FR2909872A1 - Cosmetic product useful for makeup and/or care of keratinous materials, comprises a first composition comprising a silicone compound and a second composition comprising hydrocarbon oil and/or silicone oil - Google Patents

Abstract

Cosmetic product for making up and/or caring comprises a first composition comprising a silicone compound comprising silicone elastomer, silicone resins and/or silicone gum having a molecular weight of >= 200000 g/mol, in a medium and a second composition comprising a hydrocarbon oil and/or a silicone oil having a molecular weight of = 20000 g/mol, in a medium, where at least one of two compositions comprises at least a solid particle with the surface treated by a hydrophobic agent. Independent claims are included for: (1) a kit for makeup and/or care comprising the product; and (2) a process for makeup and/or care of keratinous material, preferably skin, lips or integument, comprising applying a layer of a first composition on the keratinous materials and applying a layer of the second composition on at least a part of the applied first composition.

Description

The present invention relates to cosmetic compositions and more

  particularly makeup products and / or care "double-gesture" which consist of applying successively two layers of separate products on the skin of the face as well as the body and / or the human dander.

  Cosmetic compositions, especially makeup compositions such as lipsticks, foundations, body make-up products, concealer, eye shadow or powders, generally comprise fatty substances such as oils and / or oils. waxes, and a particulate phase generally composed of fillers and pigments.  They can thus be in the form of an anhydrous gel, in the form of a stick or stick or in the form of a flexible paste, such as certain foundations, eyeshadows or lipsticks.  They can also be in the form of a powder, which can be free, compacted or pressed.  The makeup compositions may also comprise water or a hydrophilic phase, and may then be in particular in the form of an oil-in-water emulsion, a water-in-oil emulsion or a multiple emulsion, especially when it comes to a foundation, a tinted cream, a care cream or a sun product.  Nail polishes are generally in the form of a solution of an organic solvent.  These compositions, when they are applied to the skin, the mucous membranes or the semi-mucous membranes, do not always exhibit good behavior.  It has indeed been found that some compositions have a tendency to spread within the fine lines and / or wrinkles of the skin, in the case of foundations, in the fine lines that surround the lips, in the case of reds in the folds of the eyelid, in the case of eyeshadow.  In the case of nail polishes, the product sometimes cracks, flakes or is not shock-resistant.  Moreover, when they are applied to keratin materials, especially to the skin, these compositions have the disadvantage of transferring, that is to say, of being deposited at least in part, leaving traces on certain supports. with which they can be put in contact and in particular a glass, a cup, a cigarette, a garment or the skin.  This results in poor performance of the applied film, necessitating regular renewal of the application of the foundation or lipstick composition.  Moreover, the appearance of these traces 2909872 2 unacceptable especially on collar blouse can exclude some women from the use of this type of makeup.  Finally, the appearance of sebum or sweat during the day results in a gradual loss of the homogeneity of the makeup color, and the appearance of glossy areas on the makeup surface.  All these phenomena generate an unsightly effect that we obviously want to avoid.  There is therefore a need for products, especially make-up products, which have improved hold, especially of color and dullness, while possessing good cosmetic properties.  To give satisfaction in these terms, the document EP 1 303 246 proposes to superimpose two cosmetic compositions on the surface to be made up.  In this document, a first composition comprises a pro-adhesive material and a second composition comprises a diffusing compound, for example an oil.  This results in improved holding properties.  The present invention aims to propose new associations in the image of that mentioned above.  Consequently, according to one of its aspects, the invention relates to a cosmetic makeup and / or care product comprising at least: a first composition comprising, in a cosmetologically acceptable medium, at least one silicone compound chosen from elastomers silicone resins, silicone resins and / or silicone gums having a molecular weight greater than or equal to 200,000 g / mol, and - a second composition comprising, in a cosmetologically acceptable medium, at least one hydrocarbon oil and / or silicone oil having a molecular weight less than or equal to 20 000 g / mol, at least one of the two compositions comprising at least one solid particle surface-treated with a hydrophobic agent.  For the purposes of the present invention, the hydrocarbon oils and / or silicone oils having a molecular weight less than or equal to 20,000 g / mol will be referred to hereafter as "plasticizing oils".  The inventors have noticed that the products in accordance with the invention exhibit a significantly reduced fatty and sticky effect compared to the known compositions of the prior art.  Thus, the cosmetic compositions obtained spread easily during their application, allowing a homogeneous deposition of the product on the keratin materials.  The makeup obtained is comfortable, both the application and over time.  The reduction of the transfer and the improvement of the sebum and sweat resistance of the applied product make it possible to obtain a makeup having an improved resistance in time to the color and / or the dullness.  According to another of its aspects, the subject of the invention is a process for makeup and / or cosmetic care, of keratin material (s), in particular of the skin, lips or integuments, comprising at least the steps consisting of: i.  applying to a keratin material, at least one layer of a first composition according to the invention, and ii.  applying to at least a portion of the first composition applied, at least one layer of a second composition according to the invention.  According to another of its aspects, the subject of the invention is a process for the make-up and / or cosmetic care of keratin material (s), in particular the skin, the lips or the integuments, comprising at least the steps consisting of: i.  applying to a support, in particular a keratin material, at least one layer of a second composition according to the invention and ii.  applying to at least a portion of the second applied composition, at least one layer of a first composition according to the invention.  For example, according to these methods, the amounts of the first composition and the second superimposed composition are such that the weight ratio silicone oil (s) and / or hydrocarbon (s) of the second composition / silicone compound of the first composition applied on the support varies from 0.5 to 4, in particular from 1 to 3.5.  Within the meaning of the present invention, the keratinous material on which the compositions are applied may be a natural keratin material such as the skin, the lips and superficial body growths or a fictitious keratin material such as false nails for example.  The order of application of the first and second compositions depends mainly on the type of formulation, namely liquid such as, for example, O / W or W / O emulsion, lotion, stick or solid, for example powder, used for each of the compositions.  For obvious reasons, the final application of a powder composition will be preferred.  In the case where the two compositions are of emulsion type, their order of application is less critical.  When one of them contains materials whose aesthetic effect is to be exploited at the level of the make-up, for example of the dyestuff type, the reflective particles or the goniochromatic agent, it is advantageous to apply it as a top layer. .  On the other hand, when one of these compositions contains an active agent, especially with regard to care, it is, for obvious reasons, preferable to apply it as a base layer.  According to another of its aspects, the invention relates to a makeup kit comprising at least one product according to the invention.  In general, the kit is composed of at least two separate containers, one containing a first composition and the other a second composition.  The compositions may be packaged separately or together in the same packaging article or in two (or more) separate or separate packaging articles.  It is also possible to envisage a single first composition to be associated with several second compositions of different formulations, for example containing different oils and / or a different particulate phase.  In particular, a single first composition may be associated with several second compositions of different colors or consistencies.  Conversely, a single second composition may be associated with several different first compositions.  According to another of its aspects, the subject of the invention is the use of a product or a kit according to the invention for obtaining a make-up and / or care, in particular of the skin, the lips and / or the 30 dander, having a good behavior in time of color and / or dullness.  As stated above, the first composition comprises at least one silicone compound chosen from silicone elastomers, silicone resins and / or silicone gums having a molecular weight greater than or equal to 200,000 g / mol.  Silicone Elastomer According to a preferred embodiment, the silicone compound present in the first composition is a silicone elastomer.  The silicone elastomer may be non-emulsifying or emulsifying.  According to a preferred embodiment, the silicone elastomer present in the first composition is non-emulsifying.  The term "non-emulsifying" silicone elastomers defines organopolysiloxane elastomers that do not contain a hydrophilic chain such as polyoxyalkylene or polyglycerolated units.  The non-emulsifying silicone elastomer is an elastomeric crosslinked organopolysiloxane obtainable by crosslinking addition reaction of diorganopolysiloxane containing at least one silicon-bonded hydrogen and diorganopolysiloxane having silicon-bonded ethylenically unsaturated groups, especially in the presence of a catalyst. platinum; or by condensation-crosslinking dehydrogenation reaction between a hydroxyl-terminated diorganopolysiloxane and a diorganopolysiloxane containing at least one silicon-bonded hydrogen, especially in the presence of an organotin; or by crosslinking condensation reaction of a hydroxyl-terminated diorganopolysiloxane and a hydrolyzable organopolysilane; or by thermal crosslinking of organopolysiloxane, especially in the presence of organoperoxide catalyst; or by crosslinking organopolysiloxane by high energy radiation such as gamma rays, ultraviolet rays, electron beam.  Preferably, the elastomeric crosslinked organopolysiloxane is obtained by crosslinking addition reaction (A2) of diorganopolysiloxane containing at least two hydrogens each bonded to a silicon, and (B2) diorganopolysiloxane having at least two ethylenically unsaturated groups linked to silicon, especially in the presence (C2) of platinum catalyst, as for example described in the application EP-A-295886.  In particular, the organopolysiloxane can be obtained by reaction of dimethylvinylsiloxy-terminated dimethylpolysiloxane and trimethylsiloxy-terminated methylhydrogenpolysiloxane in the presence of platinum catalyst.  The compound (A2) is the basic reagent for the formation of organopolysiloxane elastomer and the crosslinking is carried out by addition reaction of the compound (A2) with the compound (B2) in the presence of the catalyst (C2).  The compound (A2) is advantageously a diorganopolysiloxane having at least two lower alkenyl groups (for example C2-C4); the lower alkenyl group can be chosen from vinyl, allyl and propenyl groups.  These lower alkenyl groups may be located at any position of the organopolysiloxane molecule but are preferably located at the ends of the organopolysiloxane molecule.  The organopolysiloxane (A2) may have a branched chain, linear chain, cyclic or network structure but the linear chain structure is preferred.  The compound (A2) may have a viscosity ranging from the liquid state to the gum state.  Preferably, the compound (A2) has a viscosity of at least 100 centistokes at 25 C.  The organopolysiloxanes (A2) may be chosen from methylvinylsiloxane copolymers, methylvinylsiloxane-dimethylsiloxane, dimethylpolysiloxanes terminally 25 dimethylvinylsiloxy, dimethylsiloxane-methylphenylsiloxane dimethylvinylsiloxy end groups, dimethylsiloxane-diphenylsiloxane-methylvinylsiloxane containing dimethylvinylsiloxy end groups, dimethylsiloxane-methylvinylsiloxane trimethylsiloxy end groups, trimethylsiloxy-terminated dimethylsiloxane-methylphenylsiloxanemethylvinylsiloxane copolymers, dimethylvinylsiloxy-terminated methyl (3,3,3-trifluoropropyl) polysiloxane, and dimethylvinylsiloxy-terminated dimethylsiloxane-methyl (3,3,3-trifluoropropyl) siloxane copolymers.  The compound (B2) is in particular an organopolysiloxane having at least 2 silicon-bonded hydrogens in each molecule and is therefore the crosslinking agent of the compound (A2).  Advantageously, the sum of the number of ethylenic groups per molecule of compound 5 (A2) and the number of silicon-bonded hydrogen atoms per molecule of compound (B2) is at least 4.  Compound (B2) may be in any molecular structure, especially of linear chain structure, branched chain, cyclic structure.  Compound (B2) may have a viscosity at 25 ° C ranging from 1 to 50,000 centistokes, especially to be well miscible with compound (A).  It is advantageous that the compound (B2) is added in an amount such that the molecular ratio between the total amount of silicon-bonded hydrogen atoms in the compound (B2) and the total amount of all ethylenically unsaturated groups in the compound (A2) is in the range of 1/1 to 20/1.  Compound (B2) may be selected from trimethylsiloxy-terminated methylhydrogenpolysiloxanes, trimethylsiloxy-terminated dimethylsiloxane-methylhydrogenosiloxane copolymers, dimethylsiloxane-methylhydrogensiloxane cyclic copolymers.  Compound (C2) is the catalyst for the crosslinking reaction, and is especially chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, platinum black, and platinum on support.  The catalyst (C2) is preferably added from 0.1 to 1000 parts by weight, more preferably from 1 to 100 parts by weight, as clean platinum metal per 1000 parts by weight of the total amount of the compounds (A2) and (B2).  Other organic groups may be silicon-bonded in organopolysiloxanes (A2) and (B2) previously described, such as, for example, alkyl groups such as methyl, ethyl, propyl, butyl, octyl; substituted alkyl groups such as 2-phenylethyl, 2-phenylpropyl, 3,3,3-trifluoropropyl; aryl groups such as phenyl, tolyl, xylyl; substituted aryl groups such as phenylethyl; and substituted monovalent hydrocarbon groups such as an epoxy group, a carboxylate ester group, a mercapto group.  According to a preferred embodiment, the non-emulsifying silicone elastomer is generally mixed with at least one hydrocarbon oil and / or a silicone oil to form a gel.  In these gels, the non-emulsifying elastomer is in the form of non-spherical particles.  Non-emulsifying elastomers are especially described in patents US4970252, US4987169, US 5412004, US5654362, US5760116, in the application JP-A-61-194009.  Non-emulsifying elastomers which can be used are those sold under the names "KSG-6", "KSG-15", "KSG-16", "KSG-18", "KSG-41", "KSG-42", "KSG-43", "KSG-44", "USG-105", "USG-106" by Shin Etsu, "DC 9040", "DC9041", "DC 9509", "DC9505", "DC 9506" "by Dow Corning," GRANSIL "by Grant Industries," SFE 839 "15 by General Electric.  The non-emulsifying elastomers may also be in the form of a powder, in particular in the form of a spherical powder.  The non-emulsifying elastomers may also be in the form of an elastomeric crosslinked organopolysiloxane powder coated with silicone resin, especially silsesquioxane resin, as described, for example, in patent US5538793.  Such elastomers are sold under the names "KSP-100", "KSP-101", "KSP-102", "KSP-103", KSP-104 "," KSP-105 "by Shin Etsu.  Other silicone elastomers in the form of powders may be hybrid silicone powders functionalized with fluoroalkyl groups, especially sold under the name "KSP-200" by the company Shin Etsu; Hybrid silicone powders functionalized with phenyl groups, especially sold under the name "KSP-300" by Shin Etsu.  The non-emulsifying silicone elastomer may be present in the first and / or second composition of the kit according to the invention in an active material content ranging from 0.5% to 20% by weight, relative to the total weight. of the composition, preferably ranging from 1% to 10% by weight, and more preferably ranging from 2% to 7% by weight.  The silicone elastomer present in the first composition may be an emulsifying elastomer.  By emulsifying silicone elastomer is meant a silicone elastomer comprising at least one hydrophilic chain.  The emulsifying silicone elastomer may be chosen from polyoxyalkylenated silicone elastomers.  The polyoxyalkylenated silicone elastomer is a crosslinked organopolysiloxane obtainable by crosslinking addition reaction of diorganopolysiloxane containing at least one silicon-bonded hydrogen and a polyoxyalkylene having at least two ethylenically unsaturated groups.  Preferably, the polyoxyalkylenated crosslinked organopolysiloxane is obtained by a crosslinking addition reaction (Al) of diorganopolysiloxane containing at least two hydrogens each bonded to a silicon, and (B1) of polyoxyalkylene having at least two ethylenically unsaturated groups, in particular presence (Cl) of platinum catalyst, as for example described in US5236986 and US5412004.  In particular, the organopolysiloxane may be obtained by reaction of dimethylvinylsiloxy-terminated polyoxyalkylene (especially polyoxyethylene and / or polyoxypropylene) and trimethylsiloxy-terminated methylhydrogenpolysiloxane in the presence of platinum catalyst.  The organic groups bonded to the silicon atoms of the compound (Al) may be alkyl groups having from 1 to 18 carbon atoms, such as methyl, ethyl, propyl, butyl, octyl, decyl, dodecyl (or lauryl), myristyl, cetyl, stearyl; substituted alkyl groups such as 2-phenylethyl, 2-phenylpropyl, 3,3,3-trifluoropropyl; aryl groups such as phenyl, tolyl, xylyl; substituted aryl groups such as phenylethyl; and substituted monovalent hydrocarbon groups such as an epoxy group, a carboxylate ester group, or a mercapto group.  The compound (A1) can thus be chosen from trimethylsiloxy-terminated methylhydrogenpolysiloxanes, trimethylsiloxy-terminated dimethylsiloxane-methylhydrogenosiloxane copolymers, dimethylsiloxane-methylhydrogensiloxane cyclic copolymers and trimethylsiloxy-terminated dimethylsiloxane-methylhydrogensiloxane-laurylmethylsiloxane copolymers.  Compound (C1) is the catalyst for the crosslinking reaction, and is especially chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, platinum black, and the like. platinum on support.  Advantageously, the polyoxyalkylenated silicone elastomers can be formed from divinyl compounds, in particular polyoxyalkylenes having at least two vinyl groups, reacting with Si-H bonds of a polysiloxane.  According to a preferred embodiment, the polyoxyalkylene silicone elastomer according to the invention can be transported in gel form in at least one hydrocarbon oil and / or a silicone oil.  In these gels, the polyoxyalkylene elastomer is in the form of non-spherical particles.  Polyoxyalkylenated elastomers are especially described in patents US5236986, US5412004, US5837793, US5811487, the contents of which are incorporated by reference.  As the polyoxyalkylene silicone elastomer, those sold under the names "KSG-21", "KSG-20", "KSG-30", "KSG-31", KSG-32 "," KSG-33 "," can be used. KSG-210 ", 30" KSG-240 "," KSG-310 "," KSG-320 "," KSG-330 "," KSG-340 "," X-226146 "by the company Shin Etsu," DC9010 " "DC9011" by Dow Corning.  The emulsifying silicone elastomer may also be selected from polyglycerolated silicone elastomers.  The polyglycerolated silicone elastomer is an elastomeric crosslinked organopolysiloxane obtainable by crosslinking addition reaction of diorganopolysiloxane containing at least one silicon-bonded hydrogen and polyglycerolated compounds having ethylenically unsaturated groups, especially in the presence of platinum catalyst.  Preferably, the crosslinked organopolysiloxane elastomer is obtained by addition reaction crosslinking (A) of diorganopolysiloxane containing at least two hydrogens each bonded to a silicon, and (B) glycerol compounds having at least two ethylenically unsaturated groups, including in the presence (C) of platinum catalyst.  In particular, the organopolysiloxane may be obtained by reaction of dimethylvinylsiloxy-terminated polyglycerol compound and trimethylsiloxy-terminated methylhydrogenpolysiloxane in the presence of platinum catalyst.  Compound (A) is the base reagent for the formation of organopolysiloxane elastomer and the crosslinking is carried out by the addition reaction of the compound (A) with the compound (B) in the presence of the catalyst (C).  The compound (A) is in particular an organopolysiloxane having at least 2 hydrogen atoms bonded to distinct silicon atoms in each molecule.  The compound (A) may have any molecular structure, in particular a linear chain or branched chain structure or a cyclic structure.  The compound (A) may have a viscosity at 25 ° C ranging from 1 to 50,000 centistokes, especially to be well miscible with the compound (B).  The organic groups bonded to the silicon atoms of the compound (A) may be alkyl groups having from 1 to 18 carbon atoms, such as methyl, ethyl, propyl, butyl, octyl, decyl, dodecyl (or lauryl), myristyl, cetyl, stearyl, substituted alkyl groups such as 2-phenylethyl, 2-phenylpropyl, 3,3,3-trifluoropropyl; aryl groups such as phenyl, tolyl, xylyl; substituted aryl groups such as phenylethyl; and substituted monovalent hydrocarbon groups such as an epoxy group, a carboxylate ester group, or a mercapto group.  Preferably, said organic group is chosen from methyl, phenyl and lauryl groups.  The compound (A) may thus be chosen from trimethylsiloxy-terminated methylhydrogenpolysiloxanes, trimethylsiloxy-terminated dimethylsiloxane-methylhydrogenosiloxane copolymers, dimethylsiloxane-methylhydrogensiloxane cyclic copolymers, and trimethylsiloxy-terminated dimethylsiloxane-methylhydrogensiloxane-laurylmethylsiloxane copolymers.  Compound (B) may be a polyglycerolated compound having the following formula (B '): CmH2m-1 -O- [Gly] n-CmH2m-1 (B') wherein m is an integer from 2 to 6 n is an integer from 2 to 200, preferably from 2 to 100, preferably from 2 to 50, preferably n from 2 to 20, preferably from 2 to 10, and preferably from 2 to at 5, and in particular equal to 3; Gly is: -CH2-CH (OH) -CH2-O- or -CH2-CH (CH2OH) -O- Advantageously, the sum of the number of ethylenic groups per molecule of the compound (B) and the number of atoms of hydrogen bonded to silicon atoms per molecule of the compound (A) is at least 4.  It is advantageous that the compound (A) is added in an amount such that the molecular ratio between the total amount of hydrogen atoms bonded to silicon atoms in the compound (A) and the total amount of all the groups ethylenically unsaturated in the compound (B) is in the range of 1/1 to 20/1.  Compound (C) is the catalyst of the crosslinking reaction, and is especially chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, platinum black, and platinum on support.  The catalyst (C) is preferably added from 0.1 to 1000 parts by weight, more preferably from 1 to 100 parts by weight, as clean platinum metal per 1000 parts by weight of the total amount of the compounds (A) and ( B).  According to a particular embodiment, the polyglycerol silicone elastomer according to the invention is generally mixed with at least one hydrocarbon oil and / or a silicone oil to form a gel.  In these gels, the polyglycerolated elastomer is often in the form of non-spherical particles.  Such elastomers are described in particular in the patent application WO2004 / 024798.  As the polyglycerolated silicone elastomers, those sold under the names "KSG-710", "KSG-810", "KSG-820", "KSG-830", "KSG-840" by the company Shin Etsu can be used.  The silicone elastomer (including emulsifying elastomers and non-emulsifiers) may be present in the first and / or second composition of the kit according to the invention in an active material content ranging from 0.5% to 20% by weight, relative to the total weight of the composition, preferably from 1% to 10% by weight, and more preferably from 2% to 7% by weight.  Silicone Gum The first composition according to the invention may comprise at least one silicone gum having a molecular weight greater than or equal to 200,000 g / mol.  Silicone gum or silicone rubber as used herein means a silicone compound with a molecular weight greater than or equal to 200,000 g / mol, in particular ranging from 500,000 to 4,000,000 g / mol. .  The molecular weight of the silicone gums is determined by GPC gel permeation chromatography with a solvent eluent of the silicone gum.  The measurement is carried out at 70 ° C. using Plgel guard 51Ltm and Plgel Mixed-C columns.  The solvent is toluene and / or isododecane.  Calibration is done with a standard homopolymer calibration such as polystyrene.  The silicone gum is advantageously a non-grafted silicone polymer, ie a polymer obtained by polymerization of at least one monomer, without subsequent reaction of the side chains with another chemical compound.  In particular, it is possible to use a gum corresponding to the following formula: ## STR1 ## in which R1, R2, R5 and R6 are, independently of one another, an alkyl radical having 1 to 6 carbon atoms, optionally substituted by at least one fluorine atom, - R3 and R4 are, together or separately, a alkyl radical having 1 to 6 carbon atoms or an aryl radical, especially a phenyl radical, - X is an alkyl radical having 1 to 6 carbon atoms, a hydroxyl radical, an aryl radical, in particular phenyl radical, a vinyl radical, allyl or an alkoxy radical having from 1 to 6 carbon atoms, - n and p are selected such that the silicone compound has a weight average molecular weight of 200,000 g / mol or more.  Mention may more particularly be made of the polymers of formula (I) such that p = 0 and n is between 950 and 60,000, preferably between 2,300 and 30,000.  By way of non-limiting illustration of the silicone gums which are suitable for the invention, mention may especially be made of the following polydiorganosiloxanes: -polydimethylsiloxanes, -poly (dimethylsiloxane) / (methylvinylsiloxane), 5-poly (dimethylsiloxane) / (diphenylsiloxane) Poly (trimethylsiloxane) / (phenylmethylsiloxane)], poly (trimethylsiloxane) / (diphenylsiloxane) / (methylvinylsiloxane)], and mixtures thereof.  As silicone gums which can be used according to the invention, mention may be made more particularly of those corresponding to the general formula (I) in which: the substituents R 1 to R 6 and X represent a methyl group, such as that sold under the name SE30 by the company GENERAL ELECTRIC, that sold under the name AK 500000 by WACKER, and those sold under the name Silastic 4 2007 or 15 SILASTIC SGM-26 GUM by the Dow Corning Company, that sold under the name SILBIONE 70047 V by RHODIA, the substituents R 1, R 2, R 5, R 6 and X represent a methyl group, the substituents R 3 and R 4 represent an aryl group, n and p are such that the molecular weight of the polymer is 600 000 g / mol, such as that sold under the reference 761 by the company Rhodia-Chimie.  High molecular weight dimethicones such as dimethicones described in US Pat. No. 4,152,416.  They are for example marketed under the references SE30, SE33, SE 54 and SE 76 by the company General Electric.  These silicone gums may be commercially available in the form of a mixture with a solvent, in particular a silicone oil.  As examples of these gum / oil mixtures, mention may be made especially of: 1) an end-hydroxylated polydimethylsiloxane (DIMETHICONOL according to the CTFA nomenclature), with a cyclic polydimethylsiloxane (CYCLOMETHICONE according to the CTFA nomenclature), such as the product " Q2 1401 "sold by the Dow CORNING Company; 2) a polydimethylsiloxane gum with a cyclic silicone, such as the product "SF 1214 2909872 16 SILICONE FLUID" from GENERAL ELECTRIC, which is an "SE 30" gum of PM 500. 000 (Mn) solubilized in "SF 1202 SILICONE FLUID" (decamethylcyclopentasiloxane).  According to one aspect of the invention, the first composition according to the invention may comprise from 0.1 to 30% by weight, relative to the total weight of the composition of at least one silicone gum, preferably 0.5 at 10% by weight, or even 1 to 5% by weight.  Resins The first composition according to the invention may comprise at least one silicone resin.  By resin is meant a three-dimensional structure.  Silicone resins can be soluble or swellable in silicone oils.  These resins are crosslinked polyorganosiloxane polymers.  The nomenclature of silicone resins is known as "MDTQ", the resin being described in terms of the different siloxane monomer units it comprises, each of the letters "MDTQ" characterizing a type of unit.  The letter M represents the monofunctional unit of formula (CH 3) 3 SiO 1, 2, the silicon atom being connected to a single oxygen atom in the polymer comprising this unit.  The letter D signifies a difunctional unit (CH 3) 2 SiO 2 12 in which the silicon atom is connected to two oxygen atoms. The letter T represents a trifunctional unit of formula (CH 3) SiO 3 12.  In the units M, D and T defined above, at least one of the methyl groups may be substituted by a group R other than the methyl group such as a hydrocarbon radical (in particular alkyl) having from 2 to 10 carbon atoms or a group phenyl or else a hydroxyl group.  Finally, the letter Q means a tetra-functional unit SiO4 / 2 in which the silicon atom is bonded to four hydrogen atoms, themselves linked to the remainder of the polymer.  Various resins of different properties can be obtained from these different units, the properties of these polymers varying according to the type of monomers (or units), the type and number of substituted radicals, the length of the polymer chain. , the degree of branching and the size of the pendant chains.  By way of example of these silicone resins, mention may be made of: siloxysilicates, which may be trimethylsiloxysilicate of formula [(CH 3) 3XSiXOI X (SiO 412) y (MQ units) in which x and y are integers ranging from 50 to 80, 10 - polysilesquioxanes of formula (CH3SiO312). X (T units) in which x is greater than 100 and at least one of the methyl radicals may be substituted by a group R as defined above; - polymethylsilsesquioxanes which are polysilsesquioxanes in which none of the methyl radicals is substituted; by another group.  Such polymethylsilsesquioxanes are described in US 5,246,694, the contents of which are incorporated by reference.  By way of examples of commercially available polymethylsilsesquioxane resins, mention may be made of those marketed: by the company Wacker under the reference Resin MK such as Belsil PMS MK: polymer comprising repeating units CH3SiO312 (T units), also comprising up to 1% by weight of units (CH 3) 2 SiO 2 O 12 (D units) and having an average molecular weight of about 10,000, - by SHIN-ETSU under the references KR-220L which are composed of T units of the formula CH3SiO312 and have Si-OH end groups (silanol), under the reference KR-242A which comprise 98% of T units and 2% of dimethyl D units and have Si-OH terminal groups or still under reference KR-251 comprising 88% T units and 12% dimethyl D units and have Si-OH end groups.  - By the company TOSHIBA under the reference TOSPEARLTM As resins siloxysilicates include trimethylsiloxysilicate resins (TMS) 30 optionally in the form of powders.  Such resins are sold under the references 2909872 18 SR1000,. E.  1 170-002 or SS 4230, by the company GENERAL ELECTRIC or under the references TMS 803, WACKER 803 and 804 by the company WACKER SILICONE CORPORATION.  Mention may also be made of timethylsiloxysilicate resins sold in a solvent such as cyclomethicone, sold under the name "KF7312J" by the company Shin-Etsu, "DC 749", and "DC 593" by the company Dow Corning.  According to one aspect of the invention, the first composition according to the invention may comprise from 1 to 10%, by weight, relative to its total weight of the composition, of at least one silicone resin, preferably from 1 to 8 % by weight, more preferably from 2 to 4% by weight, and more preferably from 2 to 3% by weight.  SECOND COMPOSITION The second composition according to the invention comprises, as specified above, at least one silicone and / or hydrocarbon oil having a molecular weight less than or equal to 20,000 g / mol.  Silicone oil and / or hydrocarbon oil Silicone oil According to a preferred embodiment, the second composition according to the invention may comprise at least one silicone oil, having in particular a molecular weight ranging from 500 g / mol to 20 000 g / mol, preferably from 500 to 10,000 g / mol.  For the purposes of the present invention, the term "silicone oil" or "silicone oil" means an oil comprising at least one silicon atom, and in particular at least one Si-O group.  The silicone oils that may be used according to the invention may in particular be volatile or nonvolatile linear polydimethylsiloxanes (PDMSs) which are liquid at room temperature; polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, pendant and / or at the end of the silicone chain, groups each having from 2 to 24 carbon atoms; phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, 2-phenylethyl trimethylsiloxysilicates, fluoro silicones with pendant or end groupings having from 1 to 12 carbon atoms of which all or part of the hydrogen atoms is substituted by fluorine atoms, the silicones having hydroxy groups and mixtures thereof.  The silicone oils have a viscosity preferably chosen in the range of from 5 to 10,000 cSt at 25 ° C, preferably from 5 to 5,000 cSt, and more preferably from 5 to 1,000 cSt.  By way of illustration, mention may be made of Dow Corning PDMS DC 200 commercial oils of 5 to 10 cSt.  Hydrocarbon Oil The term "hydrocarbon oil" means an oil containing mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulfur and / or phosphorus atoms.  This hydrocarbon oil may be volatile or non-volatile.  Non-volatile hydrocarbon oils that may especially be mentioned include: - hydrocarbon-based oils of animal origin, - hydrocarbon-based oils of plant origin, such as, for example, triglycerides consisting of esters of fatty acids and of glycerol, the fatty acids of which may have chain lengths varied from C4 to C24, the latter may be linear or branched, saturated or unsaturated; these oils are in particular triglycerides of heptanoic acid or of octanoic acid, or else the oils of wheat germ, sunflower, grape seed, sesame, maize, apricot, shea, avocado, olive, soya, sweet almond, palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, squash, blackcurrant, evening primrose millet, barley, quinoa, rye, safflower, bancoulier, passionflower, muscat rose; or the triglycerides of caprylic / capric acids, such as those sold by the company Stearineries Dubois or those sold under the names MIGLYOL 810, 812 and 818 by the company DYNAMIT NOBEL, 2909872; synthetic ethers having from 10 to 40 carbon atoms; carbon; linear or branched hydrocarbons of mineral or synthetic origin, such as, for example, petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam, isohexadecane, squalane, paraffin oils, and mixtures thereof; synthetic esters such as, for example, the oils of formula R1000R2 in which R1 represents the residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R2 represents a particularly branched hydrocarbon-based chain containing from 1 to 40 carbon atoms at provided that R1 + R2 is 10, such as, for example, purcellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, C15-C15 alcohol benzoates, hexyl laurate, and the like. , diisopropyl adipate, isononyl isononanoate, 2-ethyl-hexyl palmitate, isostearyl isostearate, heptanoates, octanoates, decanoates or ricinoleates of alcohols or polyalcohols such as dioctano propylene glycol ate; polyol esters and pentaerythritol esters.  According to one aspect of the invention, the second composition advantageously comprises from 0.5 to 20% by weight of silicone and / or hydrocarbon oil having a molecular weight less than or equal to 20000 g / mol, preferably from 1 to 17 % by weight, and more preferably from 5 to 15% by weight.  Preferably, the silicone compound (s) present in the first composition and the hydrocarbon and / or silicone oil (s) present in the second composition are brought together in a weight oil ratio. (s) / [gum (s) and / or elastomer and / or resin] ranging from 0.5 to 5, in particular from 1 to 4.  PARTICULATE PHASE Solid particles surface-treated with a hydrophobic agent Any one of the first and / or second composition may comprise at least one solid particle surface-treated with a hydrophobic agent.  According to a preferred embodiment, the solid particles treated on the surface by an agent

  hydrophobic may be present in the applied composition as a top layer. The solid particle surface-treated with a hydrophobic agent may be chosen from pigments, fillers and / or nacres. By pigments, it is necessary to understand white or colored particles, mineral or organic, insoluble in the liquid hydrophilic phase, intended to color and / or opacify the composition. By fillers is meant colorless or white, mineral or synthetic, lamellar or non-lamellar particles. By nacres, it is necessary to understand iridescent particles, in particular produced by some shellfish in their shell or else synthesized. As inorganic pigments which may be used in the invention, mention may be made of titanium, zirconium or cerium oxides as well as oxides of zinc, iron or chromium, ferric blue, manganese violet, ultramarine blue and Chromium hydrate. Among the organic pigments that can be used in the invention, mention may be made of carbon black, D & C type pigments, and lacquers based on cochineal carmine, barium, strontium, calcium, aluminum or diketopyrrolopyrrole. (DPP) described in EP-A-542669, EP-A-787730, EP-A-787731 and WO-A-96/08537. The pigments surface-treated with at least one hydrophobic agent may be present in the first and / or second composition in a content ranging from 1 to 50% by weight, relative to the total weight of the composition, better still from 5 to 30% by weight. % in weight. The nacres may be chosen from white nacres such as mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with, for example, ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. As an illustration of the nacres that can be used in the context of the present invention, mention may be made in particular of the gold-colored nacres sold especially by ENGELHARD under the name Brillant gold 212G (Timica), Gold 222C (Cloisonne) , Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze nacres sold especially by the company Merck under the names Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by Engelhard under the name 10 Super Bronze (Cloisonne); orange nacres sold especially by the company Engelhard under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by the company Merck under the name Passion Orange (Colorona) and Matte Orange (17449) (Microna); the nacres of brown hue sold especially by Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); nacres with a copper sheen sold especially by Engelhard under the name Copper 340A (Timica); the nacres with a red glint sold especially by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents marketed by ENGELHARD under the name Yellow (4502) (Chromalite); nacres of red hue with a gold glint 20 sold by Engelhard under the name Sunstone G012 (Gemtone); pink nacres sold especially by Engelhard under the name Tan opal G005 (Gemtone); black nacres with a gold glint sold especially by ENGELHARD under the name Nu antique bronze 240 AB (Timica), blue nacres sold especially by MERCK under the name Matte bille (17433) (Microna), white nacres to silvery reflection sold especially by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl sold by Merck under the name Indian Summer (Xirona) and their mixtures. The nacres surface-treated with at least one hydrophobic agent may be present in the first and / or second composition in a content ranging from 1 to 50% by weight, relative to the total weight of the composition, better still from 5 to 30% by weight. Finally, the solid particles treated on the surface with at least one hydrophobic agent may be fillers such as, for example, talc, zinc stearate, mica, kaolin, polyamide (nylon) powders (Orgasol from Atochem), polyethylene powders, tetrafluoroethylene (Teflon) polymer powders, starch, boron nitride, polymeric microspheres such as those of polyvinylidene / acrylonitrile chloride such as Expancel 10 (Nobel Industrie), copolymers of acrylic acid (Polytrap from Dow Corning), silicone resin microbeads (Toshiba Tospearls, for example), and elastomeric organopolysiloxanes. The fillers treated at the surface with at least one hydrophobic agent may be present in the first and / or second composition in a content ranging from 1 to 20% by weight, relative to the total weight of the composition, better still from 5 to 15% by weight. % in weight. The solid particles may be totally or partially surface-treated with a compound of a silicone nature, a compound of fluorinated nature, a fluoro-silicone compound, a fatty acid or amino acid, or a mixture thereof. By silicone compound is meant a compound comprising at least one silicon atom. By fluorinated compound is meant a compound comprising at least one fluorine atom. By fluorosilicone compound is meant a compound comprising at least one fluorine atom and at least one silicon atom. The surface-treated solid particles may be prepared according to chemical, electronic, mechano-chemical or mechanical surface-treatment techniques well known to those skilled in the art. Commercial products can also be used. The surfactant can be absorbed or adsorbed onto the solid particles by solvent evaporation, chemical reaction and creation of a covalent bond. According to one variant, the surface treatment consists of a coating of solid particles. The coating may represent from 1 to 300% by weight of the weight of the untreated solid particles, for example from 5 to 200%, in particular from 10 to 100% by weight, of the weight of untreated solid particles. The coating may comprise from 0.1 to 10% by weight, and in particular from 1 to 5% by weight of the total weight of the coated pigment. The coating may be carried out, for example, by adsorption of a liquid surface agent on the surface of the solid particles by simply mixing the particles and said surfactant with stirring, optionally while hot, prior to the incorporation of the particles into the particles. other ingredients of the makeup or care composition. The coating can be carried out for example by chemical reaction of a surfactant with the surface of the solid particles and creation of a covalent bond between the surfactant and the particles. This method is described in particular in US Pat. No. 4,578,266. The chemical surface treatment may consist of diluting the surfactant in a volatile solvent, dispersing the solid particles in this mixture and then slowly evaporating the volatile solvent. so that the surfactant deposits on the surface of the solid particles. Silicone surfactant According to a preferred embodiment, the solid particles may be surface-treated totally or partially with a compound of a silicone nature. The silicone surfactants may be selected from non-elastomeric organopolysiloxanes, silicone elastomers, silane derivatives, silicone acrylate copolymers, silicone resins, and mixtures thereof. By organopolysiloxane compound is meant a compound having a structure comprising an alternation of silicon atoms and oxygen atoms and comprising organic radicals bonded to the silicon atoms. (i) Non-elastomeric organopolysiloxane Non-elastomeric organopolysiloxanes include especially polydimethylsiloxanes, polymethylhydrogensiloxanes and polyalkoxydimethylsiloxanes. The alkoxy group may be represented by the radical RO- such that R represents methyl, ethyl, propyl, butyl or octyl, 2-phenylethyl, 2-phenylpropyl or 3,3,3-trifluoropropyl radicals, aryl radicals such as phenyl , tolyl, xylyl, or substituted aryl radicals such as phenylethyl. One method of surface treating pigments or fillers with a polymethylhydrogenosiloxane is to disperse the pigments or fillers in an organic solvent and then to add the silicone compound. By heating the mixture, covalent bonds are created between the silicone compound and the surface of the solid particle. According to a preferred embodiment, the silicone surface agent may be a non-elastomeric organopolysiloxane, especially chosen from polydimethylsiloxanes. ii) Silicone elastomers The silicone elastomers are in particular those that may be present in the first composition according to the invention, described above. Iii) Alkylsilanes and Alkoxysilanes Alkoxy functional silanes are described in particular by Witucki in Silane Primer, Chemistry and Applications of Alkoxy Silanes, Journal of Coatings Technology, 65, 822, pp. 57-5, 60, 1993. Alkoxysilanes such as alkyltriethoxysilanes and alkyltrimethoxysilanes sold under the references Silquest A-137 (OSI Specialties) and Prosil 9202 (PCR) can be used for the treatment of pigments or fillers. The use of alkylpolysiloxanes having a reactive end group such as alkoxy, hydroxy, halogen, amino or imino are described in JP 077-196946. They are also suitable for the treatment of pigments or fillers. Iv) Silicone-Acrylate Polymers Grafted silicone-acrylic polymers having a silicone backbone as described in US Pat. No. 5,725,882, US 5,209,924, US 4,972,037, US 4,981,903, US 4,981,902, US Pat. US 5,468,477, and US 5,219,560 and EP 0388,582 may be used. Other silicone-acrylate polymers may be silicone polymers having in their structure the following unit of formula (I): ## STR1 ## wherein R (G 2), SiO 3 G 1 (G 2) Wherein G 1 radicals, which may be identical or different, represent hydrogen, a C 1 -C 10 alkyl radical or a phenyl radical; the radicals G2, which may be identical or different, represent a C1-C10 alkylene group; G3 represents a polymeric residue resulting from the (homo) polymerization of at least one ethylenically unsaturated anionic monomer; G4 represents a polymeric residue resulting from the (homo) polymerization of at least one hydrophobic ethylenically unsaturated monomer; m and n are 0 or 1; a is an integer ranging from 0 to 50; b is an integer ranging from 10 to 350, c is an integer from 0 to 50; provided that one of the parameters a and c is different from 0. Preferably, the unit of formula (I) above has at least one, and even more preferably all, of the following characteristics: the radicals G 1 denote an alkyl radical, preferably the methyl radical; n is non-zero, and the radicals G 2 represent a divalent radical C 1 -C 3, preferably a propylene radical; G 3 represents a polymeric radical resulting from the (homo) polymerization of at least one monomer of the ethylenically unsaturated carboxylic acid type, preferably acrylic acid and / or methacrylic acid; - G4 represents a polymeric radical resulting from the (homo) polymerization of at least one monomer of the (meth) acrylate type (C1-C10), preferably of the type (meth) acrylate of isobutyl or methyl. Examples of silicone polymers corresponding to formula (I) are, in particular, polydimethylsiloxanes (PDMS) on which are grafted, via a thiopropylene-type connecting member, mixed polymeric units of the poly (meth) acid type. acrylic and of the poly (meth) acrylate type. Other examples of silicone polymers corresponding to formula (I) are, in particular, polydimethylsiloxanes (PDMS) on which are grafted, by means of a thiopropylene type connecting member, polymeric units of the poly (meth) type. isobutyl acrylate. v) Silicone resins The silicone resins of the silicone surface agent are in particular those that may be present in the first composition according to the invention, described above. By way of example of commercial references of pigments or fillers treated with a silicone compound, mention may be made of: ## STR5 ## The boron nitride / polymethylhydrogenosiloxane sold under the reference UHP 1107 by the company Carborundum, red iron / dimethicone sold under the reference SA-C 338075-10 by Miyoshi Kasei, a pigment obtained by treatment of DC Red 7 with a silicone compound, marketed by Coletica under the reference Gransil GCM (which is a mixture D4 and polysilicone 11), elastomeric crosslinked organopolysiloxane / silicone resin powders, such as those sold under the names "KSP-100", "KSP-101", "KSP-102", "KSP-103 "KSP-104", "KSP-105" by SHIN ETSU Fluorinated surfactant The solid particles can be surface-treated wholly or partially with a fluorinated compound Fluorinated surfactants can be selected from: the perfluoroalkyl phosphates, perfluoropolyethers, polytetrafluoroethylene (PTFE) and perfluoroalkanes. Perfluoropolyethers are described in particular in the patent application EP-A-486135 and sold under the trade names Fomblin by the company Montefluis. Perfluoroalkyl phosphates are in particular described in application JP H05-86984. The perfluoroalkyl phosphate-diethanolamine sold by Asahi Glass under the reference AsahiGuard AG530 can be used. Among the linear perfluoroalkanes, mention may be made of perfluorocycloalkanes, perfluoro (alkylcycloalkanes), perfluoropolycycloalkanes, aromatic perfluorinated hydrocarbons (perfluoroarenes) and hydrocarbonaceous organo-perfluorinated compounds comprising at least one heteroatom. Among the perfluoroalkanes, there can be mentioned the series of linear alkanes such as perfluorooctane, perfluorononane or perfluorodecane. Among the perfluorocycloalkanes and perfluoro (alkylcycloalkanes), there may be mentioned perfluorodecalin sold under the name "FLUTEC PP5 GMP" by the company RHODIA, perfluoro (methyldecalin), perfluoro (C 3 -C 5 alkyl-cyclohexanes) such as perfluoro (butylcyclohexane). Among the perfluoropolycycloalkanes, mention may be made of bicyclo [3.3.1] nonane derivatives such as perfluorotrimethylbicyclo [3.3.1] nonane, adamantane derivatives such as perfluorodimethyladamantane and perfluorinated derivatives of hydrogenated phenanthrene such as tetracosafluoro- tetradecahydrophenanthrene. Among the perfluoroarenes, mention may be made of perfluorinated derivatives of naphthalene such as perfluoronaphthalene and perfluoromethyl-1-naphthalene. By way of example of commercial references of pigments and fillers treated with a fluorinated compound, mention may be made of: yellow iron oxide / perfluoroalkyl phosphate sold under the reference PF 5 Yellow 601 by the company Daito Kasei, The red iron oxide / perfluoroalkyl phosphate sold under the reference PF 5 Red R 516L by the company Daito Kasei, the black iron oxide / perfluoroalkyl phosphate sold under the reference PF 5 Black BL 100 by the company Daito Kasei Titanium dioxide / perfluoroalkyl phosphate sold under the reference PF 5 TiO 2 CR 50 by the company Daito Kasei, 2909872. Yellow iron oxide / perfluoropolymethylisopropylether sold under the reference Iron oxide yellow BF-25-3 by the company Toshiki, - DC Red 7 / perfluoropolymethylisopropylether sold under the reference D & C Red 7 FHC by the company Cardre Inc., 5 -The DC Red 6 / PTFE sold under the reference T 9506 by the company Warner-Jenkinson, - nitride boron / perfluoroperhydrophenanthrene sold under the reference Boron nitride TBN12 by the company Saint Gobain Advanced Ceramics. Fluorosilicone treatment agent The solid particles may be totally or partially surface-treated with a fluoro-silicone compound. The fluoro-silicone compound may be chosen from perfluoroalkyl dimethicones, perfluoroalkyl silanes and perfluoroalkyl trialkoxysilanes. The term "perfluoroalkyl radical" means an alkyl radical in which all the hydrogen atoms have been replaced by fluorine atoms. Perfluoroalkyl silanes include LP-IT and LP-4T products marketed by Shin-Etsu Silicone. The perfluoroalkyl dimethicones may be represented by the following formula: ## STR2 ## wherein R represents a linear or branched divalent alkyl group having from 1 to 6 carbon atoms, preferably a divalent methyl, ethyl, propyl or butyl group; Rf represents a perfluoroalkyl radical, having 1 to 9 carbon atoms, preferably 1 to 4 carbon atoms; m is chosen from 0 to 150, preferably from 20 to 100, and n is chosen from 1 to 300, preferably from 1 to 100. By way of example of commercial references of pigment treated with a fluoro-silicone compound, mention may be made of titanium dioxide / fluorosilicone sold under the reference Fluorosil Titanium dioxide 100TA by Advanced Dermaceuticals International Inc. Fatty acid or amino acid treatment agent The hydrophobic treatment agent may be selected from fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, aluminum salt of hydrogenated tallow glutamate; amino acids; N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acyl amino acids may comprise an acyl group having from 8 to 22 carbon atoms, for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be the aluminum, magnesium, calcium, zirconium, zinc, sodium or potassium salts. The amino acid can be for example lysine, glutamic acid, alanine. The term "alkyl" mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 carbon atoms. By way of example of fatty acid coated pigments, mention may be made of those sold under the commercial reference NAI-C33-8073-10, NAI-C33-8075, NAI-C47-051-10, NAI-C33-115, NAI. C33-134, NAI-C33-8001-10, NAI-C33-7001-10, NAI-C33-9001-10 from MIYOSHI KASEI Company. The solid particles surface-treated with at least one hydrophobic agent can also be present in one of the first and / or second composition in a content ranging from 1 to 50% by weight, relative to the total weight of the composition, more preferably from 5 to 30% by weight. The solid particles surface-treated with at least one hydrophobic agent may also be present simultaneously in the first and second compositions according to the invention. Additional Particle Phase In addition to the solid particles surface-treated with a hydrophobic agent, any of the first and / or second compositions of the invention may comprise an additional particulate phase. The latter may in particular comprise at least one additional pulverulent dyestuff, especially chosen from pigments and / or nacres, and / or at least one additional filler, preferably chosen from the fills defined above. The additional pulverulent dyestuffs may be present in one of the first and / or second compositions in amounts of from 0.1 to 10% by weight, in particular from 0.5 to 7% by weight, and in particular from 1 to 5% by weight. % by weight relative to the weight of the composition. According to a preferred embodiment, the second composition does not comprise additional pulverulent dyestuff which is distinct from the solid particles treated on the surface with a hydrophobic agent. In addition to the additional pulverulent dyestuffs, the first and / or second compositions of the invention may comprise additional fillers. According to a preferred embodiment, the first and / or second compositions may comprise additional fillers in a content ranging from 0.1 to 90% by weight, relative to the total weight of the first composition, in particular 0.5 to 85% by weight. % in weight. Of course, the man will adjust the additional particulate phase levels as a function of the galenic chosen for the first and second compositions. COSMETICALLY ACCEPTABLE MEDIUM In general, the first and second compositions according to the invention comprise, as a support, a cosmetically acceptable medium. By "the first and the second compositions" or "the compositions according to the invention" or "the composition" or all similar formulas, is meant "the first and / or the second composition", the respective formulations of the first and second compositions being partly related to their joint use within the product but also partly independent. Those skilled in the art are well able to judge to what extent and for which aspects the compositions according to the invention are related. By "cosmetically acceptable medium" is meant a medium that is compatible with all the keratin materials such as the skin, the nails, the hair, the eyelashes and eyebrows, the mucous membranes and the mucosae, and any other cutaneous zone of the body and the skin. face. The cosmetically acceptable medium of the first and second compositions according to the invention may comprise a fatty phase, an aqueous phase, an organic solvent phase and / or a particulate phase. Fatty Phase As the second composition contains at least one oil, the first composition may comprise a liquid fatty phase. However, in the case of the first composition, this fatty phase will be free of oil capable of interacting with the silicone compound in the image of the plasticizing oils or at least the rate of this or these oil (s) will be below the rate at which the tackiness of the first composition is maximized when contacted with the second composition. Oils Subject to this condition for the liquid fatty phase of the first composition, the fatty phases of the first and second compositions may comprise one or more oils or solvents cosmetically or dermatologically acceptable, and generally physiologically acceptable. The oil may especially be chosen from oils of mineral, animal, plant or synthetic, silicone, hydrocarbon and / or fluorinated origin, alone or as a mixture insofar as they form a homogeneous and stable mixture and where they are compatible. with the intended use. The oil may be chosen from volatile oils, non-volatile oils, and mixtures thereof. The first and / or second composition according to the invention may comprise at least one volatile oil. By volatile oil is meant within the meaning of the invention any oil capable of evaporating on contact with the skin, at room temperature and atmospheric pressure. The volatile oils of the invention are volatile cosmetic oils which are liquid at ambient temperature and have a non-zero vapor pressure at ambient temperature and atmospheric pressure, in particular ranging from 0.01 to 300 mmHg (1.33 Pa). at 40,000 Pa) and preferably greater than 0.3 mm Hg (30 Pa). The volatile oil may be chosen from volatile hydrocarbon oils, volatile silicone oils, volatile fluoro oils, and mixtures thereof. The term "hydrocarbon oil" means an oil containing mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulfur and / or phosphorus atoms. The volatile hydrocarbon oils may be chosen from hydrocarbon-based oils containing from 8 to 16 carbon atoms, and in particular C8-C16 branched alkanes such as C8-C16 isoalkanes of petroleum origin (also called isoparaffins), such as isododecane. (also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane, and for example the oils sold under the trade names of Isopars or Permethyls. Volatile silicones, such as volatile linear or cyclic silicone oils, especially those having a viscosity, can also be used as volatile oils. <5 centistokes (5 x 10-6 m2 / s), and having in particular 2 to 10 silicon atoms, preferably 2 to 7 silicon atoms, these silicones optionally containing alkyl or alkoxy groups having from 1 to 10 carbon atoms. As volatile silicone oil that may be used in the invention, mention may be made in particular of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl disiloxane, octamethyltrisiloxane, 3-butyl 1,1,1,3,5,5,5-heptamethyl trisiloxane, 3-propyl 1,1,1,3,5,5,5-heptamethyltrisiloxane, 3-ethyl 1,1,1 , 3,5,5,5-heptamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and mixtures thereof. The volatile fluorinated oil generally does not have a flash point. As fluorinated volatile oil, mention may be made of nonafluoroethoxybutane, nonafluoromethoxybutane, decafluoropentane, tetradecafluorohexane and dodecafluoropentane, and mixtures thereof. According to a preferred embodiment, the first composition according to the invention may comprise at least one volatile oil, preferably a volatile silicone oil. The volatile oils may be present in the first and / or second composition according to the invention in a content ranging from 6 to 60% by weight, relative to the total weight of the composition, preferably ranging from 6 to 50% by weight. and more preferably from 6 to 40% by weight. The first and / or second composition according to the invention may comprise at least one non-volatile oil. By "non-volatile oil" is meant an oil remaining on the skin at ambient temperature and atmospheric pressure for at least several hours and having in particular a vapor pressure of less than 0.13 Pa (0.01 mmHg). These non-volatile oils may be hydrocarbon oils, in particular of animal or vegetable origin, silicone oils, or mixtures thereof. The term "hydrocarbon-based oil" means an oil containing mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulfur and / or phosphorus atoms. The non-volatile oils may in particular be chosen from fluorinated hydrocarbon oils which may be fluorinated and / or non-volatile silicone oils. Non-volatile hydrocarbon oils that may especially be mentioned include: - hydrocarbon-based oils of animal origin, - hydrocarbon-based oils of vegetable origin, such as triglycerides consisting of esters of fatty acids and of glycerol, the fatty acids of which may have various chain lengths of C4 to C24, the latter being linear or branched, saturated or unsaturated; these oils are especially triglycerides of heptanoic acid or octanoic acid, or else the oils of wheat germ, sunflower, grape seed, sesame, maize, apricot, castor oil. , shea, avocado, olive, soya, sweet almond, palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, sesame, squash, colza, black currant, evening primrose, millet, barley, quinoa, rye, safflower, bancoulier, passionflower, rosebush; shea butter; or alternatively caprylic / capric acid triglycerides, such as those sold by Stéarineries Dubois or those sold under the names Miglyol 810, 812 and 818 by the company Dynamit Nobel, synthetic ethers having from 10 to 40 carbon atoms; linear or branched hydrocarbons of mineral or synthetic origin, such as petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam, squalane, paraffin oils, and mixtures thereof; synthetic esters, such as oils; of formula R1000R2 in which RI represents the residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R 2 represents a hydrocarbon chain, especially a branched hydrocarbon chain, containing from 1 to 40 carbon atoms, provided that R 1 + R 2 is 10, such as, for example, purcellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, C15 to C15 alcohol benzoates, hexyl laurate, diisopropyl adipate, and the like. isononyl isononanoate, isodecyl neopentanoate, 2-ethyl hexyl palmitate, isostearyl isostearate, 2-hexyl decyl laurate, 2-octyl decyl palmitate, myristate 2 -octyl-dodecyl, heptanoate s, octanoates, decanoates or ricinoleates of alcohols or polyalcohols such as propylene glycol dioctanoate; hydroxylated esters such as isostearyl lactate, diisostearyl malate, 2octyl-dodecyl lactate; esters of polyols and pentaerythritol esters, branched-chain and / or unsaturated carbon-chain-containing liquid fatty alcohols having from 12 to 26 carbon atoms, such as octyl dodecanol, isostearyl alcohol and oleic alcohol, 2-hexyldecanol, 2-butyloctanol, and 2-undecylpentadecanol; higher fatty acids such as oleic acid, linoleic acid, linolenic acid, and mixtures thereof. The non-volatile silicone oils that may be used in the composition according to the invention may be non-volatile polydimethylsiloxanes (PDMS), polydimethylsiloxanes comprising pendant alkyl or alkoxy groups and / or silicone chain ends, groups each having from 2 to 24 carbon atoms. carbon atoms, phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, and mixtures thereof. Preferred nonvolatile hydrocarbon oils are esters of formula R 1000 R 2 wherein R 1 represents the residue of a branched fatty acid having from 6 to 10 carbon atoms and R 2 represents a hydrocarbon chain (or a mixture of hydrocarbon chains) containing from 10 to 18 carbon atoms, preferably from 12 to 16 carbon atoms. The oil (or the mixture of oils) of one of the first and / or second compositions according to the invention may be present in a content ranging from 5 to 80% by weight, relative to the total weight of the first composition, preferably ranging from 6 to 50% by weight and more preferably ranging from 10 to 40% by weight. The person skilled in the art will take care to adjust the oil content according to the galenics envisaged as the first and second composition. According to a preferred embodiment, the second composition according to the invention is free of additional oil distinct from the plasticizing oil described above. Wax, gum or pasty fatty substance The fatty phase of each of the compositions may also comprise at least one wax, at least one gum and / or at least one pasty fatty substance, of vegetable, animal, mineral or synthetic origin, even silicone, and mixtures thereof. Among the waxes solid at room temperature, which may be present in the product according to the invention, mention may be made of hydrocarbon-based waxes such as beeswax, carnauba wax, Candelilla wax, Ouricoury wax, from Japan, cork fiber or sugarcane waxes, paraffin waxes, lignite waxes, microcrystalline waxes, lanolin wax, Montan wax, 5 ozokerites, polyethylene waxes, waxes obtained by Fischer-Tropsch synthesis, hydrogenated oils, fatty esters and glycerides concrete at 25 C. It is also possible to use silicone waxes, among which mention may be made of alkyl, alkoxy and / or polymethylsiloxane esters. The waxes may be in the form of stable dispersions of colloidal wax particles as may be prepared by known methods, such as "Microemulsions Theory and Practice", LM Prince Ed., Academic Press (1977), pages 21-32. As liquid wax at room temperature, mention may be made of Jojoba oil. The waxes may be present in the first and / or second composition in a proportion of 0.1 to 50% by weight, relative to the total weight of the compositions. The cosmetic compositions according to the present invention may also comprise at least one pasty compound. For the purposes of the present invention, the term "pasty" means a fatty compound with a reversible solid / liquid state change and comprising, at a temperature of 23 ° C., a liquid fraction and a solid fraction. Paste is also understood to mean vinyl polylaurate. The pasty compound within the meaning of the invention advantageously has a hardness at C ranging from 0.001 to 0.5 MPa, preferably from 0.002 to 0.4 MPa. Among the pasty compounds that may be used in the composition according to the invention, mention may be made of lanolins and lanolin derivatives, such as acetyl lanolin, oxypropylenated lanolin or isopropyl lanolate, and mixtures thereof. It is also possible to use esters of fatty acids or alcohols, in particular those having from 20 to 65 carbon atoms, for example triisotearyl citrate or cetyl citrate; arachidyl propionate; vinyl polylaurate; esters of cholesterol such as triglycerides of plant origin such as hydrogenated vegetable oils, viscous polyesters and mixtures thereof. As vegetable triglycerides, the hydrogenated castor oil derivatives, such as Rheox's "THIXINR", may be used. The fatty phase of the first and / or second composition can represent from 0.01 to 99%, by weight, relative to the total weight of each of the final compositions. When the second composition according to the invention is a powder, for example for the face, the fatty phase is preferably present at a content ranging from 1 to 30% by weight, relative to the total weight of the second composition. Aqueous Phase or Solvent The compositions according to the invention may comprise at least one non-lipidic liquid medium, and in particular an aqueous phase or an organic solvent phase. The aqueous phase may consist essentially of water or be composed of a mixture of water and at least one water-miscible organic solvent (miscibility in water greater than 50% by weight at 25 ° C.) . Similarly, the compositions according to the invention may comprise at least one organic solvent medium containing at least one volatile organic solvent at room temperature. These organic solvents are more particularly considered when the cosmetic compositions are intended for application to the nails. As organic solvent, which may or may not be volatile, at room temperature, mention may be made of: ketones which are liquid at ambient temperature, such as methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, isophorone, cyclohexanone, acetone; alcohols which are liquid at room temperature, such as ethanol, isopropanol, butanol, diacetone alcohol, 2-butoxyethanol or cyclohexanol; glycols that are liquid at room temperature, such as ethylene glycol, propylene glycol, pentylene glycol or glycerol; Propylene glycol ethers which are liquid at ambient temperature, such as propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate or dipropylene glycol mono-butyl ether; short-chain esters (having from 3 to 8 carbon atoms in total) such as ethyl acetate, methyl acetate, propyl acetate, butyl acetate, acetate of aryl, isopentyl acetate; and - their mixtures. The abovementioned organic compounds may be present in the first and / or second composition in a proportion of 0.5 to 20% by weight, relative to the total weight of the composition. The aqueous phase (water and optionally the water-miscible organic solvent) may be present in the first and / or second composition, in a content ranging from 1 to 90% by weight, relative to the total weight of the composition, in particular ranging from 3 to 80% by weight, and in particular ranging from 5 to 70% by weight. Additional cosmetic ingredients The compositions according to the invention may, in addition, comprise all the complementary ingredients conventionally used in the fields concerned and more particularly in the cosmetic and dermatological field. These ingredients are in particular chosen from water-soluble and liposoluble dyestuffs, vitamins, antioxidants, thickeners, trace elements, softeners, sequestering agents, perfumes, alkalizing or acidifying agents, preservatives, UV filters. hydrophilic or lipophilic active agents and mixtures thereof. The amounts of these various ingredients are those conventionally used in the fields concerned and for example from 0.01 to 20% of the total weight of the composition. Of course, those skilled in the art will take care to choose this or these optional additional ingredients, and / or their quantity, in such a way that the advantageous properties of the corresponding composition according to the invention are not, or not substantially, impaired by the proposed addition. Galenics: Each composition of the product according to the invention may be in any galenical form normally used for topical application and especially in the form of an oily or aqueous solution, an oily or aqueous gel, an in-water or water-in-oil, a multiple emulsion, an oil dispersion in water through vesicles, the vesicles being located at the oil / water interface, or a powder. Each composition may be fluid or solid. The compositions of the product according to the invention can be prepared in the usual manner by those skilled in the art. They may be in the form of a cast product and for example in the form of a stick or stick, in the form of a flexible dough in a hot-water bottle, or in the form of a cup that can be used by direct contact or with a sponge. In particular, they constitute, together or separately, a foundation compacted or cast, blush or eyelids compacted or cast especially colored, lipstick, gloss for the lips, concealer or eye contour. They can also be each in the form of a soft paste of an ointment, an ointment, a lotion or gel, more or less fluid cream. They can then constitute foundations or fluid or pasty lipsticks,

  lip glosses, sunscreen or skin-coloring products, eyeliners, body make-up products, or present care properties and then present themselves in the basic form or lip care balm.

According to a preferred embodiment, the first composition is a composition having an aqueous continuous phase, preferably an oil-in-water (O / W) emulsion and the second composition is a compacted or free powdery composition or a water-in-water emulsion. danshuile.

As stated above, the product according to the invention may be in the form of a kit in which the first (s) and second (s) compositions are generally packaged separately. In addition to the first and second compositions, this kit may contain the means or means necessary for the application of each of the compositions. These means may be brushes, brushes, pens, pencils, feathers, sponges and / or foams. The kit according to the invention may constitute a makeup composition such as skin products and in particular facial skin, foundation products (foundation), blushers, eyelashes, lip products, concealer products, blushes, mascaras, eyeliners, eyebrow makeup products, lip or eye pencils, nail products, such as nail polish, make-up products the body, the products of 2909872 43 hair makeup (mascara or hair spray) or an artificial tanning composition. The kit according to the invention may also be a non-therapeutic care product for the skin of the body and the face, in particular a sunscreen or skin-colored product (such as a self-tanning product). The examples which follow illustrate, in a nonlimiting manner, the first and second compositions according to the invention, as well as the use of a kit according to the invention.

EXAMPLE 1 A first O / W emulsion composition comprising the compounds specified in the table below was prepared. PHASE Name Concentration (wt%) Al Sodium hydroxide 0.182 Demineralized water 1,000 Carboxyvinyl polymer 0.550 in a mixture of ethyl acetate and cyclohexane (4) Preservatives 0.050 Demineralized water 25,000 A3 Iron oxide pigments 3,500 Preservatives 0,700 B EDTA 0.100 Demineralized water 34.418 Cl Silicone elastomer (5) 8.330 Cyclopentadimethylsiloxane 21, 670 Sorbitan monostearate 0.900 oxyethylenated (1) C2 Fatty acid mixture (2) 1,500 Glycerol ester (3) 2,100 TOTAL 100,000 15 (1) sold under the commercial reference TWEEN 60V by UNIKEMA. 2909872 44 (2) sold under the commercial reference PRISTEREN 9559 flakes by the company UNIKEMA. (3) sold under the trade reference SIMULSOL 165 by the company SEPPIC. (4) sold under the commercial reference Carbopol 980 by the company NOVEON. (5) Silicone elastomer mixed in a polydimethylsiloxane (6 cSt) sold under the reference KSG-6 by the company Shin Etsu. Procedure: Sodium hydroxide is solubilized under magnetic stirring in deionized water (Al phase). The carboxyvinyl polymer is sprinkled in demineralized water and dispersed for 1 hour at 70 ° C. with stirring with Rayneri (phase A2). A2 is then mixed with Al. The pigments (A3) are introduced into the mixture Al + A2, with Rayneri stirring. The mixture obtained is then milled, 3 times, to the three-cylinder.

Phase B is prepared by magnetic stirring on a hot plate maintained at 70 ° C. for 10 minutes. After cooling B to room temperature, it is added with Rayneri stirring in A (Al + A2 + A3). The Cl phase is prepared, cold, by introducing the silicone elastomer into the cyclopentadimethylsiloxane in an autoclave with stirring for half an hour.

Phase C2 is prepared by magnetic stirring on a heating plate maintained at 70 ° C. for 10 minutes, then incorporated in the Cl phase. The emulsion is carried out with Rayneri for 10 minutes by addition of the C phase (Cl + C2). in the whole of the aqueous phase (Al + A2 + A3 + B).

EXAMPLE 2 A second powder-like composition was prepared with the compounds specified hereinafter. Phase Name Concentration (wt%) Talc 64.70 Black iron oxide coated with 0.100 silica and polydimethysiloxane (1) Brown iron oxide coated 0.465 silica and polydimethysiloxane (2) A Yellow iron oxide coated with 2.355 silica and polydimethyl silane (3) Titanium dioxide coated with 7,100 silica and polydimethyl siloxane (4) Nylon 12 (5) 10.00 Polymethylsilsesquioxane 5.00 (6) Preservatives 0.30 B PDMS (7) 10.00 TOTAL 100.00 5 ( 1) sold under the reference SA-C 33134-10 by the company MIYOSHI KASEI. (2) sold under the reference SA-LUCE Red by the company MIYOSHI KASEI. (3) sold under the reference SA-LUCE Yellow by MIYOSHI KASEI. (4) sold under the reference SA-LUCE White by MIYOSHI KASEI. 10 (5) sold under the reference ORGASOL 2002 EXD NAT COS 204 by the company ARKEMA. (6) sold under the reference TOSPEARL 145A by the company GE TOSHIBA SILICONES. (7) sold under the reference DC 200 (5 cSt) by the company Dow Corning and having a molecular weight of about 770 g / mol.

Procedure The components of A are mixed with the Baker for five minutes (3000 rpm, 2700 rpm). Then, we add B keeping the same setting of Baker. The mixture of A and B thus obtained is introduced into an Alpine-type apparatus set at 18,000 rpm and then sieved manually at 250 m and compacted between 100 and 120 bar in suitable cups. EXAMPLE 3 A foundation product for skin makeup was made by combining the compositions of Examples 1 and 2. The application of the first composition, followed by the application of the second composition, to the skin the face of a subject provides a matte makeup possessing an improved hold in the time of color and dullness. EXAMPLE 4 A first O / W emulsion composition was prepared comprising the compounds specified in the table below. PHASE Name Concentration (% by weight) 0.10 acrylic acid / crosslinked Al acrylate polymer (1) Demineralized water 12,000 Sodium hydroxide 0.182 Carboxyvinyl polymer 0.500 in a mixture of ethyl acetate A2 and cyclohexane (2) Preservatives 0.050 Demineralized water 15.552 Preservatives 0.700 B EDTA 0.100 Demineralized water 57.556 C PDMS gum (3) 3,300 Isododecane 9,950 TOTAL 100,000 2909872 47 (1) sold under the trade reference PEMULEN TR-2 by the company NOVEON. (2) sold under the commercial reference Carbopol 980 by the company NOVEON. (3) silicone gum sold under the reference SILASTIC 42007 (600 000 g / mol) by the company Dow Corning.

Procedure: The sodium hydroxide is sprinkled in demineralized water and dispersed for 1 hour at 70 ° C. with stirring with Rayneri (Al phase). The carboxyvinyl polymer is sprinkled in demineralized water and dispersed for 1 hour at 70 ° C. with Rayneri stirring (phase A2). A2 is then mixed with Al. Phase B is prepared by magnetic stirring on a heating plate maintained at 70 ° C. for 10 minutes. After cooling to room temperature, it is added with Rayneri stirring in A (Al + A2). Phase C is prepared by solubilizing the silicone gum in isododecane in an autoclave with stirring for half an hour at 110 ° -120 ° C. The emulsion is carried out in the blender for 10 minutes by addition of the C phase in the reaction medium. whole of the aqueous phase (Al + A2 + B).

EXAMPLE 5 A second powder-like composition is prepared with the compounds specified hereinafter. Phase Name Concentration (% by mass) Talc 64.70 A Black iron oxide coated with 0.340 silica and polydimethysiloxane (1) A Brown oxide coated iron oxide 1,012 silica and polydimethysiloxane (2) A Coated yellow iron oxide 1,908 silica and polydimethylsiloxane (3) A titanium dioxide coated with 6,740 silica and polydimethylsiloxane (4) A nylon 12 (5) 10.00 A Polymethylsilsesquioxane 5.00 (6) A Preservatives 0.30 B PDMS (7) 10, 00 TOTAL 100.00 5 (1) sold under the reference SA-C 33134-10 by MIYOSHI KASEI. (2) sold under the reference SALUCE Red by the company MIYOSHI KASEI. (3) sold under the reference SA-LUCE Yellow by MIYOSHI KASEI. (4) sold under the reference SA-LUCE White by MIYOSHI KASEI. 10 (5) sold under the reference ORGASOL 2002 EXD NAT COS 204 by the company ARKEMA. (6) sold under the reference TOSPEARL 145A by the company GE TOSHIBA SILICONES. (7) sold under the reference DC 200 (5 cSt) by the company Dow Corning and with a molecular weight of 770 g / mol.

Procedure The components of A are mixed with Baker for five minutes (3000 rpm, 2700 rpm). Then, we add B keeping the same setting of Baker. The mixture of A and B thus obtained is introduced into an Alpine-type apparatus set at 18,000 rpm and then sieved manually at 250 m and compacted between 100 and 120 bar in suitable cups. EXAMPLE 6 A foundation product for skin makeup is made by combining the compositions of Examples 4 and 5. The application of the first composition, followed by the application of the second composition, to the skin of the skin. a subject's face provides matte makeup with improved color and dullness over time.

Claims (21)

claims   Cosmetic make-up and / or care product comprising at least: a first composition comprising, in a cosmetologically acceptable medium, at least one silicone compound chosen from silicone elastomers, silicone resins and / or silicone gums having a molecular weight greater than or equal to 200 000 g / mol, and - a second composition comprising, in a cosmetologically acceptable medium, at least one hydrocarbon oil and / or a silicone oil having a molecular weight less than or equal to 20 000 g / mol, at least one of the two compositions comprising at least one solid particle surface-treated with a hydrophobic agent.   2. Product according to the preceding claim, characterized in that the silicone elastomer is chosen from non-emulsifying silicone elastomers.   3. Product according to any one of the preceding claims, characterized in that the silicone elastomer is non-spherical.   4. Product according to any one of the preceding claims, characterized in that the silicone elastomer is present in an active material content ranging from 0.5% to 20% by weight, relative to the total weight of the composition, preferably ranging from 1% to 10% by weight, and more preferably ranging from 2% to 7% by weight.   5. Product according to any one of the preceding claims, characterized in that the silicone oil present in the second composition has a molecular weight ranging from 500 g / mol to 20 000 g / mol, preferably from 500 to 10,000 g / mol.   6. Product according to any one of the preceding claims, characterized in that said hydrocarbon oil is selected from hydrocarbon oils of animal origin, hydrocarbon oils of vegetable origin, synthetic ethers having from 10 to 40 carbon atoms. linear or branched hydrocarbons of mineral or synthetic origin, synthetic esters and mixtures thereof.   7. Product according to any one of the preceding claims, characterized in that said silicone oil is a non-volatile silicone oil chosen from non-volatile, linear polydimethylsiloxanes (PDMS), which are liquid at room temperature; polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, pendant and / or at the end of the silicone chain, groups each having from 2 to 24 carbon atoms; phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, 2-phenylethyl trimethylsiloxysilicates, fluorosilicones with a grouping (s) during (s) or end of chain having from 1 to 12 carbon atoms of which all or part of the hydrogen atoms is substituted by fluorine atoms, dimethiconols and mixtures thereof. 15   8. Product according to any one of the preceding claims, characterized in that the hydrocarbon oil and / or silicone is present in the second composition in a content ranging from 0.5 to 20% by weight, relative to the total weight of the composition, preferably 1 to 17% by weight, and more preferably 5 to 15% by weight. 20   9. Product according to any one of the preceding claims, characterized in that the solid particles surface-treated with a hydrophobic agent are chosen from pigments, fillers and / or nacres.   10. Product according to any one of the preceding claims, characterized in that the solid particles are totally or partially surface-treated with a compound of a silicone nature, a compound of a fluorinated nature, a compound of fluoro-silicone nature, an acid fatty acid or amino acid or a mixture thereof.   11. Product according to the preceding claim, characterized in that the silicone surface agent 30 may be a non-elastomeric organopolysiloxane, especially selected from polydimethylsiloxanes. 2909872 52   12. Product according to any one of the preceding claims, characterized in that the solid particles treated at the surface with a hydrophobic agent are present in one of the first and / or second composition in a content ranging from 1 to 50% by weight. , relative to the total weight of the composition, more preferably from 5 to 30% by weight.   13. Product according to any one of the preceding claims, characterized in that at least one of the compositions comprises, in addition to the solid particles treated at the surface with a hydrophobic agent, at least one additional particulate phase comprising at least one material. additional pulverulent dye, especially chosen from pigments and / or nacres, and / or at least one additional filler.   14. Product according to the preceding claim, characterized in that the additional pulverulent dyestuffs are present in one of the first and / or second composition in a proportion of 0.1 to 10% by weight, relative to the weight of the composition. in particular from 0.5 to 7% by weight, and especially from 1 to 5% by weight.   15. Product according to the preceding claim, characterized in that the additional charges are present in the first and / or second composition in a content ranging from 0.1 to 90% by weight, relative to the total weight of the first composition, in particular 0.5 to 85% by weight.   16. Product according to any one of the preceding claims, characterized in that the first composition is in the form of an oil-in-water emulsion and the second composition is in powder form.   17. Kit makeup and / or care, characterized in that it comprises at least one product as defined in claims 1 to 16.   18. Kit according to the preceding claim, characterized in that it is intended for the makeup and / or care of the skin of the face. 25 2909872 53   19. A method of making up and / or cosmetic care of keratinous material (s), in particular of the skin, lips or superficial body growths, comprising at least the steps of: i. applying to a keratin material, at least one layer of a first composition as defined in any one of claims 1 to 4 and 9 to 16, ii. applying to at least a portion of the first composition applied, at least one layer of a second composition as defined according to any one of claims 1 and 5 to 16.   20. Process according to any one of claims 1 to 16 and 19, characterized in that the quantities of first composition and second superimposed composition are such that the weight ratio silicone oil (s) and / or hydrocarbon (s) ( s) of the second composition / silicone compounds of the first composition applied to the support varies from 0.1 to 4, in particular from 0.25 to 2. 15   21. Use of a product or a kit according to any one of claims 1 to 20 to obtain a makeup and / or care, in particular of the skin, the lips and / or superficial body growths, having a good performance in the time of color and / or dullness, and not transferring.