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GB1023783A - Process for the preparation of vinyl ethers containing epoxy groups - Google Patents

Process for the preparation of vinyl ethers containing epoxy groups

Info

Publication number
GB1023783A
GB1023783A GB3844262A GB3844262A GB1023783A GB 1023783 A GB1023783 A GB 1023783A GB 3844262 A GB3844262 A GB 3844262A GB 3844262 A GB3844262 A GB 3844262A GB 1023783 A GB1023783 A GB 1023783A
Authority
GB
United Kingdom
Prior art keywords
epoxy
ether
vinyl ether
alcohol
ethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3844262A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consortium fuer Elektrochemische Industrie GmbH
Original Assignee
Consortium fuer Elektrochemische Industrie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consortium fuer Elektrochemische Industrie GmbH filed Critical Consortium fuer Elektrochemische Industrie GmbH
Publication of GB1023783A publication Critical patent/GB1023783A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

Vinyl ethers containing epoxy groups are made by reacting a vinyl ether, preferably in excess, with an epoxy alcohol in the presence of a salt of divalent mercury and a carboxylic acid, which in aqueous solution gives a pH 4 to 7, and isolating the epoxy vinyl ether so obtained, e.g. by distillation. The epoxy alcohol may be mono- or di-hydric, aliphatic or cycloaliphatic and may carry halogen substituents. A polymerization inhibitor, e.g. b -naphthylamine, may be added to the reaction mixture. In the examples the epoxy alcohol of the formula <FORM:1023783/C2/1> is reacted with divinyl ether in the presence of mercuric acetate, the epoxy ether thereby produced yielding on hydrolysis the alcohol of the formula <FORM:1023783/C2/2> In further examples, 2:3-epoxy-2-ethyl-hexanol is reacted with stearyl-vinyl ether to give 2:3-epoxy - 2 - ethyl - hexylvinyl ether, 2 - methyl - 4:5 - epoxy - cyclohexylmethanol with ethylvinyl ether to give 2-methyl-4:5-epoxy-cyclohexyl-methyl-vinyl ether, 2:3-epoxypropanol-1 with ethyl vinyl ether to give the 2:3-epoxy-propylvinyl ether, 1-chloro-2-hydroxy-3-(3:4-epoxytricyclo - [5:2:1:02;6] - decane - 9 - yl) - propane is reacted with ethyl vinyl ether giving the vinyl ether, epoxystearyl alcohol is converted to the vinyl ether.
GB3844262A 1961-10-21 1962-10-10 Process for the preparation of vinyl ethers containing epoxy groups Expired GB1023783A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC0025333 1961-10-21

Publications (1)

Publication Number Publication Date
GB1023783A true GB1023783A (en) 1966-03-23

Family

ID=7017860

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3844262A Expired GB1023783A (en) 1961-10-21 1962-10-10 Process for the preparation of vinyl ethers containing epoxy groups

Country Status (3)

Country Link
CH (1) CH407076A (en)
GB (1) GB1023783A (en)
NL (1) NL283968A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4908227A (en) * 1987-10-16 1990-03-13 Gaf Chemicals Corporation Divinyl epoxy ethers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4908227A (en) * 1987-10-16 1990-03-13 Gaf Chemicals Corporation Divinyl epoxy ethers

Also Published As

Publication number Publication date
CH407076A (en) 1966-02-15
NL283968A (en)

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