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GB786835A - Improvements in or relating to reforming gasoline hydrocarbons - Google Patents

Improvements in or relating to reforming gasoline hydrocarbons

Info

Publication number
GB786835A
GB786835A GB37384/55A GB3738455A GB786835A GB 786835 A GB786835 A GB 786835A GB 37384/55 A GB37384/55 A GB 37384/55A GB 3738455 A GB3738455 A GB 3738455A GB 786835 A GB786835 A GB 786835A
Authority
GB
United Kingdom
Prior art keywords
reforming
pressure
zone
atmospheres
separating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37384/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB786835A publication Critical patent/GB786835A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G61/00Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen
    • C10G61/02Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only
    • C10G61/06Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only the refining step being a sorption process
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A process for reforming a gasoline fraction containing naphthenes and paraffins comprises subjecting it in the presence of hydrogen and a catalyst at superatmospheric pressure to a reforming reaction, separating normally gaseous products from the normally liquid products, fractionally distilling the latter, and thereby separating a low boiling product fraction containing isohexanes from a higher boiling fraction, subjecting the higher boiling fraction to an extraction treatment and therein separating an aromatic hydrocarbon fraction and a raffinate largely consisting of saturated hydrocarbons including paraffins heavier than hexane, and subjecting the raffinate in a second reforming zone to reforming at a lower pressure than that in the first reforming zone. The pressure in the first zone is preferably at least 20 atmospheres and the pressure in the second zone at least 5 atmospheres lower. The initial reforming may be at a temperature of 316 DEG to 538 DEG C., a pressure of 20-68 atmospheres, with a hydrogen ratio of 0.5 to 20 mols. of hydrogen per mol. of gasoline hydrocarbon. The catalyst comprising alumina, 0.01 to 1 per cent by weight of platinum and 0.1 to 3.0 per cent of combined halogen. The extraction liquid is preferably diethylene glycol, although alcohols, glycols, aldehydes or glycerine, phenol or sulphur dioxide may be used. Specification 657,565 is referred to.
GB37384/55A 1954-12-31 1955-12-30 Improvements in or relating to reforming gasoline hydrocarbons Expired GB786835A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US786835XA 1954-12-31 1954-12-31

Publications (1)

Publication Number Publication Date
GB786835A true GB786835A (en) 1957-11-27

Family

ID=22145594

Family Applications (1)

Application Number Title Priority Date Filing Date
GB37384/55A Expired GB786835A (en) 1954-12-31 1955-12-30 Improvements in or relating to reforming gasoline hydrocarbons

Country Status (4)

Country Link
DE (1) DE1029510B (en)
FR (1) FR1145267A (en)
GB (1) GB786835A (en)
NL (1) NL99292C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3110661A (en) * 1959-01-23 1963-11-12 Texaco Inc Treatment of hydrocarbons

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2488027A (en) * 1941-01-31 1949-11-15 Standard Oil Co Method and apparatus for catalytic conversion
US2510673A (en) * 1947-12-04 1950-06-06 Pure Oil Co Reforming gasoline

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3110661A (en) * 1959-01-23 1963-11-12 Texaco Inc Treatment of hydrocarbons

Also Published As

Publication number Publication date
NL99292C (en)
FR1145267A (en) 1957-10-24
DE1029510B (en) 1958-05-08

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