GB1428552A - Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes - Google Patents
Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanesInfo
- Publication number
- GB1428552A GB1428552A GB688773A GB688773A GB1428552A GB 1428552 A GB1428552 A GB 1428552A GB 688773 A GB688773 A GB 688773A GB 688773 A GB688773 A GB 688773A GB 1428552 A GB1428552 A GB 1428552A
- Authority
- GB
- United Kingdom
- Prior art keywords
- platinum
- give
- atoms
- siloxane
- unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title abstract 8
- -1 siloxanes Chemical class 0.000 title abstract 6
- 229910052697 platinum Inorganic materials 0.000 title abstract 4
- 229920001296 polysiloxane Polymers 0.000 title abstract 2
- 150000003057 platinum Chemical class 0.000 title 1
- 125000004429 atom Chemical group 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- 239000003039 volatile agent Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0086—Platinum compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/398—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing boron or metal atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/045—Polysiloxanes containing less than 25 silicon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
1428552 Platinum-siloxane complexes GENERAL ELECTRIC CO 13 Feb 1973 [16 Feb 1972] 6887/73 Addition to 1211699 Headings C3S and C3T A platinum-siloxane complex contains 2-500 Si atoms and less than 0À1 atoms of halogen per atom of Pt and has the formula wherein R is free of aliphatic unsaturation and is a monovalent hydrocarbon or halohydrocarbon radical, R<SP>1</SP> is an aliphatically unsaturated monovalent hydrocarbon or halohydrocarbon radical, R<SP>11</SP> is a radical R<SP>1</SP> chemically combined with Pt to give IR bands at 7À5-7À6 and 8À34 microns in the spectrum of the complex, n is 0 to 2, p is 0 to 2, q is 0À0002 to 3, and n+p+q is 1 to 3. It may be obtained by reaction of a corresponding unsaturated siloxane or its hydrolysable silane precursor with a platinum halide (e.g. H 2 PtCl 6 ), followed by treatment with a base to reduce the halide content. It may be mixed with an unsaturated polysiloxane to give a composition containing at least 0À01 p.p.m. of platinum, curable by reaction with, e.g. hydrogen siloxanes. In examples the siloxanes Me 2 ViSiOSiViMe 2 and [MeViSiO] 4 are reacted with H 2 PtCl 6 .6H 2 O in ethanol under N 2 at 65‹ or 75‹ C. in the presence of NaHCO 3 ; the products are stripped of volatiles and extracted with xylene to give solutions containing 0À0027 and 0À0094 Cl atoms per Pt atom.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00226928A US3814730A (en) | 1970-08-06 | 1972-02-16 | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1428552A true GB1428552A (en) | 1976-03-17 |
Family
ID=22851029
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB688773A Expired GB1428552A (en) | 1972-02-16 | 1973-02-13 | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS55423B2 (en) |
DE (1) | DE2307085A1 (en) |
FR (1) | FR2172340B1 (en) |
GB (1) | GB1428552A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110201706A (en) * | 2019-06-18 | 2019-09-06 | 仲恺农业工程学院 | Pt/NH2-MCM-41 catalyst, preparation method and application thereof |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2724822A1 (en) * | 1977-06-02 | 1978-12-07 | Consortium Elektrochem Ind | PROCESS FOR ADDING SI-BONDED HYDROGEN TO ALIPHATIC MULTIPLE BONDING |
FR2575086B1 (en) * | 1984-12-20 | 1987-02-20 | Rhone Poulenc Spec Chim | PLATINUM-ALCENYLCYCLOHEXENE COMPLEX AS HYDROSILYLATION REACTION CATALYST AND PROCESS FOR PREPARING THE SAME |
JPH11128748A (en) * | 1997-10-31 | 1999-05-18 | Shin Etsu Chem Co Ltd | Platinum complex catalyst |
DE10250901A1 (en) * | 2002-10-31 | 2004-05-19 | Umicore Ag & Co.Kg | Process for the preparation of palladium (0) -containing compounds |
EP1520870B1 (en) * | 2003-10-04 | 2006-01-25 | Goldschmidt GmbH | Process for manufacturing organic silicon compounds |
JP4530147B2 (en) | 2004-08-25 | 2010-08-25 | 信越化学工業株式会社 | One-part organopolysiloxane gel composition |
DE102008039562A1 (en) | 2008-08-25 | 2010-03-04 | Langhals, Heinz, Prof. Dr. | New anthra(2,1,9-def;6,5,10-d'e'f')diisoquinoline-1,3,8,10-tetraone compounds useful e.g. as pigments for glue- or water- colors, lacquers and tracers in biochemistry, and in organic light emitting diode and photovoltaic devices |
DE102010011065A1 (en) | 2009-03-19 | 2010-10-21 | Langhals, Heinz, Prof. Dr. | New perylene dye compounds useful e.g. as pigment in e.g. novolacs, as mordant dye to color natural materials e.g. wood, as functional materials in compact disk, and for mass coloring of polymers e.g. polyvinylchloride |
CN103619861A (en) * | 2011-06-29 | 2014-03-05 | 道康宁公司 | Hydrosilylation reaction curable compositions and methods for their preparation and use |
DE102012014982A1 (en) | 2012-07-26 | 2014-02-13 | Ludwig-Maximilians-Universität München | Marking polymeric materials e.g. polyoxymethylene with fluorescence organic nanoparticles for their unique identification and for their sorting, for recycling purposes, by sorting machine, where nanoparticles are useful to encode materials |
WO2014138113A2 (en) | 2013-03-04 | 2014-09-12 | President And Fellows Of Harvard College | 1,2-hydrosilylation of dienes |
CN116437972A (en) * | 2020-12-07 | 2023-07-14 | 株式会社资生堂 | Oil-in-water emulsion compositions comprising platinum catalysts and methods of use thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2016946A6 (en) * | 1966-12-01 | 1970-05-15 | Gen Electric | Platinum-vinylsiloxane catalysts for - hydrosilation |
GB1211699A (en) * | 1966-12-01 | 1970-11-11 | Gen Electric | Organosilicon materials and process for their preparation |
DE1941411A1 (en) * | 1968-08-14 | 1970-12-23 | Gen Electric | Platinum-vinylsiloxane catalysts for - hydrosilation |
-
1973
- 1973-02-13 GB GB688773A patent/GB1428552A/en not_active Expired
- 1973-02-14 DE DE19732307085 patent/DE2307085A1/en not_active Ceased
- 1973-02-16 JP JP1843473A patent/JPS55423B2/ja not_active Expired
- 1973-02-16 FR FR7305536A patent/FR2172340B1/fr not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110201706A (en) * | 2019-06-18 | 2019-09-06 | 仲恺农业工程学院 | Pt/NH2-MCM-41 catalyst, preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
JPS4889960A (en) | 1973-11-24 |
JPS55423B2 (en) | 1980-01-08 |
DE2307085A1 (en) | 1973-08-23 |
FR2172340A1 (en) | 1973-09-28 |
FR2172340B1 (en) | 1976-11-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1443006A (en) | Acrylate-functional polysiloxanes | |
GB1428552A (en) | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes | |
FI110121B (en) | Pulp containing the second component of both components of two-component systems crosslinked at room temperature to organopolysiloxane elastomers | |
KR970707239A (en) | FUNCTIONALISED POLYORGANOSILOXANES AND ONE METHOD FOR PREPARING SAME | |
KR830007737A (en) | Process for preparing silane modified interpolymers of alkylene-alkyl acrylates | |
GB1200611A (en) | Novel organosilicon compounds and their production | |
GB1289217A (en) | ||
KR920006444A (en) | Thermosetting Silicone Rubber Composition | |
GB1373055A (en) | Organosiloxane gel | |
GB996744A (en) | Improvements in or relating to organosilicon compositions | |
GB1527144A (en) | Olefinic siloxanes as platinum inhibitors | |
GB1206598A (en) | Novel organosilicon compounds | |
GB1528204A (en) | Crosslinker platinum catalyst inhibitor and method of preparation thereof | |
GB1247503A (en) | Pressure sensitive adhesive | |
GB1473335A (en) | Organosilicon compounds | |
DE3666955D1 (en) | Process for preparing organopolysiloxanes containing acetoxy groups or halogen atoms which are linked directly to silicon | |
JPS6411160A (en) | Organopolysiloxane composition | |
KR880011233A (en) | Crosslinked Organosiloxane Polymer | |
GB1097453A (en) | Organosilicon compounds | |
ES2000088A6 (en) | Process for preparing polydiorganosiloxanes having alkoxy end groups. | |
GB1211699A (en) | Organosilicon materials and process for their preparation | |
AU562779B2 (en) | Rtv-silicone composition | |
KR920021626A (en) | (Meth) acryloxy group containing organosiloxane compound, its manufacturing method, and its use | |
GB1175266A (en) | Arylol Polysiloxanes | |
GB1083737A (en) | Improvements in substituted silanes |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |