FR2910296A1 - Make-up removal or cleaning of make-up films on keratinous substances, involves application of a composition comprising silicone compound and second compound capable of reacting together via hydrosilylation reaction in presence of catalyst - Google Patents

Abstract

Make-up removal and/or cleaning of make-up films formed by the application to keratinous substances of one silicone compound, second compound and catalyst, involves application of a makeup-removing and/or cleaning composition to the make-up films. The silicone compound is capable of reacting together with the second compound via a hydrosilylation reaction in the presence of a catalyst, when they are brought into contact with one another. The composition comprises in a medium, comprises a volatile silicone fatty phase comprising oil, and the oil comprises volatile linear silicone oil. Method for the make-up removal and/or the cleaning of make-up films formed by the application to keratinous substances of at least two compounds of formula X (a1), and Y1 (b1) (where at least one of the compounds X and Y1 being a silicone compound and the compounds X and Y1 being capable of reacting together via a hydrosilylation reaction in the presence of a catalyst, when they are brought into contact with one another), and at least one catalyst (c1), it being possible for the applications (a1), (b1) and (c1) to be simultaneous or sequential according to any order, with the proviso that it is favorable to the interaction of the compounds X and Y1, the method comprises at least one stage of application, to the make-up films, of a makeup-removing and/or cleaning composition comprising, in a medium, a volatile silicone fatty phase comprising at least one volatile linear silicone oil, the make-up-removing and/or cleaning composition comprising oil (at least 50 wt.%), and oil comprising volatile linear silicone oil (at least 40 wt.%). An independent claim is included for kit for making up and/or caring for keratinous substances comprising at least two different compositions packaged separately, comprising at least one compound X, at least one compound Y1, and at least one catalyst and a make-up-removing and/or cleaning composition.

Description

The subject of the present invention is a method of removing make-up and / or

  cleaning keratin materials coated with a particular polymeric film. This makeup film is formed by the application on said keratin materials of at least two compounds X and Y, able to react together, at least one of the compounds being silicone. This type of make-up makes it possible in particular to obtain a film having good non-transfer properties, good holding properties over time, in particular with water and friction, and forming a comfortable deposit on the skin, the lips, eyelashes or nails.

  Thus, this new form of formulation makes it possible to improve the performance of make-up, care or treatment products for keratin materials. In contrast, formed films are more difficult to eliminate than conventional products. However, the cleaning of the skin is crucial for the care of the face. Thus, it must be effective to remove fatty residues such as excess sebum, residues of cosmetics used daily and makeup products that accumulate in the skin folds and can clog the pores of the skin and lead appearance of buttons. Conventionally, makeup removal compositions are in the form of lotions, possibly biphasic, milks, creams, oils or gels.

  Document FR 2 861 987 discloses a makeup-removing cosmetic composition comprising a silicone-containing volatile fatty phase comprising at least one linear volatile silicone oil, the silicone-containing volatile fatty phase having an evaporation profile such that the volatile silicone oil mass evaporated at 30 minutes is from 2 mg / cm 2 to 9 mg / cm 2, said composition being free of stearic acid.

  The cleansing power of some of these compositions is in particular tested on a particular mascara product. Moreover, the type of makeup mentioned above formed from the two compounds X and Y, which is detailed below, is partly described in the documents WO 01/96450 and GB 2 407 496 which give no indication. as for removing make-up, nor does it disclose any cleansing and / or cleaning composition suitable for the removal of these particular makeup films. Accordingly, there is still a need to provide compositions for removing such particular makeup films. The inventors have discovered that it is possible to obtain a satisfactory makeup removal and / or cleaning of these particular makeup films by using a composition comprising, in a physiologically acceptable medium, a silicone volatile fatty phase comprising at least one volatile silicone oil. linear. The subject of the present invention is therefore, according to a first aspect, a method of removing make-up and / or cleaning of make-up films formed by the application to keratin materials (a) of one or more compounds X, (b) d one or more compounds Y, with at least one of the compounds X and Y being silicone and said compounds X and Y being capable of reacting together by a hydrosilylation reaction or by a condensation reaction or by a crosslinking reaction in the presence of a peroxide, when they are brought into contact with each other, and (c) where appropriate of at least one catalyst or a peroxide, the applications (a), (b) and (c) may be simultaneous or sequenced in an indifferent order provided that it is conducive to the interaction of said compounds X and Y, the method comprising at least one step of applying to said makeup films, a makeup removal composition and / or cleaning including, in a mili a physiologically acceptable silicone volatile phase comprising at least one linear volatile silicone oil, said make-up removing and / or cleaning composition comprising at least 50% by weight of oil relative to the total weight of said composition and said oil comprising at least 40% by weight of volatile silicone oil linear relative to the total weight of said composition. For the formation of the makeup films, the compound (s) X, the compound (s) Y may be applied to the keratin materials from several compositions, the compositions respectively containing the compound (s) X, the compound (s) Y, and where appropriate at least one catalyst or peroxide, alone or as a mixture, or from a single composition containing the compound (s) X and the compound (s) Y. According to a particular embodiment of formation of the makeup films, a first composition comprising at least one X compound (s) and a second composition containing at least Y compound (s) is applied to the keratin materials. In this case, the makeup films are formed by application to keratin materials, especially human skin: at least one layer of a first composition containing in a physiologically acceptable medium at least one compound X; At least one layer of a second composition containing in a physiologically acceptable medium at least one compound Y, at least one of compounds X and Y being a silicone compound, said compounds X and Y being capable of reacting together by a hydrosilylation, condensation or crosslinking reaction in the presence of a peroxide, when they are brought into contact with each other. More particularly, the formation of the makeup films may consist in applying to said keratinous materials at least one composition comprising, in a physiologically acceptable medium, at least one compound X and at least one compound Y. According to a variant, the formation of the makeup may consist in applying at least one layer of the second composition comprising the compound Y to the keratin materials, and then depositing on the layer or layers of said second composition at least one layer of the first composition comprising the compound X. It is also possible to alternately apply to the keratin materials several layers of each of the first and second compositions for the formation of the makeup films, the removal of makeup and / or cleaning is the subject of the present invention. The applied composition for forming the makeup film may also be obtained by extemporaneously mixing a first composition containing at least one of the compound X and a second composition containing at least the compound Y. In the context of the present invention, the makeup film or the first or second composition may comprise a catalyst. The applied composition may contain at least one of X and Y compounds in an encapsulated form. The subject of the present invention is also, according to a second aspect, a kit for makeup and / or care of keratin materials comprising at least two different compositions packaged separately, the kit comprising: at least one compound X, at least a compound Y, and optionally at least one catalyst or a peroxide, at least one of the compounds X and Y being silicone, with the proviso that the compounds X, Y and the catalyst or peroxide when present are not present simultaneously in the same composition, said compounds X and Y being capable of reacting together by a hydrosilylation reaction, condensation or crosslinking in the presence of a peroxide, when they are brought into contact with each other, and a make-up removing and / or cleaning composition comprising, in a physiologically acceptable medium, a silicone volatile fatty phase comprising at least one linear volatile silicone oil e, said makeup removal and / or cleaning composition comprising at least 50% by weight of oil relative to the total weight of said composition and said oil comprising at least 40% by weight of linear volatile silicone oil relative to the weight total of the composition. According to a particular embodiment of the invention, at least one of the compounds X and at least one of the compounds Y are contained in separate compositions. Thus, according to a third aspect, the invention relates to a kit comprising at least: a first composition comprising, in a physiologically acceptable medium, at least one compound X, a second composition comprising, in a physiologically acceptable medium, at least a compound Y, - a makeup removal and / or cleaning composition comprising, in a physiologically acceptable medium, a silicone volatile fatty phase comprising at least one linear volatile silicone oil, said cleansing and / or cleaning composition comprising at least 50 % by weight of oil relative to the total weight of said composition and said oil comprising at least 40% by weight of linear volatile silicone oil relative to the total weight of the composition. The first and second compositions are different from each other. For example, the first composition is advantageously devoid of compound Y and the second composition is advantageously devoid of compound X. Indeed, in view of their high reactivity for each other, compounds X and Y are not present simultaneously in a first and / or second composition included in a kit according to the invention when their interaction is not conditioned by the presence of a catalyst or a peroxide. By contrast, at the time of application or just before, the compounds X and Y are mixed and present in the same composition, resulting from the mixing of the first and second compositions included in the kit according to the invention. Preferably, the compositions of the kit and in particular the first composition comprising the compound X and the second composition comprising the compound Y of the kit are packaged in separate packages. For example, at least the first and second composition can be packaged separately in the same packaging article, for example in a bi-compartmentalized pen, the base composition being delivered by one end of the pen and the composition of the top being delivered by the other end of the pen, each end 20 being closed including sealingly by a cap. At least the first and second compositions may also be packaged in one compartment within the same packaging article, the mixture of the two compositions being effected at the end or ends of the packaging article upon delivery of each first and second composition. Alternatively, each of the first and second compositions may be packaged in a different packaging article. According to another variant, the compound X and the compound Y are included in a single composition, it being understood that at least one of the compounds X and Y is encapsulated. Thus, according to a fourth aspect, the present invention relates to a kit for makeup and / or care of keratin materials comprising at least: a composition comprising, in a physiologically acceptable medium, at least one compound X and at least one compound Y, the at least of the compounds X and Y being silicone, said compounds X and Y being capable of reacting together by hydrosilylation reaction, condensation or crosslinking in the presence of a peroxide, when they are put in contact with each other, at least one of the compounds X and Y being in an encapsulated form, 5 - a make-up removing and / or cleaning composition comprising, in a physiologically acceptable medium, a volatile silicone silicone phase comprising at least one linear volatile silicone oil. According to an alternative embodiment, the two compounds X and Y are present in separate encapsulated forms. According to this embodiment, the two compounds X and Y may be packaged in the same composition while avoiding the risk of premature reaction between them. This reaction occurs only when the composition is manipulated beforehand or when it is applied to the keratin material. The encapsulated form (s) break upon drying and compounds X and Y react to form the expected film. According to yet another variant of this aspect of the invention, the make-up removing and / or cleaning composition comprises at least 50% by weight of oil relative to the total weight of said composition and said oil comprising at least 40% by weight. volatile silicone oil linear relative to the total weight of the composition. The makeup kits according to the invention thus have the advantage of providing a makeup with good properties of non-transfer, of holding over time and a comfortable deposit on the skin, the lips, the eyelashes or the nails, while providing the appropriate means for effectively removing said makeup without attacking the masked areas. The first and second compositions are different from each other. Thus, the first composition is devoid of compound Y and the second composition is devoid of compound X. Indeed, in view of their high reactivity for each other, compounds X and Y are not simultaneously present in a first and / or second composition 30 forming a product according to the invention. Physiologically acceptable medium means a medium compatible with keratin materials, that is to say the skin, the mucous membranes (including the interior of the eyelids and lips), the nails and / or the keratinous fibers. (hair and eyelashes). It is particularly a nontoxic environment and appearance, smell and pleasant touch. By keratin materials is meant the skin, the scalp, the hair, the eyelashes, the eyebrows, the nails and the mucous membranes. COMPOUNDS X and Y Silicone compound means a compound comprising at least two organosiloxane units. According to one particular embodiment, the compounds X and the compounds Y are silicone. Compounds X and Y may be amino or non-amino. According to another embodiment, at least one of the compounds X and Y is a polymer whose main chain is formed mainly of organosiloxane units. Among the silicone compounds mentioned below, some may have both film-forming and adhesive properties, for example according to their proportion of silicone or according to whether they are used in admixture with a particular additive. It is therefore possible to modulate the film-forming properties or the adhesive properties of such compounds according to the intended use, it is in particular the case for the so-called "room temperature vulcanization" reactive elastomeric silicones. Compounds X and Y may react together at a temperature ranging from room temperature to 180 ° C. Advantageously, compounds X and Y may react together at ambient temperature (20 ° C.) and atmospheric pressure, or advantageously in the presence of a catalyst, by a hydrosilylation reaction or a condensation reaction, or a crosslinking reaction in the presence of a peroxide. Polar groups According to a particular embodiment, at least one of the compounds X and Y carries at least one polar group capable of forming at least one hydrogen bond with the keratin materials. By polar group is meant a group comprising carbon and hydrogen atoms in its chemical structure and at least one heteroatom (such as O, N, S and P), such that said group is capable of establishing at less a hydrogen bond with the keratin materials. Compounds bearing at least one group capable of establishing a hydrogen bond are particularly advantageous since they provide the compositions containing them with better adhesion to the keratin materials. The at least one polar group (s) carried by at least one of the compounds X and Y is / are capable of establishing a hydrogen bond, and comprises (s) either a hydrogen atom linked to an electronegative atom, an electronegative atom such as oxygen, nitrogen or sulfur. When the group has a hydrogen atom bonded to an electronegative atom, the hydrogen atom may interact with another electronegative atom carried, for example by another molecule, such as keratin, to form a hydrogen bond. When the group comprises an electronegative atom, the electronegative atom may interact with a hydrogen atom bonded to an electronegative atom carried, for example by another molecule, such as keratin, to form a hydrogen bond. Advantageously, these polar groups may be chosen from the following groups: carboxylic acids -COOH, alcohols, such as: -CH 2 OH or -CH (R) OH, R being an alkyl radical comprising from 1 to 6 carbon atoms, amino of formula -NR1R2, in which the RI and R2, which are identical or different, represent an alkyl radical comprising from 1 to 6 carbon atoms, or one of R1 or R2 denotes a hydrogen atom, and the other of R1 and R2 represents an alkyl radical comprising from 1 to 6 carbon atoms, 25-pyridino, -amido of formula -NH-COR 'or -CO-NH-R' in which R 'represents a hydrogen atom or an alkyl radical comprising from 1 to 6 carbon atoms, - pyrrolidino preferably chosen from groups of formula: ## STR1 ## R 1 being an alkyl radical comprising from 1 to 6 carbon atoms, - carbamoyl of formula -O-CO-NH-R ' or -NH-CO-OR ', R' being as defined above, - thiocarbamoyl such as -O-CS-NH-R 'or -NH-CS-OR', R ' as defined above, ureyl such that -NR'-CO-N (R ') 2, the groups R' identical or different being as defined above, 10-sulfonamido such as -NR'-S (= O) 2-R ', R' as defined above. Preferably, these polar groups are present at a content of less than or equal to 10% by weight relative to the weight of each compound X or Y, preferably less than or equal to 5% by weight, for example in a content ranging from 1 to 3% by weight. The polar group (s) may be located in the main chain of compound X and / or Y or may be pendant to the main chain or located at the ends of the main chain of compound X and / or Y 1-Compounds X and Y Which Can Be Reacted by Hydrosilylation According to one embodiment, the compounds X and Y are capable of reacting by hydrosilylation, this reaction can be simplified schematically as follows: SiùH + CH 2 CH W SiùCH 2 -CH 2 With W representing a carbon and / or silicone chain containing one or more unsaturated aliphatic groups. In this case, the compound X may be chosen from silicone compounds comprising at least two unsaturated aliphatic groups. By way of example, the compound X may comprise a silicone main chain whose unsaturated aliphatic groups are pendant to the main chain (side group) or located at the ends of the main chain of the compound (terminal group). In the remainder of the description, these particular compounds will be called polyorganosiloxanes with unsaturated aliphatic groups. According to one embodiment, the compound X and / or the compound Y carries at least one polar group, as described above, capable of forming at least one hydrogen bond with the keratin materials. This polar group is advantageously carried by the compound X which comprises at least two unsaturated aliphatic groups. According to one embodiment, the compound X is chosen from polyorganosiloxanes comprising at least two unsaturated aliphatic groups, for example two or three vinyl or allylic groups, each bonded to a silicon atom. According to an advantageous embodiment, the compound X is chosen from polyorganosiloxanes comprising siloxane units of formula: RmR 'Si (3, in which: R represents a monovalent hydrocarbon group, linear or cyclic, comprising from 1 to 30 atoms carbon, preferably from 1 to 20, and better still from 1 to 10 carbon atoms, such as for example a short-chain alkyl radical comprising, for example, from 1 to 10 carbon atoms, in particular a methyl radical or a grouping phenyl, preferably a methyl radical, m is equal to 1 or 2 and R 'represents: an unsaturated aliphatic hydrocarbon group comprising from 2 to 10, preferably from 2 to 5 carbon atoms, for example a vinyl group; or a group -R "- (I) CH = CHR" 'in which R "is a divalent aliphatic hydrocarbon chain, comprising from 1 to 8 carbon atoms, bonded to the silicon atom and R' is an atom of hydrogen or a radical alkyl having 1 to 4 carbon atoms, preferably a hydrogen atom; mention may be made, as group R ', of the vinyl and allyl groups and their mixtures; or o an unsaturated cyclic hydrocarbon group comprising from 5 to 8 carbon atoms, for example a cyclohexenyl group. Preferably R 'is an unsaturated aliphatic hydrocarbon group, preferably a vinyl group. According to one particular embodiment, the polyorganosiloxane also comprises units of formula: ## STR2 ## in which R is a group as defined above, and n is equal to 1, 2 or 3. According to one variant, the compound X may be a silicone resin comprising at least two ethylenic unsaturations, said resin being capable of reacting with the compound Y by hydrosilylation. Mention may be made, for example, of resins of MQ or MT type bearing itself unsaturated reactive ends -CH = CH2. These resins are crosslinked organosiloxane polymers. The nomenclature of the silicone resins is known under the name of "MDTQ", the resin being described according to the different siloxane monomeric units that it comprises, each of the letters "MDTQ" characterizing a type of unit. The letter M represents the monofunctional unit of formula (CH 3) 3 SiO 11 2, the silicon atom being connected to a single oxygen atom in the polymer comprising this unit. The letter D means a difunctional unit (CH 3) 2 SiO 2 12 in which the silicon atom is connected to two oxygen atoms. The letter T represents a trifunctional unit of formula (CH 3) SiO 3 12. In the units M, D and T defined above, at least one of the methyl groups may be substituted by a group R other than the methyl group such as a hydrocarbon radical (in particular alkyl) having from 2 to 10 carbon atoms or a phenyl group Or else a hydroxyl group. Finally, the letter Q means a tetrafunctional unit SiO412 in which the silicon atom is bonded to four hydrogen atoms themselves linked to the rest of the polymer. Examples of such resins that may be mentioned are MT silicone resins such as poly (phenyl-vinylsilsesquioxane), such as those sold under the reference SST-3PV1 by Gelest. Preferably, the compounds X comprise from 0.01 to 1% by weight of unsaturated aliphatic groups. Advantageously, the compound X is chosen from polyorganopolysiloxanes, in particular those comprising the siloxane (I) and optionally (II) units described above. The compound Y preferably comprises at least two free Si-H groups (hydrogenosilane groups). The compound Y may advantageously be chosen from polyorganosiloxanes comprising at least one alkylhydrogenosiloxane unit of the following formula: FIS G, P (III) in which: R represents a monovalent hydrocarbon group, linear or cyclic, comprising from 1 to 30 carbon atoms, as for example an alkyl radical having from 1 to 30 carbon atoms, preferably from 1 to 20 and better still from 1 to 10 carbon atoms, in particular a methyl radical, or else a phenyl group and p is equal to 1 or 2. Preferably R is a hydrocarbon group, preferably methyl. These polyorganosiloxane compounds Y with alkylhydrogenosiloxane units may further comprise units of formula: ## STR00004 ## 2910296 (II) as defined above. The compound Y may be a silicone resin comprising at least one unit selected from the units M, D, T, Q as defined above and comprising at least one Si-H group such as poly (methyl-hydridosilsesquioxane) sold under the reference SST-3MH1.1 by Gelest. Preferably, these polyorganosiloxane compounds Y comprise from 0.5 to 2.5% by weight of Si-H groups. Advantageously, the radicals R represent a methyl group in the formulas (I), (II), (III) above. Preferably, these polyorganosiloxanes Y comprise terminal groups of formula (CH 3) 3 SiOl 2. Advantageously, the polyorganosiloxanes Y comprise at least two alkylhydrogenosiloxane units of formula (H3C) (H) SiO and optionally comprise (H3C) 2SiO units. Such polyorganosiloxane compounds Y with hydrogenosilane groups are described, for example, in document EP 0465744. According to one variant, the compound X is chosen from oligomers or organic polymers (by organic means compounds whose main chain is non-silicone, preferably compounds which do not comprise silicon atoms) or among the hybrid organic / silicone polymers or oligomers, said oligomers or polymers bearing at least 2 reactive unsaturated aliphatic groups, the compound Y being chosen from the polyorganosiloxanes Y with hydrogenosilane groups mentioned above. According to one embodiment, the organic compounds X or hybrid organic / silicone bearing at least 2 reactive unsaturated aliphatic groups, carry at least one polar group as described above. Compound X, of organic nature, may then be chosen from vinyl, (meth) acrylic polymers or oligomers, polyesters, polyurethanes and / or polyureas, polyethers, perfluoropolyethers and polyolefins such as polybutene. , polyisobutylene, dendrimers or organic hyperbranched polymers, or mixtures thereof. In particular, the organic polymer or the organic part of the hybrid polymer may be chosen from the following polymers: a) polyesters with ethylenic unsaturation (s): This is a group of polyester-type polymers having at least 2 ethylenic double bonds, randomly distributed in the main chain of the polymer. These unsaturated polyesters are obtained by polycondensation of a mixture of: linear or branched or cycloaliphatic aliphatic dicarboxylic acids containing in particular from 3 to 50 carbon atoms, preferably from 3 to 20 and better still from 3 to 10 carbon atoms, such as adipic acid or sebacic acid, of aromatic dicarboxylic acids having in particular from 8 to 50 carbon atoms, preferably from 8 to 20 and better still from 8 to 14 carbon atoms, such as phthalic acids, especially terephthalic acid, and / or dicarboxylic acids derived from dimers of ethylenically unsaturated fatty acids, such as the oleic or linoleic acid dimers described in application EP-A-959 066 (paragraph [0021)) sold under the names Pripol by Unichema or Empol by Henkel, all these diacids to be free of polymerizable double bond ethers, - linear aliphatic diols or r aminated or cycloaliphatic compounds containing in particular from 2 to 50 carbon atoms, preferably from 2 to 20 and better still from 2 to 10 carbon atoms, such as ethylene glycol, diethylene glycol, propylene glycol, 1,4-butanediol or cyclohexanedimethanol, aromatic diols having 6 to 50 carbon atoms, preferably 6 to 20 and more preferably 6 to 15 carbon atoms such as bisphenol A and bisphenol B, and / or diol dimers from the reduction dimers of fatty acids as defined above, and of one or more dicarboxylic acids or their anhydrides containing at least one polymerizable ethylenic double bond and having from 3 to 50 carbon atoms, preferably from 3 to And preferably from 3 to 10 carbon atoms, such as maleic acid, fumaric acid or itaconic acid. b) polyesters with (meth) acrylate groups and / or terminal: It is a group of polymers of the polyester type obtained by polycondensation of a mixture of: - linear or branched aliphatic carboxylic or cycloaliphatic dicarboxylic acids including from 3 to 50 carbon atoms, preferably from 3 to 20 and more preferably from 3 to 10 carbon atoms, such as adipic acid or sebacic acid, of aromatic dicarboxylic acids having in particular from 8 to 50 carbon atoms; preferably 8 to 20 and more preferably 8 to 14 carbon atoms, such as phthalic acids, especially terephthalic acid, and / or dicarboxylic acids derived from ethylenically unsaturated fatty acid dimers such as dimers of oleic or linoleic acids described in the application EP-A-959 066 (paragraph [0021]) marketed under the names Pripol by the company Unichema or Empol by Henkel, all these diacids to be e xempts of polymerizable ethylenic double bonds, - linear or branched or cycloaliphatic aliphatic diols comprising in particular from 2 to 50 carbon atoms, preferably from 2 to 20 and better still from 2 to 10 carbon atoms, such as ethylene glycol, diethylene glycol, propylene glycol, 1,4-butanediol or cyclohexanedimethanol, aromatic diols having from 6 to 50 carbon atoms, preferably from 6 to 20 and more preferably from 6 to 15 carbon atoms such as bisphenol A and bisphenol B, and - at least one (meth) acrylic acid ester and a diol or polyol having 2 to 20 carbon atoms, preferably 2 to 6 carbon atoms, such as (meth) 2-hydroxyethyl acrylate, 2-hydroxypropyl (meth) acrylate and glycerol methacrylate. These polyesters differ from those described above under (a) in that the ethylenic double bonds are not located in the main chain but on side groups or at the end of the chains. These ethylenic double bonds are those of (meth) acrylate groups present in the polymer. Such polyesters are sold, for example, by the company UCB under the names EBECRYL (EBECRYL 450: molecular weight 1600, on average 6 acrylate functions per molecule, EBECRYL 652: molecular weight 1500, on average 6 acrylate functions per molecule, EBECRYL 800 molar mass 780, on average 4 acrylate functions per molecule, EBECRYL 810: molar mass 1000, on average 4 acrylate functions per molecule, EBECRYL 50,000: molar mass 1500, on average 6 acrylate functions per molecule). c) polyurethanes and / or polyureas containing (meth) acrylate groups, obtained by polycondensation: cycloaliphatic and / or aromatic aliphatic diisocyanates, triisocyanates and / or polyisocyanates having in particular from 4 to 50, preferably from 4 to 30 carbon atoms, carbon, such as hexamethylene diisocyanate, isophorone diisocyanate, toluene diisocyanate, diphenylmethane diisocyanate or isocyanurates of the formula: ## STR1 ## resulting from the trimerization of 3 molecules of OCN-R diisocyanates -CNO, where R is a linear, branched or cyclic hydrocarbon radical containing from 2 to 30 carbon atoms; Polyols, in particular diols, free of polymerizable ethylenic unsaturations, such as 1,4-butanediol, ethylene glycol or trimethylolpropane, and / or polyamines, in particular diamines, aliphatic, cycloaliphatic and / or aromatic having in particular from 3 to 50 carbon atoms, such as ethylenediamine or hexamethylenediamine, and from at least one (meth) acrylic acid ester and a diol or polyol having from 2 to 20 carbon atoms preferably 2 to 6 carbon atoms, such as 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate and glycerol methacrylate. Such acrylate-containing polyurethanes / polyureas are commercially available for example under the name SR 368 (tris (2-hydroxyethyl) isocyanurate-triacrylate) or CRAYNOR 435 by the company CRAY VALLEY, or under the name EBECRYL by the company UCB (EBECRYL 210 : 1500 molar mass, 2 acrylate functions per molecule, EBECRYL 230: 5000 molar mass, 2 acrylate functions per molecule, EBECRYL 270: 1500 molar mass, 2 acrylate functions per molecule, EBECRYL 8402: 1000 molar mass, 2 acrylate functions per molecule, EBECRYL 8804: 1300 molar mass, 2 acrylate functions per molecule, EBECRYL 220: 1000 molar mass, 6 acrylate functions per molecule, EBECRYL 2220: 1200 molar mass, 6 acrylate functions per molecule, EBECRYL 1290: 1000 molar mass, 6 acrylate functions per molecule, EBECRYL 800: 800 molar mass, 6 acrylate functions per molecule). Mention may also be made of the water-soluble aliphatic diacrylate polyurethanes sold under the names EBECRYL 2000, EBECRYL 2001 and EBECRYL 2002, and the polyurethanes diacrylate in aqueous dispersion sold under the trade names IRR 390, IRR 400 and IRR 422 IRR 424 by the company UCB. D) polyethers with (meth) acrylate groups obtained by esterification, with (meth) acrylic acid, terminal hydroxyl groups of homopolymers or copolymers of C1-4 alkylene glycols, such as polyethylene glycol, polypropylene glycol, copolymers of ethylene oxide and propylene oxide preferably having a weight average molecular weight of less than 10,000, polyethoxylated or polypropoxylated trimethylolpropane. Polyoxyethylene di (meth) acrylate of suitable molar mass are commercially available for example under the names SR 259, SR 344, SR 610, SR 210, SR 603 and SR 252 by the company CRAY VALLEY or under the name EBECRYL 11 by UCB. Polyethoxylated trimethylolpropane triacrylates are commercially available, for example, under the names SR 454, SR 498, SR 502, SR 9035, SR 415 by the company CRAY VALLEY or under the name EBECRYL 160 by the company UCB. Polypropoxylated trimethylolpropane triacrylates are sold, for example, under the names SR 492 and SR 501 by the company Cray Valley. e) epoxyacrylates obtained by reaction between at least one diepoxide chosen for example from: (i) diglycidyl ether of bisphenol A, (ii) a diepoxy resin resulting from the reaction between bisphenol A diglycidyl ether and epichlorohydrin, (iii) an epoxy ester resin having 1, 4-diepoxy ends resulting from the condensation of a dicarboxylic acid having from 3 to 50 carbon atoms with a stoichiometric excess of (i) and / or (ii), (i) iv) an α, ié-codiated epoxy ether resin resulting from the condensation of a diol having 3 to 50 carbon atoms with a stoichiometric excess of (i) and / or (ii), (v) the natural or synthetic bearing oils at least 2 epoxide groups, such as epoxidized soybean oil, epoxidized linseed oil and epoxidized vernonia oil, (vi) a phenol-formaldehyde polycondensate (Novolac resin), the ends and / or groups side were epoxidized, and - one or more carboxylic acids or polycarboxylic acids having at least one ethylenic double bond at a, 13 of the carboxylic group such as (meth) acrylic acid or crotonic acid or esters of (meth) acrylic acid and a diol or polyol having 2 to 20 carbon atoms, preferably 2 to 6 carbon atoms such as 2-hydroxyethyl (meth) acrylate. Such polymers are sold, for example, under the names SR 349, SR 601, CD 541, SR 602, SR 9036, SR 348, CD 540, SR 480, CD 9038 by the company Cray Valley, under the names EBECRYL 600 and EBECRYL. 609, EBECRYL 150, EBECRYL 860, EBECRYL 3702 by the company UCB and under the names PHOTOMER 3005 and PHOTOMER 3082 by the company HENKEL. f) poly (meth) acrylates of (C 1-50) alkyl, said alkyl being linear, branched or cyclic, comprising at least two functions with ethylenic double bond carried by the side and / or terminal hydrocarbon chains. Such copolymers are sold for example under the names IRR 375, OTA 480 and EBECRYL 2047 by the company UCB. G) polyolefins such as polybutene, polyisobutylene; h) perfluoropolyethers containing acrylate groups obtained by esterification, for example with (meth) acrylic acid, of perfluoropolyethers bearing lateral and / or terminal hydroxyl groups. Such α, β-diol perfluoropolyethers are described in particular in EP-A-1057849 and are sold by Ausimont under the name Fomblin Z Diol. i) hyperbranched dendrimers and polymers bearing (meth) acrylate or (meth) acrylamide end groups respectively obtained by esterification or amidification of dendrimers and hydroxyl or amino terminal hyperbranched polymers with (meth) acrylic acid. Dendrimers (from the Greek dendron = tree) are "tree-like", that is, highly branched, polymer molecules invented by DA Tomalia and his team in the early 1990s (Donald A. Tomalia et al., Angewandte Chemie). , Int.Eng.Ed., vol 29, n 2, pp. 138-175). These are structures built around a generally versatile central pattern. Around this central motif are chained, according to a perfectly determined structure, branched chain extension units thus giving rise to symmetrical, monodisperse macromolecules having a well-defined chemical and stereochemical structure. Dendrimers of the polyamidoamine type are marketed for example under the name STARBUST by the company DENDRITECH. The hyperbranched polymers are polycondensates, generally of polyester, polyamide or polyethyleneamine type, obtained from multifunctional monomers, which have a tree structure similar to that of dendrimers but much less regular than this one (see, for example, WO-A 93/17060 and WO 96/12754). The company PERSTORP markets under the name BOLTORN hyperbranched polyesters. Under the COMBURST name of the company DENDRITECH are hyperbranched polyethyleneamines. Hyperramified poly (esteramide) with hydroxyl ends are marketed by DSM under the name HYBRANE. These dendrimers and hyperbranched polymers esterified or amidified with acrylic and / or methacrylic acid are distinguished from the polymers described under points a) to h) above by the very large number of ethylenic double bonds present. This high functionality, most often greater than 5, makes them particularly useful by allowing them to act as a "crosslinking node", that is to say a multiple crosslinking site. These dendritic and hyperbranched polymers can thus be used in combination with one or more of the polymers and / or oligomers a) to h) above. According to one embodiment, the compositions comprising compound X and / or Y may further comprise an additional reactive compound such as: organic or mineral particles comprising at their surface at least 2 unsaturated aliphatic groups, mention may be made, for example, of surface-treated silicas, for example silicone-containing compounds containing vinyl groups such as, for example, cyclotetramethyltetravinylsiloxane-treated silica; silazane compounds such as hexamethyldisilazane. Catalyst 30 The hydrosilylation reaction is advantageously carried out in the presence of a catalyst which may be present with one or the other of compounds X or Y or may be present in isolation. For example, this catalyst may be present in the composition under an encapsulated form if the two compounds X and Y, whose interaction it is to cause, are present in the same composition in an unencapsulated form or conversely may be present in an unencapsulated form if at least one of X and Y is present in the composition in an encapsulated form. The catalyst is preferably based on platinum or tin. There may be mentioned, for example, platinum catalysts deposited on a silica gel or charcoal powder (charcoal) support, platinum chloride, platinum and chloroplatinic acid salts. The chloroplatinic acids are preferably used in hexahydrate or anhydrous form, which is easily dispersible in organosilicone media. There may also be mentioned platinum complexes such as those based on chloroplatinic acid hexahydrate and divinyl tetramethyldisiloxane. The catalyst may be present in a content ranging from 0.0001% to 20% by weight relative to the total weight of the composition comprising it. Compounds X and / or Y may be combined with polymerization inhibitors or retarders, and more particularly catalyst inhibitors. In a nonlimiting manner, mention may be made of cyclic polymethylvinylsiloxanes, and in particular tetravinyl tetramethylcyclotetrasiloxane, acetylenic alcohols, which are preferably volatile, such as

  methylisobutynol.  The presence of ionic salts, such as sodium acetate, may influence the rate of polymerization of the compounds.  By way of example of a combination of compounds X and Y reacting by hydrosilylation, mention may be made of the following references proposed by Dow Corning: DC 7-9800 Soft Skin Adhesive Parts A & B, as well as the combination of blends A and B prepared by Dow Corning: MIXTURE A: Ingredient (INCI name) N CAS Content (%) Dimethyl Siloxane Function, 68083-19-55-95 Polymer Dimethylvinylsiloxy-2 Terminals 2910296 22 Silica Silylate 68909-20-10-40 Charge 6 1,3-Diethenyl-1,1,3,3- 68478-92- Trace Catalyst Tetramethyldisiloxane 2 complexes Tetramethyldivinyldisiloxane 2627-95-4 0. 1-1 Polymer MIXING B: Ingredient (INCI name) N CAS Content (%) Function Dimethyl Siloxane, 68083-19-2 55-95 Polymer Dimethylvinylsiloxy-terminal Silica Silylate 68909-20-6 10-40 Charge Dimethyl, 68037-59 2-10 Polymer Methylhydrogen Siloxane, Trimethylsiloxy-terminates Advantageously, the compounds X and Y are chosen from silicone compounds capable of reacting by hydrosilylation; in particular, compound X is chosen from polyorganosiloxanes comprising units of formula (I) described above and compound Y is chosen from organosiloxanes comprising alkylhydrogenosiloxane units of formula (III) described above.  According to a particular embodiment, the compound X is a polydimethylsiloxane with terminal vinyl groups, and the compound Y is a polymethylhydrogenosiloxane.  2 / compounds X and Y capable of reacting by condensation According to this embodiment, compounds X and Y are capable of reacting by condensation, either in the presence of water (hydrolysis) by reaction of 2 compounds bearing alkoxysilane groups, or by so-called direct condensation by reaction of a compound bearing alkoxysilane group (s) and a silanol group-carrying compound (s) or by reaction of 2 compounds carrying silanol group (s) (s).  When the condensation is done in the presence of water, it can be in particular the ambient humidity, the residual water of the skin, the lips of the eyelashes and / or the nails, or the water brought by a source external, for example by prior humidification of the keratin material (for example by a mist, natural or artificial tears).  In this condensation reaction mode, the compounds X and Y, which are identical or different, may therefore be chosen from silicone compounds whose main chain comprises at least two alkoxysilane groups and / or at least two silanol groups (Si-OH). , side and / or at the end of the chain.  According to one embodiment, the compound X and / or the compound X carries at least one polar group, as described above, capable of forming at least one hydrogen bond with the keratin materials.  According to an advantageous embodiment, the compounds X and / or Y are chosen from polyorganosiloxanes comprising at least two alkoxysilane groups.  By alkoxysilane group is meant a group comprising at least a portion -Si-OR, R being an alkyl group comprising from 1 to 6 carbon atoms.  The compounds X and Y are in particular chosen from polyorganosiloxanes comprising alkoxysilane end groups, more specifically those which comprise at least 2 terminal alkoxysilane groups, preferably terminal trialkoxysilanes.  s '),' 2, 25 (IV) in which the groups R 9 independently of one another represent a radical selected from alkyl groups comprising from 1 to 6 carbon atoms, phenyl, fluoroalkyl groups, and s is equal to 0, 1, 2 or 3.  Preferably, the R 9 groups represent independently of each other an alkyl group comprising from 1 to 6 carbon atoms.  As alkyl group, there may be mentioned in particular methyl, propyl, butyl, hexyl and mixtures thereof, preferably methyl or ethyl.  As the fluoroalkyl group, 3,3,3-trifluoropropyl may be mentioned.  These compounds X and / or Y preferably comprise, in a majority manner, units of formula: ## STR2 ## According to one particular embodiment, the compounds X and Y, which are identical or different, are polyorganosiloxanes comprising units of formula: Wherein R9 is as described above, preferably R9 is a methyl radical, and f is such that the polymer advantageously has a viscosity at C ranging from 0.5 to 3000 Pa. s, preferably ranging from 5 to 150 Pa. s; for example, f may range from 2 to 5000, preferably from 3 to 3000, and preferably from 5 to 1000.  These X and Y polyorganosiloxane compounds comprise at least 2 terminal trialkoxysilane groups per polymer molecule, said groups having the following formula: ## STR5 ## wherein: R 1 is independently methyl, ethyl , n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, preferably a methyl or ethyl group, R 'is a methyl or ethyl group, x is 0 or 1, preferably x is 0 and Z is selected from: divalent hydrocarbon groups not having ethylenic unsaturation and comprising from 2 to 18 carbon atoms (alkylene groups), combinations of divalent hydrocarbon radicals and silo xane segments of the following formula (IX): Wherein R 9 is as described above, G is a divalent hydrocarbon radical having no ethylenic unsaturation and having 2 to 18 carbon atoms and c is an integer of 1 to 6.  Z and G may especially be chosen from alkylene groups such as ethylene, propylene, butylene, pentylene, hexylene, arylene groups such as phenylene.  Preferably, Z is an alkylene group, and better ethylene.  These polymers may have on average at least 1.2 trialkoxysilane end groups or terminal chains per molecule, and preferably on average at least 1.5 trialkoxysilane end groups per molecule.  Since these polymers may have at least 1.2 trialkoxysilane end groups per molecule, some may comprise other types of terminal groups such as terminal groups of formula CH 2 = CH-SiR 92 or of formula R 63 -Si-, in which R 9 is as defined above and each R6 group is independently selected from R9 or vinyl groups.  Examples of such end groups include trimethoxysilane, triethoxysilane, vinyldimethoxysilane and vinylmethyloxyphenylsilane groups.  Such polymers are described in US Pat. Nos. 3,175,993, 4,772,675, 4,887,827, 4,888,380, 4,898,910, 4,906,719 and 4,962,174, the contents of which are incorporated by reference. reference to this application.  Compound X and / or Y may be mentioned in particular the polymer of formula: R.  R9 R9! R.  ; R gil 5.  Z - (SiO 2 -Z) Si (OR (VII) wherein R, R ', R, Z, x and f are as described above.  The compounds X and / or Y may also comprise a polymer mixture of formula (VII) above with polymers of the following formula (VIII): ## STR2 ## in which R, R ', R9, Z, x and f are as described above.  When the compound X and / or Y polyorganosiloxanes containing alkoxysilane (s) comprises such a mixture, the various polyorganosiloxanes are present in such amounts that the terminal organosilyl chains represent less than 40%, preferably less than 25% in number of the terminal chains.  Particularly preferred compounds X and / or Y polyorganosiloxanes are those of formula (VII) described above.  Such compounds X and / or Y are described, for example, in WO 01/96450.  As indicated above, the compounds X and Y may be the same or different.  According to one variant, one of the two reactive compounds X or Y is of a silicone nature and the other is of organic nature.  For example, the compound X is chosen from organic oligomers or polymers or oligomers or hybrid organic / silicone polymers, said polymers or oligomers comprising at least two alkoxysilane groups and Y is chosen from silicone compounds such as the polyorganosiloxanes described above. .  In particular, the organic oligomers or polymers are chosen from vinyl, (meth) acrylic, polyesters, polyamides, polyurethanes and / or polyureas, polyethers, polyolefins, perfluoropolyethers, dendrimers and organic hyperbranched polymers, and their mixtures. .  According to one embodiment, the compound X of organic nature or organic hybrid nature / silicone carries at least one polar group, as described above, capable of forming at least one hydrogen bond with the keratin material.  The organic polymers of vinyl type or (meth) acrylic, bearing alkoxysilane side groups, may in particular be obtained by copolymerization of at least one vinylic organic monomer or (meth) acrylic with (meth) acryloxypropyltrimethoxysilane, a vinyl trimethoxysilane, vinyltriethoxysilane, allyltrimethoxysilane, etc. .  For example, the (meth) acrylic polymers described in the KUSABE document may be mentioned. M. Pitture e Verniei - European Coating; 12-B, pages 43-49, 2005, and in particular the alkoxysilane polyacrylates referenced MAX of 2910296 Kaneka or those described in the publication PROBSTER, M, Adhesion-Kleben & Dichten, 2004, 481 (1-2), pages 12-14.  The organic polymers resulting from a polycondensation or a polyaddition, such as polyesters, polyamides, polyurethanes and / or polyureas, polyethers, and bearing side and / or terminal alkylsilanes groups, may result for example from the reaction of an oligomeric prepolymer as described above with one of the following silane co-reactants bearing at least one alkoxysilane group: aminopropyltrimethoxysilane, aminopropyltriethoxysilane, aminoethylaminopropyltrimethoxysilane, glycidoxypropyltrimethoxysilane, glycidoxypropyltriethoxysilane, epoxycyclohexylethyltrimethoxysilane, mercaptopropyltrimethoxysilane.  Examples of polyethers and polyisobutylenes with alkoxysilane groups are described in the KUSABE publication. Mr. , Pitture e Verniei - European Coating; 12-B, pp. 43-49, 2005.  As an example of polyurethanes with terminal alkoxysilane groups, mention may be made of those described in the document PROBSTER, M. , Adhesion-Kleben & Dichten, 2004, 481 (1-2), pages 12-14 or those described in LANDON, S. , Pitture e Verniei Vol.  73, No. 11, pages 18-24, 1997 or in the document HUANG, Mowo, Pitture e Verniei Vol.  5, 2000, pages 61-67, there may be mentioned polyurethanes alkoxysilane groups of OSI-WITCO-GE.  As compounds X and / or Y polyorganosiloxane, there may be mentioned resins 20 of MQ or MT type itself bearing alkoxysilane ends and / or silanols such as poly (isobutylsilsesquioxane) resins functionalized with silanol groups proposed under the reference SST-S7C41 (3 Si-OH groups) by Gelest.  2a - Additional reactive compound According to one embodiment, compound X and / or Y may be further associated with an additional reactive compound comprising at least two alkoxysilane or silanol groups.  For example, mention may be made of: an organic or inorganic particle or particles comprising, on their surface, alkoxysilane and / or silanol groups, for example fillers surface-treated with such groups.  2b - Catalyst The condensation reaction can be carried out in the presence of a metal catalyst which may be present with one or the other of compounds X or Y or be present in isolation.  For example, this catalyst may be present in the composition in an encapsulated form if the two compounds X and Y, whose interaction it is to cause, are present in the same composition in an unencapsulated form or conversely it may be present in an unencapsulated form if at least one of the compounds X and Y is present in the composition in an encapsulated form.  The catalyst useful in this type of reaction is preferably a titanium-based catalyst.  There may be mentioned in particular tetraalkoxytitanium-based catalysts of formula: ## STR2 ## in which R 2 is chosen from tertiary alkyl radicals such as tert-butyl, tert-amyl and 2,4-diisopropyl. 3-dimethylpentyl; R 3 represents an alkyl radical comprising from 1 to 6 carbon atoms, preferably a methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl or hexyl group and y is a number ranging from 3 to 4, better from 3.4 to 4.  The catalyst may be present in a content ranging from 0.0001% to 20% by weight relative to the total weight of the composition containing it.  2c - Diluent Useful compositions comprising X and / or Y may further comprise a volatile silicone oil (or diluent) for decreasing the viscosity of the composition.  This oil may be chosen from linear short chain silicones such as hexamethyldisiloxane, octamethyltrisiloxane, cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and mixtures thereof.  This silicone oil may represent from 5% to 95%, preferably from 10 to 80% by weight relative to the weight of each composition.  By way of example of a combination of compounds X and Y bearing alkoxysilane groups and reacting by condensation, mention may be made of the following mixtures A 'and B' prepared by the company Dow Corning: 2910296 Mixture A ': Ingredient (INCI name) N CAS Level (%) Function Bis-Trimethoxysiloxyethyl PMN87176 25-45 Polymer Tetramethyldisiloxyethyl Dimethicone (1) Silica Silylate 68909-20-6 5-20 Charge Disiloxane 107-46-0 30-70 Solvent Mixture B ': Ingredient (INCI name) N CAS Content (%) Disiloxane function 107-46-0 80-99 Tetra T solvent Butyl titanate - 1-20 Catalyst 5 It should be noted that the compounds X and Y, identical, are combined in the mixture A '(cf.  (1)).  3 / Crosslinking in the presence of peroxide: This reaction is preferably carried out by heating at a temperature greater than or equal to 50 ° C., preferably greater than or equal to 80 ° C., up to 120 ° C.  The compounds X and Y, which are identical or different, comprise in this case at least two side groups ûCH3 and / or at least two side chains carrying a group -CH3.  The compounds X and Y are preferably silicone and may be chosen, for example, from high molecular weight non-volatile linear polydimethylsiloxanes having a degree of polymerization of greater than 6 and having at least two ûCH 3 side groups bonded to the silicon atom and / or at least two side chains carrying a group -CH3.  Mention may be made, for example, of the polymers described in the Reactive Silicones Catalog of Gelest Inc. , Edition 2004, page 6, and in particular the copolymers (also called gums) of vinylmethylsiloxanedimethylsiloxane with molecular weights ranging from 500,000 to 900,000 and especially with a viscosity greater than 2,000,000 cSt.  As peroxides useful in the context of the invention, mention may be made of benzoyl peroxide, 2,4-dichlorobenzoyl peroxide and mixtures thereof.  According to one embodiment, the hydrosilylation reaction, or the condensation reaction, or else the crosslinking reaction in the presence of a peroxide, between the compounds X and Y is accelerated by a heat input, for example by raising the temperature of the system between 25 C and 180 C.  In general, regardless of the type of reaction by which compounds X and Y react together, the molar percentage of X relative to all compounds X and Y, ie the ratio X / (X + Y) x 100, may range from 5% to 95%, preferably from 10% to 90%, more preferably from 20% to 80%.  Similarly, the molar percentage of Y relative to the set of compounds X and Y, ie the ratio Y / (X + Y) × 100, can vary from 5% to 95%, preferably from 10% to 90%, more preferably from 20% to 80%.  Compound X may have a weight average molecular weight (Mw) of from 150 to 1,000,000, preferably from 200 to 800,000, more preferably from 200 to 250,000.  Compound Y can have a weight average molecular weight (Mw) of from 200 to 1,000,000, preferably from 300 to 800,000, more preferably from 500 to 250,000.  The compound X can represent from 0.1% to 95% by weight relative to the total weight of the composition containing it, preferably from 1% to 90%, and better still from 5% to 80%.  Compound Y may represent from 0.1% to 95% by weight relative to the total weight of the composition containing it, preferably from 1% to 90% and better still from 5% to 80%.  The ratio between the compounds X and Y can be varied so as to modulate the reaction rate and thus the rate of formation of the film or also to adapt the properties of the formed film (for example its adhesive properties) according to the application. sought.  In particular, the compounds X and Y may be present in a molar X / Y ratio ranging from 0.05 to 20 and better still from 0.1 to 10.  Compounds X and Y may advantageously be associated with at least one filler.  Thus, the kit according to the invention may for example comprise in at least one of the compositions a filler selected from silica or silica treated on the surface.  As previously stated, according to one embodiment of the invention, the compounds X and Y may be used in the form of a single composition which then contains at least one of them or, as the case may be, the catalyst or peroxide if necessary for their interaction, in an encapsulated form.  In the context of the present invention, the encapsulated forms of heart / shell type, still called microcapsules or nanocapsules, whose bark is of a polymeric nature and the core contains compound X, compound Y, one of its X and Y compounds being optionally encapsulated with the catalyst or the peroxide if necessary to the interaction of the two compounds.  Assuming that this catalyst is not encapsulated with either one of X or Y, it is present in the cosmetic composition containing the encapsulated forms.  Many techniques are currently available to prepare this type of microcapsules or nanocapsules However, according to a preferred embodiment, the encapsulated forms considered according to the invention are nanocapsules and are obtained by a so-called solvent switching technique, particularly illustrated in the documents. EP 274 961 and EP 1 552 820.  More particularly, the shell of the nanocapsules of compound X or Y, used according to the invention, is polymeric in nature, non-crosslinked, non-water-soluble and not soluble in the heart of the capsules.  In a general manner, all the polymers, of natural or synthetic origin, soluble in a water immiscible solvent and in particular those having a melting point below the boiling point of water at atmospheric pressure ( 100 C), may be suitable.  These polymers may be biodegradable, for example polyesters, or not.  By way of illustration of the polymers that are suitable for the invention, mention may be made in particular of: C2-Cl2 alkyl cyanoacrylate polymers; polymers formed by poly-L-lactides, poly-DL-lactides, polyglycolides and the corresponding copolymers, polycaprolactones, polymers of 3-hydroxybutyric acid, copolymers of vinyl chloride and of vinyl acetate, copolymers of acid and of methacrylic ester, in particular methacrylic acid and methacrylic acid ester, polyvinyl aceto phthalate, cellulose acetate phthalate, polyvinylpyrrolidone-vinyl acetate copolymer, polyethylenevinylacetates, polyacrylonitriles, Polyacrylamides, polyethylene glycols, poly (C1-C4 hydroxyalkyl methacrylate) esters of cellulose and C1-C4 carboxylic acid, polystyrene and copolymers of styrene and anhydride. maleic, the copolymers of styrene and acrylic acid, styrene-ethylene / butylene-styrene block terpolymers, styrene-ethylene / propylene-styrene block terpolymers, styrene alkylalcohol oligomers, terpolymers of ethylene, vinyl acetate and maleic anhydride, polyamides, polyethylenes, polypropylenes, organopolysiloxanes including polydimethylsiloxanes, poly (alkylene adipates), polyol polyesters, silicone polysilsesquioxane polymers, dendritic polyesters with terminal hydroxyl, the hydrodipersible polymers but nevertheless soluble in water-immiscible solvents, for example: polyesters, poly (ester amides), polyurethanes and vinyl copolymers bearing carboxylic and / or sulphonic acid functions and in particular those described in document FR 2 787 729, block copolymers which are insoluble in water at ambient and solid temperature at room temperature, having at least one block of one of the above polymers, and mixtures thereof.  These polymers or copolymers may have a weight average molecular weight of between 1000 and 500 000 and in particular between 1500 and 100 000.  Poly (alkylene adipate), organopolysiloxanes, polycaprolactones, cellulose acetate phthalate, cellulose acetate butyrate, cellulose esters, polystyrene and its derivatives are particularly suitable for the invention.  Of course, one skilled in the art is able, by his or her knowledge, to adjust the molecular weight of the selected polymer with respect to its concentration in the solvent in order to have a viscosity of the mixture compatible with an emulsification. satisfactory.  As regards the lipophilic core, it may contain in addition to compound X or compound Y, at least one oil.  The oil may be chosen from the oils described below for the oily phase.  The oil is preferably a silicone oil.  According to a variant of the invention the encapsulated forms of compound X or compound Y may be coated with a lamellar phase.  Regarding the operating protocol for preparing nanocapsules suitable for the invention, one skilled in the art can refer in particular to the teaching of the document EP 1 552 820 cited above.  The choice of surfactants required as well as the implementation of the process makes use of the knowledge of those skilled in the art.  Linear volatile silicone oil By "volatile oil" is meant an oil (or nonaqueous medium) capable of evaporating on contact with the skin in less than one hour, at ambient temperature and atmospheric pressure.  The volatile oil is a volatile cosmetic oil which is liquid at ambient temperature, in particular having a non-zero vapor pressure, at ambient temperature and atmospheric pressure, in particular having a vapor pressure ranging from 0.13 Pa to 40 000 Pa (10 300 mm Hg), and preferably ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mm Hg), mm Hg).  By "linear" is meant a non-cyclic silicone oil having a straight chain.  The linear volatile silicone oil according to the present invention may be chosen from linear silicones of formula (I): ## STR3 ## in which R, which may be identical or different, denotes: ## STR1 ## saturated or unsaturated hydrocarbon-based hydrocarbon having 1 to 5 carbon atoms, preferably 1 to 6 carbon atoms, optionally substituted by one or more fluorine atoms or by one or more hydroxyl groups, or - a hydroxyl group, one of the radicals R possibly being a phenyl group, n is an integer ranging from 0 to 8, preferably ranging from 2 to 6, and better still ranging from 2 to 5, the silicone compound of formula (I) containing at most 15 atoms of carbon.  Preferably, in the compounds of formula (I), the ratio between the number of carbon atoms and the number of silicon atoms is between 2, 25 and 4.33.  The silicones of formula (I) may be prepared according to the known processes for the synthesis of silicone compounds.  Among the silicones of formula (I), mention may be made in particular of: a) trisiloxanes and in particular octamethyltrisiloxane, sold in particular under the name Dow Corning 200 Fluid 1 by Dow Corning, b) tetrasiloxanes and in particular decamethyltetrasiloxane, especially sold under the name DC 200 FLUID 1. C) by the company Dow Corning, c) pentasiloxanes and in particular dodecamethylpentasiloxane, sold in particular under the name DC 200 FLUID 2 cst by Dow Corning, and d) their mixtures.  The linear volatile silicone oil, alone or as a mixture, may be present in a content ranging, for example, from 40 to 100% by weight, relative to the total weight of the make-up removing and / or cleaning composition, preferably from 50 to 95% by weight, relative to the total weight of the make-up removal and / or cleaning composition.  According to a preferred variant of the invention, the make-up removal and / or cleaning composition comprises at least 55% by weight, or even 60% by weight, of oil relative to the total weight of the composition.  By oil is meant volatile oil or not.  Advantageously, the linear volatile silicone oil comprises or consists of at least one of the silicone oils decamethyltetrasiloxane and dodecamethylpentasiloxane or of their mixture.  MAKE-UP AND / OR CLEANING COMPOSITION The cleansing and / or cleaning composition may further comprise one or more non-silicone volatile oils, chosen in particular from volatile hydrocarbon or fluorinated oils.  Hydrocarbon oil is understood to mean an oil formed essentially or even consisting of carbon and hydrogen atoms, and possibly oxygen, nitrogen, and not containing silicon or fluorine atoms.  It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.  The hydrocarbon-based volatile oil may be chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof, and in particular C8-C16 branched alkanes such as isoalkanes (also known as isoparaffins) with C 8 -C 16, or isododecane, isodecane, isohexadecane and for example the oils sold under the trade names Isopar or Permethyl, branched C8-C16 esters such as isohexyl neopentanoate and mixtures thereof; isododecane or isohexadecane is preferably used.  According to a preferred variant of the invention, the make-up removing and / or cleaning composition further comprises at least one non-silicone volatile oil chosen from isoparaffins, isododecane, isodecane, isohexadecane, neopentanoate and the like. isohexyl and mixtures thereof.  The volatile oil (s) other than the linear silicone oils may be present in a content ranging from 0.1 to 70% by weight, relative to the total weight of the makeup removal and / or cleaning composition, preferably ranging from , 1 to 50% by weight, and preferably ranging from 0.1 to 30% by weight relative to the total weight of the makeup removal and / or cleaning composition.  The make-up removing and / or cleaning composition may further comprise at least one non-volatile oil.  As non-volatile oil, mention may be made of: hydrocarbon oils of mineral or synthetic origin, such as linear or branched hydrocarbons, such as paraffin oil or its derivatives, liquid petrolatum, polydecenes, hydrogenated polyisobutene such as Parléam marketed by the company Nippon Oil Fats, squalane of synthetic or vegetable origin; triglyceride-based hydrocarbon-based vegetable oils consisting of esters of fatty acids and of glycerol, the fatty acids of which may have a variety of chain lengths, the latter possibly being linear or branched, saturated or unsaturated, especially the fatty acid triglycerides, in particular of 4 to 22 carbon atoms, such as the triglycerides of heptanoic, octanoic acids, and capric / caprylic acids or else the hydroxylated triglycerides, such as almond oil, calophyllum oil, palm, grape seed, sesame, arara, rapeseed, sunflower, cotton, apricot, castor oil, alfalfa, squash, blackcurrant, macadamia, muscat rose, hazelnut, coriander, avocado, jojoba, olive, sprouts of cereals (corn, wheat, barley, rye), shea butter; fatty acid esters, in particular from 35 to 22 carbon atoms, and in particular octanoic acid, heptanoic acid, lanolic acid, oleic acid, lauric acid, stearic acid, and the like. propylene glycol dioctanoate, propylene glycol monoisostearate, polyglyceryl diisostearate, neopentyl glycol diheptanoate; the synthetic esters of formula R 1000 R 2 in which R 1 represents the residue of a linear or branched higher fatty acid containing from 7 to 40 carbon atoms and R 2 represents a branched hydrocarbon-based chain containing from 3 to 40 carbon atoms, as for example for example, purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12-C15 alcohol benzoate, ethyl 2-hexyl palmitate, 2-octyl dodecyl stearate, erucate 2-octyl dodecyl, isostearyl isostearate, 2-octyldodecyl benzoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, isopropyl myristate, isopropyl palmitate, stearate butyl, hexyl laurate, diisopropyl adipate, 2-ethyl hexyl palmitate, 2-hexyldecyl laurate, 2-octyl decyl palmitate, 2-octyldodecyl myristate, succinate 2-diethylhexyl, diisostearyl malate, isodecyl neopentanoate; hydroxylated esters such as isostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate, diisostearyl malate, triisocetyl citrate, glycerin or diglycerine triisostearate; diethylene glycol diisononanoate; pentaerythritol esters; esters of aromatic acids and alcohols comprising 4 to 22 carbon atoms, especially tridecyl trimellitate; higher C8-C26 fatty acids, such as myristic acid, oleic acid, linoleic acid, linolenic acid or isostearic acid; higher C8-C26 fatty alcohols such as oleic alcohol, linoleic or linolenic alcohol, isostearyl alcohol or octyl dodecanol; Synthetic ethers containing at least 7 carbon atoms; silicone oils such as polydimethylsiloxanes (PDMS) which are liquid at room temperature, linear, optionally phenylated, such as phenyl trimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, liquid 2-phenylethyl trimethylsiloxysilicates, optionally substituted with aliphatic and / or aromatic groups such as alkyl, alkoxy or phenyl groups, during and / or at the end of the silicone chain, groups containing from 2 to 24 carbon atoms and optionally fluorinated, or by functional groups such as hydroxyl groups, thiol and / or amine; polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes such as dimethicone copolyols or alkylmethicone copolyols; liquid fluorinated silicones; - and their mixtures.  The amount of non-volatile oil (s) may range, for example, from 0.1% to 50% by weight, relative to the total weight of the make-up removing and / or cleaning composition, preferably from 0 to 50% by weight. , 5% to 40% by weight, and preferably ranging from 1% to 30% by weight relative to the total weight of the make-up removal and / or cleaning composition.  The cleansing and / or cleansing composition may be in the form of a makeup-removing oil, a cleansing milk, an emulsion, a biphase or an anhydrous composition.  The term "anhydrous composition" means a composition which contains less than 2% by weight of water, or even less than 0.5% of water relative to the total weight of the composition, or in particular a composition which is free of water, the water not being added during the preparation of the composition but corresponding to the residual water provided by the mixed ingredients.  When the cleansing and / or cleansing composition is an emulsion or a two-phase composition, it comprises an aqueous phase and an oily phase.  The emulsions and the biphase compositions are distinguished by the fact that the biphase compositions consist of two phases which, at rest, are distinct instead of being emulsified one in the other.  The use of these two-phase compositions requires prior stirring in order to form an extemporaneous emulsion, the latter having to be of sufficient quality and stability to allow a homogeneous application of the two phases, but such that at rest, said phases separate. quickly and return to their initial state, this phenomenon being better known as "phase shift".  These two-phase compositions are described for example in the documents EP-A-370 856 and EP-A-603 080.  On the other hand, the emulsions comprise two phases, an aqueous phase and an oily phase, one phase being dispersed in the other stably.  When the cleansing and / or cleaning composition contains an aqueous phase, it contains water and may contain any water-soluble or water-dispersible additive.  The aqueous phase may also comprise water-miscible organic solvents (at 25.degree. C.), for example primary alcohols (C1-C3 monohydric alcohol), such as ethanol and isopropanol, and polyols such as propylene. glycol, butylene glycol, glycerine, hexylene glycol, polyethylene glycols such as PEG-8, dipropylene glycol and mixtures thereof.  The amount of polyol (s) in the make-up removing and / or cleaning composition is preferably such that it does not impart stickiness to the final composition.  This amount is generally from 0.05 to 20% by weight and preferably from 0.1 to 15% by weight and better still from 0.5 to 10% by weight relative to the total weight of the makeup removal composition and / or of cleaning.  When the cleansing and / or cleansing composition is in the form of an emulsion, it may be a water-in-oil (W / O) or oil-in-water (O / W) emulsion. , or multiple emulsion (W / O / W or W / E / H).  According to a preferred embodiment of the invention, the cleaning or makeup removal composition is in anhydrous form or in the form of an W / O emulsion, which are the most suitable for removing make-up films made from silicones. as described above.  The weight ratio between the aqueous phase and the oily phase may be, for example, from 10/90 to 95/5, and preferably from 30/70 to 90/10.  Thus, the aqueous phase may for example represent from 10 to 95% by weight, preferably from 30 to 90% by weight, better still from 60 to 90% by weight relative to the total weight of the composition, and the oily phase may represent for example from 5 to 90% by weight, preferably from 10 to 70% by weight, better still from 10 to 40% by weight relative to the total weight of the composition.  When the make-up removing and / or cleaning composition is in the form of a biphase, the weight ratio between the aqueous phase and the oily phase is preferably from 25/75 to 90/10 and preferably 30/70 to 70/30.  The aqueous phase therefore generally represents from 25 to 90% by weight, preferably from 30 to 70% by weight and better still from 40 to 60% by weight relative to the total weight of the makeup removal and / or cleaning composition.  The make-up removing and / or cleaning composition may also comprise one or more surfactants.  The amount of surfactant may vary to a large extent but is limited in practice for reasons of tolerance.  It also depends on the type of compositions (emulsion or other).  The amount of surfactant (s) (active material) is preferably from 0.01 to 15% by weight, more preferably from 0.02 to 10% by weight and more preferably from 0.05 to 5% by weight relative to total weight of the composition.  Any surfactant that is normally used in makeup-removing compositions can be used as surfactant.  The surfactant may be selected from nonionic surfactants, anionic surfactants, amphoteric or zwitterionic surfactants and mixtures thereof.  The makeup removal and / or cleaning composition may also contain the additives or active ingredients conventionally used in skincare products.  Mention may be made, for example, of water-soluble or liposoluble adjuvants customary in the cosmetics field, such as preservatives, sequestering agents (EDTA), antioxidants, perfumes, dyestuffs, soluble dyes or encapsulated or non-encapsulated pigments, nacres, whitening or exfoliating agents, sunscreens, hydrophilic or lipophilic cosmetic or dermatological active agents, such as water-soluble or fat-soluble vitamins, antiseptics, antiseborrhics, antimicrobials such as benzoyl peroxide, salicylic acid, triclosan, azelaic acid, niacin (vit.  PP), slimming agents such as caffeine and also optical brighteners, electrolytes, agents having the effect of improving the cosmetic properties of the skin.  The amounts of these various adjuvants are those conventionally used in the field under consideration, and for example from 0.01 to 20% of the total weight of the composition.  When the cleansing and / or cleansing composition is a biphase, it may also contain a phase shift agent, which makes it possible to improve the phase separation rate after stirring.  Of course, those skilled in the art will take care to choose this or these optional additives and / or their quantity, in such a way that the advantageous properties of the composition according to the invention are not, or not substantially, impaired by the addition envisaged. .  As preservatives, any preservative usually used in the relevant fields, such as, for example, parabens, phenoxyethanol and chlorhexidine digluconate can be used.  As bactericides, it is possible for example to use a mono (C 3 -C 9) alkyl or (C 3 -C 9) alkenyl ether of glycerol, the manufacture of which is described in the literature, in particular in E.  Baer, H. O. L.  Fischer - J.  Biol.  Chem.  140-397-1941.  Of these mono (C 3 -C 9) alkyl or (C 3 -C 9) alkenyl ether glycerol, use is preferably made of 3 - [(2-ethylhexyl) oxy] -1,2-propanediol, 3 - [(heptyl) oxy] - 1,2-propanediol, 3 - [(octyl) oxy] -1,2-propanediol and 3 - [(allyl) oxy] -1,2-propanediol.  A more particularly preferred mono (C 3 -C 9) alkyl ether of glycerol according to the present invention is 3 - [(2-ethylhexyl) oxy] -1,2-propanediol, sold by SCHULKE & MAYR G. m. b. H.  under the trade name SENSIVA SC 50 (INCI name: Ethylhexylglycerin).  Examples of exfoliating agents are exfoliating or exfoliating particles of mineral, plant or organic origin.  Thus, for example, beads or polyethylene powder, nylon powder, polyvinyl chloride powder may be used.

of

  vinyl, pumice, crushed apricot kernels or nut shells, sawdust, glass beads, alumina, and mixtures thereof.

These particles may be present in an amount ranging, for example, from 0.5 to 30% by weight, preferably from 1 to 20% by weight and better still from 1 to 10% by weight relative to the total weight of the composition of the composition. makeup and / or cleaning. When the make-up and / or cleansing composition contains exfoliating particles, it may constitute in particular a composition for scrubbing the skin of the face or body. However, the presence of exfoliating particles in the compositions intended for the removal of make-up of the eyes or the removal of make-up of sensitive skin will be avoided. According to the makeup film obtained following the application of the compound X and the compound Y as defined above and the type of keratinous material concerned, the makeup removal and / or cleaning composition may take various forms, all of which are well known to the skin. skilled person. Thus, by way of example, when the make-up is of the foundation type and is therefore applied to the skin, the make-up removal and / or cleaning composition may be similar to a conventional make-up remover, make-up removing oil or cleansing emulsion or comprise an additional component of scrubbing type, for example by the presence of exfoliating particles, or more clean type for example by the presence of adjuvants usually used in the field of cleaners.

In other words, all the combinations in terms of the presence of adjuvants for removing make-up and / or cleaning are possible provided that the composition comprises at least one linear volatile silicone oil. Therefore, the make-up and / or cleansing composition may in particular take the form of a hygiene product, for example in the form of a product for cleaning and / or removing make-up from the skin (face and / or skin). or the body), in the form of an exfoliating product (also called a scrubbing or descaling product) for the face as well as for the body or for the hands, after the addition of exfoliating particles. Thus, a rinsing step may be expected following the application of the make-up removing and / or cleaning composition.

DEMAQUILLING AND / OR CLEANING PROCESS The cleansing and / or cleaning method according to the present invention may be followed by a rinsing step, in particular when the make-up removal and / or cleaning composition contains exfoliating particles or if the user feels the need according to the sensitivity of her skin and the effect felt. Thus, this rinsing step is particularly useful when the make-up removal and / or cleaning composition takes the form of an exfoliating product. However, according to a preferred embodiment of the invention, the process is free of an additional rinsing step. The make-up removing and / or cleaning composition included in the kit according to the invention may for example be used in the following way: the composition is applied to the skin, for example with a cotton, and then it is optionally rinsed. KIT OF MAKE-UP AND / OR CARE The make-up and / or care component of the kit may take any dosage form normally used in the cosmetics field. By makeup component and / or care kit is meant the first and second compositions or the single composition comprising the two compounds X and Y, able to react together by hydrosilylation, condensation or crosslinking in the presence of a peroxide, when they are brought into contact with each other, at least one of the compounds X and Y being a silicone compound, as defined above. It can thus be a lip makeup product such as a lipstick, a lip balm, a lip gloss or a lip pencil, a complexion product, such as a background complexion, a loose or compacted powder, a blush, an eye shadow, a concealer, a blush, a mascara, an eyeliner or a makeup product body or skin color. According to one embodiment of the invention, the single composition comprising compounds X and Y or the first and second compositions are lipstick compositions. According to a preferred embodiment of the invention, the kit is intended for the makeup and / or care of keratin fibers, especially eyelashes.

Thus, according to one embodiment, the single composition comprising the compounds X and Y or the first and second compositions are compositions for coating the eyelashes or the eyebrows and more particularly the mascaras. According to yet another embodiment, the single composition comprising the compounds X and Y or the first and second compositions are compositions for coating the skin of the body or the face, more particularly compositions for making up the skin of the body or the skin. such as, for example, foundations or makeup compositions of the body. It may also be a care composition such as a product for the care of the eyelashes, the lips, the care of the skin of the body and the face, in particular a solar product. The composition or compositions of the make-up and / or care component may comprise all the conventional ingredients chosen in particular from the fatty phases, such as waxes and / or oils, pigments or dyestuffs, fillers and additives, such as cosmetic or dermatological active ingredients. .

Those skilled in the art will be able to choose the appropriate dosage form, as well as its method of preparation on the basis of its general knowledge, taking into account, on the one hand, the nature of the constituents used and on the other hand, the intended application. The single composition comprising the compounds X and Y or the first and second compositions of the kit according to the invention may be independently in the form of suspension, dispersion, solution, gel, emulsion, in particular emulsion. oil-in-water (O / W), wax-in-water or water-in-oil (W / O), or multiple (W / O / E or polyol / H / E or H / E / H), in the form of cream, paste, foam, dispersion of vesicles including ionic lipids or not, biphase or multiphase lotion, powder, paste, including soft paste.

The following examples illustrate the present invention. All amounts are given in percentage by weight relative to the total weight of the composition. In the examples of compositions described hereinafter, the combination of the following mixtures A and B prepared by the company Dow Corning is used as a combination of the compounds X and Y: MIXING A: Ingredient (INCI name) N CAS Content (%) Function Dimethyl Siloxane, 68083-19-55-95 Polymer Dimethylvinylsiloxy2 Terminals Silica Silylate 68909-20- 10-40 Charge 6 1,3-Diethenyl-1,1,3,3- 68478-92- Trace Catalyst Tetramethyldisiloxane 2 complexes Tetramethyldivinyldisiloxane 2627-95-4 0.1-1 Polymer MIXING B: Ingredient (INCI name) N CAS Content (%) Function Dimethyl Siloxane, 68083-19-2 55-95 Polymer Dimethylvinylsiloxy-terminal Silica Silylate 68909-20-6 10-40 Charge Dimethyl, 68037-59-2 1-10 Polymer Methylhydrogen Siloxane, trimethylsiloxy-terminal 44 10 2910296 EXAMPLES Example 1: Measurement of Cleansing Efficiency - Makeup Composition Chemical Name Composition Base 1 Blend B 50 Phenyl Trimethicone (1 ) 13.85 Phenyl trimethicone (2) 24.10 Polybutene (3) 12.05 Base 2 Blend A 50 Phenyl trimethicone (1) 19.88 Phenyl trimethicone (2) 15.9 Polybutene (3) 7.95 Black iron oxide (4) 6, (1) Dow Corning 556 cosmetic grade fluid from Dow Corning (phenyltrimethylsiloxytrisiloxane-viscosity 20 cSt, MW 372) (2) Wacker's Belsil PDM 1000 (polyphenyltrimethylsiloxy dimethylsiloxane) 1000 cSt viscosity, MW 3000 (3) Indopol H 100 d 'INNOVENE 10 (4) BASF black Sicovit 85 E 172 - Make-up removal test Make-up removal tests are carried out on false eyelash test specimens (black straight Caucasian hair with 19 mm long bangs, mounted between two 30 mm plates over 30 mm). The hair is made up with the composition tested by carrying out 15 passages with the base 1 then 15 passages with the base 2. The specimens are dried for 20 minutes at 37 C. The evaluation of the cleansing efficiency consists of counting the number 20 cottons it takes to completely remove makeup hair bangs. 1g of makeup remover is applied on a cotton, with which the hair fringe is pinched for 10s, then pulled. Chemical name Number of cottons Decamethylcyclopentasiloxane 7 (D5) Isohexadecane 5-6 Octamethyl trisiloxane 3 Decamethyl tetrasiloxane 3-4 Dicaprylyl Ether 6-6 2910296 46 Tests show that volatile linear silicones are more effective at removing makeup from new products than cyclic volatile silicones or volatile hydrocarbon oils.

Example 2: Make-up removal oil Dodecamethylpentasiloxane 40 Decamethyltetrasiloxane 50 PEG-20 glyceryl triisostearate (1) (1) Emalex GWIS-320EX from Nihon Emulsion Procedure: The various compounds are mixed and a makeup-removing oil is obtained. EXAMPLE 3 Cleansing Milk (O / W Emulsion) Al Water QsplOO Glycerin 3 Ammonium Acryloyldimethyltaurate / Steareth-8 0.4 Methacrylate Copolymer (1) A2 2% Soda in Water 0.7 B Decamethyltetrasiloxane 50 Isopropyl Palmitate 10 (1) Aristoflex SNC Clariant Procedure: The various phases are prepared. A2 is added to Al. The phases Al and B are separately heated to about 70 ° C., and phase B is dispersed in the Al + A2 phase, and then cooled.

EXAMPLE 4 Biphase A Decamethyltetrasiloxane Isododecane 10 B Glycerine 0.5 Fragrance 0.01 Decylglucoside (1) 0.1 Mono-potassium phosphate 0.15 Dipotassium phosphate 0.02 Polyaminopropyl biguanide (2) 0.37 Water qs 100 (1) Oramix NS 10 from Seppic (2) Cosmocil CQ from Arch Chemical 2910296 47 Procedure: The constituents of the oily phase on the one hand and those of the aqueous phase on the other hand are mixed. Then, the two phases are shaken. A composition is obtained which, at rest, comprises a distinct aqueous phase and a oily phase. When stirred, the emulsion is formed and no foam appears. After stopping the stirring, the two phases separate quickly. EXAMPLE 5 Cleansing Milk (W / O Emulsion) A. Cetyl PEG / PPG-10/1 Dimethicone (1) 2 Polyglyceryl-4 Isostearate (2) 0.9 Decamethyltetrasiloxane (4) 40 Octamethyltrisiloxane (5) 40 B. Magnesium Sulfate 0.7 Phenoxy ethanol (3) 0.5 Methyl paraben 0.25 Water QSP 100% 10 (1) ABIL EM90 GOLDSCHMIDT (2) ISOLAN GI 34 (3) SEPICIDE LD (4) DOW CORNING 200 FLUID 1.5 CST (5) Dow Corning 200 Fluid 1 cst 15 Procedure: The various phases are prepared. B-phase phase A in phase A is coldly introduced dropwise with stirring.

Claims (56)

  1. A method for removing make-up and / or cleaning makeup films formed by the application to keratin materials (a) of one or more compounds X, (b) of one or more compounds Y, with at least one of compounds X and Y being silicone and said compounds X and Y being capable of reacting together by a hydrosilylation reaction or by a condensation reaction or by a crosslinking reaction in the presence of a peroxide, when they are brought into contact with each other; with each other, and (c) where appropriate at least one catalyst or peroxide, the applications (a), (b) and (c) being able to be simultaneous or sequenced in an indifferent order provided that it is conducive to the interaction of said compounds X and Y, the process comprising at least one step of applying to said makeup films, a makeup removal and / or cleaning composition comprising, in a physiologically acceptable medium, a phase silicone volatile fat comp comprising at least one linear volatile silicone oil, said cleansing and / or cleaning composition comprising at least 50% by weight of oil relative to the total weight of said composition and said oil comprising at least 40% by weight of silicone oil volatile linear relative to the total weight of said composition.   2. Method according to the preceding claim, wherein the makeup films are formed by the application on said keratin materials of at least one composition comprising at least one compound X, at least one compound Y and optionally at least one catalyst or a peroxide.   3. Method according to the preceding claim, wherein the composition is obtained by extemporaneously mixing a first composition comprising at least compound X and a second composition comprising at least compound Y.   4. The method of claim 1, wherein the makeup films are formed by the application on keratin materials, including human skin: - at least one layer of a first composition containing in a physiologically acceptable medium at minus a compound X; at least one layer of a second composition containing, in a physiologically acceptable medium, at least one compound Y, at least one of the compounds X and Y being a silicone compound, said compounds X and Y being capable of react together by a hydrosilylation, condensation or crosslinking reaction in the presence of a peroxide, when they are brought into contact with each other. 5   5. Process according to any one of the preceding claims, in which the linear volatile silicone oil is chosen from linear silicones of formula (I) R 3 SiO- (R 2 SiO) Ri SiR 3 (I), in which R, identical or different, denotes: a hydrocarbon radical, saturated or unsaturated, having from 1 to 10 carbon atoms, preferably from 1 to 6 carbon atoms, optionally substituted by one or more fluorine atoms or by one or more hydroxyl groups, or a hydroxyl group, one of the R radicals possibly being a phenyl group, n is an integer ranging from 0 to 8, preferably ranging from 2 to 6, and better still ranging from 2 to 5, the silicone compound of formula (I) containing not more than 15 carbon atoms.   6. Method according to the preceding claim, wherein the ratio between the number of carbon atoms and the number of silicon atoms in the compound (I) is between 2.25 and 4.33.   7. Process according to any one of the preceding claims, in which the linear volatile silicone oil is chosen from octamethyltrisiloxane, decamethyltetrasiloxane and dodecamethylpentasiloxane, and mixtures thereof. 25   8. Method according to the preceding claim, wherein the linear volatile silicone oil comprises or consists of at least one of the silicone oils decamethyltetrasiloxane and dodecamethylpentasiloxane or their mixture.   9. Method according to the preceding claim, wherein the linear volatile silicone oil consists of a mixture of dodecamethylpentasiloxane and decamethyltetrasiloxane.   10. Process according to any one of the preceding claims, in which the volatile linear silicone oil is present in a content ranging from 40% to 100% by weight, relative to the total weight of the make-up removal composition and / or cleaning, preferably ranging from 50 to 95% by weight, relative to the total weight of the make-up removal and / or cleaning composition.   11. A process according to any one of the preceding claims, wherein the make-up removing and / or cleaning composition further comprises a non-silicone volatile oil.   12. Process according to any one of the preceding claims, in which the make-up removing and / or cleaning composition further comprises at least one non-silicone volatile oil chosen from isoparaffins, isododecane, isodecane and isohexadecane. , isohexyl neopentanoate and mixtures thereof.   13. The method as claimed in any one of the preceding claims, in which the make-up removing and / or cleaning composition further comprises a surfactant chosen from nonionic surfactants, anionic surfactants, amphoteric or zwitterionic surfactants and mixtures thereof. 15   The method of any of the preceding claims, wherein the makeup film or the first or second composition comprises a catalyst.   15. Process according to any one of the preceding claims, characterized in that compounds X and Y are capable of reacting by hydrosilylation. 20   16. Process according to the preceding claim, characterized in that the compound X is chosen from silicone compounds comprising at least two unsaturated aliphatic groups.   17. Process according to the preceding claim, in which the compound X is a polyorganosiloxane comprising a silicone main chain whose unsaturated aliphatic groups are pendant to the main chain (lateral group) or located at the ends of the main chain of the compound (terminal group). ).   18. Method according to the preceding claim, characterized in that the compound X is carrying at least one polar group.   19. Process according to any one of Claims 15 to 18, characterized in that the compound X is chosen from polyorganosiloxanes comprising at least two unsaturated aliphatic groups each bonded to a silicon atom. 2910296 51   20. Process according to any one of claims 15 to 19, characterized in that the compound X is chosen from polyorganosiloxanes comprising silo xane units of formula: R 'Si (I) in which: R represents a monovalent hydrocarbon group , linear or cyclic, comprising from 1 to 30 carbon atoms, m is equal to 1 or 2 and R 'represents: an unsaturated aliphatic hydrocarbon group comprising from 2 to 10, preferably from 3 to 5, carbon atoms or An unsaturated cyclic hydrocarbon group comprising from 5 to 8 carbon atoms.   21. A process according to the preceding claim wherein the polyorganosiloxane of formula (I) is such that R 'represents a vinyl group or a group -R "-CH = CHR"' in which R "is a divalent aliphatic hydrocarbon chain, comprising from 1 to 8 carbon atoms, attached to the silicon atom and R "'is a hydrogen atom or an alkyl radical comprising 1 to 4 carbon atoms, preferably a hydrogen atom. 20   22. The method of claim 20 or 21, characterized in that R represents an alkyl radical comprising 1 to 10 carbon atoms or a phenyl group and is preferably a methyl group and R 'is a vinyl group.   23. Method according to one of claims 17 to 22, characterized in that the polyorganosiloxanes further comprise units of formula: (II) in which R represents a monovalent hydrocarbon group, linear or cyclic, comprising from 1 to 30 atoms of carbon, and n is 1, 2 or 3.   24. Process according to claim 15, characterized in that the compound X is chosen from organic oligomers or polymers, oligomers or organic / silicone hybrid polymers, said oligomers or polymers carrying at least 2 unsaturated aliphatic reactive groups and their mixtures.   25. Process according to one of Claims 15 to 18, characterized in that the compound Y is chosen from organosiloxanes comprising at least two free Si-H 5 groups.   26. Process according to one of Claims 15 to 25, characterized in that the compound Y is chosen from organosiloxanes comprising at least one alkylhydrogenosiloxane unit of the following formula: ## STR1 ## in which: R represents a hydrocarbon-based group monovalent, linear or cyclic, comprising from 1 to 30 carbon atoms or a phenyl group, and p is equal to 1 or 2.   27. Process according to the preceding claim, in which the compound Y is such that the radicals R represent a C1-C10 alkyl group, preferably methyl.   28. Process according to one of claims 25 to 27, in which the organosiloxanes Y comprise at least two alkylhydrogenosiloxane units of formula - (H3C) (H) Si-O- and optionally comprise - (H3C) 2SiO- units.   29. The process according to one of claims 14 to 28, wherein the catalyst is a platinum or tin catalyst.   30. Process according to the preceding claim, characterized in that the catalyst represents from 0.0001% to 20% by weight relative to the total weight of the composition comprising it.   31. Process according to any one of claims 15 to 25, characterized in that the compound X is a polydimethylsiloxane with terminal vinyl groups and the compound Y is a methylhydrogensiloxane.   32. A process according to any one of claims 1 to 14 wherein the compound X and the compound Y are capable of reacting by condensation.   33. Method according to the preceding claim wherein compounds X and / or Y, which are identical or different, are silicone compounds whose main chain comprises at least two alkoxysilane groups and / or at least two silanol groups (Si-OH). , side and / or at the end of the chain.   34. Process according to claim 32 or 33, characterized in that the compounds X and / or Y, which are identical or different, mainly comprise units of formula (IV) in which the Rs independently represent a radical chosen from alkyl groups. comprising 1 to 6 carbon atoms, phenyl, fluorinated alkyl groups, and S is 0, 1, 2 or 3.   35. Method according to the preceding claim characterized in that the compounds X and / or Y, identical or different comprise units of formula (V) wherein R9 is as defined in claim 34, and f ranges from 2 to 5000. 15   36. Process according to one of claims 32 to 35, characterized in that the polyorganosiloxanes comprise at least 2 terminal trialkoxysilane groups per polymer molecule, said groups having the following formula in which the R radicals independently represent a methyl or ethyl group. , n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, R 'is a methyl or ethyl group, x is 0 or 1, preferably x is 0 and Z is selected from: hydrocarbon groups divalents not containing ethylenic unsaturation and comprising from 2 to 18 carbon atoms, the combinations of divalent hydrocarbon radicals and siloxane segments of formula (IX): R '') R9 being as defined in the claim 34, G is a divalent hydrocarbon radical having no ethylenic unsaturation and comprising from 2 to 18 carbon atoms and c is an integer ranging from 1 to 6.   37. Process according to one of claims 32 to 36, characterized in that the polyorganosiloxanes are chosen from the polymers of formula (VII): R1 x R9 R9 1 1 :. Wherein R, R ', R 9, Z, x and f are as defined in claim 34.   38. Process according to claim 32, characterized in that the compound X is chosen from organic oligomers or polymers or hybrid organic / silicone oligomers and polymers, said polymers or oligomers comprising at least two alkoxysilane groups and the compound Y is chosen among the polyorganosiloxanes.   39. Process according to one of claims 32 to 38, containing a titanium-based catalyst.   40. Process according to the preceding claim, characterized in that the catalyst is present in a content ranging from 0.0001% to 20% by weight relative to the total weight of the composition which comprises it.   41. Process according to any one of claims 32 to 40 wherein compounds X and Y represent a mixture of polydimethylsiloxanes containing methoxysilane groups. 20   42. Process according to any one of claims 1 to 14, characterized in that compounds X and Y are capable of reacting by crosslinking in the presence of peroxide.   43. A process according to any one of the preceding claims, in which the compound X carries at least one polar group capable of forming a hydrogen bond with the keratin materials.   44. Process according to any one of the preceding claims comprising in at least one of the compositions a filler chosen from silica or silica treated on the surface. 2910296 55   45. Process according to any one of the preceding claims, characterized in that the compound X has a weight-average molecular weight (Mw) ranging from 150 to 1,000,000, preferably from 200 to 800,000, more preferably from 200 to to 250,000.   46. A process according to any one of the preceding claims, characterized in that the compound Y has a weight-average molecular mass (Mw) of from 200 to 1,000,000, preferably from 300 to 800,000, more preferably from 500 to to 250,000.   47. Process according to any one of the preceding claims, characterized in that the compound X represents from 0.1% to 95% by weight relative to the total weight of the composition containing it, preferably from 1% to 90% by weight. better from 5% to 80%. 10   48. Process according to any one of the preceding claims, characterized in that the compound Y represents from 0.1% to 95% by weight relative to the total weight of the composition containing it, preferably from 1% to 90% by weight. better from 5% to 80%.   49. A process according to any one of the preceding claims, characterized in that compounds X and Y are present in the compositions in an X / Y molar ratio of from 0.05 to 20, and more preferably from 0.1 to 10 .   50. Kit for making up and / or caring for keratinous materials comprising at least two different compositions packaged separately, the kit comprising: at least one compound X, at least one compound Y, and optionally at least one catalyst or peroxide, at at least one of the compounds X and Y being silicone, with the proviso that the compounds X, Y and the catalyst or peroxide when they are present are not simultaneously present in the same composition, said compounds X and Y being capable of reacting together by a hydrosilylation reaction, condensation or crosslinking in the presence of a peroxide, when they are brought into contact with each other, and - a cleansing and / or cleaning composition comprising, in a medium a physiologically acceptable silicone volatile phase comprising at least one linear volatile silicone oil, said cleansing and / or cleaning composition comprising at least 50% by weight s of oil relative to the total weight of said composition and said oil comprising at least 40% by weight of linear volatile silicone oil relative to the total weight of the composition. 20 25 2910296 56   51. Kit according to the preceding claim comprising at least: - a first composition comprising, in a physiologically acceptable medium, at least one compound X, - a second composition comprising, in a physiologically acceptable medium, at least one compound Y, a composition removing makeup and / or cleaning comprising, in a physiologically acceptable medium, a silicone volatile fatty phase comprising at least one linear volatile silicone oil, said make-up removing and / or cleaning composition comprising at least 50% by weight of oil by relative to the total weight of said composition and said oil comprising at least 40% by weight of volatile silicone oil linear relative to the total weight of the composition.   52. Kit according to the preceding claim, wherein the first and second compositions are packaged separately in the same packaging article. 15   53. Kit according to any one of claims 50 to 52, characterized in that it takes the form of a make-up for the lips such as a lipstick, a lip balm, a lip gloss or a pencil. of a complexion product, such as a foundation, a loose or compacted powder, a blush or an eyeshadow, a concealer, a blush, a mascara, an eyeliner or a body makeup product or skin coloring.   54. Kit according to any one of claims 50 to 52, characterized in that it takes the form of a care composition such as a care product for eyelashes, lips, care of the skin of the body and facial, especially a solar product.   55. A kit according to any one of claims 50 to 54, wherein the make-up removing and / or cleaning composition is as defined in any one of claims 5 to 13.   56. Kit according to any one of claims 50 to 55, wherein the cleansing composition and / or cleaning takes the form of a cleansing oil, a cleansing milk or a cleansing emulsion, a product. hygiene, or an exfoliating product.