GB798163A - Process for the production of ú´,ú´-diphenyldioxy silanes - Google Patents
Process for the production of ú´,ú´-diphenyldioxy silanesInfo
- Publication number
- GB798163A GB798163A GB35317/54A GB3531754A GB798163A GB 798163 A GB798163 A GB 798163A GB 35317/54 A GB35317/54 A GB 35317/54A GB 3531754 A GB3531754 A GB 3531754A GB 798163 A GB798163 A GB 798163A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diphenyldioxy
- prepared
- diphenyl
- silane
- dihydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000004756 silanes Chemical class 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 4
- 229910000077 silane Inorganic materials 0.000 abstract 4
- 229910003910 SiCl4 Inorganic materials 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 abstract 2
- -1 mouldings Substances 0.000 abstract 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 abstract 2
- LCVCUJWKJNFDMY-UHFFFAOYSA-N 2,2-diphenylpropane-1,1-diol Chemical compound C=1C=CC=CC=1C(C(O)O)(C)C1=CC=CC=C1 LCVCUJWKJNFDMY-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 abstract 1
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 abstract 1
- 239000011888 foil Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002366 halogen compounds Chemical class 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000011346 highly viscous material Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/04—Esters of silicic acids
- C07F7/07—Cyclic esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
Abstract
The invention comprises o,o1-diphenyldioxy silanes containing the group <FORM:0798163/IV (a)/1> where the remaining valencies of the silicon atom may be satisfied with halogens, alkoxy or aroxy groups or another o,o1-diphenyldioxy group. The diphenyl group in the above formula may be hydrocarbon-substituted, e.g. by saturated or unsaturated aliphatic groups. The dihalogen derivatives are prepared by reacting a silicon tetrahalide with o,o1-diphenol or its hydrocarbon substituted derivative in equal molar proportions. The di-alkoxy or di-phenoxy derivatives are prepared from the halogen compounds by reaction with the alcohol or phenol in a molar proportion of 1 : 2. Highly polymeric substances are prepared by reacting the dihalogen compounds with dihydroxy compounds such as dihydroxy-benzene, dihydroxy - diphenyl - propane or dihydroxy-diphenyl-ether, to form polyesters which are chemically and thermally resistant and are useful for making insulating and impregnating lacquers, mouldings, foil insulations and switch oils. In the examples: (1) o,o1-diphenyldioxy dichloro silane is prepared from SiCl4 and o,o1-diphenol; some di-o-o1-diphenyldioxy silane is also obtained; (2) the product of (1) is reacted with resorcinol to give a resin which is soluble in benzene and xylene; (3) a highly viscous substance, soluble in benzene, is obtained by reacting the dihalogen compound with 4,41-dihydroxydiphenyl propane; (4) 3-allyl-2,21-diphenyldioxydichloro silane is prepared from the 3-allyl-2,21-diphenyl and SiCl4; (5) the 3-propyl derivative is similarly prepared; (6) the dihalogen compound is reacted with isobutanol to give o,o1-diphenyldioxy-diisobutoxy silane; (7) reaction of the dihalogen compound with o-hydroxy-diphenyl yields o,o1 - diphenyldioxy - di - (o - diphenyloxy) silane.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE798163X | 1953-12-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB798163A true GB798163A (en) | 1958-07-16 |
Family
ID=6711348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB35317/54A Expired GB798163A (en) | 1953-12-05 | 1954-12-06 | Process for the production of ú´,ú´-diphenyldioxy silanes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB798163A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0114148A2 (en) * | 1983-01-12 | 1984-07-25 | Ciba-Geigy Ag | Dioxasilepin and dioxasilocin stabilizers |
| EP1705525A1 (en) * | 2003-12-26 | 2006-09-27 | Orient Chemical Industries, Ltd. | Positive electrostatic charge control agent and toner for developing electrostatic image |
-
1954
- 1954-12-06 GB GB35317/54A patent/GB798163A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0114148A2 (en) * | 1983-01-12 | 1984-07-25 | Ciba-Geigy Ag | Dioxasilepin and dioxasilocin stabilizers |
| EP0114148A3 (en) * | 1983-01-12 | 1985-12-27 | Ciba-Geigy Ag | Dioxasilepin and dioxasilocin stabilizers |
| EP1705525A1 (en) * | 2003-12-26 | 2006-09-27 | Orient Chemical Industries, Ltd. | Positive electrostatic charge control agent and toner for developing electrostatic image |
| EP1705525A4 (en) * | 2003-12-26 | 2006-12-06 | Orient Chemical Ind | Positive electrostatic charge control agent and toner for developing electrostatic image |
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