GB582614A - Improvements in adhesive compositions - Google Patents
Improvements in adhesive compositionsInfo
- Publication number
- GB582614A GB582614A GB14245/44A GB1424544A GB582614A GB 582614 A GB582614 A GB 582614A GB 14245/44 A GB14245/44 A GB 14245/44A GB 1424544 A GB1424544 A GB 1424544A GB 582614 A GB582614 A GB 582614A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- butadiene
- proportion
- vulcanizing agent
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000853 adhesive Substances 0.000 title abstract 4
- 230000001070 adhesive effect Effects 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 6
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 abstract 2
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 abstract 2
- RBGDLYUEXLWQBZ-UHFFFAOYSA-N 2-chlorobenzamide Chemical compound NC(=O)C1=CC=CC=C1Cl RBGDLYUEXLWQBZ-UHFFFAOYSA-N 0.000 abstract 2
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- 241000276489 Merlangius merlangus Species 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 2
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 2
- 239000000378 calcium silicate Substances 0.000 abstract 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 2
- 239000006229 carbon black Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002366 halogen compounds Chemical class 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 150000001469 hydantoins Chemical class 0.000 abstract 2
- DZCCLNYLUGNUKQ-UHFFFAOYSA-N n-(4-nitrosophenyl)hydroxylamine Chemical group ONC1=CC=C(N=O)C=C1 DZCCLNYLUGNUKQ-UHFFFAOYSA-N 0.000 abstract 2
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000011787 zinc oxide Substances 0.000 abstract 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 244000043261 Hevea brasiliensis Species 0.000 abstract 1
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 1
- CJSBUWDGPXGFGA-UHFFFAOYSA-N dimethyl-butadiene Natural products CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 abstract 1
- 239000010985 leather Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- -1 naphtha Chemical class 0.000 abstract 1
- 229920003052 natural elastomer Polymers 0.000 abstract 1
- 229920001194 natural rubber Polymers 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001084 poly(chloroprene) Polymers 0.000 abstract 1
- 229920003051 synthetic elastomer Polymers 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000057 synthetic resin Substances 0.000 abstract 1
- 239000005061 synthetic rubber Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An adhesive composition comprises in admixture in an organic solvent a copolymer of a major proportion of an iso-olefine and a minor proportion of a diolefine, an organic vulcanizing agent for said copolymer and an organic compound which readily liberates a halogen. The copolymer is preferably a copolymer of isobutylene with butadiene, isoprene, 2,3-dimethyl-butadiene-1,3 or pentadiene-1,3 as described in Specification 523,248. The preferred vulcanizing agent is p-benzoquinone dioxime, though any of the quinone-oximes, their metal salts, ethers or esters may be used. The halogen compound may be a N-chloro amide such as chlorobenzamide or a chlorinated hydantoin such as 1,3-dichloro-5, 5-dimethyl hydantoin added in an amount up to 2 parts per 100 of copolymer. The solvent may be an aliphatic or aromatic hydrocarbon such as naphtha, together with a proportion of a nitroparaffin such as nitropropane. Fillers such as carbon black, whiting, clays or finely-divided hydrated calcium silicate and also zinc oxide and sulphur may also be added.ALSO:An adhesive composition comprises in admixture in an organic solvent a copolymer of a major proportion of a iso-olefine and a minor proportion of a diolefine, an organic vulcanizing agent for said copolymer and an organic compound which readily liberates a halogen. The copolymer is preferably a copolymer of isobutylene with butadiene, isoprene, 2, 3, dimethyl butadiene -1, 3 or pentadiene -1, 3 as described in Specification 523,248, [Group IV]. The preferred vulcanizing agent is p. benzoquinone dioxime though any of the quinone-oximes, their metal salts, ethers or esters may be used. The halogen compound may be an N-chloro amide such as chlorobenzamide or a chlorinated hydantoin such as 1, 3- dichloro -5, 5- dimethyl hydantoin added in an amount up to 2 parts per 100 of copolymer. The solvent may be an aliphatic or aromatic hydrocarbon such as naphtha together with a proportion of a nitroparaffin such as nitropropane. Fillers such as carbon black, whiting, clays or finely divided hydrated calcium silicate and also zinc oxide and sulphur may also be added. The adhesive may be used to bond natural rubber or synthetic rubbers such as polychloroprene copolymers of butadiene with styrene, acrylonitrile and isoolefines either to themselves or to leather, metals or synthetic resins such as phenolic resins and urea-formaldehyde resins.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US582614XA | 1943-11-12 | 1943-11-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB582614A true GB582614A (en) | 1946-11-21 |
Family
ID=22015695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14245/44A Expired GB582614A (en) | 1943-11-12 | 1944-07-26 | Improvements in adhesive compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB582614A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4588637A (en) * | 1983-04-05 | 1986-05-13 | Rockcor, Inc. | Adhesive composition |
-
1944
- 1944-07-26 GB GB14245/44A patent/GB582614A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4588637A (en) * | 1983-04-05 | 1986-05-13 | Rockcor, Inc. | Adhesive composition |
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