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FR3089824B1 - Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences. - Google Patents

Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences. Download PDF

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Publication number
FR3089824B1
FR3089824B1 FR1873239A FR1873239A FR3089824B1 FR 3089824 B1 FR3089824 B1 FR 3089824B1 FR 1873239 A FR1873239 A FR 1873239A FR 1873239 A FR1873239 A FR 1873239A FR 3089824 B1 FR3089824 B1 FR 3089824B1
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Prior art keywords
catalyst
metal
group vib
rejuvenation
regenerated
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FR1873239A
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English (en)
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FR3089824A1 (fr
Inventor
Elodie Devers
Etienne Girard
Philibert Leflaive
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1873239A priority Critical patent/FR3089824B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to BR112021008662-5A priority patent/BR112021008662A2/pt
Priority to KR1020217017928A priority patent/KR20210102257A/ko
Priority to PCT/EP2019/084437 priority patent/WO2020126676A1/fr
Priority to CN201980084676.4A priority patent/CN113438971A/zh
Priority to US17/414,725 priority patent/US11992826B2/en
Priority to EP19813603.8A priority patent/EP3897978A1/fr
Publication of FR3089824A1 publication Critical patent/FR3089824A1/fr
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Publication of FR3089824B1 publication Critical patent/FR3089824B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B01J38/62—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/88—Molybdenum
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B01J27/0515—Molybdenum with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/285—Regeneration or reactivation of catalysts comprising compounds of phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J38/00—Regeneration or reactivation of catalysts, in general
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    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/52—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/706—Catalytic metal recovery

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

L’invention concerne un procédé de réjuvénation d’un catalyseur au moins partiellement usé issu d’un procédé d'hydrodésulfuration d'une coupe essence oléfinique contenant du soufre, ledit catalyseur au moins partiellement usé étant issu d’un catalyseur frais un métal du groupe VIIl, un métal du groupe VIB, un support d’oxyde, ledit procédé comprenant les étapes suivantes :a) on régénère le catalyseur au moins partiellement usé dans un flux de gaz contenant de l'oxygène à une température comprise entre 350°C et 550°C,b) on met en contact le catalyseur régénéré avec une solution d’imprégnation contenant un composé comportant un métal du groupe VIB, le rapport molaire du métal du groupe VIB ajouté par métal du groupe VIB déjà présent dans le catalyseur régénéré étant compris entre 0,15 et 2,5 mol/mol,c) on effectue une étape de séchage à une température inférieure à 200°C, et l’utilisation du catalyseur réjuvéné dans un tel procédé d'hydrodésulfuration.
FR1873239A 2018-12-18 2018-12-18 Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences. Active FR3089824B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1873239A FR3089824B1 (fr) 2018-12-18 2018-12-18 Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences.
KR1020217017928A KR20210102257A (ko) 2018-12-18 2019-12-10 가솔린들의 수소화탈황 방법으로부터 소비되고 재생된 촉매의 회복 방법
PCT/EP2019/084437 WO2020126676A1 (fr) 2018-12-18 2019-12-10 Procede de rejuvenation d'un catalyseur use et regenere d'un procede d'hydrodesulfuration d'essences
CN201980084676.4A CN113438971A (zh) 2018-12-18 2019-12-10 使来自汽油加氢脱硫方法的失效并再生的催化剂恢复活性的方法
BR112021008662-5A BR112021008662A2 (pt) 2018-12-18 2019-12-10 processo de rejuvenescimento de um catalisador usado e regenerado de um processo de hidrodessulfuração de gasolinas
US17/414,725 US11992826B2 (en) 2018-12-18 2019-12-10 Method for regenerating a catalyst which is spent and regenerated by a hydrodesulfurization process of gasolines
EP19813603.8A EP3897978A1 (fr) 2018-12-18 2019-12-10 Procede de rejuvenation d'un catalyseur use et regenere d'un procede d'hydrodesulfuration d'essences

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1873239A FR3089824B1 (fr) 2018-12-18 2018-12-18 Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences.

Publications (2)

Publication Number Publication Date
FR3089824A1 FR3089824A1 (fr) 2020-06-19
FR3089824B1 true FR3089824B1 (fr) 2021-05-07

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FR1873239A Active FR3089824B1 (fr) 2018-12-18 2018-12-18 Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences.

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US (1) US11992826B2 (fr)
EP (1) EP3897978A1 (fr)
KR (1) KR20210102257A (fr)
CN (1) CN113438971A (fr)
BR (1) BR112021008662A2 (fr)
FR (1) FR3089824B1 (fr)
WO (1) WO2020126676A1 (fr)

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CN112337501A (zh) * 2020-10-28 2021-02-09 中海油天津化工研究设计院有限公司 一种硫化型再生加氢催化剂的制备方法
FR3116740A1 (fr) * 2020-11-27 2022-06-03 IFP Energies Nouvelles Procédé de préparation d’un catalyseur d’hydrodésulfuration d’une coupe essence comprenant un métal du groupe VIB, un métal du groupe VIII et du carbone graphitique
FR3117380B1 (fr) * 2020-12-15 2023-03-03 Ifp Energies Now Procédé de réjuvénation d’un catalyseur d’un procédé d'hydrotraitement et/ou d’hydrocraquage
CN116060053B (zh) * 2021-10-29 2024-10-11 中国石油化工股份有限公司 待再生催化剂的再生方法以及待再生催化剂的活性恢复方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU513580B2 (en) 1976-03-04 1980-12-11 Amoco Corporation The selective desulfurization of cracked naphthas
US4762814A (en) * 1986-11-14 1988-08-09 Phillips Petroleum Company Hydrotreating catalyst and process for its preparation
US4774220A (en) 1987-03-02 1988-09-27 Texaco, Inc. Lithium-doped gamma-alumina supported cobalt-molybdenum catalyst
CA2106900A1 (fr) * 1991-05-20 1995-03-25 David Edward Sherwood, Jr. Methode de regeneration de catalyseurs d'hydrotraitement uses a support d'alumine
US5985136A (en) 1998-06-18 1999-11-16 Exxon Research And Engineering Co. Two stage hydrodesulfurization process
FR2797639B1 (fr) 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
FR2811328B1 (fr) 2000-07-06 2002-08-23 Inst Francais Du Petrole Procede comprenant deux etapes d'hydrodesulfuration d'essence et une elimination intermediaire de l'h2s forme au cours de la premiere etape
ES2926658T3 (es) 2003-10-03 2022-10-27 Albemarle Netherlands Bv Procedimiento para activar un catalizador de hidrotratamiento
EP1737571B1 (fr) 2004-01-20 2016-06-22 Shell Internationale Research Maatschappij B.V. Procede de restauration de l'activite catalytique d'un catalyseur d'hydrotraitement use
EP1994123B1 (fr) * 2006-01-17 2018-10-31 ExxonMobil Research and Engineering Company Catalyseurs sélectifs à support de silice pour l'hydrodésulfuration de naphta
CA2636918C (fr) 2006-01-17 2015-10-06 Exxonmobil Research And Engineering Company Catalyseurs selectifs a support d'alumine haute temperature pour l'hydrodesulfuration de naphta
FR2904242B1 (fr) 2006-07-28 2012-09-28 Inst Francais Du Petrole Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des elements des groupes viii et vib
US7906447B2 (en) 2008-04-11 2011-03-15 Exxonmobil Research And Engineering Company Regeneration and rejuvenation of supported hydroprocessing catalysts
US8128811B2 (en) * 2008-04-11 2012-03-06 Exxonmobil Research And Engineering Company Hydroprocessing using rejuvenated supported hydroprocessing catalysts
JP4610664B1 (ja) 2009-07-09 2011-01-12 Ｊｘ日鉱日石エネルギー株式会社 再生水素化処理用触媒の製造方法及び石油製品の製造方法
CN102463127B (zh) 2010-11-04 2014-05-21 中国石油化工股份有限公司 一种催化剂再生活化方法
US10071370B2 (en) * 2012-07-19 2018-09-11 Chiyoda Corporation Method for reactivating used hydrogenation treatment titania catalyst, and regenerated hydrogenation treatment titania catalyst
US20160045910A1 (en) * 2013-03-28 2016-02-18 Shell Oil Company Process for rejuvenation of a used hydrotreating catalyst
JP5892989B2 (ja) * 2013-10-07 2016-03-23 日揮触媒化成株式会社 水素化脱硫触媒の再生方法
LU92430B1 (en) * 2014-04-16 2015-10-19 Catalyst Recovery Europ Sa Process for rejuvenating hydrotreating catalyst
CN105642312B (zh) 2014-12-04 2018-01-16 中国石油化工股份有限公司 一种失活加氢脱硫催化剂的再生方法
FR3035600B1 (fr) 2015-04-30 2017-04-21 Ifp Energies Now Catalyseur a base d'acide y-cetovalerique et son utilisation dans un procede d'hydrotraitement et/ou d'hydrocraquage
FR3035601B1 (fr) * 2015-04-30 2017-04-21 Ifp Energies Now Catalyseur a base de y-valerolactone et/ou de ses produits d’hydrolyse et son utilisation dans un procede d’hydrotraitement et/ou d’hydrocraquage
EP3315195A1 (fr) * 2016-10-28 2018-05-02 Repsol, S.A. Procédés d'activation d'un catalyseur d'hydrotraitement
SG11201909645UA (en) * 2017-05-05 2019-11-28 Exxonmobil Res & Eng Co Methods for regenerating and rejuvenating catalysts

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