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GB861438A - Polymerisation of organic compounds - Google Patents

Polymerisation of organic compounds

Info

Publication number
GB861438A
GB861438A GB3600656A GB3600656A GB861438A GB 861438 A GB861438 A GB 861438A GB 3600656 A GB3600656 A GB 3600656A GB 3600656 A GB3600656 A GB 3600656A GB 861438 A GB861438 A GB 861438A
Authority
GB
United Kingdom
Prior art keywords
tert
dodecyl
polymerization
mercaptans
light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3600656A
Inventor
Wilfred Cooper
Margaret Knights
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dunlop Rubber Co Ltd
Original Assignee
Dunlop Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dunlop Rubber Co Ltd filed Critical Dunlop Rubber Co Ltd
Priority to GB3600656A priority Critical patent/GB861438A/en
Publication of GB861438A publication Critical patent/GB861438A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Liquid homopolymers or copolymers are made by subjecting an aqueous medium containing one or more ethylenically unsaturated compounds and a mercaptan to the action of light. Unsaturated compounds specified are methyl and ethyl acrylates, C1-C4 alkyl methacrylates, butadiene and isoprene and mixtures of dienes with methyl acrylate, methacrylic acid or styrene. Mercaptans specified are octyl, decyl, n-dodecyl, tert-dodecyl, tetradecyl and hexadecyl mercaptans, including a mixture of tert.-dodecyl, tert.-tetradecyl and tert.-hexadecyl mercaptans. Polymerization is preferably carried in the presence of a photosensitizer, e.g. anthraquinone, 1-chloroanthraquinone, dichloramine B, N-bromosuccinimide, diazotized sulphanilic acid, azobisisobutyronitrile, diacetyl, benzil, benzoin, uranium dioxide, uranyl nitrate and iron salts, including mixtures of substances which absorb light of different wavelengths, e.g. benzoin and uranyl nitrate. Polymerization may also be carried out in the presence of potassium persulphate as an initiator. The illumination used may consist of light having a wavelength in the region of 2,000-7,000 . The aqueous polymerization medium may contain an emulsifier such as potassium oleate, sulphated methyl oleate or the sodium salts of higher secondary alkyl sulphates.
GB3600656A 1956-11-24 1956-11-24 Polymerisation of organic compounds Expired GB861438A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3600656A GB861438A (en) 1956-11-24 1956-11-24 Polymerisation of organic compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3600656A GB861438A (en) 1956-11-24 1956-11-24 Polymerisation of organic compounds

Publications (1)

Publication Number Publication Date
GB861438A true GB861438A (en) 1961-02-22

Family

ID=10383927

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3600656A Expired GB861438A (en) 1956-11-24 1956-11-24 Polymerisation of organic compounds

Country Status (1)

Country Link
GB (1) GB861438A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2283491A (en) * 1993-10-20 1995-05-10 Nat Starch Chem Corp Monoacrylate ester coating compositions
GB2283975A (en) * 1993-10-20 1995-05-24 Nat Starch Chem Corp Monoacrylate ester coating compositions
WO1998037104A1 (en) * 1997-02-19 1998-08-27 E.I. Du Pont De Nemours And Company Molecular weight controlled polymers by photopolymerization

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2283491A (en) * 1993-10-20 1995-05-10 Nat Starch Chem Corp Monoacrylate ester coating compositions
GB2283975A (en) * 1993-10-20 1995-05-24 Nat Starch Chem Corp Monoacrylate ester coating compositions
GB2283975B (en) * 1993-10-20 1998-05-06 Nat Starch Chem Corp Method of forming adhesive bond
WO1998037104A1 (en) * 1997-02-19 1998-08-27 E.I. Du Pont De Nemours And Company Molecular weight controlled polymers by photopolymerization

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