GB1364001A - Oxidation of ammonia - Google Patents
Oxidation of ammoniaInfo
- Publication number
- GB1364001A GB1364001A GB1622672A GB1622672A GB1364001A GB 1364001 A GB1364001 A GB 1364001A GB 1622672 A GB1622672 A GB 1622672A GB 1622672 A GB1622672 A GB 1622672A GB 1364001 A GB1364001 A GB 1364001A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nitrate
- cobalt
- oxide
- catalyst
- impregnated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title abstract 4
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 229910021529 ammonia Inorganic materials 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 abstract 4
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052797 bismuth Inorganic materials 0.000 abstract 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- UPWOEMHINGJHOB-UHFFFAOYSA-N cobalt(III) oxide Inorganic materials O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 abstract 2
- 239000008187 granular material Substances 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052596 spinel Inorganic materials 0.000 abstract 1
- 239000011029 spinel Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/24—Nitric oxide (NO)
- C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
- C01B21/265—Preparation by catalytic or non-catalytic oxidation of ammonia characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0063—Granulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/55—Cylinders or rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
1364001 Oxidation catalysts TRUST CESKOSLOVENSKEHO PRUMYSLU DUSIKARENSKEHO 7 April 1972 [7 April 1971] 16226/72 Heading B1E [Also in Division Cl] Catlyst for use in the preparation of nitric oxide by oxidation of ammonia comprises an oxide of iron, cobalt or nickel supported on porous support material which comprises a compound having the spinel structure and containing a spinel-forming metal, aluminium and oxygen. The spinel-forming metal may be magnesium, bismuth, manganese, iron, cobalt or nickel. The catalyst additionally may comprise a promoter, for example an oxide of magnesium, bismuth or manganese. The metal(s) other than aluminium present in the catalyst may constitute up to 70 weight per cent of the catalyst which may be in the form of granules, for example rods having a diameter of from 2 to 10 mm and a length of from 2 to 10 mm. As exemplified, catalyst is prepared either by a procedure wherein a mixture containing alumina and cobaltous-cobaltic oxide is shaped into rods, dried, sintered at 1700C, cooled, impregnated with cobalt (II) nitrate solution and heated at 300C to convert the cobalt nitrate to cobaltous-cobaltic oxide (Example 1) or by a procedure wherein cylindrical granules of alumina are impregnated with ferric nitrate solution, dried at 150C, heated at 300-400C to decompose the nitrate, sintered at 1400C, cooled, impregnated with a solution containing ferric nitrate and magnesium nitrate and heated a 300-400C to decompose the nitrates (Example 2).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS2486A CS177220B1 (en) | 1971-04-07 | 1971-04-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1364001A true GB1364001A (en) | 1974-08-21 |
Family
ID=5362132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1622672A Expired GB1364001A (en) | 1971-04-07 | 1972-04-07 | Oxidation of ammonia |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5135196B1 (en) |
| BE (1) | BE781836A (en) |
| CS (1) | CS177220B1 (en) |
| DE (1) | DE2216328C3 (en) |
| FR (1) | FR2132795B1 (en) |
| GB (1) | GB1364001A (en) |
| IT (1) | IT951243B (en) |
| NL (1) | NL7204671A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009028949A1 (en) * | 2007-08-24 | 2009-03-05 | Yara International Asa | Mixed metal oxide catalyst and production of nitric oxide by oxidation of ammonia |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2222308B1 (en) * | 1973-03-20 | 1975-10-31 | Rhone Progil | |
| JPS6055177B2 (en) * | 1981-02-18 | 1985-12-04 | 鐘淵化学工業株式会社 | catalyst diluent |
| JPS5861374A (en) * | 1982-09-03 | 1983-04-12 | Matsushita Electric Works Ltd | Automatic stop device of water |
| US5108979A (en) * | 1991-02-25 | 1992-04-28 | Intercat, Inc. | Synthetic spinels and processes for making them |
| DE19903616A1 (en) | 1999-01-29 | 2000-08-03 | Basf Ag | Process for the production of nitrogen oxides with a low degree of oxidation |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1377957A (en) * | 1963-12-27 | 1964-11-06 | Improvements in the catalytic treatment of hydrocarbons and new catalysts which can be used in particular for this treatment |
-
1971
- 1971-04-07 CS CS2486A patent/CS177220B1/cs unknown
-
1972
- 1972-04-05 DE DE2216328A patent/DE2216328C3/en not_active Expired
- 1972-04-07 FR FR7212380A patent/FR2132795B1/fr not_active Expired
- 1972-04-07 JP JP47034501A patent/JPS5135196B1/ja active Pending
- 1972-04-07 BE BE781836A patent/BE781836A/en not_active IP Right Cessation
- 1972-04-07 GB GB1622672A patent/GB1364001A/en not_active Expired
- 1972-04-07 NL NL7204671A patent/NL7204671A/xx not_active Application Discontinuation
- 1972-04-07 IT IT22902/72A patent/IT951243B/en active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009028949A1 (en) * | 2007-08-24 | 2009-03-05 | Yara International Asa | Mixed metal oxide catalyst and production of nitric oxide by oxidation of ammonia |
| AU2008293119B2 (en) * | 2007-08-24 | 2012-09-20 | Yara International Asa | Mixed metal oxide catalyst and production of nitric oxide by oxidation of ammonia |
| EA020086B1 (en) * | 2007-08-24 | 2014-08-29 | Яра Интернэшнл Аса | Method for production of gas comprising nitric oxide |
| US9725319B2 (en) | 2007-08-24 | 2017-08-08 | Yara International Asa | Mixed metal oxide catalyst and production of nitric oxide by oxidation of ammonia |
| US10618811B2 (en) | 2007-08-24 | 2020-04-14 | Yara International Asa | Mixed metal oxide catalyst and production of nitric oxide by oxidation of ammonia |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5135196B1 (en) | 1976-09-30 |
| BE781836A (en) | 1972-07-31 |
| IT951243B (en) | 1973-06-30 |
| CS177220B1 (en) | 1977-07-29 |
| DE2216328A1 (en) | 1972-10-12 |
| FR2132795A1 (en) | 1972-11-24 |
| DE2216328B2 (en) | 1977-04-14 |
| FR2132795B1 (en) | 1978-12-08 |
| NL7204671A (en) | 1972-10-10 |
| DE2216328C3 (en) | 1978-04-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |