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GB1476891A - Alkyl aryl compositions sulphonate - Google Patents

Alkyl aryl compositions sulphonate

Info

Publication number
GB1476891A
GB1476891A GB874075A GB874075A GB1476891A GB 1476891 A GB1476891 A GB 1476891A GB 874075 A GB874075 A GB 874075A GB 874075 A GB874075 A GB 874075A GB 1476891 A GB1476891 A GB 1476891A
Authority
GB
United Kingdom
Prior art keywords
acids
sulphonic acids
alkylaryl
salts
alkylbenzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB874075A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7408003A external-priority patent/FR2263026A1/en
Priority claimed from FR7424785A external-priority patent/FR2278387A2/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1476891A publication Critical patent/GB1476891A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/08Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
    • C10M135/10Sulfonic acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • C10N2070/02Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Lubricants (AREA)
  • Detergent Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1476891 Alkylaryl sulphonates EXXON RESEARCH & ENG CO 3 March 1975 [8 March 1974 17 July 1974] 8740/75 Heading C2C [Also in Division C5] An emulsifier composition comprises salts of alkylaryl sulphonic acids and an organic and an inorganic base, wherein the molecular weights of the acids from which the salts are desired are distributed according to the function C =f(M) where C denotes concentration and M denotes molecular weight of individual acids, which function has two distinct concentration maxima at molecular weights M 1 and M 2 with M 1 <M 2 wherein there are 5-95% of M 1 acids and 95- 5% M 2 acids, M 1 is 270 to 400 and (M 2 -M 1 ) is 80 to 350. The salts may be sodium salts of alkylbenzene sulphonic acids and/or alkylorthoxylene sulphonic acids, e.g. C 8 -C 10 alkylorthoxylene sulphonic acids and C 18 to C 28 alkylbenzene sulphonic acids. The alkylaryl moiety may be the akylation product of orthoxylene with tetrapropylene, and the alkylbenzene moiety may be the alkylation product of benzene and a propylene oligomer with an average of 24 C atoms per molecule. Preferred salts are sodium, ammonium, monoethanolamine, diethanolamine and triethanolamine. The sulphonates may be prepared by mixing M 1 and M 2 alkylaryl sulphonic acids or by neutralizing a mixture of M 1 and M 2 alkylaryl sulphonic acids with a base. Alternatively a mixture of alkyl aryl aromatic hydrocarbons may be sulphonated and neutralized. Alkylbenzenes used are alkylation products of benzene and its homologues with up to 10 C atoms, e.g. toluene, oxylene and ethylbenzene. The alkyl groups are preferably branched chain alkyl groups.
GB874075A 1974-03-08 1975-03-03 Alkyl aryl compositions sulphonate Expired GB1476891A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7408003A FR2263026A1 (en) 1974-03-08 1974-03-08 Emulsified salts of alkylaryl-sulphonic acids - derived from acids having different mol wt for use in emulsifying mineral oils
FR7424785A FR2278387A2 (en) 1974-07-17 1974-07-17 Emulsified salts of alkylaryl-sulphonic acids - derived from acids having different mol wt for use in emulsifying mineral oils

Publications (1)

Publication Number Publication Date
GB1476891A true GB1476891A (en) 1977-06-16

Family

ID=26218213

Family Applications (1)

Application Number Title Priority Date Filing Date
GB874075A Expired GB1476891A (en) 1974-03-08 1975-03-03 Alkyl aryl compositions sulphonate

Country Status (7)

Country Link
JP (1) JPS6012891B2 (en)
CA (1) CA1035236A (en)
DE (1) DE2510115C2 (en)
GB (1) GB1476891A (en)
IT (1) IT1029979B (en)
NL (1) NL182623C (en)
PL (1) PL99980B1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4956110A (en) * 1985-06-27 1990-09-11 Exxon Chemical Patents Inc. Aqueous fluid
EP0881276A2 (en) * 1997-05-30 1998-12-02 Tonen Corporation Lubricating oil composition containing a mixture of metal salts of aromatic organic acids

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4505830A (en) * 1981-09-21 1985-03-19 The Lubrizol Corporation Metal working using lubricants containing basic alkali metal salts
US20040248996A1 (en) * 2003-06-09 2004-12-09 Crompton Corporation Sodium petroleum sulfonate blends as emulsifiers for petroleum oils
US20070072778A1 (en) * 2003-11-12 2007-03-29 Sanjay Kalhan Emulsifier blend replacement for natural sodium sulfonates in metalworking applications
JP4695352B2 (en) * 2004-06-17 2011-06-08 Ntn株式会社 Torque limiter lubricating oil, lubricating grease and torque limiter
US7449596B2 (en) * 2005-12-21 2008-11-11 Chevron Oronite Company Llc Method of making a synthetic petroleum sulfonate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4956110A (en) * 1985-06-27 1990-09-11 Exxon Chemical Patents Inc. Aqueous fluid
EP0881276A2 (en) * 1997-05-30 1998-12-02 Tonen Corporation Lubricating oil composition containing a mixture of metal salts of aromatic organic acids
EP0881276A3 (en) * 1997-05-30 1999-09-08 Tonen Corporation Lubricating oil composition containing a mixture of metal salts of aromatic organic acids

Also Published As

Publication number Publication date
JPS6012891B2 (en) 1985-04-04
NL7502599A (en) 1975-09-10
CA1035236A (en) 1978-07-25
IT1029979B (en) 1979-03-20
DE2510115C2 (en) 1984-02-16
PL99980B1 (en) 1978-08-31
JPS50131881A (en) 1975-10-18
DE2510115A1 (en) 1975-09-18
NL182623C (en) 1988-04-18
NL182623B (en) 1987-11-16

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee
PCPE Delete 'patent ceased' from journal

Free format text: 5145, PAGE 2483

PE20 Patent expired after termination of 20 years

Effective date: 19950302