GB1251177A - - Google Patents
Info
- Publication number
- GB1251177A GB1251177A GB1251177DA GB1251177A GB 1251177 A GB1251177 A GB 1251177A GB 1251177D A GB1251177D A GB 1251177DA GB 1251177 A GB1251177 A GB 1251177A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compound
- ticl
- aluminium
- aluminium compound
- june
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1,251,177. Polymerizing alkenes. STAMICARBON N.V. 3 June, 1970 [3 June, 1969; 14 Nov., 1969], No. 26844/70. Heading C3P. Alkene polymers are prepared by polymerizing one or more alkenes in a solvent at a temperature above 110‹ C. with the aid of a catalyst obtained by mixing a titanium halide, an aluminium compound of the general formula AlR 3-m X m where R is a C 1-30 hydrocarbon, X is halogen and m is 1-3, and an organomagnesium compound, the molar ratio of the magnesium compound to the aluminium compound being (m - A)/B where mis the number of halogen atoms per aluminium atom in the aluminium compound, A is - 0.75 to + 0.97 and B is 2.2 to 2.7, the molar ratio of the aluminium compound to the titanium compound being 8-2000. In the examples: polyethylene is prepared using TiCl 4 /(C 4 H q ) 2 Mg/Al(C 2 H 5 ) 2 Cl, Al[i-C 4 -H q ) 2 Cl, Al(C 2 H 5 ) 1 . 5 Cl 1 . 5 or AlCl 3 , TiCl 4 /- (phenyl) 2 Mg/Al(C 2 H 5 ) 2 Cl; or TiBr 4 /didodecyl Mg/Al(C 2 H 5 ) 1 . 5 Cl 1 . 5 ; and ethylene is copolymerized with propylene or butylene using TiCl 4 /- (C 4 H q ) 2 Mg/Al(C 2 H 5 ) 1.5 Cl 1.5
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6908446.A NL156148B (en) | 1969-06-03 | 1969-06-03 | Process for the preparation of olefin polymers. |
| NL6917130A NL157319B (en) | 1969-11-14 | 1969-11-14 | PROCESS FOR PREPARING ALKIN POLYMERS. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1251177A true GB1251177A (en) | 1971-10-27 |
Family
ID=26644433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1251177D Expired GB1251177A (en) | 1969-06-03 | 1970-06-03 |
Country Status (12)
| Country | Link |
|---|---|
| AT (1) | AT301869B (en) |
| BE (1) | BE751315A (en) |
| CA (1) | CA924450A (en) |
| CS (1) | CS174153B2 (en) |
| DE (1) | DE2027302C3 (en) |
| ES (1) | ES380314A1 (en) |
| FI (1) | FI51594C (en) |
| FR (1) | FR2054561B1 (en) |
| GB (1) | GB1251177A (en) |
| HU (1) | HU163327B (en) |
| PL (1) | PL71758B1 (en) |
| SE (1) | SE388619B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2517567A1 (en) * | 1974-04-22 | 1975-10-30 | Dow Chemical Co | TITANATE-CONTAINING POLYMERIZATION CATALYST |
| US4172050A (en) * | 1974-04-22 | 1979-10-23 | The Dow Chemical Company | High efficiency titanate catalyst for polymerizing olefins |
| US4194075A (en) * | 1976-05-14 | 1980-03-18 | Phillips Petroleum Company | Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide |
| US4250288A (en) | 1977-02-03 | 1981-02-10 | The Dow Chemical Company | High efficiency, high temperature catalyst for polymerizing olefins |
| US4311816A (en) * | 1977-04-27 | 1982-01-19 | E. I. Du Pont De Nemours And Company | Process for the preparation of polymers of α-olefins |
| US4314912A (en) | 1977-02-03 | 1982-02-09 | The Dow Chemical Company | High efficiency, high temperature catalyst for polymerizing olefins |
| US4383938A (en) | 1977-02-11 | 1983-05-17 | Exxon Research And Engineering Co. | Catalyst system for olefinic polymerization |
| US5320994A (en) * | 1988-06-23 | 1994-06-14 | Norsolor | Process for preparing a catalyst for the polymerization of olefins |
| WO2021233930A1 (en) | 2020-05-20 | 2021-11-25 | Lanxess Organometallics Gmbh | Novel organo-magnesium compounds and their use |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL164867C (en) | 1971-03-11 | 1981-02-16 | Stamicarbon | METHOD FOR POLYMERIZING ALFA OLEGINS. |
