70 substances having an elongation at rupture at least equal to 50%, said elongation being determined in accordance with Standard ASTM-D-638. According to this definition the terms crystalline and alimentary as applied to thermoplastic polymers indicate that said thermoplastic polymers exhibit on the one hand a crystalline phase when examined by the X-ray diffraction test- (crystalline polymers) and that on the other hand they are not toxic for the animals when absorbed by the latter, furthermore said thermoplastic polymers do not cause any irritation of the skin of said animals (alimentary polymers).
Amongst the polymers that can be used for preparing the strips with a view to manufacturing artificial straw in accordance with the present invention the following may be cited as being particularly advantageous: olefin homopolymers containing 2 to 8 carbon atoms, particularly polyethylene, such as low-density polyethylene or highdensity polyethylene, polypropylene, polybutene-1, crystalline ethylene - propylene or ethylene-butene-1 copolymers, copolymers of ethylene and vinyl or aeryl esters constitued mainly by ethylene, especially copolymers of ethylene and vinyl acetate and copolymers of ethylene and alkyl acrylate or methacrylate which contain a crystalline phase, copolymers obtained by the polymerisation of styrene in the presence of polybutadiene, polyisoprene or in the presence of an amorphous ethylene-propylene copolymer, which presents a crystalline phase, polyamides, and mixtures of such polymers.' In this group of polymers the preferred polymers for manufacturing the strips are for instance polyethylene, polypropylene, polybutene-1, crystalline copolymers of ethylene and propylene or butene-1 and mixtures of such polymers and copolymers.
If necessary, various additives may be added to the polymeric substance, the nature and the amount of such additives being so selected that the obtained composition provides strips exhibiting the required mechanical properties without being toxic when absorbed by the animals, and while not causing any irritation of the skin of the animals.
It is possible, for instance, to add 50 to 1000 ppm of a phenolic antioxidant such as di-tertiobutylparacresol, 4,4'-thiobistertiobutyl metacresol, 6-octadecylC3,5 di15 tertiobutyl 4-hydroxy) phenyl] - propinonate to the polymeric substance. The latter may also contain a photophysical absorber, especially benzophenone or substituted benzophenone whioh acts as a stabilizer against the effects of ultraviolet radiation, this absorber being added in an amount up to 1% by weight preferably comprised between 0.2 to 0.6% by weight of the polymeric substance. This polymeric substance may also contain pigments, especially TiO2 and Fe2O3 or organic dyes in a convenient proportion, for example up to about 1%, so as to confer the desired coloration to the straw.
- 8 4 6 8 7 Ο
In one particular embodiment of the invention the artificial straw is constituted by strips of the abovedefined kind and has furthermore an expanded structure.
This result is obtained by shaping said strips from an expanded substance produced from compositions which contain the polymeric substance, and alimentary expansion agent, especially azodicarbonamide in an sufficient amount, for instance 500 to 5000 ppm with respect of the polymeric substance; possibly said compositions may also contain other desired additives. According to a preferred feature of this embodiment the expanded substance resulting from the expansion of the polymeric substance under the effect of the expansion agent, which expanded substance is used for shaping the strips has a density comprised between 0.5 and 0.7.
In another embodiment of the invention the strips constituting the artificial straw are shaped from a composition containing the polymeric substance and an inert filler, for instance talcum or calcium carbonate, and possibly other conventional additives (antioxidant, pigment, dye, stabilizer), the amount of the filler being lo to 50%, preferably 20 to 40% of the total weight of the polymeric substance and the filler.
These additives, especially antioxidants, stabilizers, pigments, dyes, plastifiers, expansion agents as well as the inert fillers,· which are selected from tne group of additives and fillers considered as alimentary (i.e. not toxic when absorbed by the animals and causing no irritation of the skin of the animals), are incorporated in the polymeric
6 8 7 0 substance according to operating modes well known in the art, for instance by directly mixing all the ingredients or by preparing first a so-called pilot mixture of the additives and/or the inert filler with a portion of the polymeric substance and then incorporating said pilot mixture in the remainder of the polymeric substance, while selecting convenient proportions of said pilot mixture with a view to obtaining the required additive and filler concentration in the final mixture which is used for manufacturing the strips. The mixing operations may be carried out in a barrel, in an extruder, or in any other convenient device currently used to this end.
The strips constituting the artificial straw according to the invention may also have a double-layer or multi-layer structure resulting from the superposition of two or more layers made of the above-indicated polymeric substances.
The artificial straw according to the invention may be produced from the selected polymeric substance which possibly contains the desired additives and fillers, by any method allowing strips arid especially ribbons having a convenient shape and convenient dimensions to be obtained.
It is possible, for instance,'to prepare a full or tubular round billet from the polymeric substance and to shape this billet, by conveniently machining the same, into strips having the selected shape and dimensions.
- 10 Xt is also possible to extrude the polymeric substance in the molten state through a plurality of concentric slots and to cut from the resulting tubular extrudate strips having a selected thickness and length, using a rotating tool provided with knives which are arranged in recesses placed in front of the extrusion slots; in this case, the thus shaped strips will be unrolled through said recesses.
One method which is particularly adapted to be used to manufacture the artificial straw according to the invention comprises the steps of forming an extrudate having the shape of one or more strings, of a sheet or of a sheath, from said thermoplastic alimentary polymer, feeding the extrudate at a temperature lower than the melting temperature of said polymer through a shaping zone so as to confer to said extrudate a predetermined thickness and width, said thickness corresponding to the thickness of the strip to be obtained, whereas said width represents the width of said strip when said extrudate is in the form of a string, said width corresponding to the length of said strip when said extrudate is in the form of a sheet or a sheath, then submitting said shaped extrudate to a cutting operation to cut into the strips, having when in the flat and stretched state (as herein defined), a shape and dimensions such that each strip can be contained within a parallelepiped having a length from 30 to 800 mm, a width from 1 to 20 mm and a height from 0.06 to 12 mm, the thickness of the strip being from 0.06 to 0.8 mm and collecting the strips resulting from said cutting operation.
0 8 70
The temperature of the extrudate in the shaping zone, which must be lower than the melting temperature of the polymer substance should be lower than 100°C and be comprised preferably between 40 and 7OOC. Xf necessary the extrudate is cooled by passing through a liquid suoh as water between the zone of formation and the shaping zone of the extrudate so as to bring the temperature of the latter down to a convenient value for the shaping operation.
In the shaping 2one the thickness and the width of 10 the extrudate may be brought to the selected respective values, while the surface of the extrudate remains smooth. It is also possible during the shaping operation to confer a waved or undulate form to the extrudate over its entire surface or over part of said surface. The amplitude ahd the periodicity of the undulations or waves may vary within comparatively broad limits. Advantageously said amplitude is comprised between 0.5 and 10mm, preferably 1 and 6mm and said periodicity is selected so that there are 1 to 10 undulations or corrugations/lOmm. The direction of these undulations or corrugations (waves) may be parallel or perpendicular to the direction of formation of the extrudate, or may be inclined under an intermediate angle between the above-mentioned two extreme orientations. In a preferred embodiment of the invention the direction of the undulations or waves formed in the shaping zone is inclined under an angle of more than
45°, and particularly under an angle comprised between 60 and 80° with respect to the direction of formation of the string or with respect to a direction perpendicular to the direction of the formation of the sheet or sheath.
The strips resulting from the cutting operation may be received in a bundling zone wherein they are bundled by applying a known method for bundling conventional straw such as cereal straw.
When it is desired to prepare artificial straw constituted by strips having a foamed or expanded structure or containing an inert filler, an expanded or filler-loaded extrudate is formed from the polymeric substance containing an expansion agent or an inert filler the nature and amount of which correspond substantially to those indicated hereinabove, the expanded or filler-loadedextrudate being then submitted to a shaping operation and afterwards to a cutting operation, in the same manner as in the case where a nonexpanded extrudate or an extrudate without an inert filler is used.
It is also possible to prepare an extrudate in the form of a composite sheet comprising two or more layers, such sheet being obtained by co-extrusion (simultaneous extrusion) of two or more individual sheets constituted by
2o the selected ones of the polymeric substances indicated herein-above; after shaping such extrudate and cutting the thus shaped extrudate a spiral-formed strip may be obtained from the double-layer or multi-layer sheet obtained by the above-mentioned co-extrusion operation.
According to the present invention apparatus for carrying out the above-described method of manufacturing artificial straw comprises an extruder provided with a die adapted to form an extrudate from a thermoplastic aliementary polymer (as herein defined) having an elongation at rupture of at least 50%, the extrudate being in the form of a string, a sheet or a sheath, a shaping system downstream of said extruder and comprising two mutually superimposed shaping rolls having parallel axes, said shaping rolls defining between them a shaping zone so as to confer to said extrudate a predetermined thickness and width, said thickness corresponding to the thickness of the strip to be obtained, whereas said width represents the width of said strip when said extrudate is in the form of a string, said width corresponding to the length of said strip when said extrudate is in the form of a sheet or a sheath, the thickness of said shaping zone being adjustable by varying the distance between the respective axes of said shaping rolls, driving means for rotatively driving said shaping rolls in respective opposed angular directions, two mutually superimposed driving rolls for the extrudate arranged upstream of the shaping rolls and a cutting system downstream of said shaping system, said cutting system comprising a fixed knife the edge of which is adapted to support the shaped extrudate issuing from said shaping system, at least one movable knife having an edge parallel to the edge of said fixed knife and adapted to engage the edge of said fixed knife, and driving means associated with said movable knife for causing the edge of the latter to pass cyclically along the edge of said fixed knife.
The shaping rolls may have a lateral surface which is smooth or which is formed with grooves. In a particular embodiment said shaping rolls have their surfaces formed with oblique grooves the angle of inclination of which is so selected that they produce on the strips to be manufactured
S 8 7 0 undulations or waves forming with the longitudinal axis of the strip an angle larger than 45°, preferably an angle comprised between 60 to 80°.
Where desirable, two mutually superimposed driving rolls are preferably provided with longitudinal grooves, the respective axes of said driving rolls being parallel to each other and perpendicular to the direction of extrusion, the distance between the respective peripheries of said rolls being adjustable by varying the distance between the axes of said rolls, which latter are driven rotatively in mutually opposed angular directions by convenient means comprising a motor.
The above-described apparatus may also comprise a cooling chamber or cell arranged between the outlet of the nozzle of the extruder and the inlet of the shaping system, said chamber or cell being advantageously constituted by a container containing a convenient cooling liquid, such as water, at a convenient temperature, wherein the extrudate is immersed.
it is also possible to interpose between the outlet of the shaping system and the cutting system an aspirating system constituted by a venturi system and adapted to receive the shaped extrudate issuing from said shaping system and to transfer said extrudate to the cutting system.
In one embodiment of the invention a bundling device adapted to receive the strips constituting the artificial straw and to bundle the same is placed adjacent the outlet of the cutting system.
The present Invention will now be described in a more detailed manner with reference to the appended drawings which show, by way of example but not of limitation, various embodiments of the invention.
Figs. 1, la and lb show a strip according to the invention, and, more particularly, the transverse and longitudinal sections of said strip, respectively.
Figs. 2, 2a, 2b and 2c show an oval strip, as well as the transverse and longitudinal sections thereof.
Figs. 3, 3a, 3b and 3c show a corrugated zig-zag shaped strip in the flat and stretched condition, as well as the longitudinal and transverse sections of said strip.
Figs. 4, 4a and 4b and 4c, respectively show an undulated or wayed strip according to the invention in the flat and stretched condition, as well as the longitudinal and transverse section of said strip.
Figs. 5, 5a and 5b show a flat spiral strip and its longitudinal and transverse sections.
Fig. 6 shows apparatus for manufacturing strips such as the one shown in Figs. 3 to 3c.
The strip shown schematically in Fig. 1 is a substantially rectilinear ribbon having a substantially oval constant cross-section or transverse section, said section - as indicated, for instance, by A,A' - being shown in Fig. |a; said strip further has a variable rectangular longitudinal section. When this strip is placed onto a plane P in a flat and stretched condition it defines a line of contact Δ with this plane.
The ribbon in its flat and stretched condition is inscribable in a parallelepiped which in the embodiment shown is rectangular and indicated in the Figures by dashdot lines; said parallelepiped has a length L, a width 1 and a height h equal to the thickness e of the strip which are all comprised in the above-defined intervals. The longitudinal section of the ribbon has a surface area which varies from nil when the plane of section is a tangent to the strip to a maximum value (Fig. lb) when the plane of section B,B' passes through the longitudinal axis of the strip. The maximum longitudinal section of the strip is a rectangle having a length L and a width 1, whereas the cross-section of said strip is represented by an oval inscribable in the rectangle having a length 1 and a width e.
Fig. 2 schematically shows a strip which in its flat and stretched condition has the shape of a prism with two parallel planar surfaces in the form of an oval, said strip being inscribable in a rectangular parallelepiped indicated in dash-dot lines, said parallelepiped having a length L, a width 1 and height h which is equal to the thickness e of the strip, all of which are comprised in the appropriate intervals. This strip has variable rectangular cross-sections one of the dimensions of which is equal to e (thickness of the strip), while the other dimension varies as a function of the position of the plane of section between nil and a value equal to 1 (section C,C' of Fig. 2,as indicated by Fig. 2b), while passing, between these limitvalues, through intermediate values (section D,D' of Fig. 2 as , 48870 indicated by Fig. 2a); the strip furthermore has a longitudinal section in the form of rectangles one of the dimensions of which is equal to e while the other dimension varies from nil to a value equal to L while passing, between these limit-values, through intermediate values (section Ε, E' of Fig. 2 as indicated by Fig. 2c).
The strip schematically shown in Fig. 3 has the shape of an accordion-like ribbon which is corrugated in zig-zag manner. The ridges of said ribbon are regularly spaced with an amplitude M and a period P which may be comprised, for example, in the previously defined intervals, said ridges being arranged in a direction which forms with the longitudinal axis of the strip an angle a comprised preferably between 60 and 80°. When this ribbon is in its flat and stretched condition it is inscribable in a rectangular parallelepiped having a length L, a width 1, and a height h, comprised within the desired intervals. The cross-section of the strip is constant and represents a rectangle having a length 1 and a width e (section J,J' of Fig. 3a as indicated by Fig.3c), whereas the longitudinal section of said strip has the form of a ribbon with a thickness e, said ribbon extending along an accordioft-like broken line (section F,F' of Fig.3 as indicated by Fig. 3b), e designating the thickness of the strip.
Fig. 4 shows a strip having the form of an undulated ribbon the regularly spaced undulations of Which have an amplitude M and a period T, said undulations having a direction which forms an angle u comprised substantially between 60 and 80° with the axis or the longitudinal
- 18 4 ά 8 7 0 direction of the strip. When said strip is in the flat and stretched condition, it is inscribable in a rectangular parallelepiped having a length L, a width 1 and a height h, which are comprised in the desired intervals such as defined herein-above (cf, Fig. 4a). The cross-section of the chip in the direction of the undulations (section N,N* of Fig.4a, as indicated by Fig. 4c) is constant and has substantially the shape of a rectangle having a length 1 and a width substantially equal to the thickness e of the strip, whereas the longitudinal section of said strip has the form of an undulated ribbon having a thickness substantially equal to e (section G,G'of Fig.4 as indicated by Fig. 4b), the amplitude of said undulations being indicated by the reference letter M, while their period is indicated at T.
The strip shown in Fig. 5 is a spiral strip which, when in its stretched and flat condition, has the shape of a rectangular parallelepiped (cf. Fig. 5a) having a length L, a width 1 and a height h equal to the thickness e of the strip. The cross-section of this strip (i.e. the section K,K' as indicated in Fig. 5a) has the form of a rectangle (cf. Fig. 5b) the length of which equals 1 and the width of which equals e.
The apparatus schematically shown in Fig. 6 comprises a screw extruder 1 provided with a hopper 2 by which the polymeric substance or the mixture of polymeric substance with the additive or additives (anti-oxidant, stabilizer, pigment, dye, plastifier, expansion agent)
- 19 4 5 8 7 0 and/or the inert filler (talcum, CaC03) is introduced into the extruder, as well as an extrusion die 3 through which said polymeric substance or said mixture issues from the extruder in the form of extrudate 4. The extruder shown in the drawing, is provided with a die allowing the extrusion of the polymeric substance or the mixture of said polymeric substance with the additives and/or the inert filler in the form of strings 4. It is also possible to use other extruders provided with dies which allow producing of an extrudate in the form of a sheet or a sheath; it is possible, too, to produce a sheet constituted by two co-extruded basic sheets. A cooling cell 5 constituted substantially by a container filled with water is arranged downstream of the die for cooling the extruded strings. Downstream of the said cooling cell a shaping system 6 is provided which comprises an inlet channel 7 for the strings, two superimposed driving rolls 8 and 9 the axes of which are parallel to each other and perpendicular to the direction of extrusion, said rolls being provided with longitudinal grooves and defining between them a passage zone the thickness of which is adjustable by varying the distance between the axes of said rolls; downstream of said driving rolls the shaping system comprises two shaping rolls 10 and 11 which are superimposed to each other and the axes of which are parallel to each other and perpendicular to the direction of extrusion; said shaping rolls also define between them a zone the thickness of which is adjustable by varying the distance between the axes of said shaping rolls. In the embodiment shown the shaping rolls are
4 6 8 7ο constituted by two helical gears the helical grooves of which are inclined under an angle of 20° with respect to the axes of the gears, whereby the strings passing through the interval between said two gears are shaped into a corrugated accordion-like form as shown in Fig. 3. The shaping sytem further comprises known means (not shown) such as a motor for rotatively driving the driving rolls on the one hand, and the shaping rolls on the other hand in such a way that the driving rolls rotate in respective opposed angular directions and that the shaping rolls also rotate in respective opposed angular directions so as to feed the strings in the extrusion direction; said shaping system also comprises known means {not shown) for adjusting the interval defined between the driving rolls and the interval defined between the shaping rolls by varying the relative position of the axes of said rolls, or, in other words, by varying on the one hand the distance between the respective axes of the driving rolls and, on the other hand, the distance between the respective axes of the shaping rolls. The shaping rolls 10 and 11 whieh in the embodiment shown in Fig. 6 are cylindrical and provided with helical grooves may have different shapes and be provided with other types of grooves; they may also have a substantially smooth surface, depending on the pattern of the strips to be produced. An aspirating system 13 is arranged downstream of the shaping system and receives the shaped strings 12 issuing from said shaping system. This aspirating system is constituted by a venturi tube defining a passage zone which comprises in a manner
8 7 0 known per se a convergent inlet zone connected to a divergent outlet zone, as well as a conduit 14 for introducing pressurized air, which conduit opens into the convergent zone adjacent the narrowest portion of the latter. A cutting system 15 is arranged downstream of the aspirating system 13 and comprises a fixed knife 16 the rectilinear edge 17 of which supports the shaped extrudate issuing from the aspirating system, said cutting system further comprising a rotative knife 18 having a rectilinear edge 19 which is parallel to the edge 17 of the fixed knife. Edge 19 of the rotative knife is adapted to be pressed against the edge 17 while being rotated. A channel 20 mounted on the lower part of the cutting system allows the strips 21 obtained by cutting the shaped strings to be collected.
The cutting sytem furthermore comprises means (not shown) including a motor for driving the rotary knife and for causing the edge of said knife to pass cyclicly along the edge of the fixed knife. The frequency of the passage of the edge of the movable knife along the edge of the fixed knife may be adjusted by varying the rotating speed of the movable knife in a manner known per se, e.g. by means of a variable speed transmission device interposed between the movable knife and the association driving motor.
The above-described apparatus operates as follows!
The polymeric substance selected for manufacturing the strips is introduced alone or together with convenient additives and/or convenient fillers into the extruder 1
8 7 0 through hopper 2,. Said polymeric substance issues from the extruder through extrusion die 3 in the form of strings 4 which are cooled to a convenient temperature, preferably to a temperature comprised between 40 and 60°C, by passing through the water contained in container 5 which constitutes the cooling cell. The thus cooled strings are fed into the shaping system by the receiving channel 7 associated tp said system and under the action of the driving rolls 8 and 9 of the shaping system, between which rolls said strings 4 are transported by friction; the strings penetrate the space or interval defined between the above-described helical gears 10 and 11 which constitute the shaping rolls of the shaping system. The height of this interval is so selected that at the outlet of the shaping system, i.e. after the passage of the strings through the shaping rolls, the shaped strings have a width 1, a thickness e and an accordion-like corrugated profile defined by period T and amplitude M of the ridges, as indicated in Fig. 3. The shaped strings 12 issuing from the shaping system 6 are aspired by the aspirating system 13 under the action of the pressurized air injected through conduit 14 into the convergent portion of the convergent - divergent passage 2one of said aspirating system defining a venturi tube, and are transported towards the fixed bldde 16 and the movable blade 18 of the rotary knife 15 where they are cut into strips 21 having the desired length. This length is defined by conveniently selecting the rotative speed of the movable blade of the rotary knife, taking into account the feeding speed of the
3 8 7 0 strings. The shaped strips 21 are collected in the chanel 20 from where they are removed towards a shelving zone. Channel 20 may feed the strips for instance to a bundling machine which bundles the thus formed strips.
When used for making stable litters the artificial straw according to the invention is constituted by a high number of strips of a kind described herein-above which are randomly distributed and not interconnected; this artificial straw is placed in a convenient amount and in a uniform manner into the boxes for the animals, for example by means of a fork as usual in the case where conventional cereal straw is used for making stable litters. It is not necessary to replace each time the entirety of the stable litter of a given box; it suffices indeed to replace only the soiled portion of the stable litter which, in most cases, does only represent a small section of said stable litter.
The soiled straw can be cleaned by washing by means of a water spray or by means of a machine, and the thus cleaned straw can be re-used after drying as long as its mechanical properties and its aspect remain acceptable.
The artificial straw according to the invention may be used for making stable litters for various animals, especially for farm animals, for animals kept in menageries, for horses kept in racing stables, said artificial straw can even be used for making litters for animals, especially horses, being transported by train, ship or airplane.
8 8 7 0
The invention will be described hereinafter in a more detailed manner by means of an example which is given by way of illustration but not of limitation.
EXAMPLE:
Polyethylene having a melt index of 0.3 and which had been coloured so as to present a straw-yellow hue by adding 0.2% TiO2 and 0.005% Fe2O3was use<^ f°r preparing strips by means of apparatus similar to that schematically shown in Fig. 6, said strips having the form of accordionlike corrugated ribbons as indicated in Figs. 3 to 3c.
These strips, when in their flat and stretched condition, had the form of an accordion-like ribbon inscribable in a rectangular parallelepiped having a length of about 320 mm, a width of about 5 mm and a height of about 2.5 mm, the thickness of said strips being about 0.4 mm. This corrugated accordion-like ribbon had regularly spaced corrugations or ridges, the amplitude M of which was equal to about 2 mm and the period of which was equal to about 4 mm? the direction of'said corrugations or ridges forming an angle of about 80° with the longitudinal axis of the strip.
A stable-litter for a horse-box was prepared using 100 kg of the artificial straw constituted by such strips which were randomly distributed and not interconnected. The horse which was placed onto said stable litter, did not show any sign of difficulty to adapt itself to the litter and its behaviour was similar to that of a horse placed onto a conventional stable-litter made of cereal straw. Each time the stable-litter of this box was remade, only the soiled oortion of the litter was replaced, while the remainder of the litter was left in place as being immediately reusable? for remaking the litter about 10 kg artificial straw (i.e. about 1/10 of the amount which would have been necessary if the stable-litter were constituted by cereal straw and would consequently have to be replaced entirely) were used. Furthermore, the soiled straw was cleaned after each remake of the litter, said cleaning operation being performed by a water-spray, and after drying the cleaned straw could be re-used until its mechanical properties and its aspect had become unacceptable. Under these conditions the total amount of the artificial straw initially put into the box was replaced after only three months with fresh straw, i.e. with straw which had not been submitted to any intermediate cleaning operation.
Tests have also been run with artificial straw constituted by polypropylene or a crystalline copolymer of ethylene and propylene containing 10% by weight of ethylene and containing also the same additives as those whioh have been used for the above-mentioned polyethylene strips? these polyethylene or copolymeric strips have the form of ribbons similar to those shown in Fig. 5, which ribbons have in their flat and stretched condition the form of a rectangular parallelepiped having a length of about 320 mm, a width of about 6 mm and a height of about 0.5 mm, said height being equal to the thickness of the strip. These strips were prepared by means of apparatus
- 26 similar to that shown in Fig. 6, however the apparatus used was provided with shaping rolls having a substantially'smooth surface without grooves. The results obtained were similar to those obtained when using the artificial styaw constituted by polyethylene strips.
The present invention is not limited to the above-described embodiments and examples; numerous modificiations may be made by any person skilled in the art, within the scope of the invention as defined in the appended claims.
Claims (10)
1. Artificial straw for stable litters comprising strips of a crystalline thermoplastic alimentary polymer (as herein defined) having an elongation at rupture of at least 50%, and having, when in the flat and stretched state
2.5 cutting system downstream of said shaping system, said cutting system comprising a fixed knife the edge of which is adapted to support the shaped extrudate issuing from j * t said shaping system, at least one movable knife having an edge parallel to the edge of said fixed knife and adapted 2o to engage the edge of said fixed knife, and driving means associated with said movable knife for causing the edge of the latter to pass cyclically along the edge of said fixed knife. 24. The apparatus according to claim 23, wherein said 25 shaping rolls have a smooth lateral surface or a lateral surface provided with preferably oblique grooves the inclination of which is so selected that they produce on said chips undulations or corrugations which are inclined with respect to the longitudinal axis of the chip under an 33 4387 0 angle larger than 45%, preferably under an angle comprised between 60 and 80°. 25. The apparatus according to any of claims 23 and 24, wherein said two mutually superimposed driving
3. Artificial straw of any of Claims 1 and 2, wherein the strips, when in the flat and stretched state, have each a form and dimensions such as to be contained within a parallelepiped having a length from 150 to 400 mm, a width 20 from 2.5 to 8 mm, and a height from 0.15 to 6 mm, the thickness of said strips being from 0.15 to 0.5 mm. 4. S 8 7 Ο polybutadiene, polyisopropene or an amorphous ethylene copolymer;- the polyamides and mixtures of the abovementiOned polymers. 10. The straw according to any of claims 1 to 9, 4 6 8 70
4. Artificial straw according to any of Claims 1 to 3, wherein said strips are in the form of substantially rectilinear or spiral ribbons, each ribbon when in the 25 flat or stretched state, having substantially rectangular, oval or seni-cval longitudinal cross-sections. 5. Substantially as herein described with reference to the Example. 29. Artificial straw whenever made by a method according to any of Claims 15 to 22 and 28. 30. Artificial straw for stable litters according to Claim 1, substantially as herein described with reference to and as shewn in Figures 5 rolls are provided with longitudinal grooves, said driving rolls having parallel axes which are perpendicular to the direction, of extrusion, and said shaping rolls defining between them an interval adapted to be adjusted by varying the distance between said’ axes of said driving rolls, the 10 latter being rotatively driven in respective opposed angular directions by driving means including a motor 26. The method according to any of claims 23 to 25, further comprising an aspirating system of the venturi type providing a passage zone defined by a convergent inlet 15 zone connected to a divergent outlet zone and having an inlet conduit adapted to he connected to a source of pressurized air and opening into the convergent zone adjacent the narrowest part of the latter, said apparatus possibly further comprising a cooling cell for cooling the 2o extrudate, said cooling oell being arranged between the outlet of the die of the extruder and said shaping system, the shaping and cutting zones being arranged so that the strips obtained have when in the flat and stretched state (as herein defined), a shape and dimensions such that each 25 strip can be contained v/ithin a parallelepiped having a length from 30 to 800 mm, a width from 1 to 20 mm and a height from 0.06 to 12 mm, the thickness of the strip being from 0.06 to 0.8 mm. -45870 27. Apparatus for manufacturing artificial straw according to Claim 23, substantially as herein described with reference to and as shown in Figure 6 of the accompanying drawings. 28. A method of manufacturing artificial straw according to Claim 15, 5 to the thickness of the strip to be obtained, whereas said width represents the width of said strip when said extrudate is in the form of a string, said width corresponding to the length of said strip when said extrudate is in the form of a sheet or a sheath, the thickness of said shaping zone being 4o adjustable by varying the distance between the respective axes of said shaping rolls driving means for rotatively driving said shaping rolls in respective opposed angular directions, two mutually superimposed driving rolls for the extrudate arranged upstream of the shaping rolls and a 5 wherein the polymeric substance constituting Said strips is selected from the group comprising polyethylene, polypropylene, polybutene-1, crystalline copolymer of ethylene and propylene or butene-1, and mixtures of these polymers. 11. The straw according to any of claims 1 to 10, wherein said strips have an expanded structure. 12. The straw according to any of Claims 1 to 11, wherein said strips are produced from a polymeric substance containing an inert filler of the alimentary 15 type, such as talcum or calcium carbonate, the amount of said filler representing 10 to 50%, and preferably 20 to 40% of the total weight of the polymeric substance and the inert filler. 13. The straw according to any of claims 1 to 12, 20 wherein said strips are produced from a polymeric substance containing additives such as pigments, dyes, stabilizers, anti-oxidants, plastifiers of the alimentary type. 14. The straw according to any of claims 1 to 13, wherein said strips have a double-layer or multi-layer 25 structure resulting from the superposition of two or more layers of polymeric substance. 15. A method of manufacturing artificial straw according to any of claims 1 to 14, comprising the steps of forming an extrudate having the shape of one or more 30 strings, of a sheet or of a sheath, from said thermoplastic - 30 alimentary polymer, feeding the extrudate at a temperature lewer than the melting temnerature, of said polymer through a shaping zone so as to confer to said extrudate a predetermined thickness and width, said thickness corresponding to the thickness of the strip to be obtained, whereas said width represents the width of said strip when said extrudate is in the form of a string, said width corresponding to the length of said strip when said extrudate is in the form of a sheet or a sheath, then submitting said'shaped extrudate to a cutting operation to cut it into strips, having when in the flat and stretched state (as herein defined) a shape and dimensions such that each strip can be contained within a parallelepiped having a length from 30 to 800 mm, a width from 1 to 20 mm and a height from 0.06 to 12 mm, the thickness of the strip being from 0.06 to 0.8 mm and collecting the strips resulting from said cutting operation. 16. The method according to claim 15 wherein the temperature of the extrudate in the shaping zone is lower than 100OC, and preferably comprised between 40 and 70°C. 17. The method according to any of claims 15 and 16, wherein said shaping operation is carried out in such a manner that the resulting shaped extrudate has a zig-zaglike corrugated or undulated shape over its entire surface or over a portion of its surface. 18. The method according to claim 17 wherein the amplitude of said undulations or corrugations of the shaped extrudate is comprised between 0.5 and 10 mm, and preferably between 1 and 6 mm. 19. The method according to any of claims 17 and 18, wherein the periodicity of the undulations or corrugations of the shaped extrudate is so selected that the latter has 1 to 10 undulations or corrugations per 10 mm. 20. The method according to any of claims 17 to 19, wherein the direction of the undulations or corrugations of the shaped extrudate forms an angle larger than 45°, and preferably 'comprised between 60 and 80° with the direction of formation of the extrudate in the form of a string, or With a direction perpendicular to the direction of formation of the extrudate in the form of a sheet or a sheath. 21. The method according to any of claims 15 to 20, wherein said extrudate is constituted by a composite sheet having 2 or more layers, said composite sheet being obtained by co-extrusion of 2 or more sheets of polymeric substance. 22. The method according to any of claims 15 to 21, wherein said extrudate is formed from a polymeric substance containing additives such as pigments, dyes, anti-oxidants, stabilizers, plastifiers, expansion agents and/or inert fillers of the alimentary type. 23. Apparatus for manufacturing artificial straw comprising an extruder provided with a die adapted to form an extrudate from a thermoplastic alimentary polymer (as herein defined) having an elongation at rupture of at least 50%, the extrudate being in the form of a string, a sheet or a sheath, a shaping system downstream of said extruder and comprising two mutually superimposed shaping rolls having parallel axes, said shaping rolls defining between them a shaping zone so as to confer to said extrudate a predetermined thickness and width, said thickness corresponding
5. Artificial straw according to any of Claims 1 to 3, wherein said strips are in the form of substantially rectilinear or spiral ribbons which are undulated or corrugated in a zig-zag manner over at least part of their length and the longitudinal sections of which represent broken or undulated lines, while their sections in the direction of the corrugations and undulations are substantially rectangular, oval or semi-oval. 5 (as herein defined), a shape and dimensions such that each strip can be contained within a parallelepiped having a length from 30 to 800 mm, a width from 1 to 20 mm and a height from 0.06 to 12 mm, the thickness of the strip being from 0.06 to 0.8 mm. 10 2. Artificial straw according to Claim 1, wherein the strips, when in the flat and stretched state can each be contained within a parallelepiped having a length from 100 to 600 mm, a width from 2 to 15 mm and a height from 0.1 to 8 mm, ‘the thickness of said strips being from 0.1 15 to 0.6 mm.
6. The straw according to Claim 5, wherein the amplitude of said undulations or corrugations of the strips is comprised between 0.5 and 10 mm, preferably between 1 -and 6 mm.
7. The straw according to any of Claims 5 and 6, wherein the periodicity of the undulations or corrugations of said strips is so selected that each strip comprises 1 to 10 undulations or corrugations per 10 mm.
8. The straw according to any of Claims 5 to 7, wherein the direction of said undulations or corrugations of the strips is inclined under an angle comprised between 60 to 80°, with respect to the longitudinal direction of the strips.
9. The straw according to any of claims 1 to 8, wherein said polymeric substance constituting said strips is selected from the group constituted by the olefin homopolymers having 2 to 8 carbon atoms, especially polyethylene, polypropylene, polybutene-1, the crystalline copolymers of ethylene and propylene or butene-1, the copolymers of ethylene and vinyl esters or acryl esters containing a major proportion of ethylene, the copolymers obtained by polymerization of styrene in the presence of
10. 1 to 5 of the accompanying drawings.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7627769A FR2363986A1 (en) | 1976-09-09 | 1976-09-09 | Reusable artificial straw for animal bedding - consists of strips of opt. crimped plastic |
FR7721870A FR2400837A1 (en) | 1977-07-18 | 1977-07-18 | Reusable artificial straw for animal bedding - consists of strips of opt. crimped plastic |
Publications (2)
Publication Number | Publication Date |
---|---|
IE45870L IE45870L (en) | 1978-03-09 |
IE45870B1 true IE45870B1 (en) | 1982-12-15 |
Family
ID=26219631
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE1859/77A IE45870B1 (en) | 1976-09-09 | 1977-09-07 | Artificial straw for making stable litters |
Country Status (6)
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US (1) | US4171401A (en) |
JP (1) | JPS5354580A (en) |
DE (1) | DE2740758A1 (en) |
GB (1) | GB1553039A (en) |
IE (1) | IE45870B1 (en) |
IT (1) | IT1084232B (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2623362B1 (en) * | 1987-11-23 | 1990-07-13 | Alimel Sa | STRAW CONDITIONING PROCESS |
US4855166A (en) * | 1988-12-05 | 1989-08-08 | Allison John G | Artificial pine needle |
US5405694A (en) * | 1989-06-02 | 1995-04-11 | Fossnit A/S | Stuffing |
DK271989A (en) * | 1989-06-02 | 1990-12-03 | Fossnit As | FILL |
US5330804A (en) * | 1991-03-27 | 1994-07-19 | Earth Trends, Inc. | Synthetic wood mulch |
GB9117795D0 (en) * | 1991-08-17 | 1991-10-09 | Dunlop Ltd | Livestock bedding |
EP0609267A1 (en) * | 1991-10-08 | 1994-08-10 | Cofo Ltd. | Animal housing accessory |
US5429073A (en) * | 1993-10-26 | 1995-07-04 | Shakespeare Company | Bedding materials for animals |
US20030196742A1 (en) * | 1997-02-07 | 2003-10-23 | Weder Donald E. | Synthetic decorative moss simulating Spanish moss and method for making same |
US6468196B1 (en) * | 1998-07-09 | 2002-10-22 | Southpac Trust International, Inc. | Synthetic decorative grass simulating Spanish moss and method for making same |
US6340522B1 (en) * | 2000-07-13 | 2002-01-22 | Wr Grace & Co.-Conn. | Three-dimensional twisted fibers and processes for making same |
US6615536B2 (en) | 2001-03-23 | 2003-09-09 | David Carvin | Artificial pine needle |
US20070243028A1 (en) * | 2006-04-18 | 2007-10-18 | Garza Mario C | Synthetic ground cover |
KR101032197B1 (en) * | 2010-12-29 | 2011-05-02 | 김용태 | Composition for manufacturing of artificial rice straw, manufacturing method of artificial rice straw and artificial rice straw using the method |
CA3185829A1 (en) | 2014-07-25 | 2016-01-28 | Innovive, Inc. | Animal containment enrichment compositions and methods |
US11147891B1 (en) * | 2019-07-18 | 2021-10-19 | James Gatto | Reusable straw and case with integrated cleaning, drying and sanitizing member |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2000013A (en) * | 1931-11-05 | 1935-05-07 | Celanese Corp | Method of producing artificial straw and product thereof |
US2354435A (en) * | 1941-08-20 | 1944-07-25 | Firestone Tire & Rubber Co | Plastic fabric |
US3015873A (en) * | 1955-03-08 | 1962-01-09 | Schiesser Ag Trikotfabriken | Complex artificial filaments |
US3402548A (en) * | 1963-02-11 | 1968-09-24 | Eastman Kodak Co | Process for fracturing flat ribbons and the product thereof |
US3565742A (en) * | 1967-07-17 | 1971-02-23 | Monsanto Co | Flocked golf green |
US3597312A (en) * | 1969-05-07 | 1971-08-03 | Westvaco Corp | Synthetic fibrous filler and paper containing the filler |
US3634570A (en) * | 1969-10-20 | 1972-01-11 | Du Pont | Elastomer granulation process |
US3940522A (en) * | 1971-05-27 | 1976-02-24 | E. I. Du Pont De Nemours And Company | Synthetic fibers and pile fabrics made therefrom |
JPS5655266Y2 (en) * | 1972-06-14 | 1981-12-23 | ||
US4061804A (en) * | 1976-08-12 | 1977-12-06 | Akzona Incorporated | Non-directional rectangular filaments and products |
-
1977
- 1977-09-07 IE IE1859/77A patent/IE45870B1/en unknown
- 1977-09-07 GB GB37333/77A patent/GB1553039A/en not_active Expired
- 1977-09-08 US US05/831,419 patent/US4171401A/en not_active Expired - Lifetime
- 1977-09-08 IT IT27382/77A patent/IT1084232B/en active
- 1977-09-08 JP JP10732177A patent/JPS5354580A/en active Pending
- 1977-09-09 DE DE19772740758 patent/DE2740758A1/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
US4171401A (en) | 1979-10-16 |
JPS5354580A (en) | 1978-05-18 |
IE45870L (en) | 1978-03-09 |
IT1084232B (en) | 1985-05-25 |
GB1553039A (en) | 1979-09-19 |
DE2740758A1 (en) | 1978-03-16 |
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