GB1224518A - Preparation of carboxylic esters - Google Patents
Preparation of carboxylic estersInfo
- Publication number
- GB1224518A GB1224518A GB5331768A GB5331768A GB1224518A GB 1224518 A GB1224518 A GB 1224518A GB 5331768 A GB5331768 A GB 5331768A GB 5331768 A GB5331768 A GB 5331768A GB 1224518 A GB1224518 A GB 1224518A
- Authority
- GB
- United Kingdom
- Prior art keywords
- liquid
- ester
- reactor
- preparation
- nov
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,224,518. Carboxylic acid esters. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 10 Nov., 1969 [11 Nov., 1968], No. 53317/68. Heading C2C. Carboxylic esters are obtained by reacting an ether of formula R 1 -O-R 2 , wherein R 1 and R 2 represent the same or different organic radicals, with CO in the presence of H 2 O- containing liquid HF. The liquid HF preferably contains 0À1 to 5% H 2 O. Substantially pure CO or mixtures thereof with inert gases may be used. The process may be carried out batchwise or continuously. In the latter case the process comprises the steps of (a) introducing into a reactor liquid HF, the ether, CO and H 2 O; (b) separating an ester phase and a substantially ester-free phase from liquid reactor effluent; and (c) recycling at least part of the substantially ester-free phase formed in step (b) to the reactor in step (a). A schematic apparatus suitable for carrying out the process is described. An example is given for the preparation of methyl trimethylacetate.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5331768A GB1224518A (en) | 1968-11-11 | 1968-11-11 | Preparation of carboxylic esters |
| FR6938386A FR2023002A1 (en) | 1968-11-11 | 1969-11-07 | ESTER PREPARATION PROCESS |
| NL6916889A NL6916889A (en) | 1968-11-11 | 1969-11-10 | |
| BE741512D BE741512A (en) | 1968-11-11 | 1969-11-10 | |
| DE19691956466 DE1956466A1 (en) | 1968-11-11 | 1969-11-10 | Hydrocarbon refining |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5331768A GB1224518A (en) | 1968-11-11 | 1968-11-11 | Preparation of carboxylic esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1224518A true GB1224518A (en) | 1971-03-10 |
Family
ID=10467356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5331768A Expired GB1224518A (en) | 1968-11-11 | 1968-11-11 | Preparation of carboxylic esters |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1224518A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107628949A (en) * | 2016-07-19 | 2018-01-26 | 赢创德固赛有限公司 | Method for making ether alkoxycarbonylation |
| CN113912646A (en) * | 2021-11-18 | 2022-01-11 | 浙江新化化工股份有限公司 | Preparation method of bidentate phosphine ligand |
-
1968
- 1968-11-11 GB GB5331768A patent/GB1224518A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107628949A (en) * | 2016-07-19 | 2018-01-26 | 赢创德固赛有限公司 | Method for making ether alkoxycarbonylation |
| CN107628949B (en) * | 2016-07-19 | 2020-08-04 | 赢创运营有限公司 | Process for the alkoxycarbonylation of ethers |
| CN113912646A (en) * | 2021-11-18 | 2022-01-11 | 浙江新化化工股份有限公司 | Preparation method of bidentate phosphine ligand |
| CN113912646B (en) * | 2021-11-18 | 2024-05-17 | 浙江新化化工股份有限公司 | Preparation method of bidentate phosphine ligand |
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