| NL171825C (en) * | 1973-01-22 | 1983-05-16 | Stamicarbon | PROCESS FOR PREPARING POLYMER FIBERS |
| DE2929325A1 (en) * | 1979-07-19 | 1981-02-05 | Wacker Chemie Gmbh | METHOD FOR POLYMERIZING AT LEAST ONE ALPHA -OLEFIN |
| EP0041828A3 (en) * | 1980-06-11 | 1981-12-23 | Imperial Chemical Industries Plc | Transition metal composition, production and use |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3118865A (en) * | 1960-02-03 | 1964-01-21 | Du Pont | Olefin polymerization catalyst |
| NL153221B (en) * | 1968-05-15 | 1977-05-16 | Stamicarbon | PROCESS FOR THE PREPARATION OF A SULFUR-VULCANIZABLE POLYMER OF ETHENE AND AT LEAST ANOTHER ALPHA ALKES. |
-
1970
- 1970-06-01 PL PL14102070A patent/PL71758B1/en unknown
- 1970-06-02 FI FI156470A patent/FI51594C/en active
- 1970-06-02 ES ES380314A patent/ES380314A1/en not_active Expired
- 1970-06-02 SE SE764770A patent/SE388619B/en unknown
- 1970-06-02 AT AT490470A patent/AT301869B/en not_active IP Right Cessation
- 1970-06-02 BE BE751315D patent/BE751315A/en not_active IP Right Cessation
- 1970-06-02 HU HUSA002100 patent/HU163327B/hu unknown
- 1970-06-03 CS CS389070A patent/CS174153B2/cs unknown
- 1970-06-03 GB GB1251177D patent/GB1251177A/en not_active Expired
- 1970-06-03 DE DE19702027302 patent/DE2027302C3/en not_active Expired
- 1970-06-03 FR FR7020341A patent/FR2054561B1/fr not_active Expired
- 1970-06-03 CA CA084528A patent/CA924450A/en not_active Expired
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2517567A1 (en) * | 1974-04-22 | 1975-10-30 | Dow Chemical Co | TITANATE-CONTAINING POLYMERIZATION CATALYST |
| US4163831A (en) * | 1974-04-22 | 1979-08-07 | The Dow Chemical Company | High efficiency titanate catalyst for polymerizing olefins |
| US4172050A (en) * | 1974-04-22 | 1979-10-23 | The Dow Chemical Company | High efficiency titanate catalyst for polymerizing olefins |
| US4194075A (en) * | 1976-05-14 | 1980-03-18 | Phillips Petroleum Company | Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide |
| US4250288A (en) | 1977-02-03 | 1981-02-10 | The Dow Chemical Company | High efficiency, high temperature catalyst for polymerizing olefins |
| US4314912A (en) | 1977-02-03 | 1982-02-09 | The Dow Chemical Company | High efficiency, high temperature catalyst for polymerizing olefins |
| US4383938A (en) | 1977-02-11 | 1983-05-17 | Exxon Research And Engineering Co. | Catalyst system for olefinic polymerization |
| US4311816A (en) * | 1977-04-27 | 1982-01-19 | E. I. Du Pont De Nemours And Company | Process for the preparation of polymers of α-olefins |
| US5320994A (en) * | 1988-06-23 | 1994-06-14 | Norsolor | Process for preparing a catalyst for the polymerization of olefins |
| WO2021233930A1 (en) | 2020-05-20 | 2021-11-25 | Lanxess Organometallics Gmbh | Novel organo-magnesium compounds and their use |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2027302B2 (en) | 1980-04-10 |
| DE2027302A1 (en) | 1970-12-10 |
| ES380314A1 (en) | 1973-04-16 |
| AT301869B (en) | 1972-09-25 |
| HU163327B (en) | 1973-07-28 |
| FI51594C (en) | 1977-02-10 |
| BE751315A (en) | 1970-12-02 |
| FI51594B (en) | 1976-11-01 |
| SE388619B (en) | 1976-10-11 |
| DE2027302C3 (en) | 1980-12-11 |
| FR2054561A1 (en) | 1971-04-23 |
| CA924450A (en) | 1973-04-10 |
| FR2054561B1 (en) | 1973-04-06 |
| PL71758B1 (en) | 1974-06-29 |
| CS174153B2 (en) | 1977-03-31 |
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| GB1251177A (en) | ||
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |