GB1425669A - Electrolytic process for the preparation of dimethyl sebacate - Google Patents
Electrolytic process for the preparation of dimethyl sebacateInfo
- Publication number
- GB1425669A GB1425669A GB313374A GB313374A GB1425669A GB 1425669 A GB1425669 A GB 1425669A GB 313374 A GB313374 A GB 313374A GB 313374 A GB313374 A GB 313374A GB 1425669 A GB1425669 A GB 1425669A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dimethyl sebacate
- sebacate
- preparation
- jan
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
1425669 Electrolytic preparation of dimethyl sebacate; sebacic acid ASAHI KASEI KOGYO KK 23 Jan 1974 [31 Jan 1973 26 March 1973 3 Oct 1973 17 Dec 1973] 03133/74 Heading C2C [Also in Division C7] Electrolytic condensation of monomethyl adipate and a salt thereof to dimethyl sebacate is conducted in the presence of at least 5 wt. per cent dimethyl sebacate which is maintained throughout the reaction, with a liquid velocity in the cell of at least 2 m./sec. The sebacate salt may be with LiOH, KOH, NaOH, NaOCH 3 or NH 3 and the degree of neutralization may be up to 60% molar. The ester may be hydrolysed with 10-30% HNO 3 , H 2 SO 4 , or HCl at 90- 120 C. by adding less ester than corresponds with the saturation solubility of sebacic acid in the hydrolytic bath, while simultaneously removing the methanol formed.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1188373A JPS5323816B2 (en) | 1973-01-31 | 1973-01-31 | |
| JP48034863A JPS49117418A (en) | 1973-03-26 | 1973-03-26 | |
| JP11121873A JPS563434B2 (en) | 1973-10-03 | 1973-10-03 | |
| JP48141604A JPS5089317A (en) | 1973-12-17 | 1973-12-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1425669A true GB1425669A (en) | 1976-02-18 |
Family
ID=27455697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB313374A Expired GB1425669A (en) | 1973-01-31 | 1974-01-23 | Electrolytic process for the preparation of dimethyl sebacate |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3896011A (en) |
| CA (1) | CA1057232A (en) |
| CH (1) | CH598176A5 (en) |
| DE (1) | DE2404560C3 (en) |
| FR (1) | FR2216261B1 (en) |
| GB (1) | GB1425669A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113416969A (en) * | 2021-06-18 | 2021-09-21 | 万华化学集团股份有限公司 | Electrochemical synthesis method of dimethyl sebacate |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4124453A (en) * | 1975-09-29 | 1978-11-07 | National Research Development Corporation | Electrochemical processes |
| GB2001312B (en) * | 1977-07-20 | 1982-03-10 | Asahi Chemical Ind | Process for producing sebacic acid |
| US4237317A (en) * | 1977-07-20 | 1980-12-02 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing sebacic acid |
| EP0097719B1 (en) * | 1982-01-12 | 1987-06-03 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing higher dibasic acid dimethyl ester |
| US5290404A (en) * | 1990-10-31 | 1994-03-01 | Reilly Industries, Inc. | Electro-synthesis of alcohols and carboxylic acids from corresponding metal salts |
| US8647492B2 (en) | 2009-07-23 | 2014-02-11 | Ceramatec, Inc. | Method of producing coupled radical products from biomass |
| US9957622B2 (en) * | 2009-07-23 | 2018-05-01 | Field Upgrading Limited | Device and method of obtaining diols and other chemicals using decarboxylation |
| US9493882B2 (en) | 2010-07-21 | 2016-11-15 | Ceramatec, Inc. | Custom ionic liquid electrolytes for electrolytic decarboxylation |
| WO2012103135A2 (en) | 2011-01-25 | 2012-08-02 | Ceramatec, Inc. | Production of fuel from chemicals derived from biomass |
| CN107326051B (en) * | 2017-08-02 | 2021-06-08 | 上海凯赛生物技术股份有限公司 | Sebacic acid produced by microbial fermentation method and preparation method thereof |
| CN111850596B (en) * | 2020-07-13 | 2021-04-20 | 万华化学(四川)有限公司 | Continuous production method for electrochemically synthesizing sebacate compounds |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2439425A (en) * | 1946-04-01 | 1948-04-13 | Du Pont | Process for preparing dialkyl esters of dicarboxylic acids |
| US3589990A (en) * | 1968-02-29 | 1971-06-29 | Vnii Pi Monomerov | Process for the production of sebacic acid |
| DE2014985C3 (en) * | 1970-03-28 | 1978-06-08 | Basf Ag, 6700 Ludwigshafen | Process for the electrolytic condensation of carboxylic acids |
| DE2039991A1 (en) * | 1970-08-12 | 1972-02-17 | Basf Ag | Process for the preparation of sebacic acid diesters of higher alcohols |
-
1974
- 1974-01-23 GB GB313374A patent/GB1425669A/en not_active Expired
- 1974-01-24 US US436275A patent/US3896011A/en not_active Expired - Lifetime
- 1974-01-29 CA CA191,139A patent/CA1057232A/en not_active Expired
- 1974-01-30 FR FR7403064A patent/FR2216261B1/fr not_active Expired
- 1974-01-31 DE DE2404560A patent/DE2404560C3/en not_active Expired
- 1974-01-31 CH CH135574A patent/CH598176A5/xx not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113416969A (en) * | 2021-06-18 | 2021-09-21 | 万华化学集团股份有限公司 | Electrochemical synthesis method of dimethyl sebacate |
Also Published As
| Publication number | Publication date |
|---|---|
| US3896011A (en) | 1975-07-22 |
| DE2404560C3 (en) | 1982-04-29 |
| FR2216261B1 (en) | 1978-07-13 |
| FR2216261A1 (en) | 1974-08-30 |
| CA1057232A (en) | 1979-06-26 |
| DE2404560A1 (en) | 1974-08-01 |
| DE2404560B2 (en) | 1981-07-23 |
| CH598176A5 (en) | 1978-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19930123 |