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GB487493A - Production of biological preparations - Google Patents

Production of biological preparations

Info

Publication number
GB487493A
GB487493A GB31338/36A GB3133836A GB487493A GB 487493 A GB487493 A GB 487493A GB 31338/36 A GB31338/36 A GB 31338/36A GB 3133836 A GB3133836 A GB 3133836A GB 487493 A GB487493 A GB 487493A
Authority
GB
United Kingdom
Prior art keywords
benzene
fatty acid
acidified
ether
fatty
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31338/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Organon NV
Original Assignee
Organon NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Organon NV filed Critical Organon NV
Publication of GB487493A publication Critical patent/GB487493A/en
Expired legal-status Critical Current

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  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Steroid Compounds (AREA)

Abstract

A fatty acid concentrate capable of increasing the activity of male hormones (testosteron, androstandiol or androstendion) is prepared by the steps comprising treating body liquids, animal organs, fatty oils and other lipoid-containing materials to extract a fatty acid fraction therefrom, partitioning the fatty acid fraction between mixtures of solvents which form two phases in order to separate the fatty acids from impurities such as hormones, fats, salts, sterols, separating the solid fatty acids by treatment with heavy metal salts treating the remaining fatty acid fraction in solution with bromine, removing the precipitate formed and debrominating the non-precipitated substances to obtain the desired agent. The starting materials may be subjected to acid or alkaline hydrolysis and the hydrolysate, acidified if required, extracted with a solvent such as benzene or ether. In the case of certain materials rich in sterols and phosphatides, e.g. testicles and suprarenals, the hydrolysis may be dispensed with and the material purified by freezing out with acetone, the cold acetone-soluble part being subjected to the solvent distribution process and the insoluble part first hydrolyzed. The distribution treatment is effected by the successive use of solvents consisting of aqueous alcohol and petroleum ether, aqueous alkaline alcohol and benzene, and aqueous pyridine and benzene, the substance containing the active material being present in the petroleum ether, the benzene, and the pyridine layers respectively. In an example, the pyridine layer as above obtained is acidified and shaken with benzene, the residue of the benzene solution dissolved in alcohol and treated with lead acetate and filtered. The filtrate is acidified with nitric acid extracted with ether. The fatty acids obtained from the ether solution esterified, dissolved in petroleum ether and brominated. A precipitate is formed which is removed, the solution evaporated and the residue debrominated in methyl alcohol, saponified, acidified and shaken with benzene. The dry residue from the benzene is dissolved in oil and injected with testosterone. Materials specified as suitable sources are testicles, fatty oils, urine, blood, liver, wheat germs, egg lecithine, yeast. The Specification as open to inspection under Sect. 91 includes a number of examples describing the preparation of hormone activators from various sources of the above-named classes by methods suitable for the separation of fatty acids, these methods including in some instances partition of the fatty acid fraction between non-miscible solvents as above mentioned. This subject-matter does not appear in the Specification as accepted.ALSO:A fatty acid concentrate capable of increasing the activity of male hormones (testosteron, androstandiol or androstendion) is prepared by the steps comprising treating body liquids, animal organs, fatty oils and other lipoid-containing materials to extract a fatty acid fraction therefrom, partitioning the fatty acid fraction between mixtures of solvents which form two phases in order to separate the fatty acids from impurities such as hormones, fats, salts, sterols, separating the solid fatty acids by treatment with heavy metal salts, treating the remaining fatty acid fraction in solution with bromine, removing the precipitate formed and debrominating the non-precipitated substances to obtain the desired agent. The starting materials may be subjected to acid or alkaline hydrolysis and the hydrolysate, acidified if required, extracted with a solvent such as benzene or ether. In the case of certain materials rich in sterols and phosphatides, e.g. testicles and suprarenals, the hydrolysis may be dispensed with and the material purified by freezing out with acetone, the cold acetone-soluble part being subjected to the solvent distribution process and the insoluble part first hydrolyzed. The distribution treatment is effected by the successive use of solvents consisting of aqueous alcohol and petroleum ether, aqueous alkaline alcohol and benzene, and aqueous pyridine and benzene, the substance containing the active material being present in the petroleum ether, the benzene, and the pyridine layers respectively. In an example, the pyridine layer as above obtained is acidified and shaken with benzene, the residue of the benzene solution dissolved in alcohol and treated with lead acetate and filtered. The filtrate is acidified with nitric acid and extracted with ether. The fatty acids obtained from the ether solution esterified, dissolved in petroleum ether and brominated. A precipitate is formed which is removed, the solution evaporated and the residue debrominated in methyl alcohol, saponified, acidified and shaken with benzene. The dry residue from the benzene is dissolved in oil and injected with testosterone. Materials specified as suitable sources are testicles, fatty oils, urine, blood, liver, wheat germs, egg lecithine, yeast. The Specification as open to inspection under Sect. 91 includes a number of examples describing the preparation of hormone activators from various sources of the above-named classes by methods suitable for the separation of fatty acids, these methods including in some instances partition of the fatty acid fraction between non-miscible solvents as above mentioned. This subject-matter does not appear in the Specification as accepted.
GB31338/36A 1935-11-16 1936-11-16 Production of biological preparations Expired GB487493A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL487493X 1935-11-16

Publications (1)

Publication Number Publication Date
GB487493A true GB487493A (en) 1938-06-21

Family

ID=19786646

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31338/36A Expired GB487493A (en) 1935-11-16 1936-11-16 Production of biological preparations

Country Status (1)

Country Link
GB (1) GB487493A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0796112A1 (en) * 1994-11-30 1997-09-24 Amur Research Corp. Phosphocholine drug derivatives
WO2011046522A2 (en) * 2009-10-16 2011-04-21 Rached Smida Novel uses of reconstituted free testosterone

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0796112A1 (en) * 1994-11-30 1997-09-24 Amur Research Corp. Phosphocholine drug derivatives
EP0796112A4 (en) * 1994-11-30 1999-12-01 Amur Research Corp Phosphocholine drug derivatives
WO2011046522A2 (en) * 2009-10-16 2011-04-21 Rached Smida Novel uses of reconstituted free testosterone
WO2011046522A3 (en) * 2009-10-16 2011-09-09 Rached Smida Novel uses of reconstituted free testosterone

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