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GB1174845A - The Polymerisation of Vinyl-Aromatic Compounds, and the Resulting Polyvinyl-Aromatic Compounds - Google Patents

The Polymerisation of Vinyl-Aromatic Compounds, and the Resulting Polyvinyl-Aromatic Compounds

Info

Publication number
GB1174845A
GB1174845A GB3922367A GB3922367A GB1174845A GB 1174845 A GB1174845 A GB 1174845A GB 3922367 A GB3922367 A GB 3922367A GB 3922367 A GB3922367 A GB 3922367A GB 1174845 A GB1174845 A GB 1174845A
Authority
GB
United Kingdom
Prior art keywords
aromatic compounds
polymerization
vinyl
molecular weight
aromatic compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3922367A
Inventor
Robert Nobbs Haward
Alec Norman Roper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB3922367A priority Critical patent/GB1174845A/en
Publication of GB1174845A publication Critical patent/GB1174845A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,174,845. Polymerization of vinyl aromatic compounds. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 21 Aug., 1968 [25 Aug., 1967], No. 39223/67. Heading C3P. In the anionic polymerization of vinyl aromatic compounds, the monomer contains in solution at least 10% by weight of a non-volatile additive which is inert to the anionic catalyst such that a major proportion of the heat of polymerization is absorbed with the reaction mixture. The additive may consist of a preformed polymer of the vinyl aromatic compound, i.e. low molecular weight polystyrene, or a lubricant and/or a toughening agent for the resulting polyvinyl aromatic compound, and may be used in an amount which is sufficient to maintain the temperature of the reaction mixture during polymerization below that at which any substantial vaporization of monomeric vinyl-aromatic compound occurs. In the example, a solution of low molecular weight polystyrene in styrene is mixed with a toluene solution of n-butyl lithium to initiate the anionic polymerization of styrene. The polymer product had a molecular weight in the range 40,000 to 100,000.
GB3922367A 1967-08-25 1967-08-25 The Polymerisation of Vinyl-Aromatic Compounds, and the Resulting Polyvinyl-Aromatic Compounds Expired GB1174845A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3922367A GB1174845A (en) 1967-08-25 1967-08-25 The Polymerisation of Vinyl-Aromatic Compounds, and the Resulting Polyvinyl-Aromatic Compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3922367A GB1174845A (en) 1967-08-25 1967-08-25 The Polymerisation of Vinyl-Aromatic Compounds, and the Resulting Polyvinyl-Aromatic Compounds

Publications (1)

Publication Number Publication Date
GB1174845A true GB1174845A (en) 1969-12-17

Family

ID=10408368

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3922367A Expired GB1174845A (en) 1967-08-25 1967-08-25 The Polymerisation of Vinyl-Aromatic Compounds, and the Resulting Polyvinyl-Aromatic Compounds

Country Status (1)

Country Link
GB (1) GB1174845A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4666987A (en) * 1985-02-22 1987-05-19 The Dow Chemical Company In-mold polymerization of vinyl aromatic compound
US8420876B2 (en) 2007-06-07 2013-04-16 Albemarle Corporation Adducts, adducts and oligomers, or adducts, oligomers and low molecular weight polymers, and their preparation
US8476373B2 (en) 2008-12-02 2013-07-02 Albemarle Corporation Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
US8642821B2 (en) 2008-12-02 2014-02-04 Albemarle Corporation Bromination of telomer mixtures derived from toluene and styrene
US8648140B2 (en) 2008-12-02 2014-02-11 Albemarle Corporation Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom
US8753554B2 (en) 2009-05-01 2014-06-17 Albemarle Corporation Pelletized low molecular weight brominated aromatic polymer compositions
US8802787B2 (en) 2009-05-01 2014-08-12 Albemarle Corporation Bromination of low molecular weight aromatic polymer compositions
US8933159B2 (en) 2008-12-02 2015-01-13 Albemarle Corporation Brominated flame retardants and precursors therefor
US8993684B2 (en) 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4666987A (en) * 1985-02-22 1987-05-19 The Dow Chemical Company In-mold polymerization of vinyl aromatic compound
US8420876B2 (en) 2007-06-07 2013-04-16 Albemarle Corporation Adducts, adducts and oligomers, or adducts, oligomers and low molecular weight polymers, and their preparation
US8796388B2 (en) 2007-06-07 2014-08-05 Albemarle Corporation Low molecular weight brominated polymers and their use in thermoplastic formulations
US8822743B2 (en) 2007-06-07 2014-09-02 Albemarle Corporation Adducts, adducts and oligomers, or adducts, oligomers and low molecular weight polymers, and their preparation
US8993684B2 (en) 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
US9914830B2 (en) 2008-06-23 2018-03-13 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
US8476373B2 (en) 2008-12-02 2013-07-02 Albemarle Corporation Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
US8642821B2 (en) 2008-12-02 2014-02-04 Albemarle Corporation Bromination of telomer mixtures derived from toluene and styrene
US8648140B2 (en) 2008-12-02 2014-02-11 Albemarle Corporation Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom
US8933159B2 (en) 2008-12-02 2015-01-13 Albemarle Corporation Brominated flame retardants and precursors therefor
US8753554B2 (en) 2009-05-01 2014-06-17 Albemarle Corporation Pelletized low molecular weight brominated aromatic polymer compositions
US8802787B2 (en) 2009-05-01 2014-08-12 Albemarle Corporation Bromination of low molecular weight aromatic polymer compositions

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees