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GB1213122A - Clays - Google Patents

Clays

Info

Publication number
GB1213122A
GB1213122A GB4068566A GB4068566A GB1213122A GB 1213122 A GB1213122 A GB 1213122A GB 4068566 A GB4068566 A GB 4068566A GB 4068566 A GB4068566 A GB 4068566A GB 1213122 A GB1213122 A GB 1213122A
Authority
GB
United Kingdom
Prior art keywords
ammonium
clay
octadecyl
ions
minerals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4068566A
Inventor
Barbara Susan Neumann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik LIL Ltd
Original Assignee
Laporte Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laporte Industries Ltd filed Critical Laporte Industries Ltd
Priority to GB4068566A priority Critical patent/GB1213122A/en
Priority to GB1228155D priority patent/GB1228155A/en
Priority to NO169699A priority patent/NO122012B/no
Priority to BE703698D priority patent/BE703698A/xx
Priority to DK453667A priority patent/DK135035B/en
Priority to AT835267A priority patent/AT283271B/en
Priority to SE1259267A priority patent/SE330156B/xx
Priority to DE1667502A priority patent/DE1667502B2/en
Priority to CH1271667A priority patent/CH483373A/en
Priority to FR1565348D priority patent/FR1565348A/fr
Priority to NL6712477A priority patent/NL156115B/en
Priority to SE498/70A priority patent/SE343280B/xx
Publication of GB1213122A publication Critical patent/GB1213122A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/44Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/40Clays
    • C01B33/405Clays not containing aluminium
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Civil Engineering (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Lubricants (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

1,213,122. Synthetic clay-like minerals. LAPORTE INDUSTRIES Ltd. 11 Dec., 1967 [12 Sept., 1966(3)], Nos. 40683/66, 40684/66 and 40685/66. Heading C1A. [Also in Divisions C3and.C5] A process for the production of a clay-like mineral having the empirical formula given below comprises precipitating a magnesium silicate from a solution containing the cations and anions required to be present in the clay, maintaining a pH of at least 8 throughout, and, without washing free from soluble salts, heating the precipitated product under pressure to bring about crystal growth. Synthetic clay-like minerals of the following empirical formula, having a cation exchange capacity of 50 to 120 m.e.g./100 g. and when M is Na+ or Li+ a Bingham Yield Value of from 40 to 250 dynes/ cm.<SP>2</SP> as a 2% w./v. dispersion in tap water, are claimed per se: where M is a sodium, lithium or an equivalent of an organic cation and the values of a, b and c such that either a<6; b > 0 ; c>0 and b + c < 2 ; Œ(o+b+c-6)<2; or a<6; b=0; Œc<2 and Œ(a+b - 6) < 2. Preferred values of a and b are b= 06to 1.05 or, when b=0a=4À5 to 5À9, preferably 5-0 to 5-8. The organic cations may be ammonium, phosphonium, stibonium, arsonium, oxonium or sulphonium ions but are preferably ammonium ions having at least 10 carbon atoms preferably at least 18 and preferred examples are, dimethyl dioctadecyl ammonium, trimethyl octadecyl ammonium, dodecyl ammonium, hexadecyl ammonium, dioctadecyl morpholinium, 1 - propyl - 2 - octadecyl imidazolinium and bis-(2-hydroxyethyl) octadecyl ammonium ions, these may be used singly or in combinations. The clays may be used in making lubricating greases or organosols, they may also be used to form refractory articles.
GB4068566A 1966-09-12 1966-09-12 Clays Expired GB1213122A (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
GB4068566A GB1213122A (en) 1966-09-12 1966-09-12 Clays
GB1228155D GB1228155A (en) 1966-09-12 1967-04-04
NO169699A NO122012B (en) 1966-09-12 1967-09-11
BE703698D BE703698A (en) 1966-09-12 1967-09-11
DK453667A DK135035B (en) 1966-09-12 1967-09-11 Synthetic magnesium silicate and process for its synthesis.
AT835267A AT283271B (en) 1966-09-12 1967-09-12 Process for the synthesis of a new, clay-like, aqueous magnesium silicate mineral
SE1259267A SE330156B (en) 1966-09-12 1967-09-12
DE1667502A DE1667502B2 (en) 1966-09-12 1967-09-12 Synthetic, swellable, clay-like material
CH1271667A CH483373A (en) 1966-09-12 1967-09-12 Synthesis process of a clay mineral
FR1565348D FR1565348A (en) 1966-09-12 1967-09-12
NL6712477A NL156115B (en) 1966-09-12 1967-09-12 PROCESS FOR PREPARING A SYNTHETIC CLAY.
SE498/70A SE343280B (en) 1966-09-12 1970-01-15

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB4068566A GB1213122A (en) 1966-09-12 1966-09-12 Clays
GB4068466 1966-09-12
GB4068366 1966-09-12
GB1534367 1967-04-04

Publications (1)

Publication Number Publication Date
GB1213122A true GB1213122A (en) 1970-11-18

Family

ID=27448305

Family Applications (2)

Application Number Title Priority Date Filing Date
GB4068566A Expired GB1213122A (en) 1966-09-12 1966-09-12 Clays
GB1228155D Expired GB1228155A (en) 1966-09-12 1967-04-04

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1228155D Expired GB1228155A (en) 1966-09-12 1967-04-04

Country Status (10)

Country Link
AT (1) AT283271B (en)
BE (1) BE703698A (en)
CH (1) CH483373A (en)
DE (1) DE1667502B2 (en)
DK (1) DK135035B (en)
FR (1) FR1565348A (en)
GB (2) GB1213122A (en)
NL (1) NL156115B (en)
NO (1) NO122012B (en)
SE (2) SE330156B (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049780A (en) * 1972-11-14 1977-09-20 Laporte Industries Limited Production of magnesium silicates
WO1994016996A1 (en) * 1993-01-26 1994-08-04 Laporte Industries Limited Synthetic clay minerals
US6274111B1 (en) 1997-07-01 2001-08-14 Clariant Gmbh Synthetic magnesium silicate
WO2004000729A1 (en) * 2002-06-21 2003-12-31 Rockwood Additives Limited Synthetic magnesium silicate compositions and process for the production thereof
EP1393924A2 (en) 2002-08-27 2004-03-03 Eastman Kodak Company Ink jet printing process
US6730719B2 (en) 1999-04-28 2004-05-04 Southern Clay Products, Inc. Process for treating smectite clays to facilitate exfoliation
WO2004056704A1 (en) * 2002-12-20 2004-07-08 Rockwood Additives Limited Process for the production of synthetic magnesium silicate compositions
GB2401103A (en) * 2003-04-29 2004-11-03 Rockwood Additives Ltd Synthetic magnesium silicate compositions, methods and uses
US6890502B2 (en) 2001-08-24 2005-05-10 Southern Clay Products, Inc. Synthetic clay compositions and methods for making and using
EP1702887A1 (en) * 2003-09-18 2006-09-20 Teijin Limited Phyllosilicate and thermoplastic resin composition containing the same

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1432770A (en) * 1972-11-14 1976-04-22 Laporte Industries Ltd Production of magnesium silicates
DE3207886A1 (en) * 1982-03-05 1983-09-15 Hoechst Ag, 6230 Frankfurt METHOD FOR PRODUCING A SYNTHETIC HECTORITE
DE3526405A1 (en) * 1985-07-24 1987-02-05 Henkel Kgaa LAYERED SILICATES WITH RESTRICTED SOURCE, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN DETERGENT AND CLEANING AGENTS
DE3631764A1 (en) 1986-09-18 1988-03-24 Henkel Kgaa USE OF SWELLABLE, SYNTHETIC LAYERED SILICATES IN AQUEOUS DRILL RING AND HOLE TREATMENT AGENTS
TW223043B (en) * 1991-11-30 1994-05-01 Laporte Industries Ltd
DE4224537A1 (en) * 1992-07-27 1994-02-03 Henkel Kgaa Mineral additives for adjusting and / or regulating the rheology and gel structure of aqueous liquid phases and their use
GB9500089D0 (en) * 1995-01-04 1995-03-01 Sofitech Nv Thixotropic materials

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049780A (en) * 1972-11-14 1977-09-20 Laporte Industries Limited Production of magnesium silicates
WO1994016996A1 (en) * 1993-01-26 1994-08-04 Laporte Industries Limited Synthetic clay minerals
US6274111B1 (en) 1997-07-01 2001-08-14 Clariant Gmbh Synthetic magnesium silicate
US6730719B2 (en) 1999-04-28 2004-05-04 Southern Clay Products, Inc. Process for treating smectite clays to facilitate exfoliation
US6890502B2 (en) 2001-08-24 2005-05-10 Southern Clay Products, Inc. Synthetic clay compositions and methods for making and using
WO2004000729A1 (en) * 2002-06-21 2003-12-31 Rockwood Additives Limited Synthetic magnesium silicate compositions and process for the production thereof
EP1393924A2 (en) 2002-08-27 2004-03-03 Eastman Kodak Company Ink jet printing process
WO2004056704A1 (en) * 2002-12-20 2004-07-08 Rockwood Additives Limited Process for the production of synthetic magnesium silicate compositions
GB2401103A (en) * 2003-04-29 2004-11-03 Rockwood Additives Ltd Synthetic magnesium silicate compositions, methods and uses
EP1702887A1 (en) * 2003-09-18 2006-09-20 Teijin Limited Phyllosilicate and thermoplastic resin composition containing the same
EP1702887A4 (en) * 2003-09-18 2009-03-11 Teijin Ltd Phyllosilicate and thermoplastic resin composition containing the same
US7759420B2 (en) 2003-09-18 2010-07-20 Teijin Limited Layered silicate and thermoplastic resin composition containing it

Also Published As

Publication number Publication date
NO122012B (en) 1971-05-10
AT283271B (en) 1970-07-27
SE343280B (en) 1972-03-06
GB1228155A (en) 1971-04-15
CH483373A (en) 1969-12-31
DE1667502B2 (en) 1978-10-26
DK135035B (en) 1977-02-28
SE330156B (en) 1970-11-09
NL156115B (en) 1978-03-15
DK135035C (en) 1977-09-12
FR1565348A (en) 1969-05-02
DE1667502A1 (en) 1971-06-16
NL6712477A (en) 1968-03-13
BE703698A (en) 1968-03-11

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee