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GB1349449A - Imperial chemical industries ltd steam reforming of hydrocarbons - Google Patents

Imperial chemical industries ltd steam reforming of hydrocarbons

Info

Publication number
GB1349449A
GB1349449A GB4104070A GB1349449DA GB1349449A GB 1349449 A GB1349449 A GB 1349449A GB 4104070 A GB4104070 A GB 4104070A GB 1349449D A GB1349449D A GB 1349449DA GB 1349449 A GB1349449 A GB 1349449A
Authority
GB
United Kingdom
Prior art keywords
bed
catalyst
hydrocarbons
steam
reforming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4104070A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of GB1349449A publication Critical patent/GB1349449A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

1349449 Making combustible gas IMPERIAL CHEMICAL INDUSTRIES Ltd 2 Aug 1971 [26 Aug 1970] 41040/70 Heading C5E In a continuous process for catalytically steam reforming hydrocarbons, e.g. methane, optionally in the presence of hydrogen, the catalyst bed contains less than 0À5% alkali (calculated as equivalent K 2 O), and the following conditions are observed: the temperature of the reactants entering the bed is in the range 250‹ to 650‹ C., the temperature of the reactants leaving the bed is 750‹ to 1000‹ C., the pressure is at least 200 p.s.i.g., and the space velocity (steam plus hydrocarbons) is at least 3 kg. per litre of catalyst per hour. The rate of reaction of hydrocarbon and steam is such that at the region of the bed which is at 700‹ C. the reaction mixture satisfies the condition that F exceeds 6, where and P= pressure in atmospheres absolute. The value of F is kept above 6 by ensuring adequate catalyst activity, e.g. by desulphurizing the feed to below 0À5 p.p.m. of sulphur by weight, or by supplying hydrogen to the inlet or to an intermediate part of the bed. The process mitigates overheating of catalyst-containing tubes in certain bands. Recycling of H 2 -containing gas before or after shift-conversion and CO 2 removal, to the reforming process and to a catalytic desulphurization stage preceding it, is described. Reforming catalysts may be supported nickel and may include a promoter comprising an oxide of an alkaline earth metal, or of U, or of Zr.
GB4104070A 1970-08-26 1970-08-26 Imperial chemical industries ltd steam reforming of hydrocarbons Expired GB1349449A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4104070 1970-08-26

Publications (1)

Publication Number Publication Date
GB1349449A true GB1349449A (en) 1974-04-03

Family

ID=10417837

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4104070A Expired GB1349449A (en) 1970-08-26 1970-08-26 Imperial chemical industries ltd steam reforming of hydrocarbons

Country Status (7)

Country Link
JP (1) JPS4825001A (en)
AU (1) AU3258171A (en)
BE (1) BE771538A (en)
DE (1) DE2140530A1 (en)
FR (1) FR2103522B1 (en)
GB (1) GB1349449A (en)
NL (1) NL7111793A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7378370B2 (en) 2004-07-09 2008-05-27 Süd-Chemie Inc Process for the preparation of promoted calcium-aluminate supported catalysts

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52148604A (en) * 1976-06-03 1977-12-10 Daiichi Lace Kk Production of suede like sheet material
JPS5311893A (en) * 1976-07-20 1978-02-02 Fujimi Kenmazai Kougiyou Kk Catalysts

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7378370B2 (en) 2004-07-09 2008-05-27 Süd-Chemie Inc Process for the preparation of promoted calcium-aluminate supported catalysts
US7767619B2 (en) 2004-07-09 2010-08-03 Sud-Chemie Inc. Promoted calcium-aluminate supported catalysts for synthesis gas generation

Also Published As

Publication number Publication date
FR2103522A1 (en) 1972-04-14
FR2103522B1 (en) 1974-05-10
AU3258171A (en) 1973-02-22
JPS4825001A (en) 1973-04-02
DE2140530A1 (en) 1972-03-16
BE771538A (en) 1972-02-21
NL7111793A (en) 1972-02-29

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees