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IE32624B1 - Trifluoromethyl-phenyl-ureas and pesticidal preparations containing them - Google Patents

Trifluoromethyl-phenyl-ureas and pesticidal preparations containing them

Info

Publication number
IE32624B1
IE32624B1 IE80/69A IE8069A IE32624B1 IE 32624 B1 IE32624 B1 IE 32624B1 IE 80/69 A IE80/69 A IE 80/69A IE 8069 A IE8069 A IE 8069A IE 32624 B1 IE32624 B1 IE 32624B1
Authority
IE
Ireland
Prior art keywords
group
atom
ureas
substituted
oxygen
Prior art date
Application number
IE80/69A
Other versions
IE32624L (en
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of IE32624L publication Critical patent/IE32624L/en
Publication of IE32624B1 publication Critical patent/IE32624B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
    • C07D295/215—Radicals derived from nitrogen analogues of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C275/32—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms
    • C07C275/34—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms having nitrogen atoms of urea groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/64—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups singly-bound to oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/39—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton at least one of the nitrogen atoms being part of any of the groups, X being a hetero atom, Y being any atom
    • C07C323/43—Y being a hetero atom
    • C07C323/44—X or Y being nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C335/00—Thioureas, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C335/04—Derivatives of thiourea
    • C07C335/16—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C335/18—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D203/00—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D203/04—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D203/06—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D203/16—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with acylated ring nitrogen atoms
    • C07D203/20—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with acylated ring nitrogen atoms by carbonic acid, or by sulfur or nitrogen analogues thereof, e.g. carbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/04—1,3-Oxazines; Hydrogenated 1,3-oxazines
    • C07D265/06—1,3-Oxazines; Hydrogenated 1,3-oxazines not condensed with other rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,260,386. Trifluoromethyl - phenyl - ureas. CIBA-GEIGY A.G. 23 Jan., 1969 [23 Jan., 1968], No. 3873/69. Heading C2C. Trifluoromethylphenyl ureas of the general formula in which X and Y each represents an oxygen or sulphur atom; R 1 represents an alkyl, alkenyl, alkinyl or alkoxy group which may be substituted by a halogen atom, or an alkyl group whose chain contains 1 or 2 oxygen atoms, or a phenyl group which may be substituted by a single -CF 3 group, and/or by one or more substituents, which may be the same or different, selected from halogen atoms, -CH 3 or -OCH 3 groups; R 2 represents a hydrogen atom or a lower alkyl group, or R 1 and R 2 together with the nitrogen atom linked with them form a heterocycle, and R 3 represents a lower aliphatic group whose chain may be interrupted by an oxygen or sulphur atom, or a phenyl group which may be unsubstituted or substituted in at most 3 positions by halogen atoms, lower alkyl, alkoxy, alkylmercapto, cyano and/or trifluoromethyl groups with the proviso that when both X and Y represent an O atom, R 2 represents a hydrogen atom or a C 1 -C 4 alkyl group and R 1 represents a methyl group, R 3 does not represent a substituted or unsubstituted phenyl group may be prepared by reacting an aromatic residue of the general formula with a second reactant B, which together are capable of forming the thioureas or ureas corresponding to the final formula, in which X and R 3 have the above meanings, and one of the substituents A or B represents the grouping -N-CYYR<SP>1</SP>, -N-CY-halogen, -N-CY-NH 2 or -N=C-Y, in which Y represents oxygen or sulphur and R<SP>1</SP> represents any desired residue that contains carbon and is easy to eliminate, and the other substituent represents the basic group -NH, in which the free valencies are linked with hydrogen unless they form part of a primary or secondary, linear or cyclic amine, in each case, if desired, with additional alkylation and/or additional halogenation. Several compounds are claimed per se. The compounds are used as active ingredients in herbicidal compositions and some act as defoliants. [GB1260386A]
IE80/69A 1968-01-23 1969-01-21 Trifluoromethyl-phenyl-ureas and pesticidal preparations containing them IE32624B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH102268A CH493195A (en) 1968-01-23 1968-01-23 Pesticides

Publications (2)

Publication Number Publication Date
IE32624L IE32624L (en) 1969-07-23
IE32624B1 true IE32624B1 (en) 1973-10-03

Family

ID=4200614

Family Applications (1)

Application Number Title Priority Date Filing Date
IE80/69A IE32624B1 (en) 1968-01-23 1969-01-21 Trifluoromethyl-phenyl-ureas and pesticidal preparations containing them

Country Status (15)

Country Link
BE (1) BE727286A (en)
BG (1) BG17267A3 (en)
CH (1) CH493195A (en)
CS (1) CS158236B2 (en)
DE (1) DE1901501C3 (en)
DK (1) DK124443B (en)
FR (1) FR2000570A1 (en)
GB (1) GB1260386A (en)
IE (1) IE32624B1 (en)
IL (1) IL31444A (en)
NL (1) NL159091B (en)
RO (1) RO54785A (en)
SE (1) SE375095B (en)
SU (1) SU404191A3 (en)
YU (1) YU34874B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3222974A1 (en) * 1982-06-19 1983-12-22 Basf Ag, 6700 Ludwigshafen NEW 5-PHENOXYBENZISOTHIAZOL-4'-UREA DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS HERBICIDES
ATE103589T1 (en) * 1989-11-10 1994-04-15 Agrolinz Agrarchemikalien PROCESS FOR THE PRODUCTION OF PURE UNBALANCED DISUBSTITUTED UREAS.
DE10029564A1 (en) 2000-06-22 2002-01-03 Continental Ag elastomeric bearings
AU2003243921B2 (en) 2002-06-27 2009-05-07 Novo Nordisk A/S Aryl carbonyl derivatives as therapeutic agents
DK1723128T3 (en) 2004-01-06 2013-02-18 Novo Nordisk As Heteroarlurines and their use as glucokinase activators
JP2009500378A (en) 2005-07-08 2009-01-08 ノボ・ノルデイスク・エー／エス Dicycloalkylcarbamoylureas as glucokinase activators
ES2422383T3 (en) 2005-07-14 2013-09-11 Novo Nordisk As Urea glucokinase activators
WO2008084043A1 (en) 2007-01-09 2008-07-17 Novo Nordisk A/S Urea glucokinase activators
CA2675111C (en) 2007-01-11 2016-04-05 Novo Nordisk A\S Urea glucokinase activators
KR20210020866A (en) 2018-06-12 2021-02-24 브이티브이 테라퓨틱스 엘엘씨 The therapeutic use of glucokinase activators in combination with insulin or insulin analogues

Also Published As

Publication number Publication date
NL159091B (en) 1979-01-15
YU34874B (en) 1980-04-30
IL31444A (en) 1973-03-30
SE375095B (en) 1975-04-07
DK124443B (en) 1972-10-23
DE1901501C3 (en) 1978-05-03
GB1260386A (en) 1972-01-19
BE727286A (en) 1969-07-22
CS158236B2 (en) 1974-10-15
SU404191A3 (en) 1973-10-26
IL31444A0 (en) 1969-03-27
FR2000570A1 (en) 1969-09-12
CH493195A (en) 1970-07-15
BG17267A3 (en) 1973-07-25
YU15469A (en) 1979-10-31
DE1901501B2 (en) 1977-09-22
RO54785A (en) 1973-05-17
NL6901066A (en) 1969-07-25
DE1901501A1 (en) 1969-08-28
IE32624L (en) 1969-07-23

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