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GB921798A - Aqueous copolymer emulsions and coatings and impregnations made therefrom - Google Patents

Aqueous copolymer emulsions and coatings and impregnations made therefrom

Info

Publication number
GB921798A
GB921798A GB1491761A GB1491761A GB921798A GB 921798 A GB921798 A GB 921798A GB 1491761 A GB1491761 A GB 1491761A GB 1491761 A GB1491761 A GB 1491761A GB 921798 A GB921798 A GB 921798A
Authority
GB
United Kingdom
Prior art keywords
butadiene
styrene
methacrylamide
butyl acrylate
acrylamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1491761A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB921798A publication Critical patent/GB921798A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D157/06—Homopolymers or copolymers containing elements other than carbon and hydrogen
    • C09D157/12—Homopolymers or copolymers containing elements other than carbon and hydrogen containing nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/56—Acrylamide; Methacrylamide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Paper (AREA)

Abstract

Coating compositions comprise aqueous emulsions of polymers comprising (A) 1 to 24% by weight of conjugated dienes, (B) 2 to 20% by weight of acrylamide and/or a -substituted acrylamides, (C) 97-56% by weight of at least one additional olefinically unsaturated compound and in which the proportion of "elasticizing" monomers is between 15 and 60%. (A) may be butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, chloroprene, 2,3-dichloro-1,3,-butadiene or 2-cyano-1,3,-butadiene. (B) may be acrylamide, methacrylamide, a -dodecyl-, a -chloro-, a -cyano- and a -carboxy-acrylamide. Monomer (C) may be acrylonitrile or substitution products, styrene or substitution products, esters of acrylic or methacrylic acids, N-alkyl-and N,N-dialkyl amides of acrylic and a -alkyl-acrylic acids, esters of maleic and fumaric acid with alcohols and halfesters with ether alcohols, vinyl esters, vinylidene chloride, vinyl pyridine or aliphatic unsaturated hydrocarbons. The "elasticizing" monomer is defined as comprising conjugated dienes, esters of acrylic acid with saturated aliphatic alcohols containing 2 to 18 carbon atoms or ether alcohols of dihydric alcohols or esters of methacrylic acid with an aliphatic alcohol containing 4 to 18 carbon atoms. Polymerization may take place in aqueous emulsion by free radical methods. The curing agents used may be peroxides, applied in aqueous emulsion. Examples specify (I) a copolymer of styrene, methacrylamide and butylacrylate with styrene, butyl acrylate and butadiene grafted on; (II) butyl acrylate, styrene, methacrylamide, acrylonitrile, isoprene; (III) methacrylamide, ethyl acrylate, styrene, butadiene; (IV) butadiene, butyl acrylate, styrene, acrylamide; (V) methacrylamide, vinylidene chloride, butyl methacrylate, butadiene; (VI) butadiene, styrene, g -methoxy-butyl acrylate, acrylamide; (VII) butadiene, acrylonitrile, butyl acrylate, vinyl acetate, acrylamide, monododecyl maleate; (VIII) butadiene, acrylonitrile, styrene, butyl acrylate, methacrylamide; (IX) butadiene, butyl acrylate, acrylonitrile, styrene, acrylic acid, methacrylamide. The resulting emulsions may be mixed with ammonium polyacrylate or a butadiene latex stabilizer such as 2,6-ditert. butyl cresol and are used to impregnate paper and textiles and coat metals. Specification 649,258 is referred to.
GB1491761A 1960-04-28 1961-04-25 Aqueous copolymer emulsions and coatings and impregnations made therefrom Expired GB921798A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF31109A DE1224428B (en) 1960-04-28 1960-04-28 Coating and impregnating agent based on aqueous mixed polymer emulsions

Publications (1)

Publication Number Publication Date
GB921798A true GB921798A (en) 1963-03-27

Family

ID=7094052

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1491761A Expired GB921798A (en) 1960-04-28 1961-04-25 Aqueous copolymer emulsions and coatings and impregnations made therefrom

Country Status (2)

Country Link
DE (1) DE1224428B (en)
GB (1) GB921798A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4581034A (en) * 1983-05-19 1986-04-08 Basf Aktiengesellschaft Finishing leather with a synthetic carboxylated rubber dispersion
US4831078A (en) * 1984-08-31 1989-05-16 Nippon Zeon Co., Ltd. Process for producing copolymer latex

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2946435C2 (en) * 1979-11-17 1982-02-18 Bayer Ag, 5090 Leverkusen Process for dressing leather by treating it with rubber latices

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2401885A (en) * 1941-10-21 1946-06-11 Goodrich Co B F Copolymers of butadiene-1, 3 and nu-dialkyl acrylamides
DE828276C (en) * 1948-10-02 1952-01-17 Chemische Werke Huels G M B H Paints
GB749719A (en) * 1953-10-21 1956-05-30 Ici Ltd Coating compositions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4581034A (en) * 1983-05-19 1986-04-08 Basf Aktiengesellschaft Finishing leather with a synthetic carboxylated rubber dispersion
US4831078A (en) * 1984-08-31 1989-05-16 Nippon Zeon Co., Ltd. Process for producing copolymer latex

Also Published As

Publication number Publication date
DE1224428B (en) 1966-09-08

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