GB415427A - Improvements in or relating to the hydration of olefines - Google Patents
Improvements in or relating to the hydration of olefinesInfo
- Publication number
- GB415427A GB415427A GB231533A GB231533A GB415427A GB 415427 A GB415427 A GB 415427A GB 231533 A GB231533 A GB 231533A GB 231533 A GB231533 A GB 231533A GB 415427 A GB415427 A GB 415427A
- Authority
- GB
- United Kingdom
- Prior art keywords
- enough
- per cent
- baked
- linseed oil
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000036571 hydration Effects 0.000 title 1
- 238000006703 hydration reaction Methods 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 5
- 235000021388 linseed oil Nutrition 0.000 abstract 4
- 239000000944 linseed oil Substances 0.000 abstract 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 3
- 229910052796 boron Inorganic materials 0.000 abstract 3
- 235000011007 phosphoric acid Nutrition 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 2
- 229910052788 barium Inorganic materials 0.000 abstract 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 239000008187 granular material Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 125000005341 metaphosphate group Chemical group 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 235000019198 oils Nutrition 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 229910052712 strontium Inorganic materials 0.000 abstract 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Catalysts for the production of alcohols from olefines (other than ethylene) and steam are compounded from an oxide of calcium, barium, strontium or magnesium, and if desired boron, and an amount of phosphoric acid more than enough to form the orthophosphates but less than enough to form the metaphosphates of the metals. The catalysts may be used as granules or flakes or on supports such as electrode carbon, and a drying oil may be used in their preparation as described in Specification 404,115. A suitable catalyst may be prepared from 1 mol CaO, 0,5B2O3, 2,6H3PO4, the mixture being evaporated, with the addition of 5 per cent of linseed oil during the final stages. The product is baked at 200 DEG C., tabletted with an additional 3 per cent of linseed oil, and again baked at 200 DEG C. Specifications 407,722, [Group IV], and 408,313 also are referred to.ALSO:Olefines other than ethylene, such as propylene, butene-1 or -2 and isobutylene are reacted with steam in presence of a solid catalyst compounded from an oxide of calcium, barium, strontium or magnesium and, if desired, boron, and an amount of phosphoric acid more than enough to form the orthophosphates of the metals, but less than enough to form the metaphosphates and the normal phosphate of the boron if present. The reaction may be effected at atmospheric or increased pressure. The catalysts may be used as granules or flakes or upon inert supports such as electrode carbon, and a drying oil may be used in their preparation as described in Specification 404,115, [Group III]. The temperature of the reaction may be 100--350 DEG C. and the pressure may be up to 250 atmospheres. A suitable catalyst may be prepared from 1 mol. CaO, 0,5 B2O3, 2,6 H3PO4, the mixture being evaporated with the addition of 5 per cent of linseed oil during the final stages. The product is baked at 200 DEG C., tabletted with an additional 3 per cent of linseed oil and again baked at 200 DEG C. Specifications 407,722 and 408,313 also are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB231533A GB415427A (en) | 1933-01-24 | 1933-01-24 | Improvements in or relating to the hydration of olefines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB231533A GB415427A (en) | 1933-01-24 | 1933-01-24 | Improvements in or relating to the hydration of olefines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB415427A true GB415427A (en) | 1934-08-24 |
Family
ID=9737384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB231533A Expired GB415427A (en) | 1933-01-24 | 1933-01-24 | Improvements in or relating to the hydration of olefines |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB415427A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8558036B2 (en) | 2010-11-15 | 2013-10-15 | Saudi Arabian Oil Company | Dual phase catalysts system for mixed olefin hydrations |
| WO2021064733A2 (en) | 2019-10-02 | 2021-04-08 | Polaris Solutions Ltd. | Method and device for generating a thermal signature |
-
1933
- 1933-01-24 GB GB231533A patent/GB415427A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8558036B2 (en) | 2010-11-15 | 2013-10-15 | Saudi Arabian Oil Company | Dual phase catalysts system for mixed olefin hydrations |
| US8865951B2 (en) | 2010-11-15 | 2014-10-21 | Saudi Arabian Oil Company | Dual phase catalysts system for mixed olefin hydrations |
| US9056315B2 (en) | 2010-11-15 | 2015-06-16 | Saudi Arabian Oil Company | Dual phase catalysts system for mixed olefin hydrations |
| WO2021064733A2 (en) | 2019-10-02 | 2021-04-08 | Polaris Solutions Ltd. | Method and device for generating a thermal signature |
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