GB622374A - Improvements in and relating to the photo-polymerisation of compounds containing theethylene double bond - Google Patents
Improvements in and relating to the photo-polymerisation of compounds containing theethylene double bondInfo
- Publication number
- GB622374A GB622374A GB7123/47A GB712347A GB622374A GB 622374 A GB622374 A GB 622374A GB 7123/47 A GB7123/47 A GB 7123/47A GB 712347 A GB712347 A GB 712347A GB 622374 A GB622374 A GB 622374A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- methacrylate
- photo
- methyl
- fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 abstract 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- GPOGMJLHWQHEGF-UHFFFAOYSA-N 2-chloroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCl GPOGMJLHWQHEGF-UHFFFAOYSA-N 0.000 abstract 1
- IGDLZDCWMRPMGL-UHFFFAOYSA-N 2-ethenylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(C=C)C(=O)C2=C1 IGDLZDCWMRPMGL-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- -1 azo compound Chemical class 0.000 abstract 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 abstract 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 abstract 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 abstract 1
- 229960004419 dimethyl fumarate Drugs 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical class 0.000 abstract 1
- LVQPBIMCRZQQBC-UHFFFAOYSA-N methoxymethyl 2-methylprop-2-enoate Chemical compound COCOC(=O)C(C)=C LVQPBIMCRZQQBC-UHFFFAOYSA-N 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/04—Azo-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Unsaturated monomers, singly or in admixture, are photo-polymerized in the presence of an azo compound in which the two valencies of the azo group are attached to aliphatic carbon atoms. The process may be carried out using bulk, emulsion, granular or solution methods. Monomers specified are acrylic, haloacrylic and methacrylic acids, esters, amides and nitriles, such as methyl methacrylate, octyl methacrylate, methoxymethyl methacrylate, chloroethyl methacrylate and corresponding esters of acrylic and a -chloroacrylic acids, acrylonitrile, methacrylonitrile, vinyl chloride or fluoride, vinylidene chloride or fluoride, vinyl acetate, chloracetate, propionate or stearate, N-vinyl phthalimide, styrene, vinyl naphthalene, methyl vinyl ketone, chlorotrifluoroethylene, methyl fumarate, and ethylene. Azo compounds specified are a -a 1-azodiisobutyronitrile, dimethyl a ,a 1-azodiisobutyrate, 1,11-azodi-(cyclohexanecarbonitrile). The process may be used to form sheets or to unite two surfaces. Specification 604,902 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US622374XA | 1946-03-16 | 1946-03-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB622374A true GB622374A (en) | 1949-05-02 |
Family
ID=22041107
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7123/47A Expired GB622374A (en) | 1946-03-16 | 1947-03-14 | Improvements in and relating to the photo-polymerisation of compounds containing theethylene double bond |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR951735A (en) |
GB (1) | GB622374A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3047553A (en) * | 1959-11-30 | 1962-07-31 | Du Pont | Polymerization process using polyfluoroazoalkanes as initiators |
EP0003302A1 (en) * | 1978-02-01 | 1979-08-08 | Bayer Ag | Process for the production of dust-free plant protection granules |
EP0006972A1 (en) * | 1978-07-15 | 1980-01-23 | Röhm Gmbh | Photopolymerisation process |
JPS5644085B1 (en) * | 1971-06-18 | 1981-10-17 | ||
US11643797B2 (en) | 2020-03-24 | 2023-05-09 | Hansgrohe Se | Wall installation connection box unit |
US11777291B2 (en) | 2020-03-24 | 2023-10-03 | Hansgrohe Se | Sanitary wall installation connection box unit having an electric line feed-through |
US11811204B2 (en) | 2020-03-24 | 2023-11-07 | Hansgrohe Se | Wall installation connection box unit with an extension sleeve |
US11982072B2 (en) | 2020-03-24 | 2024-05-14 | Hansgrohe Se | Wall installation connection box unit with a functional surface body |
-
1947
- 1947-03-14 GB GB7123/47A patent/GB622374A/en not_active Expired
- 1947-08-07 FR FR951735D patent/FR951735A/en not_active Expired
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3047553A (en) * | 1959-11-30 | 1962-07-31 | Du Pont | Polymerization process using polyfluoroazoalkanes as initiators |
JPS5644085B1 (en) * | 1971-06-18 | 1981-10-17 | ||
EP0003302A1 (en) * | 1978-02-01 | 1979-08-08 | Bayer Ag | Process for the production of dust-free plant protection granules |
EP0006972A1 (en) * | 1978-07-15 | 1980-01-23 | Röhm Gmbh | Photopolymerisation process |
US11643797B2 (en) | 2020-03-24 | 2023-05-09 | Hansgrohe Se | Wall installation connection box unit |
US11777291B2 (en) | 2020-03-24 | 2023-10-03 | Hansgrohe Se | Sanitary wall installation connection box unit having an electric line feed-through |
US11811204B2 (en) | 2020-03-24 | 2023-11-07 | Hansgrohe Se | Wall installation connection box unit with an extension sleeve |
US11982072B2 (en) | 2020-03-24 | 2024-05-14 | Hansgrohe Se | Wall installation connection box unit with a functional surface body |
Also Published As
Publication number | Publication date |
---|---|
FR951735A (en) | 1949-11-02 |
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