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GB1077083A - Polymerizable compositions for bonding articles and other purposes - Google Patents

Polymerizable compositions for bonding articles and other purposes

Info

Publication number
GB1077083A
GB1077083A GB27141/64A GB2714164A GB1077083A GB 1077083 A GB1077083 A GB 1077083A GB 27141/64 A GB27141/64 A GB 27141/64A GB 2714164 A GB2714164 A GB 2714164A GB 1077083 A GB1077083 A GB 1077083A
Authority
GB
United Kingdom
Prior art keywords
compound
components
monomer
sulphur dioxide
articles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27141/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1077083A publication Critical patent/GB1077083A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/04—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving separate application of adhesive ingredients to the different surfaces to be joined
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

A non-aqueous polymerizable system comprises at least two separate components one of which contains an ethylenically unsaturated monomer and a first compound and another of which consists of or contains a second compound, the one of the first and second compounds not being sulphur dioxide when the other is an organic hydroperoxide, the first and second compounds constituting the two parts of a redox catalyst system which when mixed causes at least 50% of the monomer to polymerize within 10 minutes at 50 DEG C. or below. Suitable systems are t.-butyl hydroperoxide+ sulphuryl chloride, and ascaridole+sulphur dioxide. In addition at least one of the components may contain a polymer dispersed or dissolved therein such that polymerization may take place in the form of a film or by bonding particles together. The invention also provides a method of bonding articles which comprises forming and allowing to polymerize between the articles a film containing the components of a non-aqueous polymerizable system, one of which components contains a monomer and a first compound and another of which components consists of or contains a second compound, the first and second compounds constituting the two parts of a redox catalyst system which on mixing causes at least 50% of the monomer to polymerize within 10 minutes at a temperature of 50 DEG C. or below. The second compound may be gaseous, e.g. sulphur dioxide, and may diffuse between the articles to be bonded. In an example a resin containing epoxide groups was dissolved in a mixture of methylacrylate, methyl methacrylate and acrylic acid. t.-Butyl hydroperoxide was added and the composition was coated on steel panels. Sulphur dioxide gas was sprayed over the sufaces and the panels were joined. The monomers polymerized whereafter the epoxide groups reacted with each other and with the active hydrogens of the polymer.ALSO:Articles are coated by forming and allowing to polymerize on the surface a film containing two components, the first component, comprising an ethylenically unsaturated monomer and a first compound and the second component comprising or consisting of a second compound, the two compounds constituting the two parts of a redox catalyst system which causes at least 50% of the monomer to polymerise within 10 minutes at 50 DEG C. or less. In an example copper wire is passed through a composition comprising a copolymer of ethyl acrylate and methyl methacrylate dissolved in methylacrylate and ethylene glycol diacrylate containing ascanidole; and then into an atmosphere containing sulphur dioxide.
GB27141/64A 1962-07-30 1964-07-01 Polymerizable compositions for bonding articles and other purposes Expired GB1077083A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US21313962A 1962-07-30 1962-07-30
US29215563A 1963-07-01 1963-07-01
US37349064A 1964-06-08 1964-06-08

Publications (1)

Publication Number Publication Date
GB1077083A true GB1077083A (en) 1967-07-26

Family

ID=27395828

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27141/64A Expired GB1077083A (en) 1962-07-30 1964-07-01 Polymerizable compositions for bonding articles and other purposes

Country Status (2)

Country Link
DE (1) DE1546910A1 (en)
GB (1) GB1077083A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4106971A (en) * 1975-02-21 1978-08-15 E. I. Du Pont De Nemours And Company Method of adhesive bonding
DE2720534A1 (en) * 1977-05-06 1978-11-09 Polychemie Gmbh ADDITIVES TO ELASTIC SEALING COMPOUNDS AND ADHESIVE MATERIALS
US4182644A (en) * 1975-03-27 1980-01-08 E. I. Du Pont De Nemours And Company Polymer in monomer adhesive composition and method employing same
US4287106A (en) 1978-08-16 1981-09-01 Ciba-Geigy Corporation Adhesive or adhesive component containing chlorosulfonated amide or imide
WO2018104053A1 (en) * 2016-12-05 2018-06-14 Tesa Se Reactive 2-component adhesive system in film form having improved heat-and-humidity resistance

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4106971A (en) * 1975-02-21 1978-08-15 E. I. Du Pont De Nemours And Company Method of adhesive bonding
US4112013A (en) * 1975-02-21 1978-09-05 E. I. Du Pont De Nemours And Company Adhesive composition
US4182644A (en) * 1975-03-27 1980-01-08 E. I. Du Pont De Nemours And Company Polymer in monomer adhesive composition and method employing same
DE2720534A1 (en) * 1977-05-06 1978-11-09 Polychemie Gmbh ADDITIVES TO ELASTIC SEALING COMPOUNDS AND ADHESIVE MATERIALS
US4287106A (en) 1978-08-16 1981-09-01 Ciba-Geigy Corporation Adhesive or adhesive component containing chlorosulfonated amide or imide
WO2018104053A1 (en) * 2016-12-05 2018-06-14 Tesa Se Reactive 2-component adhesive system in film form having improved heat-and-humidity resistance
CN110050048A (en) * 2016-12-05 2019-07-23 德莎欧洲股份公司 The reactive two component adhesive system of heat-resisting moist form membrane with improvement
CN110050048B (en) * 2016-12-05 2022-01-11 德莎欧洲股份公司 Reactive two-component adhesive system in the form of a film with improved resistance to heat and moisture
US11898067B2 (en) 2016-12-05 2024-02-13 Tesa Se Reactive 2-component adhesive system in film form having improved heat-and-humidity resistance

Also Published As

Publication number Publication date
DE1546910A1 (en) 1969-12-18

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