HUP9904527A2 - Új heterogyűrűs metallocének és ezeket tartalmazó polimerizációs katalizátorok - Google Patents
Új heterogyűrűs metallocének és ezeket tartalmazó polimerizációs katalizátorokInfo
- Publication number
- HUP9904527A2 HUP9904527A2 HU9904527A HUP9904527A HUP9904527A2 HU P9904527 A2 HUP9904527 A2 HU P9904527A2 HU 9904527 A HU9904527 A HU 9904527A HU P9904527 A HUP9904527 A HU P9904527A HU P9904527 A2 HUP9904527 A2 HU P9904527A2
- Authority
- HU
- Hungary
- Prior art keywords
- pipe dust
- containing pipe
- whose value
- integer whose
- ring
- Prior art date
Links
- 125000000623 heterocyclic group Chemical group 0.000 title abstract 2
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 239000000428 dust Substances 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- -1 pentadienyl Chemical group 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 125000006413 ring segment Chemical group 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 239000004575 stone Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052714 tellurium Inorganic materials 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
- C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
- C07D333/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
- C07D333/70—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
- C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D495/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Indole Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A találmány tárgyát heterőgyűrűs metallőcének egy új ősztálya képezi,tővábbá az ezt tartalmazó katalizátőr-rendszer és addíciósanpőlimerizálható mőnőmerek pőlimerizálása a találmány szerintikatalizátőr-rendszer alkalmazásával. A találmány szerinti heterőgyűrűsmetallőcének az (I) általánős képlettel írhatók le - a képletben Yjelentése hat p elektrőnt tartalmazó, közpőnti csőpőrttal bírókőőrdináló csőpőrt, amely Me-t közvetlenül kőőrdinálja, és amellyelegy vagy több őlyan gyűrű van összeőlvadva, amely legalább egy nemszénatőmőt tartalmaz, amelyek jelentése: B, N, O, Al, P, S, Ga, Ge, As,Se, In, Sn, Sb és Te; R'' jelentése az Y és Z csőpőrtőkat összekötődivalens híd; Z jelentése kőőrdináló csőpőrt, amelynek jelentése az Yhelyettesítőre megadőtt, vagy nyitőtt pentadienőiltartalmú csőpőrt,ciklőpentadieniltartalmú csőpőrt, heterőgyűrűsciklőpentadieniltartalmú csőpőrt, nitrőgéntartalmú csőpőrt,főszfőrtartalmú csőpőrt, őxigéntartalmú csőpőrt vagy kéntartalmúcsőpőrt; Me jelentése a periódűsős rendszer 3., 4., 5., 6. csőpőrtjábavagy a lantanidák vagy aktinidák körébe tartőzó elem; Q egyenes vagyelágazó láncú, telített vagy telítetlen alkilcsőpőrt, arilcsőpőrt,alkil-aril-csőpőrt, aril-alkil-csőpőrt vagy halőgénatőm; P jelentésestabil, nem-kőőrdináló vagy pszeűdő nem-kőőrdináló elleniőn; ijelentése egész szám, amelynek értéke 0 vagy 1; j jelentése egészszám, amelynek értéke 1 és 3 közötti; jj jelentése egész szám,amelynek értéke 0 és 2 közötti; k jelentése egész szám, amelynekértéke 1 és 3 közötti; l jelentése egész szám, amelynek értéke 0 és 2közötti. YjR''ZjjMeQkPe (I) ŕ
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96118369 | 1996-11-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HUP9904527A2 true HUP9904527A2 (hu) | 2000-05-28 |
Family
ID=8223400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU9904527A HUP9904527A2 (hu) | 1996-11-15 | 1997-11-12 | Új heterogyűrűs metallocének és ezeket tartalmazó polimerizációs katalizátorok |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US7238818B2 (hu) |
| EP (2) | EP1327636B1 (hu) |
| KR (1) | KR100536794B1 (hu) |
| CN (1) | CN1113890C (hu) |
| AR (1) | AR009613A1 (hu) |
| AU (1) | AU733813B2 (hu) |
| BR (1) | BR9715006B1 (hu) |
| CA (1) | CA2271861C (hu) |
| DE (2) | DE69721807T2 (hu) |
| ES (2) | ES2256662T3 (hu) |
| HU (1) | HUP9904527A2 (hu) |
| ID (1) | ID22443A (hu) |
| IL (1) | IL129600A0 (hu) |
| NO (1) | NO992352L (hu) |
| PE (1) | PE52899A1 (hu) |
| PL (1) | PL188107B1 (hu) |
| RU (1) | RU2194708C2 (hu) |
| TR (1) | TR199901635T2 (hu) |
| TW (1) | TW394779B (hu) |
| WO (1) | WO1998022486A1 (hu) |
| ZA (1) | ZA9710211B (hu) |
Families Citing this family (115)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HUP9904527A2 (hu) * | 1996-11-15 | 2000-05-28 | Montell Technology Company B.V. | Új heterogyűrűs metallocének és ezeket tartalmazó polimerizációs katalizátorok |
| US6451938B1 (en) † | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
| JP4540755B2 (ja) | 1997-11-12 | 2010-09-08 | バセル テクノロジー カンパニー ベスローテン フェンノートシャップ | メタロセンおよびオレフィン重合用の触媒 |
| WO2000018808A1 (en) | 1998-09-30 | 2000-04-06 | Exxon Chemical Patents Inc. | Cationic group 3 catalyst system |
| DE19903306A1 (de) * | 1999-01-28 | 2000-08-03 | Targor Gmbh | Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung |
| EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
| KR20020034193A (ko) | 1999-09-22 | 2002-05-08 | 간디 지오프레이 에이치. | 올레핀 중합을 위한 촉매 시스템 및 방법 |
| WO2001032758A1 (en) | 1999-11-04 | 2001-05-10 | Exxon Chemical Patents Inc. | Propylene copolymer foams and their use |
| US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| US6281306B1 (en) | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
| WO2001046278A2 (en) | 1999-12-21 | 2001-06-28 | Exxon Chemical Patents Inc. | Adhesive alpha-olefin inter-polymers |
| DE19962814A1 (de) | 1999-12-23 | 2001-06-28 | Targor Gmbh | Neues Katalysatorsystem und dessen Verwendung |
| DE19962910A1 (de) | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| ATE373669T1 (de) * | 1999-12-28 | 2007-10-15 | Basell Polyolefine Gmbh | Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren |
| AU3016401A (en) | 1999-12-28 | 2001-07-09 | Basell Technology Company B.V. | Process for the preparation of ethylene polymers |
| DE60024595T2 (de) | 1999-12-28 | 2006-07-27 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Ethylenpolymeren |
| ATE292148T1 (de) * | 2000-01-18 | 2005-04-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis |
| WO2001062764A1 (en) | 2000-02-24 | 2001-08-30 | Basell Technology Company B.V. | Organometallic compound useful as cocatalyst for polymerizing olefins |
| US20040072975A1 (en) | 2000-03-17 | 2004-04-15 | Jorg Schottek | Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins |
| GB0007002D0 (en) * | 2000-03-22 | 2000-05-10 | Borealis Polymers Oy | Catalysts |
| DE10025412A1 (de) | 2000-05-24 | 2001-11-29 | Basell Polypropylen Gmbh | Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| DE10028432A1 (de) | 2000-06-13 | 2001-12-20 | Basell Polyolefine Gmbh | Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation |
| US6703458B2 (en) | 2000-12-22 | 2004-03-09 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins |
| US7183332B2 (en) | 2000-12-22 | 2007-02-27 | Basell Poliolefine Italia S.P.A. | Process for the preparation of porous polymers and polymers obtainable thereof |
| EP1387827B1 (en) | 2001-05-15 | 2008-09-24 | Basell Polyolefine GmbH | Synthesis of cyclopentadiene derivatives |
| DE60202524T2 (de) | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
| DE10126265A1 (de) | 2001-05-29 | 2002-12-05 | Basell Polyolefine Gmbh | Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte |
| ATE519789T1 (de) | 2001-06-12 | 2011-08-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von buten-1 |
| US7074864B2 (en) | 2001-06-12 | 2006-07-11 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| ATE321061T1 (de) | 2001-06-22 | 2006-04-15 | Basell Polyolefine Gmbh | Metallocene, verwendung in katalysatoren für olefinpolymerisation |
| DE10145453A1 (de) | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
| EP1430088B1 (de) | 2001-09-14 | 2008-10-22 | Basell Polyolefine GmbH | Verfahren zur polymerisation von olefinen |
| US7022793B2 (en) | 2001-11-27 | 2006-04-04 | Basell Polyolefine Gmbh | Process for the treatment of polymer compositions |
| DE60213452T2 (de) | 2001-11-30 | 2007-08-23 | Basell Polyolefine Gmbh | Metallocene und verfahren zur herstellung von propylenpolymeren |
| EP1525261B1 (en) * | 2002-06-26 | 2012-07-11 | Basell Poliolefine Italia S.r.l. | Impact-resistant polyolefin compositions |
| PL372195A1 (en) * | 2002-06-26 | 2005-07-11 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| WO2004007570A2 (en) | 2002-07-15 | 2004-01-22 | Basell Polyolefine Gmbh | Preparation of supported catalyst systems |
| WO2004007569A1 (en) | 2002-07-15 | 2004-01-22 | Basell Polyolefine Gmbh | Preparation of catalyst systems |
| US20060089253A1 (en) * | 2002-08-13 | 2006-04-27 | Shahram Mihan | Monocyclopentadienyl complexes |
| AU2003264065A1 (en) | 2002-08-22 | 2004-03-11 | Basell Polyolefine Gmbh | Monocyclopentadienyl complexes |
| AU2003260432A1 (en) | 2002-09-06 | 2004-03-29 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| CN101724110B (zh) | 2002-10-15 | 2013-03-27 | 埃克森美孚化学专利公司 | 用于烯烃聚合的多催化剂体系和由其生产的聚合物 |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| WO2004041871A1 (en) | 2002-11-04 | 2004-05-21 | Basell Polyolefine Gmbh | Preparation of catalyst compositions having improved activity |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| US7534848B2 (en) | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
| DE10260095A1 (de) | 2002-12-19 | 2004-07-01 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von heterocyclischen Ketonen |
| AU2003294888A1 (en) | 2002-12-20 | 2004-07-14 | Basell Polyolefine Gmbh | COPOLYMERS OF ETHYLENE WITH Alpha-OLEFINS |
| DE60321822D1 (de) | 2002-12-20 | 2008-08-07 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
| US7195806B2 (en) | 2003-01-17 | 2007-03-27 | Fina Technology, Inc. | High gloss polyethylene articles |
| WO2004087776A1 (en) | 2003-04-03 | 2004-10-14 | Basell Polyolefine Gmbh | Preparation of polyolefins having high molecular weights in the presence of an organic transition metal compound in a gas-phase fluidized-bed reactor |
| CN100362025C (zh) | 2003-04-17 | 2008-01-16 | 巴塞尔聚烯烃意大利有限责任公司 | 气相烯烃聚合方法 |
| US7507782B2 (en) | 2003-05-21 | 2009-03-24 | Basell Polyolefine Gmbh | Transition-metal complexes with tridentate, nitrogen-containing ligands |
| JP4709748B2 (ja) | 2003-07-04 | 2011-06-22 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィン重合方法 |
| DE10352139A1 (de) * | 2003-11-04 | 2005-06-09 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem und Verfahren zur Herstellung von Polyolefinen |
| KR20060118552A (ko) | 2003-12-16 | 2006-11-23 | 바젤 폴리올레핀 게엠베하 | 모노시클로펜타디에닐 착물 |
| US7629464B2 (en) | 2003-12-19 | 2009-12-08 | Basell Polyolefine Gmbh | Monocyclopentadienyl complexes |
| EP1697428B1 (en) | 2003-12-23 | 2014-01-15 | Basell Polyolefine GmbH | Catalyst system for olefin polymerization |
| BRPI0418117B1 (pt) | 2003-12-23 | 2015-10-13 | Basell Polyolefine Gmbh | preparação de cocatalisadores suportados |
| US7335250B2 (en) | 2004-02-06 | 2008-02-26 | Ivoclar Vivadent Ag | Dental composites based on X-ray-opaque mixed oxides prepared by flame spraying |
| EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
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1997
- 1997-11-12 HU HU9904527A patent/HUP9904527A2/hu unknown
- 1997-11-12 DE DE69721807T patent/DE69721807T2/de not_active Expired - Lifetime
- 1997-11-12 WO PCT/EP1997/006297 patent/WO1998022486A1/en active IP Right Grant
- 1997-11-12 PL PL97333462A patent/PL188107B1/pl not_active IP Right Cessation
- 1997-11-12 EP EP03075392A patent/EP1327636B1/en not_active Expired - Lifetime
- 1997-11-12 KR KR10-1999-7004277A patent/KR100536794B1/ko not_active IP Right Cessation
- 1997-11-12 RU RU99112514/04A patent/RU2194708C2/ru not_active IP Right Cessation
- 1997-11-12 ES ES03075392T patent/ES2256662T3/es not_active Expired - Lifetime
- 1997-11-12 IL IL12960097A patent/IL129600A0/xx unknown
- 1997-11-12 DE DE69735068T patent/DE69735068T2/de not_active Expired - Lifetime
- 1997-11-12 ES ES97950179T patent/ES2197377T3/es not_active Expired - Lifetime
- 1997-11-12 CA CA002271861A patent/CA2271861C/en not_active Expired - Lifetime
- 1997-11-12 CN CN97181299A patent/CN1113890C/zh not_active Expired - Lifetime
- 1997-11-12 EP EP97950179A patent/EP0938491B1/en not_active Expired - Lifetime
- 1997-11-12 AU AU53216/98A patent/AU733813B2/en not_active Ceased
- 1997-11-12 TR TR1999/01635T patent/TR199901635T2/xx unknown
- 1997-11-12 BR BRPI9715006-1A patent/BR9715006B1/pt not_active IP Right Cessation
- 1997-11-12 ZA ZA9710211A patent/ZA9710211B/xx unknown
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- 1997-11-17 PE PE1997001036A patent/PE52899A1/es not_active Application Discontinuation
- 1997-11-17 AR ARP970105366A patent/AR009613A1/es active IP Right Grant
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