GB2299088A - Post-treated dispersants - Google Patents

Description

POST-TREATED DISPERSANTS 2299088 This invention relates to dispersants

useful as additives in lubricating oils. especially lubricating oils for internal combustion engines and vehicles driven by such engines. More particularly, the present invention provides novel ashless dispersants which have reduced reactivity towards fluoroelastomers.

A continuing problem in the art of the lubrication is to provide lubricant compositions which meet the requirements of original equipment manufacturers. one such requirement is that the lubricant does not cause or contribute to premature deterioration of seals, clutch face plates or other 'parts made from f luoroclastomers. Many currently used dispersants contain basic nitrogen. and it is known that such dispersants, including more particularly the commonly used succinimide dispersants, tend to have an adverse effect upon fluoroelastomers which causes them to lose flexibility and tensile strength, to become brittle, ande in severe cases, to disintegrate.

Standard test methods for evaluating fluoroelastomer compatibility of lubricant compositions include the Volkswagen PV-3334 Seal Test, the CCMC Viton Seal Test (CEC L-39-T-87 oillelastomer compatibility test) and the Volkswagen PV-3344 Seal Test. The last of these is a more severe fluoroelastomer test procedure, and a variety of commercially available premium motor oils from various manufacturers fail to meet the requirements of the test.

There is therefore a continuing need for novel dispersants which satisfy current requirements for compatibility with f luoroelastomers while at the same time meeting the other requirements for ashless dispersants to be used in lubricant oils.

The present invention provides a process for preparing a novel class of oil-soluble ashless dispersants which have improved compatibility with fluoroelastomers, and which moreover have desirable viscometric properties.

The process of the invention comprises reacting a polyamine with a terpolymeric acylating agent derived from (1) a high molecular weight polyolef in containing on average at least 30. preferably at least 50, carbon atoms per molecule in which at least 30% of the residual olefin groups are in the form of vinylidene radicals of formula: -CR=CE2 where R is alkyl of 1 to 6 carbon atoms; (2) an a-olefin (3) an unsaturated dicarboxylic acid or derivative thereof, followed by post-treatment with one or more post-treating agents. Dispersants prepared by the process described herein also form part of the present invention.

In the field of lubrication, viscosity index improvers are routinely incorporated in lubricating oils to provide effective lubrication over a range of temperatures by increasing the viscosity of the oil at high temperatures without unduly increasing oil viscosity at low temperature.

- 3 Post-treatment has unexpectedly been found to yield dispersants which impart viscosity lift to lubricating oils in which they are used. By "viscosity lift" is meant an increase in viscosity of lubricating oil when compared with the viscosity observed using similar dispersants which have not been subjected to post-treatment. Post-treatment thus provides dispersants which have a surprising and beneficial effect on the viscometric properties of lubricating oils in which they are incorporated, such that their use reduces, or even eliminates, the normal requirement for viscosity index improvers to be incorporated in the lubricant.

Moreover, the viscosity lift observed has been found to correlate with the degree of seal compatibility the dispersant exhibits. Dispersants having high seal compatibility have been found to impart increased viscosity lift when compared with dispersants having lower seal Compatibility. The present invention thus includes within its scope the use of a dispersant prepared in accordance with the process described above as an additive for controlling the viscometric properties of a lubricant composition comprising a major proportion of oil of lubricating viscosity. The term Ilviscometric properties" is intended to mean low and high temperatures viscosities and viscosity index.

Post-treatment may be carried out in known manner, for example by reaction with an inorganic or organic phosphorus compound, boron compound, or monoor poly-carboxylic acid or - 4 derivative thereof, or with any other post-treating agents known in the art. Reference may be made. for example, to usp 5137980 and the United States Patents referred to therein, to USP 4857214 and USP 5164103 and to European specification 5 0460309.

Suitable post-treating agents include dicarboxylic acylating agents selected from (a) acyclic dicarboxylic acids having up to 12 carbon atoms in the molecule and wherein the carboxyl groups are attached to adjacent carbon atoms, (b) anhydrides of the said dicarboxylic acids, (c) acyl halides of the said dicarboxylic acids, and (d) acyclic mono- and/or dihydrocarbyl esters of the said dicarboxylic acids having no more than 7 carbon atoms per hydrocarbyl group. Examples of these acylating agents include maleic acid, maleic anhydride, a-etbylmaleic acid, malic acid, fumaric acid, itaconic acid, itaconic anhydride, citraconic acid, citraconic anhydride, succinic acid, succinic anhydride, a-methylsuccinic acid, a,a-dimetbylsuccinic acid, a,#- dimethylsuccinic acid, a-ethylsuccinic acid, thiomalic acid, tartaric acid, the monoalkyl esters of the foregoing acids wherein the alkyl group has from 1 to 7 carbon atoms, the dialkyl esters of the foregoing acids wherein each alkyl group has from I to 7 carbon atoms, the monoalkenyl esters of the foregoing acids wherein the alkenyl group has from 2 to 7 carbon atoms, the dialkenyl esters of the foregoing acids wherein each alkenyl group has from 2 to 7 carbon atoms, the acyl chlorides of the foregoing acids, and the like. The most preferred post-treating agent f or use in the practice of this invention is maleic anhydride. other post-treating agents which may be used include phosphorus compounds or mixtures of phosphorus compounds capable of introducing phosphorus-containing species into the dispersant undergoing such reaction. Any phosphorus compound, organic or inorganic, capable of undergoing such reaction can thus be used. Accordingly, use can be made of such inorganic phosphorus compounds as the inorganic phosphorus acids, and the inorganic phosphorus oxides, including their hydrates. Typical organic phosphorus compounds include full and partial esters of phosphorus acids. such as the mono-, di-, and tri esters of phosphoric acid, thiophosphoric acid, dithiophosphoric acid, trithiophosphoric acid and tetrathiophosphoric acid; the mono-O di-, and tri esters of phosphorous acid, dithiophosphorous acid and trithiophosphorous acid, the trihydrocarbyl phosphine oxides; the trihydrocarbyl phosphine sulphides; the mono- and dihydrocarbyl phosphonates, (RPO(ORI) (OR") where R and R' are hydrocarbyl and R's is a hydrogen atom or a hydrocarbyl group), and their mono-, diand trithio analogs; the mono- and dihydrocarbyl phosphonites, (RP(ORI) (OR') where R and R' are hydrocarbyl and W' is a hydrogen atoms or a hydrocarbyl group) and their mono- and dithio analogs; and the like. Thus, use can be made of such compounds as, for example, phosphorous acid (R3P03, sometimes depicted as E2 (RPO3), are sometimes called - 6 ortho-phosphorous acid or phosphonic acid), phosphoric acid (H3PO4, sometimes called orthophosphoric acid), hypophosphoric acid (HP20JI metaphosphoric acid (HP03)l pyrophosphoric acid MP207) 1 hypophosphorous acid (H3PO2, sometimes called phosphinic acid). pyrophosphorous acid (H4P20.1 sometimes called pyrophosphonic acid), phospbinous acid (H3PO), tripolyphosphoric acid (HsP3010), tetrapolyphosphoric acid 016P400J. trimetaphosphoric acid MP3001 phosphorus trioxide, phosphorus tetraoxide, phosphorus pentoxide, and the like.

Partial or total sulphur analogs such as phosphorotetrathioic acid (H3pS4)1 phosphoromonothioic (H3PO3S), phosphorodithioic acid MPOA). phosphorotrithioic acid MPOSO. phosphorus sesquisulfide, phosphorus heptasulfide, and phosphorus pentasulfide (P2SSI sometimes referred to as P4S,,) can also be is used in the practice of this invention. Also usable, though less preferred, are the inorganic phosphorus halide compounds such as PC131 PBr3, POC131 PSC13, etc. The preferred phosphorus reagent is phosphorous acid, MPOO.

Likewise use can be made of such organic phosphorus compounds as mono-, di-, and triesters of phosphoric acid (e.g., trihydrocarbyl phosphates, dihydrocarbyl monoacid phosphates, monohydrocarbyl diacid phosphates, and mixtures thereof), mono-, di-, and triesters of phosphorous acid (e.g. trihydrocarbyl phosphites, dihydrocarbyl hydrogen phosphites, hydrocarbyl diacid phosphites, and mixtures thereof), esters of pbospbonic acids (both "primary", RP(O) (OR)2, and "secondary", R2P(O) (OR)), esters of pbosphinic acids, phosphonyl halides (e. g. RP (0) C12 and R2P (0) Cl) j halophosphites (e. g. (RO)PC12 and (RO)2pCl), halophosphates (e.g. ROP(O)Cl, and (RO2)P(O)Cl),. tertiary pyrophosphate asters (e.g. (RO)2P(O)_O_P(O) (OR)2), and the total or partial sulphur analogs of any of the foregoing organic phosphorus compounds, and the like wherein each hydrocarbyl group contains up to about 100 carbon atoms, preferably up to about 50 carbon atoms, more preferably up to about 24 carbon atoms, and most preferably up to about 12 carbon atoms. Also usable, although less preferred, are the halophosphine halides (e.g. hydrocarbyl phosphorus tetrahalides, dihydrocarbyl phosphorus tribalides, and trihydrocarbyl phosphorus dihalides), and the halophosphines (monohalophosphines and dihalophosphines).

when using an organic phosphorus compound, it is preferable to use a water-hydrolyzable phosphorus compound, especially a water hydrolyzable dihydrocarbyl hydrogen phosphite, and water in the phosphorylation reaction so that the phosphorus compound is partially (or completely) hydrolyzed during the reaction.

It is also possible to post-treat with a boron compound or mixture of boron compounds capable of introducing boroncontaining species into the dispersant undergoing the reaction. Any boron compound, organic or inorganic, capable of undergoing such reaction can be used. Accordingly use can be made of boron oxide, boron oxide hydrate, boron trifluoride, boron tribromide, boron trichloride, HBF4, boron acids such as boronic acid (e. g. alkyl-B (OH). or aryl-B (OH) 2) 1 boric acid (i.e. H3BO3), tetraboric acid (i.e. 112B.07),, metaboric acid (i.eo HBO.), Ammonium salts of boron acids, and esters of such boron acids. The use of complexes of a boron trihalide with ethers, organic acids, inorganic acids, or hydrocarbons is a convenient means of introducing the boron reactant into the reaction mixture. Such complexes are known and are exemplified by boron trifluoride-diethyl ether, boron trifluoride- phenyl, boron trifluoride-phosphoric acid, boron trichloride-chloroacetic acid, boron tribromidedioxane, and boron trifluoride-methyl ethyl ether.

Specific examples of boronic acids include methyl boronic acid, phenylboronic acid, cyclobexyl boronic acid, p-heptylphenyl boronic acid and dodecyl boronic acid.

is The boron acid esters include especially mono, di-, and tri-organic esters of boric acid with alcohols or phenols such as, e.g. methanol, ethanol, isopropanol, cyclohexanol, cyclopentanol, I-octanol, 2- octanol, dodecanol, behenyl alcohol, oleyl alcohol, stearyl alcohol, benzyl alcohol, 2- butyl cyclohexanol, ethylene glycol, propylene glycol, trimethylene glycol, 1,3-butanediol, 2,4-hexanediol, 1,2cyclohexanediol, 1,3- octanediol, glycerol, pentaerythritol, diethylene glycol, carbitol, Cellosolve, triethylene glycol, tripropylene glycol, phenol, naphthol, pbutylphenol, o,p- dibeptylphenol, n-cyclohexylphenol, 2,2-bis-(p-hydroxyphenyl) propane, polyisobutene (molecular weight of 1500)-substituted phenol, ethylene chlorohydrin, o-chlorophenol, m-nitrophenol, 6-bromo-octanol, and 7-keto-decanol. Lower alcohols, 1,2glycols, and 1,3- glycols, i.e. those having less than about a carbon atoms are especially useful for preparing the boric acid esters for the purpose of this invention.

Any combination of the aforesaid post-treatments can be carried out by the simultaneous or consecutive reaction with the chosen post-treatment agents. Preferably, the posttreatment agent is an inorganic phosphorus acid or anhydride, boric acid, an unsaturated dicarboxylic acid or derivative thereof, or a mixture of these, more preferably an unsaturated dicarboxylic acid or derivative thereof, or a mixture of these. The use of boric acid and maleic anhydride is also preferred.

The olefins used in making the terpolymeric succinic acylating agents are preferably polyisobutenes or polypropylenes. Especially preferred are polyisobutenes, particularly polyisobutenes having a number average molecular weight in the range from about 800 to about 5,000, preferably about 900 to 2500. Such high molecular weight polyolefins are generally mixtures of individual molecules of different molecular weights and different structures. It is a requirement for the polyolefins to be used in the present invention that they must contain at least 30%, preferably at least 50%, of the residual olefinic groups in the form of vinylidene radicals of formula -CR2CR2' More preferably, the preferred polyisobutenes contain at least 60%, and especially at least 70%, of their olefin groups in the form of radicals - 10 of formula -CM"":CK2t where R is hereinbefore defined and is preferably methyl. Such polyolefins are commercially available.

The a-olefins used in making the terpolymers used in the present invention normally contain 2 to 40 carbon atoms. It is preferred to use a-olefins of formula:

ReeCH=CR2 in which R' is an aliphatic group of 1 to 26 carbon atoms.

More preferably the radical R' is an alkyl radical of 10 to 26 carbon atoms. Long chain a-olefins of this type are commercially available from Chevron, Shell, Albemarle and other companies.

The third component of the terpolymers used in the present invention is an unsaturated dicarboxylic acid or derivative thereof. The component introduces acidic groups into the terpolymer. Preferably, component (3) is an unsaturated dicarboxylic acid or derivative thereof capable of reacting with a polyamine. The acid derivative is typically an ester, amide, acyl halide, metal or ammonium salt, or anhydride. Such unsaturated dicarboxylic acids and their derivatives may be represented by the formula:

X-CO-CH=CH-CO-V in which X and V are each -OH, -0-hydrocarbyl, -0-M (where X is a metal or ammonium), -14H2. -Cl, or Br, or X and X' together are -0-. Specific unsaturated acidic compounds which can be used include maleic anhydrides substituted by methyl, phenyl, chlorine, bromine and other substitutents and - 11 isomers of such compounds including fumaric acid and its derivatives, and the esters and nitriles of such acids. Especially preferred are maleic or fumaric acid and their derivatives especially their anhydrides.

The molecular weights of the terpolymers used in the invention may be determined by Gel Permeation Chromatography (GPC) using the following procedure. (a) Apparatus used Instrument Detector Column Oven Data System Columns Hewlett Packard 1050 Differential Refractive Index Anachem Polymer Lab GPC Software 3 x SAm PL Gel columns of 300 mm length with pore sizes of 100, 500, and 10001.

(b) calibration Narrow range PIB standards were prepared by preparative GPC and their molecular weights were determined by vapour phase osmometry (VPO). These samples were used to construct a calibration curve. Rexadecane and a set of narrow range polystyrene standards were then run and their molecular weights defined in terms of PIB equivalent using the Primary calibration curve. These standards Rn 284-7500 (PIB equivalent) were then used to construct a calibration curve for the particular apparatus used as follows.

A saturated solution of flowers of sulphur in tetrahydrofuran (THP; stabilized with BET) is prepared and - 12 diluted to 50%. The narrow range polystyrene standards are prepared by dissolving each standard at an approximate concentration of 0.5% w/v in the THP solution containing sulphur. The concentration is adjusted to give approximately equal peak heights of the standard and sulphur peaks. Each standard is chromatographed and used to construct a calibration curve. (c) Secondary Standard A secondary PIB standard is used whenever a sample is run. This standard is a standard PIB which has been run several times against the calibration standards and whose Rn has been determined as 1078. (d) Molecular Weight Measurement The secondary standard is dissolved in the TRP solution at a concentration of about 0.5% w/v and chromatographed.

The sample is similarly dissolved in the THP solution and chromatographed. The molecular weight (Rn) is calculated, after corrections for the flow rate have been carried out, by reference to the value of Hn for the secondary standard. 20 The acid value of the terpolymer may be determined using the following method. The terpolymer sample was dissolved in a 1:1 toluene:nbutanol mixture and titrated with a sodium isopropoxide titrant to its potentiometric endpoint. The Total Acid 25]Number is then calculated and divided by 56.1 to give the acid value in mequivIg.

The terpolymer of the present invention may be prepared - 13 by reacting high molecular weight poly-olefin the a-olefin. and the unsaturated acidic reactant in the presence of a free radical initiator.

The reaction may be conducted neat, that is, both the polyolefin, a-olefin and acidic reactant and the free radical initiator are combined in the proper ratio, and then stirred at the reaction temperature.

Alternatively, the reaction may be conducted in a diluent. For example, the reactants may be combined in a solvent. Suitable solvents include those in which the reactants and free radical initiator are soluble and include acetone., tetrahydrofuran, chloroform, methylene chloride, dichloroethane, toluene, dioxane, chlorobenzene, xylenes, or the like. After the reaction is complete, volatile components may be stripped off. When a diluent is employed, it is preferably inert to the reactants and products formed and is generally used in an amount sufficient to ensure efficient stirring.

In general, the copolymerization can be initiated by any free radical initiator. Such initiators are well known in the art. However, the choice of free radical initiator may be influenced by the reaction temperature employed.

The preferred free-radical initiators are the peroxidetype polymerization initiators and the azo-type polymerization initiators. Radiation can also be used to initiate the reaction, if desired.

The peroxide-type free-radical initiator can be organic - 14 or inorganic, the organic having the general formula: R30OR13 where R3 is any organic radical and R13 is selected from the group consisting of hydrogen and any organic radical. Both R3 and R'F3 can be organic radicals, preferably hydrocarbon, arcyl, and acyl radicals, carrying, if desired, substituents such as halogens. Preferred peroxides include di-tert-butyl peroxide, tert-butyl peroxybenzoate, and dicumyl peroxide.

Examples of other suitable peroxides, which in no way are limiting, include benzoyl peroxides, lauroyl peroxide, tertiary butyl peroxides, 2,4-dichlorobenzoylperoxide, tertiary buty1hydroperoxide, cumene hydroperoxide, diacetyl peroxide, acetyl hydroperoxide, diethylperoxycarbonate, tertiary butylperbenzoate, and the like.

The azo-type compounds, typified by alpha,alphal- IS azobisisobutyronitrile are also well known free-radical promoting materials. These azo compounds can be defined as those having present in the molecule a group -N=N- wherein the balances are satisfied by organic radicals, at least one of which is preferably attached to a tertiary carbon. Other suitable azo compounds include, but are not limited to, pbromobenzenediazonium fluoroborate, p-tolyldiazoaminobenzene, pbromobenzenediazonium hydroxide, azomethane and phenyl-diazonium halides, azomethane and phenyl diazonium halides. A suitable list of azo-type compounds can be found in US Patent No. 2,SS1,813.

The amount of initiator to employ, exclusive of radiation, depends to a large extent on the particular - is - initiator chosen, the polyolefin used and the reaction conditions. The initiator must, of course, be soluble in the reaction medium. The usual concentrations of initiator are between 0.001:1 and 0.2:1 moles of initiator per mole of acidic reactant, with preferred amounts between 0. 005:1 and 0.10:1.

The polymerization temperature must be sufficiently high to break down the initiator to produce the desired freeradicals. For example. using benzoyl peroxide as the initiator, the reaction temperature can be between about 750C and about 900C, preferably between about 800C and about 850C. Higher and lower temperatures can be employed, a suitable broad range of temperatures being between about 200C and about 2000C, with preferred temperatures between about 500C and about 1500C. The reaction pressure should be sufficient to maintain the solvent in the liquid phase. Pressures can therefore vary between about atmospheric and higher but the preferred pressure is atmospheric. The reaction time is usually sufficient to result in the substantially complete conversion of the acidic reactant, a-olefin and polyolefin to terpolymer. The reaction time is suitably between one and 24 hours with preferred reaction times between two and ten hours. 25 As noted above, the reaction is a solution type polymerization reaction. The polyolefin, a-olefin, acidic reactant, solvent and initiator can be brought together in - 16 any suitable manner. The important factors are intimate contact of the monomers in the presence of the free-radical producing material. The reaction, for example, can be conducted in a batch system where the polyolefin and &-olefin are added all initially to a mixture of acidic reactant, initiator and solvent or polyolefin and a-clefin can be added intermittently or continuously to the reaction pot. Alternatively, the reactants may be combined in other order, for example, acidic reactant and initiator may be added to high molecular weight polyolefin and a-olefin and solvent in the reaction pot. In another manner the components in the reaction mixture can be added continuously to a stirred reactor with continuous removal of a portion of the product to a recovery train or to other reactors in series. The reaction can also suitably take place in a coil-type reactor where the components are added at one or more points along the coil.

The reaction solvent, as noted above, must be one which dissolves both the acidic reactant and the polyolefin. It is necessary to dissolve the acidic reactant and polyolefin so as to bring them into intimate contact in the solution polymerization reaction. It has been found that the solvent must also be one in which the resultant terpolymer is soluble.

Suitable solvents include liquid saturated or aromatic hydrocarbons having from six to twenty carbon atoms, ketones having from three to five carbon atoms, and liquid saturated 17 aliphatic dihalogenated hydrocarbons having from one to five carbon atoms per molecule, preferably from one to three carbon atoms per molecule. By "liquid" is meant liquid under the conditions of polymerization. In the dihalogenated hydrocarbons, the halogens are preferably on adjacent carbon atoms. By "halogen" is meant F, Cl and Br. The amount of solvent must be such that it can dissolve the acidic reactant and polyolefin in addition to the resulting copolymers. The volume ratio of high molecular weight olefin to solvent is suitably between 100:1 and 1:2, and is preferably between 4:1 and 1:1.

Suitable solvents include the ketones having from three to six carbon atoms and the saturated dichlorinated hydrocarbons having from one to five, more preferably one to three, carbon atoms.

Examples of suitable solvents include, but are not limited to:

1. ketones, such as acetone, methylethyketone, diethylketone, and methylisobutylketone; aromatic hydrocarbons, such as benzene, xylene and toluene; saturated dihalogenated hydrocarbons, such as dichloromethane, dibromoethane, 1-bromo-2chloroethane, 1,1-dibromoethane, 1, 1dichloroethane, 1,2-dichloroethane, 1,3dibromopropane, 1,2dibromopropane, 1.2-dibromo-2methylpropane, 1,2-dichloropropane, 1,1- 2.

3.

- 18 dichloropropane, 1,3-dichloropropane, 1-bromo-2chloropropaneo 1,2dichlorobutane, 1,5dibromopentane, and 1,5-dichloropentane; or mixtures of the above, such as benzene methylethylketone.

The terpolymer is conveniently separated from the solvent and unreacted acidic reactant by conventional procedures such as phase separation, solvent distillation, precipitation and the like. If desired, dispersing agents andlor cosolvents may be used during the reaction.

The polyamine used in making the oil soluble dispersant of this invention is one or a mixture of polyamines which pref erably has at least one primary amino group in the molecule and which additionally contains an average of at least two other amino nitrogen atoms in the molecule.

One preferred type of polyamine is comprised of alkylene polyamines such as those represented by the formula: E214 (CE2) a (14K (CH2) a) ^ wherein n is 2 to about 10 (preferably 2 to 4, more preferably 2 or 3, and most preferably 2) and m is 0 to 10, (preferably 1 to about 6). Illustrative are ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine, spermine, pentaethylene hexamine, propylene diamine (1,3-propanediamine), butylene diamine (1,4-butanediamine), hexamethylene diamine (1,6-hexanediamine), decamethylene diamine (1,10-decanediamine), and the like. Preferred for use is - 19 tetraethylene pentamine or a polamine mixture which approximates tetraethylene pentamine (TEPA). These mixtures are commercially available (e.g., S-1107 available from Dow Chemical Company).

Cyclic polyamines such an aminoalkyl-piperazines, e.g. P-aminoethylpiperazine, can also be used in the invention.

Another preferred type of polyamine is comprised of hydrocarbyl polyamines containing from 10 to so weight percent acyclic alkylene polyamines and 50 to 90 weight percent cyclic alkylene polyamines. Preferably such mixture is a mixture consisting essentially of polyethylene polyamines, especially a mixture having an overall average composition approximating that of polyethylene pentamine or a mixture having an overall average composition approximating that of polyethylene tetramine. Another useful mixture has an overall average composition approximating that of polyethylene hexamine. In this connection, the terms 61polyalkylene" and "polyethylene', when utilised in conjunction with such terms as "polyamine", "tetramine".

"perLtamine",, "hexamine", etc., denote that some of the adjacent nitrogen atoms in the product mixture are joined by a single alkylene group whereas other adjacent nitrogen atoms in the product mixture are joined by two alkylene groups thereby forming a cyclic configuration, i.e. , a substituted piperazinyl structure. For example, the following mixture of compounds:

is (a) H2N-C2H4-NH-C2H4-NH-C2H4-NH2 (b) H2N-C2H4-N-C2H4-NH2 1 C2H4-NH2 (c) H2N-C2H4-N.C2H4., N-C2H4-NH2 C2H4 11 -C2H4--, (d) HN,, C2H4.N-C2H4-NH-C2H4-NH2 (c) HN CH2CH2-, N-CH2CH2-N..CH2CH2--, NH CH2CH2 111 CH2CH2 1.1 is termed herein a "polyethylene tetramine" inasmuch as its overall composition is that of a tetramine (four amino groups per molecule) in which acyclic components (a) and (b) have three ethylene groups per molecule, cyclic components (c) and (d) have four ethylene groups per molecule, and cyclic component (e) has five ethylene groups per molecule. Thus, if the above mixture contains from 10 to So weight percent of components (a) and (b) -- or either of them -- and from 90 to 50 weight percent of components (c), (d) or (e) -- or any two or all three of them - - it is a polyethylene tetramine suitable for use in the practise of this invention. Small amounts of lower and/or higher molecularweight species may of course be present in the mixture.

Among the especially preferred embodiments of this invention are dispersants derived by:

1) use of a mixture of polyalkylene polyamines (10-50% acyclic; 90-50% cyclic) having an overall composition approximating that of polyalkylene pentamine and further characterized by containing on a weight basis:

a) from 2 to 10% of polyalkylene tetramines; b) from 60 to 85% of polyalkylene pentamines; c) from 10 to 20% of polyalkylene hexamines; and d) up to 10% lower andlor higher analogs of the foregoing.

2) use of a mixture of polyalkylene polyamines (10-50% io acyclic; 90-50% cyclic) having an overall composition approximating that of polyalkylene pentamine and further characterized by containing on a weight basis:

a) at least 30% of the cyclic isomer depicted as b) and N - N = N - N N at least 10% of the cyclic isomer depicted as N = N - N - N N c) at least 2% of the acyclic branched isomer depicted as N-N-N-N 1 N d) at least 5% of the acyclic linear isomer depicted as N - N - N - N - IN 3) use of a mixture of polyalkylene polyamines (10-50% acyclic; 90-50% cyclic) having an overall composition approximating that of polyalkylene tetramine and further is - 22 characterised by containing on a weight basis:

a) at least 5% linear acyclic alkylene polyamines; b) at least 10% branched acyclic alkylene polyamines; and c) at least 60% cyclic alkylene polyamines.

4) use of a mixture of polyalkylene polyamines (10-50% acyclic; 90-50% cyclic) having an overall composition approximating that of polyalkylene tetramine and further characterised by containing on a weight basis:

a) at least 30% of the cyclic isomer depicted as N - N = N - N b) at least 20% of the cyclic isomer depicted as 19 = N - N - N c) at least 10% of the acyclic branched isomer depicted as and N-N-N 1 N d) at least 5% of the acyclic linear isomer depicted as N - N - N - N In the structural representations depicted in 2) and 4) above, the 11-11 (whether horizontal or vertical) represents an alkylene group each of which contains up to 6 carbon atoms, preferably from 2 to 4 carbon atoms, and most preferably is the ethylene (dimethylene) group. i.e., the -CH.CH,- group. Similarly, the 11=11 represents a pair of such alkylene groups - 23 each having up to 6 carbon atoms and preferably having from 2 to 4 carbon atoms each. In the most preferred cases, the represents a pair of ethylene (dimethylene) groups, each having the formula -CH2CE,-. As is indicated by the structural representations presented above, both of the alkylene groups in the cyclic structure depicted as 11=11 extend between the same pair of proximate nitrogen atoms.

In the above depictions, hydrogen atoms satisfying the trivalent character of the nitrogen atoms are not shown.

Thus, when 91-11 is ethylene and 11=11 is a pair of ethylene groups, the depiction 'IN = N - N - NII is a simplified version of the formula:

-CH2CH2-, HW, CH2CH2.. N-CH2CH2- NH -CH2CH2-NH2 is Also suitable are aliphatic polyamines containing one or more ether oxygen atoms and/or one or more hydroxyl groups in the molecule. Mixtures of various polyamines of the type referred to above are also suitable.

In principle, therefore, any polyamine having at least one primary amino group and an average of at least three amino nitrogen atoms in the molecule can be used in forming the dispersants of this invention. Product mixtures known in the trade as 11triethylene tetramine", 'Itetraethylene pentamine", and "pentaethylene hexamine" are most preferred.

Such a polyamine may be alkoxylated e.g. by incorporation of 1 to 2 Nsubstituted C2 or C. hydroxyalkyl - 24 groups per molecule, preferably P-hydroxyethyl groups. In this embodiment of the invention the terpolymeric acylating agent may be reacted with an alkoxylated diethylene triamine or other polyamine having an average of from 1 to 2 Nsubstituted C2 or C3 hydroxyalkyl groups per molecule, the reactants being employed in proportions of at least 2 moles (typically from 2 to 2. 8 Moles. and preferably from 2 to 2.5 moles) of said acylating agent per mole of said alkoxylated diethylene triamine, with the proviso that where said average of N-substituted C2 or C3 hydroxyalkyl groups is 1.7 or more, said proportions are such that there are more than 2 moles of said acylating agent per mole of said alkoxylated diethylene triamine. Dispersants wherein the hydroxyalkyl groups are Phydroryethyl groups are preferred. It is also preferable that the average number of N-substituted hydroxyalkyl groups per molecule of the dispersant fall in the range of 1.1 to 1.6. To achieve good results in the Volkswagen PV-3334 Seal Test, the average number of N- substituted hydroxyalkyl groups per molecule of the dispersant is preferably in the range of 1.1 to 1.3, and most preferably is 1.2. On the other hand, to achieve a good balance of seal performance in the Volkswagen PV-3344 Seal Test together with dispersancy, the average number of N-substituted hydroxyalkyl groups per molecule of the dispersant is preferably in the range of 1.4 to 1.6, preferably about 1.5.

The mole ratio of the polyolefin (1) to the a-olefin (2) in the terpolymers used in the dispersants of the present - 25 invention may be in the range from 99:1 to 5:95# but is usually in the range 98:2 to 10:90, and more preferably in the range 95:5 to 20:80.

The mole ratio of the total olef ins used in making the terpolymer to the maleic anhydride or other unsaturated acidic reactant is normally not more than 1:5, and is generally in the range of 1:1.3 to 1:0.5, more usually 1:1.2 to 1:0.75, and preferably in the range 1:1.1 to 1:0.8.

The ashless dispersants of the present invention may be prepared by reacting the polyamine with the terpolymeric succinic acylating agent in the desired mole ratio at a temperature in the range of 80 to 1500C. After the addition has been completed the reaction temperature is raised to a higher temperature, e.g. 150 to 1700C to complete the reaction. Typically, the mole ratio of total polyamine to total terpolymeric acylating agent is from 2:1 to 1:3, preferably from 1:1 to 1:2. While the reaction between the polyamine and the acylating agent can be carried out in the absence of any solvent, it is usually preferable to dilute the terpolymeric acylating agent with a suitable solvent, e.g. a mineral oil, preferably 100 solvent neutral mineral oil, before the polyamine is added.

Surprisingly, it has been found that varying the mole ratio of terpolymeric acylating agent reacted initially with the polyamine to acylating agent reacted subsequently with polyamine can be used to adjust the viscometrics of lubricating oils in which the dispersants are incorporated.

- 26 This has the advantage of allowing the viscometrics of lubricating oils to be manipulated to meet specific requirements, and enables all or at least most viscosity index improver to be left out of the finished lubricant. The present invention thus also includes within its scope the use of the dispersants described herein as additives for controlling the viscometric properties of a lubricant composition comprising a major proportion of oil of lubricating viscosity.

As stated above, in preparing the oil-soluble ashless dispersants of the invention the mole ratio of total polyamine to total terpolymeric acylating agent is normally from 2:1 to 1:3, preferably from 1:1 to 1:2.5. Rore favourable results are observed using a mole ratio of total polyamine to total terpolymeric acylating agent of approximately 1:1.8.

Varying the mole ratio of terpolymeric acylating agent reacted initially with polyamine to terpolymeric acylating agent reacted subsequently with polyamine can be used to influence the viscometric properties of lubricating oils in which the dispersant is incorporated. Typically, this mole ratio is from 20:1 to 1:3, preferably 20:1 to 1:2, more preferably still 4:1 to 1.5:1. It has been found that a more marked effect is observed using lower initial charges of terpolymeric acylating agent.

The polyamine is added to and reacted with the initial charge of terpolymeric acylating agent at a temperature typically in the range of 80 to 1500C. This reaction is normally allowed to run to completion before the remainder of terpolymeric acylating agent is added. A convenient way of confirming that the reaction is complete is to measure the acid value of the reaction mixture. This can be done by known methods. As the reaction proceeds acid value decreases. The reaction is regarded as complete when the acid value falls below a critical value, for example below approximately 0.06mequivIg. After the remainder of terpolymeric acylating agent has been added the reaction temperature is raised to a higher temperature, e.g. 150 to 1700C to complete the reaction. The remainder may be added as a single charge, or as a number of charges. Alternatively, the reaction temperature can first be raised and the remainder of terpolymeric acylating agent subsequently added. It is also possible to add the remainder of acylating agent at the same time as the temperature is raised.

The invention includes within its scope compositions, especially lubricant compositions, comprising a mixture of an oil of lubricating viscosity and a dispersant as described above. Such compositions may comprise from 1 to 99% by weight of the oil of lubricating viscosity and from 99 to 1% by weight of the dispersant of the invention.

A further embodiment of the invention is the use of above described dispersants to lubricate an engine, e.g. an internal combustion engine, or other device, particularly wherein said lubricant composition comes into contact with a fluoroclastomer. As noted above. the dispersants of the invention show a remarkably reduced tendency to degrade or otherwise adversely effect fluoroelastomers.

The dispersants of the invention may conveniently be provided in the form of an additive concentrate. Such concentrates typically comprise from 1 to 99% weight dispersant and from 99 to 1% by weight of solvent or diluent for the dispersant. the solvent or diluent being miscible andlor capable of dissolving in the lubricating oil in which the concentrate is to be used. The lubricating oil to which the concentrate is to be added may be used as solvent or diluent.

The invention is further illustrated in the following Examples.

EXAMPLE 1

A terpolymer (ftn 1873; 150.8g) made from polyisobutene (Mn 1300) a C2.. 24 a-olef in (Chevron) and maleic anhydride having an acid value of 0.67 mequiv/g in 100 SN mineral oil (39.1g) was heated to 900C. A polyamine mix equivalent to TEPA (10.55g) was added over 20 minutes while the temperature was kept at 950C or below. At the end of the polyamine addition the mixture was heated to 1670C for 3 hours under vacuum. After this time the temperature was reduced to 1524C and boric acid (11.75g) was added over 1 hour. After stirring for 2 hours, with the last hour under vacuum, the vacuum was released and maleic anhydride (1.73g) was added 29 rapidly. After stirring for 15 minutes the mixture was stripped under vacuum for 15 minutes. More mineral oil was then added and the product filtered to give a product with an oil content of 23.5% and a nitrogen content of 1.7%. EXAMPLE 2 A terpolymer (Xn 2683. 100g) made from PIB (Mn 2350), CM-24 a-olefin (Chevron) in a 70:30 mole ratio and maleic anhydride with a total olefin:maleic anhydride mole ratio of 1:1 (acid value 0.44 mequiv/g) was mixed with 100 SN mineral oil (36.0g) and heated to 900C. A polyamine mix equivalent to TEPA (4.62g) was added over 10 minutes while the temperature was kept under 950C. The mixture was heated to 1670C and stirred for 3 hours. A further charge of oil (35.6g) was made and the temperature was reduced to 1506C and boric acid (4.93g) and maleic anhydride (0.73g) were added.

After stirring for 30 minutes, the mixture was vacuum stripped for 1 hour and filtered. The product had a nitrogen content of 0.89% and a boron content of 0.31%.

EXAMPLE 3

A terpolymer (Xn 1757, 1000g) made from PIB (Mn 1300), CM-24 a-olefin (Chevron) and maleic anhydride having an acid value of 0.69 mequiv/g, was mixed with 100 SN mineral oil (375g) and heated to 900C. A polyamine mix equivalent to TEPA (72.5g) was added over 1 hour while the temperature was kept below 950C. The procedure described in Example 4 was then followed using boric acid (77.3g) and maleic anhydride (11.4g). The product after filtration contained 1.67% N and - 30 0.81% B. EXAMPLE 4

A terpolymer (Mn 1534, 100g) made from PIB (Mn 1300) C20.24 a-olefin (Chevron) and maleic anhydride having an acid number of 0.75 mequiv/g and process oil (37.3g) were heated to 900C. Aminoethylpiperazine (9.68g) was added. After stirring for 30 minutes, the temperature was raised to IOSOC and maleic anhydride (3.68g) was added. The mixture was heated to 1670C and stirred for 3 hours. After stripping 1 hour under vacuum the mixture was filtered to give a product containing 2.0% N.

EXAMPLE 5

A terpolymer (Nn 2799, 100g) made from PIB (Nn 2350), -olefin (averaging C. from Albemarle) in a 90:10 mole ratio and maleic anhydride with a total olefin:maleic anhydride ratio of 1:1 (acid value 0.37 mequiv/g) was mixed with 100 SN mineral oil (35.S4g), and heated to 900C. The procedure of Example 2 was then followed using polyamine mix (3.83g), process oil (35.54g), boric acid (4.08g) and maleic anhydride (0.60g). The product had a nitrogen content of 0.76% and a boron content of 0.35%.

EXAMPLE 6

Example 5 was repeated except that a terpolymer (Mn 2766, 92.9) made from PIB (Kn 2350), a-olefin (averaging C24 from Albemarle) in a 70:30 mole ratio and maleic anhydride with a total olefin:maleic anhydride ratio of 1:1 (acid value 0.42 mequiv/g) was used. The charge quantities were 100 SN mineral oil (33.3g). polyamine mix (4.05g), process oil (33.3g), boric acid (4.32g) and maleic anhydride (0.63g).

The product contained 0.81%N and 0.32%B.

EXA"LE 7 A terpolymer (Xn 17330 100.6g) made from PIB (Kn 1300), a C2..2. a-olefin (Cheveron) and maleic anhydride having an acid value of 0.78 mequiv/g was charged to a flask along with process oil (40.3g) and heated to 900C. A polyamine mix equivalent to TEPA (13.25g) was added over 10 minutes while the temperature was kept below 950C. After stirring for 30 minutes, more terpolymer (61.9g) was added, and the temperature was increased to 1670C. After stirring for 3 hours the mixture was stripped under vacuum. The resultant product was charged to a flask with process oil (33.2g) and the temperature adjusted to 1500C. Boric acid (9.50g) was added followed by maleic anhydride (1.42g) and the mixture stirred for one hour. The mixture was stripped for one hour and then diluted with oil (159.6g). After filtration the product had a nitrogen content of 1.67% and a boron content of 0.86%.

EXAMPLE 8

A terpolymer (Xn 2061, 123.0g) made from PIB (Kn 1300), a C2.-2. a-olefin (Chevron) and maleic anhydride, having an acid number of 0.77mequiv/g was charged to a flask with process oil (83.9g) and heated to 900C. A polyamine equivalent to TEPA (16.27g) was added over 15 minutes and the reaction mixture stirred for 35 minutes. The temperature was - 32 raised to 1050C and a further charge of terpolymer added (77.0g). The temperature was raised to 1676C and stirred for three hours and then stripped for 45 minutes. After releasing the vacuum the temperature was adjusted to 1509C and boric acid (15.67g) and maleic anhydride (2.36g) added. The mixture was stripped for one hour and then filtered to give a product with a nitrogen content of 1.61% and a boron content of 0.78%.

EXA"LE 9 A terpolymer (Xn 1733, 147.0g)r made from PIB (Xn 1300), a C2..2. a-olefin (Chevron) and maleic anhydride, having an acid number of 0.7amequiv/g was charged to a flask along with process oil (56.0g) and heated to 900C. A polyamine mix equivalent to TEPA (12.04g) was added over 45 minutes and then the mixture heated to 1670C. After stirring for three hours the mixture was stripped for 45 minutes. The temperature was reduced to 1500C and boric acid (12.84g) followed by maleic anhydride (1.89g) added. After stirring for one hour the mixture was stripped for one hour and then filtered to give a product with a nitrogen content of 1.70%.

=LE 10 A terpolymer (Kn 2061, 430g), made from PIB (Mn 1300), a C2.-2. a-olef in (Chevron) and maleic anhydride, having an acid number of 0.77mequiv/g was charged to a flask along with process oil (291.8g) and heated to 900C. A polyamine mix equivalent to TEPA (56.4g) was added over 40 minutes and then the mixture heated to 1050C. A further charge of copolymer - 33 (270.2g) was made and at the end of the addition the temperature was raised to 1676C. After stirring for three hours the mixture was stripped for 45 minutes. The temperature was reduced to 1500C and boric acid (54. 52g) followed by maleic anhydride (8.23g) added. After stirring for one hour the mixture was stripped for one hour and then filtered to give a product with a nitrogen content of 1.72%.

EXILE 11 A terpolymer (Kn 1534, 130.3g), made from PIB (Xn 1300), a C20-24 a-olefin (Chevron) and maleic anhydride, having an acid number of 0.75mequiv/g was charged to a flask along with process oil (48.35g) and heated to 900C. Aminoethylpiperazine (12.6g) was added over 30 minutes and then the mixture heated to 1500C. Maleic anhydride (4.79g) was added and the mixture heated to 1670C. After stirring for three hours the mixture was stripped for 45 minutes and then filtered to give a product with a nitrogen content of 1.93%.

EXAMPLE 12

A terpolymer (Xn 2184, 140.7g), made from PIB (Mn 1300)# a C2.-.4 cc-olefin (Chrevon) and maleic anhydride, having an acid number of 0.78mequiv/g was charged to a flask along with process oil (52.43g) and heated to 900C.

Aminoethylpiperazine (14.18g) was added over 30 minutes and then the mixture heated to 1500C. Maleic anhydride (5.38g) was added and the mixture heated to 1670C. A further charge of process oil (52.43g) was made and the mixture stirred for - 34 three hours. After stripping for one hour the product was filtered to give a product with a nitrogen content of 1.72% The product of Examples 1, 9 and 10 were blended into a standard 15W-40 engine oil formulation from which the conventional ashless dispersant had been omitted. The dispersant was used at a concentration in the finished lubricant of 7 wt% (including the diluent oil associated with the dispersant). The finished lubricant was thus made up by weight of 72.4% 150 SN mineral oil, 5.0% 500 SH mineral oil, 9.7% OCP viscosity index improver, 1.31% zinc dialkyl dithiophosphate, 2.6% overbased calcium sulfonate, 0.64% low base calcium sulfonate, 0.8% phenolic antioxidant, 0.25% aromatic amine antioxidant, 0.004% antifoam agent, 0.296% process oil, and the 7% of dispersant under test, the proportions of the additive components being on an as received basis. The lubricant was subject to the Volkswagen PV-3344 Seal Test. The viscometrics of the blend were also measured. For comparison dispersant products based on a conventional PIBSA were made. In each a molar ratio of reactants PIBSA: polyamine of 1.8:1 was used. one of these was unpost-treated and had a N content of 1.8%. The other was post-treated using boric acid and maleic anhydride, the N content being 1.7%. These conventional dispersants were used at 7 wt% including diluent oil. The following results were obtained.

is - 35 PV-3344 test Viscometrics TS Elong Cracks V100 V40 VI MPa % cSt cSt Product of 11.2 266 No x 3 19.82 143.8 159 Example 1

Product of 8.9 191 No 13.93 97.91 145 Example I

Product of 10.2 195 No 15.2 107.6 148 Example 10

PIBSA based <8.3 <148 Crack 13.89 104.5 134 equivalent break (unpost treated) PIBSA based 8.3 148 No x 2 13.90 102.0 138 equivalent Yes x 1 (post treated) Pass Limit 8.0 160 No min min I I I I I I I ccs cp (-15-C) 2892 2712 2821 3250 3250 The unpost-treated PIBSA-based dispersant failed the PV3344 seal test. Post-treatment of the PIBSA-based dispersant gives an improvement in seal compatability but a fail result is still observed. It should be noted that post-treatment has virtually no effect on the viscometric properties of the conventional PIBSA based dispersant.

1 The terpolymer-based dispersants of the present invention give an excellent pass in the PV-3344 test. In terms of viscometrics the terpolymer based dispersants of the present invention give a much higher V100 and VI (viscosity index) without adversely affecting the CCS which is indeed lower. This would enable all or at least most of the VI Improver to be left out of the finished lubricant. comparing the results for Examples 1, 9 and 10 shows that, in accordance with the present invention, dispersants having greater seal compatability exhibit increased viscosity lift.

Claims (37)

- 37 CLAIMS

1. A process for preparing an oil-soluble dispersant which comprises reacting a polyamine and a terpolymeric acylating agent derived from (1) a polyolefin containing an average of at least 30 carbon atoms per molecule in which at least 30% of the residual olefin groups are in the form of vinylidene radicals of formula:

-CR=CH2 where R is alkyl of 1 to 6 carbon atoms; (2) an a-olefin and (3) an unsaturated dicarboxylic acid or derivative thereof, followed by post-treatment with one or more post-treating agents.

2. A process according to claim 1, wherein the posttreating agent is an inorganic or organic phosphorus compound, boron compound, or mono- or poly-carboxylic acid or derivative thereof.

3. A process according to claim 2, wherein the posttreating agent is an inorganic phosphorus acid or anhydride, boric acid, an unsaturated dicarboxylic acid or derivative thereof, or a mixture of these.

4. A process according to claim 3, wherein the posttreating agent is an unsaturated dicarboxylic acid or derivative thereof, or a mixture of these.

5. A process according to claim 3, wherein post- treatment is with boric acid and maleic anhydride.

6. A process according to claim 4, wherein posttreatment is with maleic anhydride.

7. A process according to any one of claims 1 to 6, wherein the polyolefin (1) contains on average at least 50 carbon atoms.

8. A process according to any one of claims 1 to 7, wherein (3) is an unsaturated dicarboxylic acid or derivative thereof capable of reacting with a polyamine.

9. A process according to claim 8, wherein the derivative is an ester, amide, acyl halide, metal or ammonium salt, or anhydride.

10. A process according to any one of claims 1 to 9, wherein.the unsaturated dicarboxylic acid or derivative thereof (3) has the formula:

X-CO-CH=CH-CO-M in which X and X' are each -OR, -0-hydrocarbyl, -0-M (where X is a metal or ammonium), _"21 -Cl, or -Br, or X and X' together are -0-.

11. A process according to claim 10, wherein the unsaturated dicarboxylic acid or derivative thereof (3) is maleic or fumaric acid or anhydride.

12. A process according to any one of claims 1 to 11, wherein the polyolefin (1) of the terpolymeric acylating agent is a polyisobutene.

13. A process according to any one of claims 1 to 12, wherein the polyolefin (1) of the terpolymeric acylating agent is a polyisobutene having a number average molecular weight in the range 800 to 5000 and in which at least 50% of the olefin groups are in the form of vinylidene radicals of 39 - f ormula:

-C (R) =CK2 where R is as defined in claim 1.

14. A process according to any one of claims 1 to 13, wherein the aolefin (2) contains from 2 to 40 carbon atoms.

15. A process according to any one of claims 1 to 14, wherein the aolefin (2) is of formula:

R I CH=C"2 in which RI is an aliphatic group of 1 to 26 carbon atoms.

16. A process according to any one of claims 1 to 15, wherein the polyamine comprises a polyalkylene polyamine containing 3 to 6 primary and secondary amino groups per molecule.

17. A process according to claim 16, wherein the polyamine comprises tetraethylene pentamine, or a mixture of polyamines having an average composition which approximates tetraethylene pentamine.

18. A process according to any one of claims 1 to 17, wherein the polyamine is a mixture of hydrocarbyl polyamines containing 10 to 50 weight percent acylic alkylene polyamines and 90 to 50 weight percent cyclic alkylene polyamines, an aliphatic polyamine containing one or more ether oxygen atoms and/or one or more hydroxyl groups in the molecule, or a basic salt of aminoguanidine, or a mixture thereof.

19. A process according to any one of claims 1 to is, wherein the mole ratio of polyolefin (1) to a-olefin (2) is from 99:1 to 5:95, preferably from 95:5 to 20:80.

20. A process according to any one of claims 1 to 19, wherein the mole ratio of total olefins (1) and (2) to acid or anhydride (3) used in making the terpolymer is from 1:1.3 to 1:0.5, preferably from 1:1.1 to 1:0.8.

21. A process according to any one of claims 1 to 20, wherein the polyamine is reacted with an initial charge of the terpolymeric acylating agent, at least one further charge of the terpolymeric acylating agent being added subsequently.

22. A process according to claim 21, wherein in the 10 reaction the mole ratio of total polyamine to total terpolymeric acylating agent is from 2:1 to 1:3.

23. A process according to claim 22, wherein the mole ratio of total polyamine to total terpolymeric acylating agent is from 1:1 to 1:2.5.

is

24. A process according to any one of claims 21 to 23 wherein the mole ratio of terpolymeric acylating agent reacted initially with polyamine to terpolymeric acylating agent added subsequently is from 20:1 to 1:3.

25. A process according to claim 24, wherein the mole 20 ratio is from 4:1 to 1.5:1.

26. A process according to claim 1 substantially as hereinbefore described in any of Examples 1 to 12.

27. An oil-soluble dispersant obtained by the process claimed in any one of claims 1 to 26.

28. An additive concentrate for use in a lubricating oil comprising from 1 to 99% by weight of a dispersant as claimed in claim 27 and from 99 to 1% by weight of solvent or - 41 diluent for the dispersant, the solvent or diluent being miscible andlor capable of dissolving in the lubricating oil in which the concentrate is to be used.

29. A lubricant composition comprising a dispersant as 5 claimed in claim 27 and an oil of lubricating viscosity.

30. The use of a lubricant composition as claimed in claim 29 to lubricate an engine or other device.

31. The use according to claim 30, wherein the lubricant composition comes in contact with a 10 fluoroelastomer.

32. The use of a dispersant obtained by the process claimed in any one of claims 1 to 21 as an additive for controlling the viscometric properties of a lubricant composition comprising a major proportion of oil of 15 lubricating viscosity.

33. The use of a dispersant obtained by the process claimed in any one of claims 21 to 25 as an additive for controlling the viscometric properties of a lubricant composition comprising a major proportion of oil of 20 lubricating viscosity.

34. A dispersant according to claim 27 substantially as hereinbefore described.

35. Use according to claim 30 substantially as hereinbefore described.

36. Use according to claim 32 substantially as hereinbefore described.

37. Use according to claim 33 substantially as hereinbefore described.