GB766927A - Linear superpolymers of mixed diamines - Google Patents
Linear superpolymers of mixed diaminesInfo
- Publication number
- GB766927A GB766927A GB27462/54A GB2746254A GB766927A GB 766927 A GB766927 A GB 766927A GB 27462/54 A GB27462/54 A GB 27462/54A GB 2746254 A GB2746254 A GB 2746254A GB 766927 A GB766927 A GB 766927A
- Authority
- GB
- United Kingdom
- Prior art keywords
- para
- adipic
- meta
- xylylene
- diamines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Artificial Filaments (AREA)
Abstract
766,927. Linear polyamides. CALIFORNIA RESEARCH CORPORATION. Sept. 22,1954 [Sept. 29, 1953], No. 27462/54. Drawings to Specification. Class 2 (5). Linear polyamides are formed from adipic; suberic or sebacic acid and a mixture of meta- and para-xylylene diamines containing 5-90 per cent by weight of the para-isomer. The xylylene diamines may be prepared from commercial mixtures of xylenes in which the para isomer commonly constitutes 25-30 per cent of the mixed meta-para-isomers. In Example I an aqueous solution of a salt was prepared from adipic acid mixed m- and p-xylylene diamines (90: 10). Water was removed by heating in a current of nitrogen. Polymerization commenced at 190‹ C. and a low polymer was formed. Continuous heating at 275‹ C. and low pressure produced a crystalline polymer melting at 245 C. Example II is similar. A number of polymers from adipic or sebacic acid and mixed diamines with varying proportions of the two isomers are also described and compared with polymers prepared from adipic or sebacic acid with pure meta- or para-xylylene diamine, and with polymers from meta-xylylene diamine and mixtures of adipic and terephthalic acid. The products of the invention are characterized by high melting points and heat distortion points and suitability for melt spinning or extrusion.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US766927XA | 1953-09-29 | 1953-09-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB766927A true GB766927A (en) | 1957-01-30 |
Family
ID=32028537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27462/54A Expired GB766927A (en) | 1953-09-29 | 1954-09-22 | Linear superpolymers of mixed diamines |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE1024234B (en) |
FR (1) | FR1112203A (en) |
GB (1) | GB766927A (en) |
NL (1) | NL86085C (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3489724A (en) * | 1961-09-29 | 1970-01-13 | Toho Rayon Kk | Linear copolyamides from caprolactam,adipic acid and a mixture of m- and p-xylylene diamines |
US8022170B2 (en) | 2002-12-17 | 2011-09-20 | Ems-Chemie Ag | Copolyamides |
US8268956B2 (en) | 2006-12-08 | 2012-09-18 | Ems-Chemie Ag | Transparent mold made of a polyamide molding material |
US8383244B2 (en) | 2011-06-17 | 2013-02-26 | Ems-Patent Ag | Semiaromatic molding compounds and uses thereof |
US8404323B2 (en) | 2010-03-12 | 2013-03-26 | Ems-Patent Ag | Impact-resistant modified polyamide moulding compound and container formed therefrom |
US8586662B2 (en) | 2007-11-16 | 2013-11-19 | Ems-Patent Ag | Filled polyamide molding materials |
US8604120B2 (en) | 2010-07-30 | 2013-12-10 | Ems-Patent Ag | Polyamide moulding compound for producing moulded articles with a soft-touch surface and also corresponding moulded articles |
US9109115B2 (en) | 2013-03-15 | 2015-08-18 | Ems-Patent Ag | Polyamide moulding compound and moulded articles produced herefrom |
US9133322B2 (en) | 2012-10-02 | 2015-09-15 | Ems-Patent Ag | Polyamide moulding compounds and use thereof in the production of moulded articles |
US9453106B2 (en) | 2012-05-23 | 2016-09-27 | Ems-Patent Ag | Scratch-resistant, transparent and tough copolyamide moulding compounds, moulded articles produced therefrom and uses thereof |
US9963591B2 (en) | 2012-12-18 | 2018-05-08 | Ems-Patent Ag | Polyamide molding material and moldings manufactured from same |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2916475A (en) * | 1956-10-24 | 1959-12-08 | Eastman Kodak Co | Polyamides of xylenediamine and an aliphatic dibasic acid up-graded with trans-1, 4-cyclohexanedicarboxylic acid or oxalic acid |
US3012994A (en) * | 1956-10-24 | 1961-12-12 | Eastman Kodak Co | Polyamides derived from cyclohexanebis |
US2916476A (en) * | 1956-10-24 | 1959-12-08 | Eastman Kodak Co | Polyamides of xylenediamine and an aliphatic dibasic acid up-graded with 1, 4-cyclohexanebis |
US2985626A (en) * | 1957-01-24 | 1961-05-23 | Eastman Kodak Co | High melting copolyamides from omegaaminocarboxylic acids, terephthalic acid and 1, 4-cyclohexanebis |
US2985627A (en) * | 1957-01-24 | 1961-05-23 | Eastman Kodak Co | High melting omega-amino carboxylic copolyamides |
US2985628A (en) * | 1957-01-24 | 1961-05-23 | Eastman Kodak Co | High melting copolyamides from omega-aminocarboxylic acids, 1, 4-cyclohexanedicarboxylic acid and 1, 4-cyclohexanebis |
US3094511A (en) * | 1958-11-17 | 1963-06-18 | Du Pont | Wholly aromatic polyamides |
US3133138A (en) * | 1958-12-19 | 1964-05-12 | Du Pont | Stretching and heat crystallization of poly(meta-phenylene isophthalamide) fibers |
US3322728A (en) * | 1963-06-17 | 1967-05-30 | Du Pont | Sulfonyl aromatic polyamides |
US3349062A (en) * | 1966-07-21 | 1967-10-24 | Du Pont | Halogenated aromatic polyamides |
US3536804A (en) * | 1967-12-19 | 1970-10-27 | Toyo Boseki | Process for producing polyxyleneadipamide fibers |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB461237A (en) * | 1935-01-02 | 1937-02-09 | Du Pont | The manufacture of new compositions of matter and of artificial filaments, fibres, sheets, films and the like therefrom |
GB667771A (en) * | 1947-11-26 | 1952-03-05 | Ici Ltd | Diamines and polyamides therefrom |
BE487516A (en) * | 1948-05-01 |
-
1954
- 1954-09-20 FR FR1112203D patent/FR1112203A/en not_active Expired
- 1954-09-22 GB GB27462/54A patent/GB766927A/en not_active Expired
- 1954-09-28 DE DEC10018A patent/DE1024234B/en active Pending
- 1954-09-28 NL NL191115A patent/NL86085C/xx active
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3489724A (en) * | 1961-09-29 | 1970-01-13 | Toho Rayon Kk | Linear copolyamides from caprolactam,adipic acid and a mixture of m- and p-xylylene diamines |
US8022170B2 (en) | 2002-12-17 | 2011-09-20 | Ems-Chemie Ag | Copolyamides |
US8268956B2 (en) | 2006-12-08 | 2012-09-18 | Ems-Chemie Ag | Transparent mold made of a polyamide molding material |
US8586662B2 (en) | 2007-11-16 | 2013-11-19 | Ems-Patent Ag | Filled polyamide molding materials |
US8404323B2 (en) | 2010-03-12 | 2013-03-26 | Ems-Patent Ag | Impact-resistant modified polyamide moulding compound and container formed therefrom |
US8604120B2 (en) | 2010-07-30 | 2013-12-10 | Ems-Patent Ag | Polyamide moulding compound for producing moulded articles with a soft-touch surface and also corresponding moulded articles |
US8383244B2 (en) | 2011-06-17 | 2013-02-26 | Ems-Patent Ag | Semiaromatic molding compounds and uses thereof |
US9453106B2 (en) | 2012-05-23 | 2016-09-27 | Ems-Patent Ag | Scratch-resistant, transparent and tough copolyamide moulding compounds, moulded articles produced therefrom and uses thereof |
US9133322B2 (en) | 2012-10-02 | 2015-09-15 | Ems-Patent Ag | Polyamide moulding compounds and use thereof in the production of moulded articles |
US9963591B2 (en) | 2012-12-18 | 2018-05-08 | Ems-Patent Ag | Polyamide molding material and moldings manufactured from same |
US9109115B2 (en) | 2013-03-15 | 2015-08-18 | Ems-Patent Ag | Polyamide moulding compound and moulded articles produced herefrom |
Also Published As
Publication number | Publication date |
---|---|
DE1024234B (en) | 1958-02-13 |
FR1112203A (en) | 1956-03-09 |
NL86085C (en) | 1957-08-15 |
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