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GB2067437A - Method for producing clad steel plate - Google Patents

Method for producing clad steel plate Download PDF

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Publication number
GB2067437A
GB2067437A GB8100381A GB8100381A GB2067437A GB 2067437 A GB2067437 A GB 2067437A GB 8100381 A GB8100381 A GB 8100381A GB 8100381 A GB8100381 A GB 8100381A GB 2067437 A GB2067437 A GB 2067437A
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GB
United Kingdom
Prior art keywords
steel plate
cladding metal
clad steel
contact surfaces
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8100381A
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GB2067437B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP115480A external-priority patent/JPS5911394B2/en
Priority claimed from JP115580A external-priority patent/JPS5699089A/en
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Publication of GB2067437A publication Critical patent/GB2067437A/en
Application granted granted Critical
Publication of GB2067437B publication Critical patent/GB2067437B/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/04Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a rolling mill

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

A clad steel plate is produced by superposing a backing steel and a cladding metal having their contact surfaces cleaned, with a metallic foil or a metallic plating layer applied onto the contact surface of at least one of the backing steel and the cladding metal interposed as a medium layer between them, welding the superposed backing steel and cladding metal together along contact lines between their peripheral edges into a composite slab leaving at least one portion of the contact lines unwelded, exhausting any air remaining between the contact surfaces of the backing steel and the cladding metal by cold rolling or cold pressing under light reduction, welding the one or more unwelded portions on the peripheral edges together to isolate the contact surfaces from the external atmosphere, heating the composite slab to a rolling temperature, and hot-rolling it.

Description

SPECIFICATION Method for producing clad steel plate The present invention relates generally to a method for producing a clad steel plate and more particularly to a method for producing a clad steel plate of a high bonding strength in a high yield rate.
Clad steel plates have been heretofore used widely in various fields. Recently, however, there arose a strong demand particularly for such clad steel plates having a high bonding strength and a very high quality.
Among various methods for producing clad steel plates used heretofore, the most typical methods utilized in industrial scales are cold pressure cladding, hot pressure cladding, and explosion cladding. In any of these conventional methods, however, a poor bond between the backing steel and the cladding metal was frequently caused by oxidation of these materials in the contact surfaces, resulting in a decrease in the yield rate of the products.
In order to obtain a better bond between the backing steel and the cladding metal in the conventional hot pressure welding process, various means as described below were used: a. The backing steel and the cladding metal were welded together along the entire contact lines between their peripheral edges into a slab and any air remaining between the contact surfaces was exhausted through a vent hole provided in a portion of the contact lines using a vacuum pump; b. The backing steel and the cladding metal were superposed within a vacuum chamber and welded along the entire contact lines between their peripheral edges by an electron beam; and c. A space was intentionally provided between the backing steel and the cladding metal into which an inert gas such as argon was sealed, and then the inert gas was exhausted from the space through a vent hole during the hot rolling process.
In any of these means, however, it was difficult to exhaust the air from between the contact surfaces to some practically effective extent, and the backing steel and the cladding metal were oxidized in their contact surfaces during heating by a small quantity of the air still remaining between the contact surfaces, resulting in that scales which were formed therein prevented the formation of a satisfactory metallurgical bond therebetween and such insufficient metallurgical bond would appear as a defect in ultrasonic inspection. The poor bond used to readily appear particularly in the neighborhood of the securely welded contact lines between the peripheral edges of the slab and presents a serious problem in the yield rate of the ultrasonic inspection.
In an alternative means actually practised, for the purpose of preventing a decrease in a shear strength of clad interface, a metal such as nickel was plated onto the contact surface of either one of the backing steel and the cladding metal and the plated metal was diffused along the contact surfaces of both the backing steel and the cladding metal to form a strong bonding alloy layer. This alternative means, however, had disadvantages of the increase of production cost and inability of complete prevention of oxidation in the contact surfaces.
Accordingly, an object of the present invention is to provide a method for producing a clad steel plate of a high bonding strength in a high yield rate.
The method for producing a clad steel plate according to the present invention comprises the steps of cleaning a contact surface of each of a backing steel and a cladding metal, superposing the backing steel and the cladding metal with a medium layer interposed between the contact surfaces of the backing steel and the cladding metal, welding the backing steel and the cladding metal together along contact lines therebetween to form a composite slab leaving at least one portion of the contact lines unwelded as a vent hole for air, applying a light reduction to the composite slab to exhaust any air remaining between the contact surfaces through the vent hole, close the vent hole of the reduced composite slab by welding to isolate the contact surfaces from the external atmosphere, charging the welded composite slab into a heating furnace and heating it to a rolling temperature, and hot-rolling the heated composite slab.
The medium layer may be a metallic foil or a metallic plating layer. The metallic plating layer may be provided on one or both of the backing steel and the cladding metal. The metallic foil may be used in one or more kinds.
The insufficient bond which results in the decrease of the yield rate of products is caused mostly by oxidation in the contact surfaces. In the method according to the present invention, it is made possible to prevent the oxidation in the contact surfaces during the hot rolling and, accordingly, to sharply increase the bonding yield rate because the final welding is performed after the air is exhausted from between the contact surfaces to bring them into a tight contact with each other.
Further, in the method according to the present invention, the medium layer provided between the backing steel and the cladding metal is diffused in both of them during the hot rolling to thereby form a strong metallurigical bond therebetween and to prevent carbon migration occuring from the backing steel to the cladding metal.
In the case where the metallic foil is used as the medium layer, one or more kinds of the metallic foils are laid on the backing steel, on top of which the cladding metal is superposed. This requires no special equipment therefor and, accordingly, no initial cost. Since there is no limitation in the size of the welded composite slab the cost per unit weight of the slab is considerably low. It is quite easy to make the metallic foil thicker in contrast to the fact that it is difficult to make the plating layer thicker. Accordingly, by providing a metallic foil of a greater thickness it becomes easier to prevent the carbon migration occurring from the backing steel to the cladding metal, with which the embrittlement of the interface can be prevented and to roll the slab with a high workability in the hot rolling to thereby reduce sharply the cost per unit weight of the slab.Further, in view of the purchasing and handling costs of the metallic foil which are far lower than in the metallic plating layer, the use of the metallic foil in the method according to the present invention has made it possible to make the composite slab at the cost equivalent to several percent of the cost by the metallic plating process.
Heretofore, it has been commonly considered that a metallic foil interposed between the backing steel and the cladding metal would move freely between the contact surfaces of them during the hot rolling and would not roll uniformly with them. However, the inventors have experimentally discovered that the diffusion of the constituents of the metallic foil which had begun in both the backing steel and the cladding metal during the heating penetrates deeper into them with the progress of the hot rolling, whereby the backing steel and the cladding metal are rolled well in one body, resulting in the uniform rolling of the metallic foil.
Heretofore, further, it has also been commonly considered that the metallic foil was prevented from rolling to a sufficiently small thickness by the inclusions unexceptionally present in the foils. However, the inventors have experimentally discovered also that the metallic foil can be rolled into the sufficiently small thickness on the order of 4 Rm without breaking between the backing steel and the cladding metal.
In the producing method according to the present invention, the ultrasonic inspection yield rate of the hot-rolled clad steel plates is sharply increased from the order of 70 - 80% in the conventional producing method to the order of 95 - 100%.
In production of clad steel plates in the method similar to that of the present invention without using the medium layer, the ultrasonic inspection yield rate of the hot-rolled plates can be fairly increased in some cases. Without the medium layer, however, the backing steel and the cladding metal generally diffuses in each other across the interface to form an alloy layer there, which alloy layer is, in most cases, fragile and brittle. Such a fragile alloy layer formed along the interface will be easily broken in the succeeding bending and/or welding process to make the cladding metal separable from the backing steel and be detected as a defect in ultrasonic inspection, resulting in a decrease in the yield rate of the final products.
Generally, in widely used stainless steel clad steel produced without the medium layer, the diffusion produced a martensite layer along the interface, a cemented layer on the stainless steel side and a decarburized layer on the backing steel side. Any of these layers were fragile and easily cracked in the succeeding working processes, thus presenting a serious defect in ultransonic inspection.
In some special cases of such combination of metals that will not make a fragile alloy layer by diffusion between the backing steel and the cladding metal (for example, nickel clad steel), the medium layer is not always necessary. Further, a metal plate can well be used as the medium layer providing equivalent effects as the metallic foil and the metallic plating layer.
The invention will be better understood from the following description taken in connection with the accompanying drawings in which: Figure 7 is a block diagram illustrating steps of the method according to the present invention; Figures 2A and 2B are schematic illustrations of the welding step of the method according to the present invention; Figure 3 is a graph showing the results of measurement of a clad steel plates obtained by an example of practice of the method according to the present invention by an electron probe micro analyzer (E.P.M.A.); Figure 4 is a microstructure of a section of a steel plate of Figure 3; Figure 5 is a graph showing the results of E.P.M.A. measurement of a clad steel plate obtained by another example of practice of the method according to the present invention;; Figure 6 is a microstructure of a section of a steel plate of Figure 6; Figure 7 is a graph showing the results of E.P.M.A. measurement of a clad steel plate obtained by a further example of practice of the method according to the present invention; and Figure 8 is a microstructure of a section of a steel plate of Figure 7.
The method for producing a clad steel plate according to present invention will now be described in detail with reference to Figure 1. In the first step 1 of the method according to the present invention, the backing steel and the cladding metal are cleaned in their contact surfaces. In the succeeding second step 2, the backing steel and the cladding metal are superposed with a medium layer interposed between their contact surfaces. In the third step 3, the superposed backing steel and the cladding metal are welded together along the contact lines in their peripheral edges leaving at least a portion of the contact lines unwelded as vent holes, to form a composite slab. In the fourth step 4, the composite slab is subjected to a light reduction to exhaust any air remaining between the contact surfaces through the vent holes. In the fifth step 5, the vent holes of the slab after the light reduction are closed by welding. In the sixth step 6, the composite slab which has been welded along the entire contact lines is charged into a heating furnance and heated to a rolling temperature. Finally in the seventh step 7, the heated composite slab is hot-rolled into a clad steel plate.
In the first step 1, the cleaning of the contact surfaces of the backing steel and the cladding metal is performed by any conventional means such as machining and/or grinding. In the second step 2, the medium layer is formed either by plating a metal or by laying a metallic foil.
In the case of the metal plating, a layer of the metal plating is formed on one or both of the backing steel and the cladding metal each of which is cleaned in the contact surface. The metal to be plated is preferably nickel or pure iron.
In the case of the metallic foil laying, one or more kinds of metallic foils are laid on the cleaned contact surface of the backing steel or the cladding metal, and then the cladding metal or the backing steel is superposed on the metallic foils with its contact surface downward. The foil is preferably of such metals as titanium, aluminum, nickel, chromium, and pure iron in the thickness of 20 - 2001lem.
In the third step, the welding of the superposed backing steel and the cladding metal along the edge of their contact surfaces is performed by any conventional means such as arc welding. In this step, the one or more vent holes are formed by welding the backing steel and the cladding metal together along the contact lines between them leaving a portion unwelded at the center of the bottom edge of the slab (as shown in Figure 2A) or more portions unwelded one at the center of the bottom edge and a few in the lateral edges (as shown in Figure 2B). In Figures 2A and 2B, designated generally by the reference numeral 10 is the slab, in which the reference numeral 11 denotes weld beads, 12 denotes the vent holes, and 13 denotes the direction of advancement of the rolling or pressing.
In the fourth step 4, the light reduction of the slab is performed by either of a common rolling mill or press machine without heating the slab.
In the sixth step 6, the slab is charged into a common heating furnace, in which it is heated to an ordinary rolling temperature of the cladding metal (for example, in the case of stainless steel clad steel, to 1000 1250 C).
In the seventh step 7, the heated slab is rolled by a common hot rolling mill into the clad steel plate.
Specific examples of the practice of the method according to the present invention will now be described.
Example 1 (1) Backing Steel Name: Welding Structural Steel Plate (J1SG3106SM41) Chemical composition (wt %): C Si Mn Fe 0.20 0.30 0.80 Remainder Size (mm): length 1500 x width 1000 x thickness 77 (2) Cladding Metal Name: Cupro-Nickel Plate Chemcial composition (wt %): Cu Ni 90 10 Size (mm): length 1500 x width 1000 x thickness 17.5 (3) Medium Layer:Nickel Foil of thickness of 56 Rm (4) Producing Condition The backing steel and the cladding metal were finished in the contact surfaces by grinding, superposed with the nickel foil interposed between their opposed contact surfaces, welded together along the contact lines in the peripheral edges into a composite slab leaving a portion of 100 mm in length at the center of the bottom edge of the slab along the contact line unwelded as a vent hole, cold rolled under a light reduction into the original total thickness of the backing steel and the cladding metal, 94.5 mm, so as to exhaust any air remaining between the contact surfaces through the vent hole, supplementally welded to close the air vent into the slab of the thickness of 94.5 mm, and heated to the temperature of 1000 C and then hot-rolled into the clad steel plate of the overall thickness of 13.5 mm, in which the thickness of the backing steel, the cladding metal and the nickel foil were 2.5 mum, 11.0 mm and 8 Rm, respectively.
(5) Clad Steel Plate The ultrasonic inspection of the clad steel plate thus produced resulted in the yield rate as high as almost 100%. This shows that the air remaining between the contact surfaces was entirely exhausted by the cold rolling and, accordingly, the defect in bonding due to oxidation in the contact surfaces was pefectly prevented.
Then, the state of diffusion in the area of bonding between the backing steel and the cladding metal was inspected by an electron probe micro analyzer (E.P.M.A.). The results of the inspections are shown in Figure 3, and the microstructure of a section of the clad steel plate is shown in Figure 4.
As seen from Figures 3 and 4, the nickel of the foil interposed as the medium layer was diffused satisfactorily both in the backing steel and in the cladding metal to produce a strong metallurgical bond therebetween.
Fillet weld tests performed on this clad steel plate showed'that the metallurgical bond thus produced was so strong that it was not detached from the interface by a welding strain.
Example 2 The backing steel, the cladding metal and the metallic foil were same as in Example 1. A composite slab was formed in the same manner as in Example 1, and any air remaining between the contact surfaces was exhausted through the vent hole by cold pressing. Thereafter, the composite slab was formed into a clad steel plate in the same manner as in Example 1, in which the cladding metal, the backing steel and the metallic foil had the thickness of 2.5 mm, 11 mm and 8 calm, respectively. Ultrasonic inspections of the clad steel plate thus produced showed the yield rate of almost 100%, as in Example 1.
Example 3 (1) Backing Steel Name: Welding Structural Steel Plate (JIS SM 41) Chemical composition (wt %): C Si Mn Fe 0.20 0.30 0.80 Remainder Size (mm): length 1500 x width 1000 x thickness 56 (2) Cladding Metal Name: Stainless Steel Plate (SUS 316L) Chemical composition (wt%) C Si Mn Ni Cr Mo Fe 0.02 0.70 1.60 13 17 2.5 Remainder Size (mm): length 1500 x width 1000 x thickness 21 (3) Medium Layer: Nickel Foil of thickness of 56 ism (4) Producing Condition A composite slab was formed in the same condition as in Example 1. The slab was heated to 1200 C and then hot-rolled into a clad steel plate having the overall thickness of 11 mm, in which the thicknesses of the cladding metal, the backing steel and the metallic foil were 3 mm, 8 mm and 8 Fm, respectively.
The results of E.P.M.A. inspections and the micro-photograph of a section of the clad steel plate thus produced are shown in Figures 5 and 6, respectively. As seen from Figures 5 and 6, the nickel of the foil interposed as the medium layer was diffused satisfactorily both in the backing steel and in the cladding metal to produce a strong metallurgical bond therebetween. Fillet weld tests performed on this clad steel plate showed that the metallurgical bond thus produced was so strong that it was not detached from the interface by a welding strain. Further, it was confirmed that the severe cementation from the backing steel into the cladding metal was perfectly prevented in this area by the nickel foil interposed therebetween.
Example 4 (1) Backing Steel: Same as in Example 3.
(2) Cladding Metal Name: Cupro-Nickel Plate Chemical composition (wt%): CU Ni 90 10 Size (mm): length 1500 x width 1000 x thickness 21 (3) Medium layer: Nickel Plating of thickness of 28 item (4) Producing Condition After a nickel plating layer of the thickness of 28 #m was formed on the contact surface of the cladding metal, a composite slab was formed in the same condition as in Example 1. The slab was heated to 1000 C and then hot-rolled into a clad steel plate of the overall thickness of 11 mm, in which the thicknesses of the cladding metal, the backing steel and the nickel plating layer were 3 mum. 8 mm and 4 item, respectively.
Ultrasonic inspections of this clad steel plate resulted in the yield rate of almost 100%. This shows that a very small quantity of air remaining between the contact surfaces was completely exhausted through the vent hole by the cold rolling step and the insufficient bonding due to oxidation in the contact surfaces was perfectly prevented.
The results of E.P.M.A. inspections and the micro-photograph of a section of the clad steel plate thus produced are shown in Figures 7 and 8, respectively. As seen from Figures 7 and 8, the nickel component of the medium layer was diffused satisfactorily both in the backing steel and in the cladding metal to produce a strong metallurgical bond therebetween. Further, fillet weld tests performed on this clad steel plate showed that the metallurgical bond thus produced was so strong that it was not detached from the interface by a welding strain.
While we have described and illustrated certain preferred practices of the present invention, it is to be distinctly understood that the invention is not limited thereto but may be otherwise variously practiced within the scope of the appended claims.

Claims (8)

1. A method for producing a clad steel plate, comprising the steps of: cleaning a contact surface of each of a backing steel and a cladding metal; superposing the backing steel and the cladding metal with a medium layer interposed between the contact surfaces thereof; welding the backing steel and the cladding metal together along contact lines therebetween to form a composite slab, leaving at least a portion of the contact lines unwelded as a vent hole for air; applying a light reduction to the composite slab to exhaust any air remaining between the contact surfaces through the vent hole; closing by welding the vent hole of the light-reduced slab to isolate the contact surfaces therein from the external atmosphere; charging the welded composite slab into a heating furnace and heating it to a rolling temperature; and hot-rolling the heated composite slab.
2. A method for producing a clad steel plate as set forth in claim 1, characterized in that said medium layer is formed by at least a kind of metallic foil.
3. A method for producing a clad steel plate as set forth in claim 1, characterized in that said medium layer is formed by applying a metallic plating to at least one of the contact surfaces of the backing steel and the cladding metal.
4. A method for producing a clad steel plate as set forth in any one of claims 1 to 3, characterized in that said composite slab is applied with the light reduction by cold rolling.
5. A method for producing a clad steel plate as set forth in any of claims 1 to 3, characterized in that said composite slab is applied with the light reduction by cold pressing.
6. A method for producing a clad steel plate as set forth in any one of claims 1 to 5, characterized in that said vent hole is formed in the bottom edge of the slab.
7. A method for producing a clad steel plate substantially as hereinbefore specifically described with particular reference to the drawings.
8. A clad steel plate when produced by a method as claimed in any one of claims 1 to 7.
GB8100381A 1980-01-09 1981-01-07 Method for producing clad steel plate Expired GB2067437B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP115480A JPS5911394B2 (en) 1980-01-09 1980-01-09 Manufacturing method of clad steel plate with excellent bonding strength
JP115580A JPS5699089A (en) 1980-01-09 1980-01-09 Manufacture of clad steel plate

Publications (2)

Publication Number Publication Date
GB2067437A true GB2067437A (en) 1981-07-30
GB2067437B GB2067437B (en) 1983-05-18

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Family Applications (1)

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GB8100381A Expired GB2067437B (en) 1980-01-09 1981-01-07 Method for producing clad steel plate

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AU (1) AU540499B2 (en)
CA (1) CA1151818A (en)
DE (1) DE3100501C2 (en)
FR (1) FR2473379B1 (en)
GB (1) GB2067437B (en)
IT (1) IT1134960B (en)
SE (1) SE449061B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4228218A1 (en) * 1992-08-25 1994-03-10 Siemens Ag Planarisation process for semiconductor substrate layer - applying pressure across entire surface of layer to remove unevenness prior to structuring
CN1943967B (en) * 2005-10-09 2010-05-12 易思竞 Method for producing composite steel billet
CN101947571A (en) * 2010-09-06 2011-01-19 杨自芬 Manufacturing method of compound steel
CN102179405A (en) * 2011-01-27 2011-09-14 东北大学 Method for preventing interface of stainless steel compound plate subjected to vacuum composite rolling from being oxidized

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3212857A1 (en) * 1982-04-06 1983-10-06 Kraftwerk Union Ag Method of producing an austenitic cladding
DE19953079B4 (en) * 1999-11-04 2013-12-19 Alstom Technology Ltd. Method for welding components
DE102011108164B4 (en) * 2011-07-22 2017-09-21 Markus Balbach Process for producing stainless damascus steel and damascus steel produced by the process

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB616798A (en) * 1944-09-20 1949-01-27 Joseph Kinney Jr Improvements in or relating to composite multi-ply metal strip and method of making same
US2473686A (en) * 1946-02-12 1949-06-21 Superrior Steel Corp Composite billet and manufacture thereof
DE914094C (en) * 1948-10-02 1954-06-24 Rheinische Roehrenwerke Ag Process for the production of clad sheets
GB707996A (en) * 1950-08-09 1954-04-28 Joseph Kinney Jr Improvements in or relating to method of producing multiply metal
DE913611C (en) * 1951-12-30 1954-06-28 Rheinische Roehrenwerke Ag Process for the production of composite sheets
US4146164A (en) * 1977-11-09 1979-03-27 Aluminum Company Of America Production of aluminum brazing sheet
CA1125629A (en) * 1978-01-06 1982-06-15 John B. Ulam Multiple member clad metal products and methods of making the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4228218A1 (en) * 1992-08-25 1994-03-10 Siemens Ag Planarisation process for semiconductor substrate layer - applying pressure across entire surface of layer to remove unevenness prior to structuring
DE4228218C2 (en) * 1992-08-25 1998-12-10 Siemens Ag Method and device for planarizing a layer on a semiconductor substrate
CN1943967B (en) * 2005-10-09 2010-05-12 易思竞 Method for producing composite steel billet
CN101947571A (en) * 2010-09-06 2011-01-19 杨自芬 Manufacturing method of compound steel
CN101947571B (en) * 2010-09-06 2012-08-08 杨自芬 Manufacturing method of compound steel
CN102179405A (en) * 2011-01-27 2011-09-14 东北大学 Method for preventing interface of stainless steel compound plate subjected to vacuum composite rolling from being oxidized
CN102179405B (en) * 2011-01-27 2013-01-02 东北大学 Method for preventing interface of stainless steel compound plate subjected to vacuum composite rolling from being oxidized

Also Published As

Publication number Publication date
SE8100072L (en) 1981-07-10
CA1151818A (en) 1983-08-16
IT8119034A0 (en) 1981-01-07
DE3100501A1 (en) 1981-11-19
GB2067437B (en) 1983-05-18
SE449061B (en) 1987-04-06
DE3100501C2 (en) 1986-06-26
FR2473379B1 (en) 1985-08-30
IT1134960B (en) 1986-08-20
AU540499B2 (en) 1984-11-22
FR2473379A1 (en) 1981-07-17
AU6586180A (en) 1981-07-16

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 19960107