HUP0003040A2 - Process for the manufacture of carboxylic acids - Google Patents
Process for the manufacture of carboxylic acidsInfo
- Publication number
- HUP0003040A2 HUP0003040A2 HU0003040A HUP0003040A HUP0003040A2 HU P0003040 A2 HUP0003040 A2 HU P0003040A2 HU 0003040 A HU0003040 A HU 0003040A HU P0003040 A HUP0003040 A HU P0003040A HU P0003040 A2 HUP0003040 A2 HU P0003040A2
- Authority
- HU
- Hungary
- Prior art keywords
- reactor
- carboxylic acids
- reacted
- branched
- cauldron
- Prior art date
Links
- 150000001735 carboxylic acids Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 238000010992 reflux Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002798 polar solvent Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical class O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Atalálmány szerinti eljárással elágazó láncú karbonsavakat állítanakelő oly módon, hogy egy elágazó láncú olefint egy üstreaktorban vagyegy visszakeveredés-mentes reaktorban szén-monoxiddal és vízzelreagáltatnak, vagy egy alkoholt, észtert vagy étert, mint egy elágazóláncú olefinprekurzort, egy üstreaktorban vagy egy visszakeveredés-mentes reaktorban szén-monoxiddal reagáltatnak egy szilárd, szulfonáltsavas ioncserélő gyanta jelenlétében, amely gyanta savassága legalább65tömeg%-os kénsav savasságával ekvivalens, egy kémiailag inert,poláris oldószer jelenlétében, amely oldószer karbonsavak vagy ezekésztere, vagy adott esetben szubsztituált választott szulfolán körébőlmegválasztott, és ahol a víz/olefin mólaránya 0,5-2. ÓBranched-chain carboxylic acids are prepared by the process according to the invention in such a way that a branched-chain olefin is reacted with carbon monoxide and water in a cauldron reactor or a non-reflux reactor, or an alcohol, ester or ether as a branched-chain olefin precursor is reacted with carbon in a cauldron reactor or a non-reflux reactor are reacted with -monoxide in the presence of a solid, sulphonated acid ion exchange resin, the acidity of which is equivalent to at least 65% by mass of sulfuric acid, in the presence of a chemically inert, polar solvent, which solvent is selected from the range of carboxylic acids or their esters, or optionally substituted sulfolane, and where the water/olefin molar ratio 0.5-2. HE
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97201893 | 1997-06-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HUP0003040A2 true HUP0003040A2 (en) | 2001-01-29 |
Family
ID=8228466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU0003040A HUP0003040A2 (en) | 1997-06-20 | 1998-06-16 | Process for the manufacture of carboxylic acids |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6294691B1 (en) |
| EP (1) | EP0989969B1 (en) |
| JP (1) | JP2002504919A (en) |
| KR (1) | KR20010013976A (en) |
| CN (1) | CN1260776A (en) |
| AT (1) | ATE215923T1 (en) |
| AU (1) | AU725397B2 (en) |
| BR (1) | BR9810189A (en) |
| CA (1) | CA2294393A1 (en) |
| DE (1) | DE69804792T2 (en) |
| HU (1) | HUP0003040A2 (en) |
| WO (1) | WO1998058896A1 (en) |
| ZA (1) | ZA985290B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2607301A (en) | 1999-12-29 | 2001-07-09 | Ormco Corporation | Custom orthodontic appliance forming method and apparatus |
| CN106631755A (en) * | 2016-12-14 | 2017-05-10 | 安阳师范学院 | Method for catalytically synthesizing organic carboxylic acid by strong-acidic ion exchange resin |
| CN111790443B (en) * | 2020-07-17 | 2022-11-04 | 万华化学集团股份有限公司 | Supported catalyst and preparation method and application thereof |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3036124A (en) * | 1959-08-24 | 1962-05-22 | Hercules Powder Co Ltd | Manufacture of carboxylic acids |
| GB998974A (en) * | 1962-03-07 | 1965-07-21 | Unilever Ltd | Synthesis of organic carboxylic acids |
| GB1362997A (en) * | 1971-10-20 | 1974-08-14 | Bp Chem Int Ltd | Catalysts and catalytic precesses |
| US4652677A (en) * | 1980-03-10 | 1987-03-24 | The Standard Oil Company | Selective hydrocarboxylation of propylene to isobutyric acid |
| JPS62187424A (en) * | 1986-02-13 | 1987-08-15 | Mitsubishi Chem Ind Ltd | Carbonylation of olefins |
| DE3620581A1 (en) * | 1986-06-19 | 1987-12-23 | Basf Ag | METHOD FOR THE PRODUCTION OF CARBONIC ACIDS |
| US5241112A (en) * | 1991-04-09 | 1993-08-31 | Catalytica, Inc. | Preparation of trialkylacetic acids, particularly of pivalic acid, using solid acid catalysis |
| US5250726A (en) * | 1992-08-24 | 1993-10-05 | E. I. Du Pont De Nemours And Company | Process for the preparation of 3-pentenoic acid from butadiene |
| WO1996010006A1 (en) * | 1994-09-29 | 1996-04-04 | Idemitsu Petrochemical Co., Ltd. | Process for producing monocarboxylic and/or dicarboxylic acids |
| JPH10511666A (en) * | 1994-12-28 | 1998-11-10 | エクソン・ケミカル・パテンツ・インク | Production of trialkylacetic acid using solid cationic resin catalyst system |
-
1998
- 1998-06-16 AU AU86302/98A patent/AU725397B2/en not_active Ceased
- 1998-06-16 BR BR9810189-7A patent/BR9810189A/en not_active Application Discontinuation
- 1998-06-16 EP EP98937552A patent/EP0989969B1/en not_active Expired - Lifetime
- 1998-06-16 CA CA002294393A patent/CA2294393A1/en not_active Abandoned
- 1998-06-16 AT AT98937552T patent/ATE215923T1/en not_active IP Right Cessation
- 1998-06-16 KR KR19997012002A patent/KR20010013976A/en not_active Application Discontinuation
- 1998-06-16 JP JP50380899A patent/JP2002504919A/en active Pending
- 1998-06-16 CN CN98806234A patent/CN1260776A/en active Pending
- 1998-06-16 HU HU0003040A patent/HUP0003040A2/en unknown
- 1998-06-16 WO PCT/EP1998/003998 patent/WO1998058896A1/en not_active Application Discontinuation
- 1998-06-16 DE DE69804792T patent/DE69804792T2/en not_active Expired - Fee Related
- 1998-06-18 ZA ZA985290A patent/ZA985290B/en unknown
- 1998-06-22 US US09/102,983 patent/US6294691B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU8630298A (en) | 1999-01-04 |
| AU725397B2 (en) | 2000-10-12 |
| DE69804792D1 (en) | 2002-05-16 |
| ZA985290B (en) | 1999-01-11 |
| BR9810189A (en) | 2000-08-08 |
| ATE215923T1 (en) | 2002-04-15 |
| WO1998058896A1 (en) | 1998-12-30 |
| JP2002504919A (en) | 2002-02-12 |
| EP0989969B1 (en) | 2002-04-10 |
| CN1260776A (en) | 2000-07-19 |
| US6294691B1 (en) | 2001-09-25 |
| KR20010013976A (en) | 2001-02-26 |
| EP0989969A1 (en) | 2000-04-05 |
| WO1998058896A8 (en) | 1999-12-23 |
| DE69804792T2 (en) | 2002-08-14 |
| CA2294393A1 (en) | 1998-12-30 |
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