HRP20240677T1 - Pripravak strukturnog ljepila - Google Patents
Pripravak strukturnog ljepila Download PDFInfo
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- HRP20240677T1 HRP20240677T1 HRP20240677TT HRP20240677T HRP20240677T1 HR P20240677 T1 HRP20240677 T1 HR P20240677T1 HR P20240677T T HRP20240677T T HR P20240677TT HR P20240677 T HRP20240677 T HR P20240677T HR P20240677 T1 HRP20240677 T1 HR P20240677T1
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- Croatia
- Prior art keywords
- preparation according
- methacrylate
- monomer
- structural adhesive
- butadiene
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 13
- 239000000853 adhesive Substances 0.000 title claims 8
- 230000001070 adhesive effect Effects 0.000 title claims 8
- 239000000178 monomer Substances 0.000 claims 12
- 239000000463 material Substances 0.000 claims 9
- 239000005062 Polybutadiene Substances 0.000 claims 7
- 229920002857 polybutadiene Polymers 0.000 claims 7
- 239000002685 polymerization catalyst Substances 0.000 claims 7
- 229920001400 block copolymer Polymers 0.000 claims 6
- 239000002245 particle Substances 0.000 claims 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 5
- 239000003795 chemical substances by application Substances 0.000 claims 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 4
- 229920001971 elastomer Polymers 0.000 claims 4
- 239000000806 elastomer Substances 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 3
- 239000007870 radical polymerization initiator Substances 0.000 claims 3
- 229920001169 thermoplastic Polymers 0.000 claims 3
- 239000004416 thermosoftening plastic Substances 0.000 claims 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 239000002318 adhesion promoter Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- -1 phosphate ester Chemical class 0.000 claims 2
- 229920001084 poly(chloroprene) Polymers 0.000 claims 2
- 229920001195 polyisoprene Polymers 0.000 claims 2
- 239000011347 resin Substances 0.000 claims 2
- 229920005989 resin Polymers 0.000 claims 2
- 229910000077 silane Inorganic materials 0.000 claims 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 claims 1
- MKWLYHVMTQWQHI-UHFFFAOYSA-N 1,3-dioxan-5-yl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1COCOC1 MKWLYHVMTQWQHI-UHFFFAOYSA-N 0.000 claims 1
- GJGBXCGXKNONJU-UHFFFAOYSA-N 1,3-dioxolan-4-ylmethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1COCO1 GJGBXCGXKNONJU-UHFFFAOYSA-N 0.000 claims 1
- YIJYFLXQHDOQGW-UHFFFAOYSA-N 2-[2,4,6-trioxo-3,5-bis(2-prop-2-enoyloxyethyl)-1,3,5-triazinan-1-yl]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCN1C(=O)N(CCOC(=O)C=C)C(=O)N(CCOC(=O)C=C)C1=O YIJYFLXQHDOQGW-UHFFFAOYSA-N 0.000 claims 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims 1
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 claims 1
- KFCDDRTYJQZGKK-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enenitrile Chemical compound C=CC#N.CC(=C)C(O)=O KFCDDRTYJQZGKK-UHFFFAOYSA-N 0.000 claims 1
- 239000004925 Acrylic resin Substances 0.000 claims 1
- 229920000178 Acrylic resin Polymers 0.000 claims 1
- 239000004342 Benzoyl peroxide Substances 0.000 claims 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 claims 1
- 229920000459 Nitrile rubber Polymers 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical group C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims 1
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 235000019400 benzoyl peroxide Nutrition 0.000 claims 1
- VZIBAPMSKYQDFH-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;prop-2-enenitrile;styrene Chemical compound C=CC=C.C=CC#N.CC(=C)C(O)=O.C=CC1=CC=CC=C1 VZIBAPMSKYQDFH-UHFFFAOYSA-N 0.000 claims 1
- LKAVYBZHOYOUSX-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;styrene Chemical compound C=CC=C.CC(=C)C(O)=O.C=CC1=CC=CC=C1 LKAVYBZHOYOUSX-UHFFFAOYSA-N 0.000 claims 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- 229940119545 isobornyl methacrylate Drugs 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 claims 1
- 239000012764 mineral filler Substances 0.000 claims 1
- 150000002978 peroxides Chemical group 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 239000003505 polymerization initiator Substances 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims 1
- 150000004992 toluidines Chemical class 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/23—Azo-compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (29)
1. Pripravak koji se može koristiti u strukturnom ljepilu, pri čemu navedeni pripravak sadrži (težinski):
(a) između 35% i 60% najmanje jednog (met)akrilatnog monomera, koji uključuje
i. najmanje 20 % molekule opće formule (I), molekulu opće formule (II) ili smjesu molekula opće formule (I) i (II)
[image]
pri čemu su R, R1 i R2 redom i neovisno H ili CH3,
ii. najmanje 5% jednog ili više drugih (met)akrilatnih monomera,
(b) od 8 do 30% % čestica formiranih od termoplastične ljuske i elastomerne jezgre
(c) između 9 i 15 % elastomernog blok kopolimera koji sadrži stiren i najmanje jedan drugi monomer ili smjese takvih blok kopolimera
(d) između 5 i 25% elastomera, odabranog između nefunkcionaliziranog polibutadiena, polibutadiena s karboksilnim završetkom, polibutadiena s vinilnim završetkom, metakriliranog polibutadiena, poliizoprena, polikloroprena, kopolimera butadien-akrilonitril i njihovih smjesa;
pri čemu je zbroj postotaka spojeva (b), (c) i (d) najmanje 35%.
2. Pripravak prema zahtjevu 1, naznačen time što je navedeni monomer formule (I) ili i (II) smjesa 1,3-dioksan-5-il metakrilata i 1,3-dioksolan-4-ilmetil metakrilata.
3. Pripravak prema zahtjevu 1 ili 2, naznačen time što sadrži između 25 i 35% monomera opće formule (I) ili (II) i najmanje 10% drugog monomera.
4. Pripravak prema jednom od zahtjeva 1 do 3, naznačen time što je drugi monomer odabran iz skupine koju čine izobornil metakrilat, 2-etilheksil metakrilat, 2-etilheksil akrilat, 2-hidroksietil metakrilat, 2-hidroksipropil metakrilat, lauril metakrilat, esteri na bazi polietilen glikola i smjese tih estera.
5. Pripravak prema jednom od zahtjeva 1 do 4, naznačen time što sadrži najmanje 5% 2-etilheksil akrilata.
6. Pripravak prema jednom od zahtjeva 1 do 5, naznačen time što čestice (b), elastomerni blok kopolimer (c) i elastomer (d) sadrže butadien.
7. Pripravak prema jednom od zahtjeva 1 do 6, naznačen time što sadrži 15 do 25% čestica koje se sastoje od termoplastične ljuske i elastomerne jezgre (b).
8. Pripravak prema jednom od zahtjeva 1 do 6, naznačen time što sadrži između 9 i 12% elastomernog blok kopolimera (c).
9. Pripravak prema jednom od zahtjeva 1 do 6, naznačen time što sadrži između 10 i 25% elastomera (d).
10. Pripravak prema jednom od zahtjeva 1 do 9, naznačen time što su čestice (b) odabrane između čestica akrilonitril-butadien-stirena, metakrilat-butadien-stirena, metakrilat-akrilonitrila-butadien-stirena, metakrilat-akrilonitrila i njihovih smjesa.
11. Pripravak prema jednom od zahtjeva 1 do 10, naznačen time što je količina čestica formiranih od termoplastične ljuske i elastomerne jezgre (ljuske jezgre) (b) manja ili jednaka 26%.
12. Pripravak prema jednom od zahtjeva 1 do 11, naznačen time što je drugi monomer elastomernog blok kopolimera (c) odabran između izoprena i butadiena.
13. Pripravak prema jednom od zahtjeva 1 do 12, naznačen time što je elastomerni blok kopolimer (c) odabran između SIS, SBS, SIBS, SEBS i njihovih smjesa.
14. Pripravak prema jednom od zahtjeva 1 do 13, naznačen time što je navedeni elastomer (d) odabran između nefunkcionaliziranog polibutadiena, polibutadiena funkcionaliziranog karboksilnim krajevima, polibutadiena funkcionaliziranog vinilnim krajevima, poliizoprena, polikloroprena i smjesa ovih elemenata.
15. Pripravak prema jednom od zahtjeva 1 do 14, naznačen time što također sadrži amin odabran iz skupine koja se sastoji od toluidina, anilina i supstituiranih ili nesupstituiranih fenola.
16. Pripravak prema jednom od zahtjeva 1 do 15, naznačen time što također sadrži kristalno ljubičasti lakton ili 4,4',4" metilidnetris (N, N-dimetilanilin).
17. Pripravak prema jednom od zahtjeva 1 do 16, naznačen time što također sadrži promotor adhezije na bazi fosfatnog estera, poželjno metakriliran.
18. Pripravak prema zahtjevu 9, naznačen time što je navedeni promotor adhezije na bazi fosfatnog estera 2-hidroksietil metakrilat fosfat ester ili smjesa 2-hidroksietil metakrilat mono- i di-fosfat estera.
19. Pripravak prema jednom od zahtjeva 1 do 18, naznačen time što nadalje sadrži monomer metalnog akrilata.
20. Pripravak prema jednom od zahtjeva 1 do 19, naznačen time što također sadrži najmanje jedan dodatni spoj odabran između reološkog sredstva, kiselog monomera, trimetilolpropan trimetakrilata i tris (2-hidroksi etil) izocijanurat triakrilata.
21. Dvokomponentno strukturno ljepilo koje sadrži:
a. pripravak prema bilo kojem od zahtjeva 1 do 20, i
b. sredstvo katalizatora polimerizacije, za dodavanje navedenom pripravku za iniciranje polimerizacije met(akrilatnih) monomera, koje sadrži inicijator polimerizacije slobodnih radikala.
22. Dvokomponentno strukturno ljepilo prema zahtjevu 21, naznačen time što je sredstvo za iniciranje polimerizacije slobodnih radikala prisutno u sredstvu katalizatora polimerizacije peroksid, naročito benzoil peroksid, i što sadrži između 5 i 40% (poželjno između 10 i 20%) težinski sredstva za iniciranje polimerizacije.
23. Dvokomponentno strukturno ljepilo prema zahtjevu 21 ili 22, naznačen time što navedeni katalizator polimerizacije također sadrži epoksidirani silan, pri čemu je navedeni epoksidirani silan između 1 i 30% težinski.
24. Dvokomponentno strukturno ljepilo prema jednom od zahtjeva 21 do 23, naznačen time što katalizator polimerizacije dodatno sadrži epoksidnu smolu.
25. Dvokomponentno strukturno ljepilo prema zahtjevima 21 do 24, naznačeno time što katalizator polimerizacije dodatno sadrži mineralna punila.
26. Uložak za nanošenje dvokomponentnog strukturnog ljepila prema jednom od zahtjeva 21 do 25, koji sadrži
i. odjeljak koji sadrži navedenu (met)akrilnu smolu koja sadrži akrilatne ili metakrilatne monomere prema jednom od zahtjeva 1 do 20
ii. drugi odjeljak koji sadrži navedeno sredstvo katalizatora polimerizacije
27. Kombinirana upotreba smole prema bilo kojem od zahtjeva 1 do 20 i sredstva katalizatora koji sadrži radikal peroksidnog tipa kao inicijator polimerizacije u postupku za lijepljenje jednog materijala na drugi materijal.
28. Upotreba prema zahtjevu 27, naznačena time što je najmanje jedan materijal metalan.
29. Postupak lijepljenja prvog materijala na drugi materijal, naznačen time što uključuje korake
i. nanošenje pripravaka prema jednom od zahtjeva 1 do 20, pomiješanog sa sredstvom katalizatora polimerizacije koji sadrži inicijator polimerizacije slobodnih radikala, na prvi materijal, i
ii. nanošenje drugog materijala preko prvog materijala,
dva materijala se lijepe jedan na drugi nakon polimerizacije smole.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| FR1856878A FR3084370B1 (fr) | 2018-07-24 | 2018-07-24 | Composition pour adhesif structural |
| EP19740593.9A EP3827036B1 (fr) | 2018-07-24 | 2019-07-23 | Composition pour adhésif structural |
| PCT/EP2019/069781 WO2020020877A1 (fr) | 2018-07-24 | 2019-07-23 | Composition pour adhesif structural |
Publications (1)
| Publication Number | Publication Date |
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| HRP20240677T1 true HRP20240677T1 (hr) | 2024-08-16 |
Family
ID=63834214
Family Applications (1)
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| HRP20240677TT HRP20240677T1 (hr) | 2018-07-24 | 2019-07-23 | Pripravak strukturnog ljepila |
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| Country | Link |
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| US (1) | US20210332266A1 (hr) |
| EP (2) | EP3827036B1 (hr) |
| JP (1) | JP2021532231A (hr) |
| KR (1) | KR20210036932A (hr) |
| CN (2) | CN112469749B (hr) |
| CA (1) | CA3106497A1 (hr) |
| DK (1) | DK3827036T3 (hr) |
| ES (1) | ES2980168T3 (hr) |
| FR (1) | FR3084370B1 (hr) |
| HR (1) | HRP20240677T1 (hr) |
| HU (1) | HUE067173T2 (hr) |
| LT (1) | LT3827036T (hr) |
| MX (1) | MX2021000945A (hr) |
| PL (1) | PL3827036T3 (hr) |
| PT (1) | PT3827036T (hr) |
| WO (1) | WO2020020877A1 (hr) |
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| CN115803413A (zh) * | 2020-07-02 | 2023-03-14 | 汉高股份有限及两合公司 | 两部分硅烷改性聚合物/可自由基固化粘合剂体系 |
| WO2022210703A1 (ja) * | 2021-03-31 | 2022-10-06 | デンカ株式会社 | 接着剤組成物および物品 |
| FR3125055A1 (fr) * | 2021-07-12 | 2023-01-13 | Bostik Sa | Composition à base de monomères ( méth )acrylate |
| WO2023228050A1 (en) * | 2022-05-25 | 2023-11-30 | 3M Innovative Properties Company | Composite adhesives comprising polymeric nanoparticles |
| WO2024154634A1 (ja) * | 2023-01-20 | 2024-07-25 | デンカ株式会社 | 組成物、物品およびモータ |
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| US3985703A (en) | 1975-06-24 | 1976-10-12 | Rohm And Haas Company | Process for manufacture of acrylic core/shell polymers |
| US4223115A (en) | 1978-04-24 | 1980-09-16 | Lord Corporation | Structural adhesive formulations |
| US4304709A (en) | 1979-11-01 | 1981-12-08 | Hooker Chemicals & Plastics Corp. | Polymer blends with improved hydrolytic stability |
| DD225856A3 (de) * | 1982-09-01 | 1985-08-07 | Zeiss Jena Veb Carl | Lichthaertbare esterether-optikklebstoffe |
| EP0232364B1 (en) | 1985-07-24 | 1994-02-23 | Loctite Corporation | Substituted saccharin compounds and curable compositions containing same |
| JPS6426686A (en) * | 1987-04-23 | 1989-01-27 | Showa Denko Kk | Adhesive |
| US5106917A (en) | 1990-02-28 | 1992-04-21 | Shell Oil Company | Peelable lidstock based on polybutylene block copolymer blends |
| US6512043B2 (en) | 2000-05-10 | 2003-01-28 | Illinois Tool Works Inc. | Two-part structural adhesive having long working time |
| US20020119329A1 (en) | 2000-12-22 | 2002-08-29 | Roesler Richard R. | Two-component coating compositions containing silane adhesion promoters |
| US6433091B1 (en) | 2001-05-10 | 2002-08-13 | Henkel Loctite Corporation | Adhesive composition |
| US6730411B1 (en) | 2002-02-07 | 2004-05-04 | Illinois Tool Works Inc. | Two-part structural adhesive systems and laminates incorporating the same |
| FR2838334B1 (fr) | 2002-04-16 | 2006-05-26 | Polymerexpert Sa | Activateur non toxique de polymerisation radicalaire pour ciments osseux ou dentaires |
| US6660805B1 (en) | 2002-05-16 | 2003-12-09 | Lord Corporation | Two-part adhesive: part A-monomer, toughener(s), optional adhesion promotor and reducing agent; part B-epoxy resin |
| DE10355830A1 (de) * | 2003-11-26 | 2005-06-09 | Röhm GmbH & Co. KG | Verfahren zur Herstellung von Glycerincarbonatmethacrylat |
| US20050238603A1 (en) | 2004-04-06 | 2005-10-27 | Agnes Themens | Anhydrous cosmetic composition comprising at least one oil, at least one polymeric gelling agent and at least one polyurethane powder |
| ES2271780T3 (es) | 2004-06-23 | 2007-04-16 | Sika Technology Ag | Adhesivo (met)acrilico de olor reducido y alta resistencia al impacto. |
