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GB2006232A - Olefin polymerization process - Google Patents

Olefin polymerization process

Info

Publication number
GB2006232A
GB2006232A GB7840089A GB7840089A GB2006232A GB 2006232 A GB2006232 A GB 2006232A GB 7840089 A GB7840089 A GB 7840089A GB 7840089 A GB7840089 A GB 7840089A GB 2006232 A GB2006232 A GB 2006232A
Authority
GB
United Kingdom
Prior art keywords
iii
alkyl
halide
polymerization process
olefin polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7840089A
Other versions
GB2006232B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Naphtachimie SA
Original Assignee
Naphtachimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Naphtachimie SA filed Critical Naphtachimie SA
Publication of GB2006232A publication Critical patent/GB2006232A/en
Application granted granted Critical
Publication of GB2006232B publication Critical patent/GB2006232B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Powdery copolymers of ethylene and C3-6 olefins having particular physical properties are prepared by polymerization in a fluidized bed of materializing copolymer in the presence of an organometallic compound of a Group II or III metal and a catalyst component formed by reacting at -20 to 150 DEG C (i) an alkoxide, halide or alkoxyhalide of quadrivalent titanium, (ii) an alkyl halide and (iii) (a) an alkyl Grignard reagent, (b) a magnesium dialkyl or (c) metallic magnesium, where all the alkyl and alkoxy groups are C1-8 groups and all the halogens are chlorine or bromine, in certain molecular proportions depending on the nature of component (iii).
GB7840089A 1977-10-12 1978-10-11 Olefin polymerization process Expired GB2006232B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7730662A FR2405961A1 (en) 1977-10-12 1977-10-12 PROCESS FOR THE COPOLYMERIZATION OF OLEFINS IN A GAS PHASE IN THE PRESENCE OF A FLUIDIZED COPOLYMER BED AND A CATALYST CONTAINING TITANIUM AND MAGNESIUM

Publications (2)

Publication Number Publication Date
GB2006232A true GB2006232A (en) 1979-05-02
GB2006232B GB2006232B (en) 1982-08-18

Family

ID=9196402

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7840089A Expired GB2006232B (en) 1977-10-12 1978-10-11 Olefin polymerization process

Country Status (10)

Country Link
JP (1) JPS6053044B2 (en)
BE (1) BE871221A (en)
CA (1) CA1106099A (en)
DE (1) DE2844312C2 (en)
ES (1) ES474076A1 (en)
FR (1) FR2405961A1 (en)
GB (1) GB2006232B (en)
IT (1) IT1099775B (en)
LU (1) LU80350A1 (en)
NL (1) NL184165C (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5692902A (en) * 1979-12-26 1981-07-28 Nippon Oil Co Ltd Production of copolymer
EP0041405A2 (en) * 1980-06-04 1981-12-09 Mitsui Petrochemical Industries, Ltd. Tubular polymerization reactor, and process for polymerization
EP0081940A1 (en) * 1981-12-04 1983-06-22 Mobil Oil Corporation Preparation of a catalyst for and a method of producing linear low density polyethylene
FR2521570A1 (en) * 1982-02-12 1983-08-19 Enoxy Chimica ETHYLENE POLYMERS WITH LINEAR STRUCTURE AND PROCESS FOR THEIR PREPARATION
US4481301A (en) * 1981-12-04 1984-11-06 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
US4721763A (en) * 1982-06-24 1988-01-26 Bp Chemicals Limited Process for the polymerization and copolymerization of alpha-olefins in fluidized bed
US4748206A (en) * 1985-11-11 1988-05-31 Nippon Petrochemicals Company, Limited Polyolefin composition and the same used for vehicle exterior members
US4762882A (en) * 1985-07-08 1988-08-09 Mitsubishi Chemical Industries Limited Modified polyolefin resin and a composition containing the same
US4857611A (en) * 1984-05-02 1989-08-15 Bp Chemicals Limited Gas fluidized bed terpolymerization of olefins
US5241023A (en) * 1990-03-09 1993-08-31 Bp Chemicals Limited Process and device for the gas phase polymerization of alpha-olefins

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5529512A (en) * 1978-08-22 1980-03-01 Nippon Oil Co Ltd Preparation of polyolefin
JPS5552309A (en) * 1978-10-11 1980-04-16 Nippon Oil Co Ltd Preparation of copolymer
JPS5556110A (en) * 1978-10-20 1980-04-24 Nippon Oil Co Ltd Preparation of copolymer
JPS5556111A (en) * 1978-10-20 1980-04-24 Nippon Oil Co Ltd Preparation of copolymer
JPS5558210A (en) * 1978-10-26 1980-04-30 Nippon Oil Co Ltd Production of copolymer
FR2460964A1 (en) * 1979-07-06 1981-01-30 Naphtachimie Sa ELASTOMERIC COPOLYMERS OF ETHYLENE AND PROPYLENE, THEIR MANUFACTURE AND THEIR APPLICATIONS
JPS56136806A (en) * 1980-03-29 1981-10-26 Mitsui Petrochem Ind Ltd Storage of solid titanium catalyst component containing highly active magnesium
JPS5738837A (en) * 1980-08-19 1982-03-03 Mitsubishi Chem Ind Ltd Production of polyolefin film
FR2493856B1 (en) * 1980-11-13 1986-03-21 Naphtachimie Sa HIGH IMPACT RESISTANCE POLYPROPYLENE COMPOSITIONS
FR2493855B1 (en) * 1980-11-13 1986-01-10 Naphtachimie Sa IMPROVED IMPACT RESISTANCE POLYPROPYLENE COMPOSITIONS
FR2493854B1 (en) * 1980-11-13 1985-10-11 Naphtachimie Sa IMPROVED POLYETHYLENE COMPOSITIONS FOR EXTRUSION IN PARTICULAR FOR EXTRUSION-BLOWING
FR2509315A1 (en) * 1981-07-10 1983-01-14 Charbonnages Ste Chimique HETEROGENEOUS COPOLYMERS OF ETHYLENE FOR THE MANUFACTURE OF FILMS
JPS5975910A (en) * 1982-10-25 1984-04-28 Mitsui Petrochem Ind Ltd Ethylene copolymer
FR2565591B1 (en) * 1984-06-08 1986-08-29 Inst Francais Du Petrole PROCESS FOR THE MANUFACTURE OF AN ETHYLENE-BUTENE-1 COPOLYMER FROM ETHYLENE
FR2566781B1 (en) * 1984-06-28 1986-11-14 Bp Chimie Sa PROCESS FOR THE POLYMERIZATION OR CO-POLYMERIZATION OF ALPHA-OLEFINS IN A FLUIDIZED BED, IN THE PRESENCE OF A ZIEGLER-NATTA CATALYST SYSTEM
FR2581564B1 (en) 1985-05-13 1993-05-07 Bp Chimie Sa FLUIDIZED BED APPARATUS HAVING A MULTI-SLOPE FLUIDIZING GRID
US5256351A (en) * 1985-06-17 1993-10-26 Viskase Corporation Process for making biaxially stretched, heat shrinkable VLDPE films
CA1340037C (en) * 1985-06-17 1998-09-08 Stanley Lustig Puncture resistant, heat-shrinkable films containing very low density polyethylene copolymer
FR2666337B1 (en) † 1990-08-31 1994-04-08 Bp Chemicals Snc REGULATED POLYMERIZATION PROCESS FOR OLEFIN IN THE GASEOUS PHASE USED WITH A ZIEGLER-NATTA-TYPE CATALYST.
DE4241533C2 (en) * 1992-12-10 1999-03-25 Buna Sow Leuna Olefinverb Gmbh Process for the production of high density polyethylene
DE4241530C2 (en) * 1992-12-10 1999-03-25 Buna Sow Leuna Olefinverb Gmbh Process for the production of high density polyethylene
US20030113496A1 (en) 2001-12-17 2003-06-19 Harris Michael G. Polyethylene melt blends for high density polyethylene applications
US6822051B2 (en) 2002-03-29 2004-11-23 Media Plus, Inc. High density polyethylene melt blends for improved stress crack resistance in pipe

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU61816A1 (en) * 1970-10-06 1972-06-28
NL7113778A (en) * 1970-10-13 1972-04-17
US3907760A (en) * 1971-02-16 1975-09-23 Dow Chemical Co Process for manufacture of high bulk density powders of olefin polymers
BE785673A (en) * 1971-06-30 1973-01-02 Naphtachimie Sa POLYMERIZATION CATALYZERS OF OLEFINS PREPARED FROM DECOMPOSED ORGANOMAGNESIANS
AR206852A1 (en) * 1975-03-10 1976-08-23 Union Carbide Corp PROCEDURE FOR PREPARING LOW AND MEDIUM DENSITY ETHYLENE POLYMERS IN A FLUID BED REACTOR
IT1042180B (en) * 1975-08-29 1980-01-30 Montedison Spa PROPOLENE CRYSTAL POLYMERS AND COPOLYMERS AND PROCEDURE FOR THEIR PREPARATION

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6042806B2 (en) * 1979-12-26 1985-09-25 日石三菱株式会社 Copolymer manufacturing method
JPS5692902A (en) * 1979-12-26 1981-07-28 Nippon Oil Co Ltd Production of copolymer
EP0041405A2 (en) * 1980-06-04 1981-12-09 Mitsui Petrochemical Industries, Ltd. Tubular polymerization reactor, and process for polymerization
EP0041405A3 (en) * 1980-06-04 1981-12-23 Mitsui Petrochemical Industries, Ltd. Tubular polymerization reactor, and process for polymerization
EP0081940A1 (en) * 1981-12-04 1983-06-22 Mobil Oil Corporation Preparation of a catalyst for and a method of producing linear low density polyethylene
US4481301A (en) * 1981-12-04 1984-11-06 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
FR2521570A1 (en) * 1982-02-12 1983-08-19 Enoxy Chimica ETHYLENE POLYMERS WITH LINEAR STRUCTURE AND PROCESS FOR THEIR PREPARATION
US4721763A (en) * 1982-06-24 1988-01-26 Bp Chemicals Limited Process for the polymerization and copolymerization of alpha-olefins in fluidized bed
US5087522A (en) * 1982-06-24 1992-02-11 Bp Chemicals Limited Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed
US4857611A (en) * 1984-05-02 1989-08-15 Bp Chemicals Limited Gas fluidized bed terpolymerization of olefins
EP0164215B2 (en) † 1984-05-02 2002-10-30 BP Chemicals Limited Gas fluidised bed terpolymerisation of olefins
US4762882A (en) * 1985-07-08 1988-08-09 Mitsubishi Chemical Industries Limited Modified polyolefin resin and a composition containing the same
US4748206A (en) * 1985-11-11 1988-05-31 Nippon Petrochemicals Company, Limited Polyolefin composition and the same used for vehicle exterior members
US5241023A (en) * 1990-03-09 1993-08-31 Bp Chemicals Limited Process and device for the gas phase polymerization of alpha-olefins

Also Published As

Publication number Publication date
JPS6053044B2 (en) 1985-11-22
NL184165B (en) 1988-12-01
JPS5462292A (en) 1979-05-19
ES474076A1 (en) 1979-04-16
NL7810217A (en) 1979-04-18
DE2844312A1 (en) 1979-04-19
CA1106099A (en) 1981-07-28
BE871221A (en) 1979-04-12
GB2006232B (en) 1982-08-18
LU80350A1 (en) 1979-03-16
IT1099775B (en) 1985-09-28
NL184165C (en) 1992-03-16
IT7828577A0 (en) 1978-10-10
DE2844312C2 (en) 1985-07-11
FR2405961B1 (en) 1980-08-22
FR2405961A1 (en) 1979-05-11

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19971011