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GB1510854A - Oxidation catalyst and process for preparing unsaturated acids aldehydes and nitriles - Google Patents

Oxidation catalyst and process for preparing unsaturated acids aldehydes and nitriles

Info

Publication number
GB1510854A
GB1510854A GB3623275A GB3623275A GB1510854A GB 1510854 A GB1510854 A GB 1510854A GB 3623275 A GB3623275 A GB 3623275A GB 3623275 A GB3623275 A GB 3623275A GB 1510854 A GB1510854 A GB 1510854A
Authority
GB
United Kingdom
Prior art keywords
give
oxidation
nitriles
sept
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3623275A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/606,973 external-priority patent/US4034008A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1510854A publication Critical patent/GB1510854A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1510854 Oxidation and ammoxidation of olefins UNION CARBIDE CORP 3 Sept 1975 [3 Sept 1974 25 Aug 1975] 36232/75 Heading C2C [Also in Division B1] Alpha, beta-unsaturated mono-olefins are oxidized to the corresponding acids and aldehydes or ammoxidized to the corresponding nitriles using an oxidic catalyst formed by calcining a composition containing the elements Mo, Bi, Fe, Ni and/or Co, Si, Ru and/or Sb and, optionally, Cl in the atomic ratio Mo a Bi b Fe c T d Si e X f Cl g wherein: T=Ni and/or Co; X=Ru and/or Sb; a=10; b=0À1-5À0; c=d/ 3 -d/ 5À5 ; d=2À0-9À0; e=1-20; f=0À1- 10; g=0-5. The olefin feed may be propylene to give acrolein, acrylic acid or acrylonitrile; butene-2 to give crotanaldehyde, crotonic acid or crotononitrile or isobutylene to give methacrolein; methacrylic acid or methacrylonitrile. The reaction mixture may contain, per mole olefin, 0À5-3 moles oxygen, 0À5 to 20 moles steam and, if required, ammonia and inert diluents. Specified reaction conditions are 350-450‹ C., 1 to 10 atmospheres pressure, a contact time of 0À1-10 secs. and a space velocity of 1000-10,000 hr.<SP>-1</SP>. The examples describe the oxidation of propylene to acrolein and acrylic acid.
GB3623275A 1974-09-03 1975-09-03 Oxidation catalyst and process for preparing unsaturated acids aldehydes and nitriles Expired GB1510854A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US50255074A 1974-09-03 1974-09-03
US05/606,973 US4034008A (en) 1975-08-25 1975-08-25 Process for preparing unsaturated acids and aldehydes

Publications (1)

Publication Number Publication Date
GB1510854A true GB1510854A (en) 1978-05-17

Family

ID=27054198

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3623275A Expired GB1510854A (en) 1974-09-03 1975-09-03 Oxidation catalyst and process for preparing unsaturated acids aldehydes and nitriles

Country Status (7)

Country Link
JP (1) JPS5152114A (en)
CA (1) CA1046491A (en)
DE (1) DE2539060C3 (en)
FR (1) FR2329638A1 (en)
GB (1) GB1510854A (en)
IT (1) IT1044619B (en)
NL (1) NL182399C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2462537A (en) * 2008-08-15 2010-02-17 Pegler Ltd A thermostatic control head for a flow valve
CN110280256A (en) * 2019-07-10 2019-09-27 兰州科润化工技术有限公司 A kind of catalyst and preparation method thereof being used to prepare methacrylaldehyde

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2125032C3 (en) * 1970-05-26 1979-11-22 Nippon Catalytic Chem Ind Process for the production of (meth) acrolein in addition to small amounts of (meth) acrylic acid
DE2161471C3 (en) * 1970-12-26 1982-05-13 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka Process for the production of acrolein and acrylic acid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2462537A (en) * 2008-08-15 2010-02-17 Pegler Ltd A thermostatic control head for a flow valve
GB2462537B (en) * 2008-08-15 2013-01-09 Pegler Ltd Compact control head for a thermostatic valve
CN110280256A (en) * 2019-07-10 2019-09-27 兰州科润化工技术有限公司 A kind of catalyst and preparation method thereof being used to prepare methacrylaldehyde

Also Published As

Publication number Publication date
NL7510393A (en) 1976-03-05
CA1046491A (en) 1979-01-16
FR2329638B1 (en) 1980-01-11
JPS5152114A (en) 1976-05-08
IT1044619B (en) 1980-04-21
DE2539060B2 (en) 1981-04-16
NL182399C (en) 1988-03-01
DE2539060C3 (en) 1982-06-16
FR2329638A1 (en) 1977-05-27
NL182399B (en) 1987-10-01
DE2539060A1 (en) 1976-03-11

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19930903