| CN1721491A (zh) * | 2004-06-23 | 2006-01-18 | Sika技术股份公司 | 具有低气味和高抗冲击性的(甲基)丙烯酸类粘结剂 |
| PL2102298T3 (pl) | 2006-12-27 | 2018-01-31 | Jacret | Kompozycja dla kleju strukturalnego |
| AU2008238011B2 (en) * | 2007-04-05 | 2013-02-07 | Jacret | Composition for structural adhesive |
| FR2928931B1 (fr) * | 2008-03-21 | 2011-03-25 | Jacret | Composition pour adhesif structural |
| WO2009126373A2 (en) | 2008-04-07 | 2009-10-15 | Arkema Inc. | Functional mbs impact modifiers for use in engineering resins |
| FR2950059B1 (fr) * | 2009-09-16 | 2016-09-16 | Jacret | Composition pour adhesif structural |
| EP2582761B1 (de) * | 2010-06-17 | 2015-03-18 | Basf Se | Wässrige bindemittelzusammensetzungen |
| US9238764B2 (en) * | 2011-03-31 | 2016-01-19 | Basf Se | Two-component coating compositions |
| EP2551102B1 (en) * | 2011-07-29 | 2014-12-03 | 3M Innovative Properties Company | Self-stick foam adhesive |
| DE102011109139A1 (de) | 2011-08-02 | 2013-02-07 | Evonik Röhm Gmbh | Geruchsarme (meth)acrylische Reaktionsharze |
| WO2014111503A2 (de) * | 2013-01-18 | 2014-07-24 | Basf Se | Block-copolymere mit einem polydimethylsiloxan-block |
| DE102016201660A1 (de) * | 2016-02-03 | 2017-08-03 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Monomeren aus Isomerenmischungen |
| EP3538615A4 (en) * | 2016-11-11 | 2020-07-08 | Hempel A/S | ANTIFOULING COATING COMPOSITION COMPRISING NEW CARBON-BASED HYDROLYSABLE POLYMERS |
-
2018
- 2018-07-24 FR FR1856878A patent/FR3084370B1/fr active Active
-
2019
- 2019-07-23 PT PT197405939T patent/PT3827036T/pt unknown
- 2019-07-23 PL PL19740593.9T patent/PL3827036T3/pl unknown
- 2019-07-23 HR HRP20240677TT patent/HRP20240677T1/hr unknown
- 2019-07-23 CN CN201980049139.6A patent/CN112469749B/zh active Active
- 2019-07-23 WO PCT/EP2019/069781 patent/WO2020020877A1/fr unknown
- 2019-07-23 EP EP19740593.9A patent/EP3827036B1/fr active Active
- 2019-07-23 HU HUE19740593A patent/HUE067173T2/hu unknown
- 2019-07-23 US US17/262,295 patent/US20210332266A1/en active Pending
- 2019-07-23 CA CA3106497A patent/CA3106497A1/fr active Pending
- 2019-07-23 DK DK19740593.9T patent/DK3827036T3/da active
- 2019-07-23 EP EP24161034.4A patent/EP4372064A3/fr active Pending
- 2019-07-23 JP JP2021503774A patent/JP2021532231A/ja active Pending
- 2019-07-23 LT LTEPPCT/EP2019/069781T patent/LT3827036T/lt unknown
- 2019-07-23 ES ES19740593T patent/ES2980168T3/es active Active
- 2019-07-23 CN CN202311382651.7A patent/CN117363223A/zh active Pending
- 2019-07-23 MX MX2021000945A patent/MX2021000945A/es unknown
- 2019-07-23 KR KR1020217003765A patent/KR20210036932A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| MX2021000945A (es) | 2021-03-31 |
| KR20210036932A (ko) | 2021-04-05 |
| CN112469749A (zh) | 2021-03-09 |
| US20210332266A1 (en) | 2021-10-28 |
| DK3827036T3 (da) | 2024-05-27 |
| CN112469749B (zh) | 2023-11-14 |
| CA3106497A1 (fr) | 2020-01-30 |
| JP2021532231A (ja) | 2021-11-25 |
| WO2020020877A1 (fr) | 2020-01-30 |
| HUE067173T2 (hu) | 2024-10-28 |
| PT3827036T (pt) | 2024-05-27 |
| PL3827036T3 (pl) | 2024-09-16 |
| ES2980168T3 (es) | 2024-09-30 |
| EP3827036B1 (fr) | 2024-03-06 |
| FR3084370A1 (fr) | 2020-01-31 |
| CN117363223A (zh) | 2024-01-09 |
| EP3827036A1 (fr) | 2021-06-02 |
| EP4372064A2 (fr) | 2024-05-22 |
| LT3827036T (lt) | 2024-06-10 |
| FR3084370B1 (fr) | 2021-03-05 |
| EP4372064A3 (fr) | 2024-07-24 |
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