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GB875069A - Manufacture of shaped articles such as filaments of aromatic polysulphonamides - Google Patents

Manufacture of shaped articles such as filaments of aromatic polysulphonamides

Info

Publication number
GB875069A
GB875069A GB3662257A GB3662257A GB875069A GB 875069 A GB875069 A GB 875069A GB 3662257 A GB3662257 A GB 3662257A GB 3662257 A GB3662257 A GB 3662257A GB 875069 A GB875069 A GB 875069A
Authority
GB
United Kingdom
Prior art keywords
aqueous solution
polysulphonamides
solution
aromatic
meta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3662257A
Inventor
Ralph John Basil Marsden
John Francis Lloyd Roberts
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3662257A priority Critical patent/GB875069A/en
Publication of GB875069A publication Critical patent/GB875069A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/76Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)

Abstract

In the production of filaments by extruding a solution of an aromatic polysulphonamide into an aqueous coagulating bath of acidity greater than that of the polymer solvent, the coagulating bath comprises an aqueous solution buffered to maintain a substantially constant pH, and the solvent is miscible in all proportions with the coagulating bath liquid. The latter preferably has a pH value of not less than about 5,0 and may be made from an aqueous solution of a weak organic acid in which is dissolved a salt of the acid with a strong base such as caustic soda. The polysulphonamides may be aromatic meta-or para-polysulphonamides prepared from meta-or para-disulphonic acids and diamines such as hexamethylene diamine. In an example, a 25% solution of polyhexamethylenebenzene-meta-disulphonamide in an aqueous solution of 200 grams per litre of caustic soda is spun into an aqueous solution of 100 grams per litre concentration of sodium bicarbonate at 65 DEG C. In another example, the polymer solution is spun into an aqueous solution of acetic acid and sodium acetate having a pH value of about 6,5. Specifications 875,067, 875,068, 875,070 and 875,071 are referred to.
GB3662257A 1957-11-25 1957-11-25 Manufacture of shaped articles such as filaments of aromatic polysulphonamides Expired GB875069A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3662257A GB875069A (en) 1957-11-25 1957-11-25 Manufacture of shaped articles such as filaments of aromatic polysulphonamides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3662257A GB875069A (en) 1957-11-25 1957-11-25 Manufacture of shaped articles such as filaments of aromatic polysulphonamides

Publications (1)

Publication Number Publication Date
GB875069A true GB875069A (en) 1961-08-16

Family

ID=10389785

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3662257A Expired GB875069A (en) 1957-11-25 1957-11-25 Manufacture of shaped articles such as filaments of aromatic polysulphonamides

Country Status (1)

Country Link
GB (1) GB875069A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6837996B2 (en) 2000-05-23 2005-01-04 Ge Osmonics, Inc. Polysulfonamide matrices
US6987150B2 (en) * 2000-05-23 2006-01-17 Osmonics, Inc. Modified sulfonamide polymers
US7138058B2 (en) 2000-05-23 2006-11-21 Ge Osmonics, Inc. Acid stable membranes for nanofiltration

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6837996B2 (en) 2000-05-23 2005-01-04 Ge Osmonics, Inc. Polysulfonamide matrices
US6987150B2 (en) * 2000-05-23 2006-01-17 Osmonics, Inc. Modified sulfonamide polymers
US7138058B2 (en) 2000-05-23 2006-11-21 Ge Osmonics, Inc. Acid stable membranes for nanofiltration

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