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GB1016944A - Process for the preparation of an elastomeric polydiene composition - Google Patents

Process for the preparation of an elastomeric polydiene composition

Info

Publication number
GB1016944A
GB1016944A GB799664A GB799664A GB1016944A GB 1016944 A GB1016944 A GB 1016944A GB 799664 A GB799664 A GB 799664A GB 799664 A GB799664 A GB 799664A GB 1016944 A GB1016944 A GB 1016944A
Authority
GB
United Kingdom
Prior art keywords
molecular weight
polymerization
composition
polydiene
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB799664A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1016944A publication Critical patent/GB1016944A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

An elastomeric polydiene composition is produced by (1) forming a hydrocarbon solution comprising a polydiene elastomer and 5 to 25% by weight based on the polydiene, of diene monomer in the presence of 100 to 2500 p.p.m. based on the monomer of a lithium alkyl catalyst. Monomers specified are butadiene and isoprene. In the examples isoprene dissolved in mixed isoamylenes is first polymerized using a low concentration of butyl lithium as catalyst, the polymerization being terminated with methanol and reinitiated three times, to produce a high molecular weight polymer and then the polymerization is completed with the same catalyst present but in a much higher concentration to produce a low molecular weight component. The resultant composition is coagulated with steam and hot water and dried. Block polymers may be formed by polymerizing a vinyl compound, e.g. styrene, with either the high molecular weight polymer before the final polymerization or with the final composition.
GB799664A 1963-02-28 1964-02-26 Process for the preparation of an elastomeric polydiene composition Expired GB1016944A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US26185163A 1963-02-28 1963-02-28

Publications (1)

Publication Number Publication Date
GB1016944A true GB1016944A (en) 1966-01-12

Family

ID=22995153

Family Applications (1)

Application Number Title Priority Date Filing Date
GB799664A Expired GB1016944A (en) 1963-02-28 1964-02-26 Process for the preparation of an elastomeric polydiene composition

Country Status (4)

Country Link
BE (1) BE644353A (en)
DE (1) DE1520854A1 (en)
GB (1) GB1016944A (en)
NL (1) NL6401809A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12110358B2 (en) 2016-11-15 2024-10-08 Zeon Corporation Synthetic polyisoprene latex

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537936A (en) * 1981-04-30 1985-08-27 Sumitomo Chemical Company, Limited Diene rubber composition, method of preparing the same and tire employing said composition
US6579940B1 (en) 1999-10-28 2003-06-17 Edwards Lifesciences Corporation Thermoplastic elastomeric material as a replacement for natural rubber latex

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12110358B2 (en) 2016-11-15 2024-10-08 Zeon Corporation Synthetic polyisoprene latex

Also Published As

Publication number Publication date
NL6401809A (en) 1964-08-31
DE1520854A1 (en) 1969-04-17
BE644353A (en) 1964-08-26

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