FR2974504A1 - Composition, useful for dyeing keratin fibers, preferably human keratin fibers such as hair, comprises fatty substance, surfactant, oxidation base, 2-hydroxynaphthalene coupler, alkalizing agent and chemical oxidizing agent - Google Patents

Abstract

Composition comprises at least one fatty substance, surfactant, oxidation base, 2-hydroxynaphthalene coupler, alkalizing agent and optionally chemical oxidizing agent, where the amount of fatty substance is at least 25 wt.%. Independent claims are included for: (1) dyeing keratin fibers, preferably human keratin fibers such as hair, comprising applying the composition to the fibers in the presence of chemical oxidizing agent; and (2) a multi-compartment device comprising a first compartment containing the anhydrous composition, at least a second compartment containing the first aqueous composition and at least a third compartment containing the second aqueous composition, where the compositions of the compartments are intended to be mixed together before application to give a composition after mixing the anhydrous composition and the first and the second aqueous composition.

Description

The subject of the present invention is a dyeing composition for keratin fibers, comprising one or more fatty substances and one or more surfactants. one or more oxidation bases and one or more couplers of which at least one coupler is a 2-hydroxynaphthalene derivative, one or more alkalinizing agents, optionally one or more chemical oxidizing agents, and the fat content in the composition representing at least one total at least 25% by weight relative to the total weight of the composition. The present invention also relates to a dyeing method employing this composition and a multi-compartment device, suitable for the implementation of this composition.

For a long time, many people have been trying to change the color of their hair and in particular to hide their white hair. One of the staining modes is the so-called permanent or oxidation coloration which uses dyeing compositions containing oxidation dye precursors, generally known as oxidation bases. These oxidation bases are colorless or weakly colored compounds which, when combined with oxidizing products, can give rise to colored compounds by a process of oxidative condensation. It is also known that the shades obtained with these oxidation bases can be varied by combining them with couplers or color modifiers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols and meta-amines. diphenols and certain heterocyclic compounds such as indole compounds. The variety of molecules involved in the oxidation bases and couplers allows a rich palette of colors to be obtained. It is also possible to use direct dyes to give particular reflections to the coloring obtained. These direct dyes are colored molecules and dyes, having an affinity for the fibers. For example, mention may be made of nitrobenzene, anthraquinone, nitropyridine, azo, xanthene, acridine, azine or triarylmethane direct dyes. The permanent coloring processes therefore consist in using, with the dye composition, an aqueous composition comprising at least one oxidizing agent, under alkaline pH conditions in the vast majority of cases. This oxidizing agent has the role, at least in part, of degrading the melanin of the hair, which, depending on the nature of the oxidizing agent present, leads to a more or less pronounced lightening of the fibers. The oxidizing agent employed is usually hydrogen peroxide. One of the difficulties encountered in carrying out the prior art dyeing processes is that they are carried out under alkaline conditions and that the most commonly used alkalizing agents are ammonia and ammonia. amines. Indeed, the basifying agent makes it possible to adjust the pH of the composition to an alkaline pH to allow the activation of the oxidizing agent. In addition, this basifying agent causes swelling of the keratinous fiber, with uprising of the scales, which promotes the penetration of the oxidant, as well as dyes if they are present, essentially the oxidation dyes, inside. fiber, and thus increases the efficiency of the coloring or lightening reaction. However, these alkalinizing agents and in particular ammonia causes inconvenience to the user because of their strong characteristic odor. Furthermore, the user may be not only bothered by the odor but may also be confronted with greater risks. intolerance, such as irritation of the scalp resulting in particular tingling. It is also important to obtain colorings that resist light. But the use of certain couplers such as meta-phenylene diamines for example induces degradation by solar radiation.

Moreover, it has been proposed in the conventional oxidation dyeing the implementation of naphthalenic couplers in the presence of oxidation bases with relatively photostable shades but with this type of couplers on the one hand the color intensity obtained on the whole of the hair (lengths, points) is rather weak and on the other hand the coverage of the roots is very mediocre.

One of the objectives of the present invention is to provide compositions for staining human keratinous fibers such as the hair which do not have the disadvantages of existing compositions. In particular, the composition according to the invention in the presence of a chemical oxidant makes it possible to obtain satisfactory colors, in particular in terms of covering or raising the color at the root of the hair, which makes it possible to avoid a "root" effect. Coloring. In addition, it is possible to obtain very stable colorations with respect to light.

In addition, the invention makes it possible to achieve significant degrees of lightening while coloring, without using persalts or to force the amount of chemical oxidizing agent or alkalizing agent.

These and other objects are achieved by the present invention which therefore relates to a coloring composition of keratinous fibers, in particular human keratinous fibers such as the hair, comprising: a) one or more fatty substances; b) one or more surfactants; - c) one or more oxidation bases; d) one or more 2-hydroxynaphthalene couplers; e) one or more basifying agents; f) optionally one or more chemical oxidizing agents; and the fat content of a total of at least 25% by weight relative to the total weight of the formulation

The invention also relates to dyeing processes using the composition of the invention containing at least one chemical oxidizing agent, and a multi-compartment device for carrying out the composition of the invention.

Thus, the use of the dyeing composition according to the invention, especially in the presence of a chemical oxidizing agent, leads to powerful, intense, chromatic and / or slightly selective coloring, that is to say dyes which are homogeneous on the along the fiber. The dyeing process of the invention also makes it possible to cover the keratinous fibers at their roots particularly particularly up to three centimeters from the base of said fibers. In addition, the colors obtained after treatment of the fibers remain stable, particularly with respect to light.

The invention also makes it possible to reduce the amounts of active agents of the invention such as dyes and / or alkanilizing agents and / or oxidizing agents. Furthermore, the processes according to the invention implement less smelly formulations when they are applied to the hair or during their preparation.

Other characteristics and advantages of the invention will emerge more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field. The human keratinous fibers treated by the process according to the invention are preferably the hair. The expression "at least one" is equivalent to the expression "one or more". a) Fatty body

As has been mentioned, the composition of the invention comprises a) one or more fatty substances. By "fatty substance" is meant an organic compound that is insoluble in water at ordinary temperature (25 ° C.) and at atmospheric pressure (760 mmHg) (solubility of less than 5% and preferably of 1%, even more preferentially at 0.1%). They have in their structure at least one hydrocarbon chain containing at least 6 carbon atoms or a chain of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same conditions of temperature and pressure, such as, for example, chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran ( THF), petrolatum oil or decamethylcyclopentasiloxane.

Preferably, the fatty substances of the invention do not contain salified or non-salified carboxylic acid groups (COOH or COO-). In particular, the fatty substances of the invention are neither polyoxyalkylenated nor polyglycerolated. By "oil" is meant a "fat" which is liquid at room temperature (25 ° C), and at atmospheric pressure (760 mm Hg). The term "non-silicone oil" means an oil containing no silicon atom (Si) and a "silicone oil" an oil containing at least one silicon atom.

More particularly, the fatty substances are chosen from C 6 -C 16 alkanes, non-silicone oils of animal, vegetable mineral or synthetic origin, fatty alcohols, fatty acid esters and / or fatty alcohol esters, and waxes. non-silicone silicones.

It is recalled that for the purposes of the invention, the alcohols, esters and fatty acids more particularly have at least one hydrocarbon group, linear or branched, saturated or unsaturated, comprising 6 to 30 carbon atoms, which is optionally substituted, in particular by one or more hydroxyl groups (in particular 1 to 4). If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise.

As regards the C6-C16 alkanes, the latter are linear, branched, optionally cyclic. By way of example, mention may be made of hexane, dodecane and isoparaffins, such as isohexadecane and isodecane.

As oils of animal, vegetable, mineral or synthetic origin, which may be used in the composition of the invention, mention may be made, for example, of: 4-hydrocarbon-based oils of animal origin, such as perhydrosqualene. triglyceride oils of vegetable or synthetic origin, such as liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, for example triglycerides of heptanoic or octanoic acids, or else, for example, sunflower, corn, soya, squash, grape seed, sesame, hazelnut, apricot, macadamia, arara, sunflower, castor oil, avocado, caprylic / capric acid triglycerides as sold by the company Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil. linear or branched hydrocarbons, of mineral or synthetic origin, of more than 16 carbon atoms, such as liquid paraffins, petroleum jelly, liquid petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam®. fluorinated oils such as perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names "FLUTEC® PC1" and "FLUTEC® PC3" by BNFL Fluorochemicals; perfluoro-1,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names "PF 5050®" and "PF 5060®" by the company 3M, or bromoperfluorooctyl sold under the name "Foralkyl®" by the company Atochem; nonafluoro-methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives, such as 4-trifluoromethyl perfluoromorpholine sold under the name "PF 5052®" by the company 3M.

The fatty alcohols that are suitable for carrying out the invention are more particularly chosen from linear or branched saturated or unsaturated alcohols containing from 6 to 30 carbon atoms, preferably from 8 to 30 carbon atoms. For example, cetyl alcohol, stearyl alcohol and their mixture (cetylstearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleic alcohol or linoleic alcohol may be mentioned; .

With regard to fatty acid esters and / or fatty alcohols, advantageously different from the triglycerides mentioned previously; mention may be made in particular of saturated or unsaturated, linear or branched C1-C26 aliphatic or monohydric acid esters and saturated or unsaturated, linear or branched C1-C26 aliphatic mono- or polyalcohols, the total number of carbon of the esters being greater or equal to 6, more preferably greater than or equal to 10. Among the monoesters, mention may be made of dihydroabietyl behenate; octyldodecyl behenate; isoketyl behenate; cetyl lactate; C12-C15 alkyl lactate; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; (iso) stearyl octanoate; isocetyl octanoate; octyl octanoate; cetyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; methyl ricinoleate acetyl; myristyl stearate; octyl isononanoate; 2-ethylhexyl isononate; octyl palmitate; octyl pelargonate; octyl stearate; octyldodecyl erucate; oleyl erucate; ethyl and isopropyl palmitates, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate; , styryl, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate.

Still in the context of this variant, it is also possible to use esters of C 4 -C 22 di or tricarboxylic acids and of C 1 -C 22 alcohols and esters of mono di or tricarboxylic acids and di, tri, alcohols. C2-C26 tetra or pentahydroxy. These include: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; di-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythrityl monoricinoleate; pentaerythrityl tetraisononanoate; pentaerythrityl tetrapelargonate; pentaerythrityl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate, tridecyl erucate; triisopropyl citrate; triisotearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate, propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisanonate; and polyethylene glycol distearates. Among the esters mentioned above, it is preferred to use ethyl, isopropyl, myristyl, cetyl, stearyl palmitates, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, myristates of alkyls such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate and isononyl isononanate, cetyl octanoate.

The composition may also comprise, as fatty ester, esters and diesters of C 6 -C 30, preferably C 12 -C 22, fatty acid sugars. It is recalled that "sugar" is understood to mean oxygenated hydrocarbon compounds which have several alcohol functions, with or without an aldehyde or ketone function, and which comprise at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides. Suitable sugars include, for example, sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, lactose, and their derivatives. especially alkylated, such as methylated derivatives such as methylglucose.

The esters of sugars and fatty acids may be chosen in particular from the group comprising the esters or mixtures of esters of sugars described above and of C 6 -C 30, preferably C 12 -C 22 fatty acids, linear or branched, saturated or unsaturated. If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise. The esters according to this variant may also be chosen from mono-, di-, tri- and tetraesters, polyesters and mixtures thereof. These esters may be for example oleate, laurate, palmitate, myristate, behenate, cocoate, stearate, linoleate, linolenate, caprate, arachidonates, or mixtures thereof, such as, in particular, the mixed oleo-palmitate, oleostearate and palmitostearate esters. More particularly, the mono- and di-esters are used, and especially the mono- or dioleate, stearate, behenate, oleopalmitate, linoleate, linolenate, oleostearate, sucrose, glucose or methylglucose.

By way of example, mention may be made of the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate. Mention may also be made, by way of examples, of esters or mixtures of esters of fatty acid sugar: the products sold under the names F160, F140, F110, F90, F70, SL40 by the company Crodesta, respectively denoting sucrose palmito-stearates of 73% monoester and 27% di- and tri-ester, 61% monoester and 39% di-, tri- and tetraester, 52% monoester and 48% monoester; % di-, tri- and tetraester, 45% monoester and 55% di-, tri- and tetraester, 39% monoester and 61% di-, tri-, and tetra. -ester, and sucrose mono-laurate; the products sold under the name Ryoto Sugar Esters, for example referenced B370 and corresponding to sucrose behenate formed from 20% monoester and 80% di-triester-polyester; the sucrose mono-dipalmito-stearate marketed by Goldschmidt under the name Tegosoft® PSE.

The non-silicone wax or waxes are chosen in particular from carnauba wax, candelilla wax, and alfa wax, paraffin wax, ozokerite, vegetable waxes such as olive wax or rice wax. hydrogenated jojoba wax or the absolute waxes of flowers such as the essential wax of blackcurrant sold by the company BERTIN (France), animal waxes such as beeswax, or modified beeswax (cerabellina) ; other waxes or waxy raw materials that can be used according to the invention are, in particular, marine waxes, such as the one sold by SOPHIM under the reference M82, and polyethylene or polyolefin waxes in general.

The silicones that can be used in the cosmetic compositions of the present invention are volatile or cyclic, linear or branched, volatile or non-volatile silicones, modified or not with organic groups, having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. C and preferably 1.10-5 to 1 m2 / s.

The silicones that can be used in accordance with the invention can be in the form of oils, waxes, resins or gums. Preferably, the silicone is chosen from polydialkylsiloxanes, in particular polydimethylsiloxanes (PDMS), and organomodified polysiloxanes comprising at least one functional group chosen from poly (oxyalkylene) groups, amino groups and alkoxy groups. Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968), Academie Press. They can be volatile or nonvolatile. When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic polydialkylsiloxanes containing from 3 to 7, preferably from 4 to 5 silicon atoms. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBONE® 70045 V2 by RHODIA, decamethylcyclopentasiloxane sold under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBONE ® 70045 V5 by RHODIA, as well as their mixtures. Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the VOLATILE® SILICONE FZ 3109 marketed by UNION CARBIDE, of formula: pD "-D 'D" -D'-1 CH3 with D: -Si-O The mixtures of cyclic polydialkylsiloxanes with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 ', may also be mentioned. (hexa-2,2,2 ', 2', 3,3'-trimethylsilyloxy) bis-neopentane; (ii) linear volatile polydialkylsiloxanes having 2 to 9 silicon atoms and having a viscosity of less than or equal to 5 × 10 -6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200 "by the company TORAY SILICONE. Silicones falling into this class are also CH3 with D "-Si-O1CH3 described in the article published in Cosmetics and Toiletries, Vol 91, Jan. 76, p 27-32 - TODD & BYERS Volatile Silicone fluids for cosmetics Non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above organofunctional groups and mixtures thereof are preferably used, and these silicones are more particularly chosen from polydialkylsiloxanes, of which the polydimethylsiloxanes with trimethylsilyl end groups are mainly mentioned.The viscosity of the silicones is measured at 25 ° C. according to ASTM 445 Appendix C.

Among these polydialkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE® oils of the 47 and 70 047 series or the MIRASIL® oils marketed by RHODIA, such as, for example, the 70 047 V 500 000 oil; the oils of the MIRASIL® series marketed by RHODIA; the oils of the 200 series of Dow Corning, such as DC200 having a viscosity of 60,000 mm 2 / s; - VISCASIL® oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC. Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups known under the name of dimethiconol (CTFA), such as the oils of the 48 series from the company RHODIA. In this class of polydialkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX® 9800 and 9801" by GOLDSCHMIDT, which are polydialkyl (C1-C20) siloxanes.

The silicone gums that can be used in accordance with the invention are in particular polydialkylsiloxanes, preferably polydimethylsiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures. More particularly useful products according to the invention are mixtures such as: - mixtures formed from an end-hydroxylated polydimethylsiloxane, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such that the product Q2 1401 marketed by the company Dow Corning; mixtures of a polydimethylsiloxane gum and a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500,000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s. This product preferably comprises 15% of SE gum and 85% of an SF 96 oil. The organopolysiloxane resins that can be used in accordance with the invention are crosslinked siloxane systems containing the units: R 2 SiO 2/2, R 3 SiO 1/2, RSiO 3 / 2 and SiO4 / 2 wherein R represents an alkyl having 1 to 16 carbon atoms. Among these products, those that are particularly preferred are those in which R denotes a C1-C4 lower alkyl group, more particularly methyl.

Among these resins may be mentioned the product marketed under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shin-Etsu. The organomodified silicones that may be used in accordance with the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group. In addition to the silicones described above, the organomodified silicones may be polydiarylsiloxanes, in particular polydiphenylsiloxanes, and polyalkylarylsiloxanes functionalized with the organofunctional groups mentioned above.

The polyalkylarylsiloxanes are especially chosen from polydimethyl / methylphenylsiloxanes, linear and / or branched polydimethyl / diphenylsiloxanes with a viscosity ranging from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C. Among these polyalkylarylsiloxanes include by way of example the products sold under the following names: SILBONE® oils of the 70 641 series from RHODIA; . RHODORSIL® 70 633 and 763 RHODIA series of oils; . DOW CORNING 556 COSMETIC GRAD FLUID oil from DOW CORNING; . silicones of the PK series from BAYER, such as the product PK20; . silicones of the PN and PH series of BAYER, such as the PN1000 and PH1000 products; . certain oils of the SF series of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265. Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally comprising C 6 -alkyl groups; C24 such as the products called dimethicone copolyol marketed by the company Dow Corning under the name DC 1248 or the oils SILWET® L 722, L 7500, L 77, L 711 of the company UNION CARBIDE and the alkyl (C12) -methicone copolyol sold by the company Dow Corning under the name Q2 5200; substituted or unsubstituted amine groups such as the products sold under the name GP 4 Silicone Fluid and GP 7100 by the company Genesee or the products sold under the names Q2 8220 and Dow Corning 929 or 939 by the company Dow Corning. The substituted amino groups are, in particular, C1-C4 aminoalkyl groups; alkoxylated groups, such as the product sold under the name "Silicone Copolymer F-755" by SWS Silicones and Abil Wax® 2428, 2434 and 2440 by the company GOLDSCHMIDT.

Preferably, the fatty substances do not comprise an oxyalkylenated C2-C3 unit or a glycerolated unit. More particularly, the fatty substances are chosen from liquid or pasty compounds at room temperature (25 ° C.) and at atmospheric pressure. Preferably, the fatty substance is a liquid compound at a temperature of 25 ° C. and at atmospheric pressure.

The fatty substances are advantageously chosen from C 6 -C 16 alkanes, non-silicone oils of plant, mineral or synthetic origin, fatty alcohols, fatty acid esters and / or fatty alcohol esters, silicones, or their mixtures.

Preferably, the fatty substance is chosen from liquid petrolatum, C6-C16 alkanes, polydecenes, liquid esters of fatty acid and / or fatty alcohol, liquid fatty alcohols or mixtures thereof. Better still, the fatty substance is chosen from petrolatum oil and C6-C16 alkanes, and polydecenes.

The composition according to the invention comprises at least 25% by weight of fatty substances. The composition according to the invention more particularly has a fat content ranging from 25 to 80% by weight, preferably from 30 to 70% by weight, still more advantageously from 30 to 60% by weight, relative to the weight of the Composition b) Surfactants The composition of the invention also comprises b) one or more surfactants. In particular, the surfactant or surfactants are chosen from anionic, amphoteric, zwitterionic, cationic or nonionic surfactants, and preferentially nonionic surfactants.

The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups -C (O) OH, -C (O) O-, -SO3H, -S (O) 2O-, -OS (O) 2OH, -OS (O) 2O- , -P (O) OH2, -P (O) 2O-, -P (O) O2, -P (OH) 2, = P (O) OH, -P (OH) O-, = P (O) O-, = POH, = PO-, the anionic parts comprising a cationic counterion such as an alkali metal, an alkaline earth metal, or an ammonium.

As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates and alkyl aryl sulphonates. , alpha-olefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, monoester salts alkyl and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether-carboxylic acid salts, alkyl acid salts amidoether carboxylic acids, and the corresponding non-salified forms of all these compounds, alkyl and acyl groups of all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.

The salts of C 6 -C 24 alkyl monoesters and polyglycoside polycarboxylic acids may be chosen from C 6 -C 24 alkyl polyglycoside citrates, C 6 -C 24 alkyl polyglycoside tartrates and polyglycoside sulfosuccinates. C6-C24 alkyl. When the agent or the anionic surfactants are in the salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salts. By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine, the salts of 2-12-amino-2-methyl-1 propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used.

Of the abovementioned anionic surfactants, it is preferred to use (C 6 -C 24) alkyl sulphates, C 6 -C 24 alkyl ether sulphates comprising from 2 to 50 ethylene oxide units, in particular in the form of alkali metal or ammonium salts. , aminoalcohols, and alkaline earth metals, or a mixture of these compounds. In particular, it is preferred to use (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metal salts, ammonium salts, aminoalcohol , and alkaline earth metals, or a mixture of these compounds. More preferably, it is preferred to use sodium lauryl ether sulfate with 2.2 moles of ethylene oxide.

The amphoteric or zwitterionic surfactant (s), preferably non-silicone, which may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain containing from 8 to 8 carbon atoms. at 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate group, sulfonate, sulfate, phosphate or phosphonate. Mention may in particular be made of (C 8 -C 20) alkyl betaines, sulphobetaines, (C 8 -C 20) alkylamido (C 3 -C 8) alkyl betaines and (C 8 -C 20) alkylamidalkyl (C 6 -C) sulphobetaines. . Among the derivatives of secondary or tertiary aliphatic amines, optionally quaternized, which may be used, as defined above, there may also be mentioned the compounds of the following respective structures (Al) and (A2): Ra-C (O) -NH-CH 2 Embedded image in which: Ra represents a C10-C30 alkyl or alkenyl group derived from an acid RaCOOH, from preferably present in hydrolysed coconut oil, a heptyl, nonyl or undecyl group; Rb is a beta-hydroxyethyl group; and Rc is a carboxymethyl group; M + is a cationic counterion derived from an alkaline, alkaline earth metal , such as sodium, an ammonium ion or an ion derived from an organic amine, and X represents an organic or inorganic anionic counterion, such as that selected from halides, acetates, phosphates, nitrates, alkyl (C1-C4) ) sulfates, (C1-C4) alkyl or (C1-C4) alkylsulphonates, in particular methylsulphate and ethylsulfate, or M + and X "are absent; Ra'-C (O) -NH-CH 2 -CH 2 -N (B) (B ') (A2) Formula (A2) wherein: B is the group -CH2-CH2-OX '; B 'represents the group - (CH2) Y', with z = 1 or 2; X 'represents the group -CH2-C (O) OH, -CH2-C (O) OZ', -CH2-CH2-C (O) OH, -CH2-CH2-C (O) OZ ', or hydrogen atom; Y 'represents the group -C (O) OH, -C (O) OZ', -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z '; Z 'represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra, represents a C10-C30 alkyl or alkenyl group of a Ra'-C (O) OH acid preferably present in coconut oil or in hydrolyzed linseed oil, an alkyl group, especially C17 and its iso form, an unsaturated C17 group.

These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, acid lauroamphodipropionic, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate. Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of alkyl (C 8 -C 20) betaines such as cocobetaine, (C 8 -C 20) alkylamido (C 3 -C 8) alkyl betaines such as cocamidopropylbetaine, and their mixtures. More preferably, the amphoteric or zwitterionic surfactant (s) is (are) chosen from cocamidopropylbetaine and cocobetaine.

The cationic surfactant (s) that may be used in the composition according to the invention comprise, for example, primary, secondary or tertiary fatty amine salts, optionally polyoxyalkylenated, quaternary ammonium salts, and mixtures thereof. As quaternary ammonium salts, mention may be made, for example: - those of the following general formula (A4): ## STR2 ## wherein R 1 at R11, which may be identical or different, represent a linear or branched aliphatic group containing from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, it being understood that at least one of the groups R8 to R11 comprise from 8 to at 30 carbon atoms, and preferably from 12 to 24 carbon atoms; and X represents an organic or inorganic anionic counterion, such as that selected from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylaryl- sulfonates, in particular methylsulfate and ethylsulfate.

The aliphatic groups of R8 to R 'may further comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens. The aliphatic groups of R8 to R 'are, for example, chosen from C1-C30alkyl, C1-C30alkoxy, polyoxyalkylene (C2-C6), C1-C30alkylamide, (C12-C22alkyl) amidoalkyl (C2- C6), (C12-C22) alkyl, and C1-C30 hydroxyalkyl, X- is an anionic counterion selected from halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, alkyl (C1-C4) or alkyl (C1-C4) aryl sulfonates. Among the quaternary ammonium salts of formula (A4), tetraalkylammonium chlorides, for example dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group comprises from about 12 to 22 carbon atoms, are preferred. carbon, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium chlorides or secondly distearoylethylhydroxyethylmethylammonium methosulphate, dipalmitoylethylhydroxyethylammonium methosulphate or distearoylethylhydroxyethylammonium methosulphate, or else finally palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl (myristyl acetate) ammonium chloride sold under the name CERAPHYL® 70 by VAN DYK; the quaternary ammonium salts of imidazoline, for example those of the following formula (A5): embedded image in which: R 12 represents an alkenyl or alkyl group comprising from 8 to 30 carbon atoms, for example fatty acid derivatives of tallow; R14 X (A5) - R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group containing from 8 to 30 carbon atoms; R14 represents a C1-C4 alkyl group; - R15 represents a hydrogen atom, a C1-C4 alkyl group; X represents an organic or inorganic anionic counterion, such as that chosen from halides, phosphates, acetates, lactates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylaryl- sulfonates. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl group, R15 denotes a hydrogen atom. Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO; quaternary di- or triammonium salts, in particular of the following formula (A6): ## STR2 ## in which formula (R): alkyl group having about 16 to 30 carbon atoms, optionally hydroxylated and / or interrupted by one or more oxygen atoms; R 17 is chosen from hydrogen, an alkyl group comprising from 1 to 4 carbon atoms or a group - (CH 2) 3 -N + (R 16a) (R 17a) (R 18a), X; R16a, R17a, R16a, R15, R19, R20 and R21, which are identical or different, are chosen from hydrogen and an alkyl group comprising from 1 to 4 carbon atoms; and X-, which may be identical or different, represent an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkyl. -C4) arylsulfonates, in particular methylsulfate and ethylsulfate. Such compounds are, for example, the Finquat CT-P proposed by Finetex (Quaternium 89), the Finquat CT proposed by Finetex (Quaternium 75); quaternary ammonium salts containing one or more ester functions, such as those of the following formula (A7) 2+ 2X X / (CsH2s) z R25 O-CrHr2 (OH) ry 1 N + CtHt2 (OH) t.0 JX R23 R22 (A7) Formula (A7) wherein: R22 is selected from C1-C6 alkyl and hydroxyalkyl or C1-C6 dihydroxyalkyl, R23 is selected from: O - R26 C - R27 hydrocarbon groups C1-C22, linear or branched, saturated or unsaturated, - the hydrogen atom, R25 is chosen from: O II - the group R28 C - R29 hydrocarbon groups C1-C6, linear or branched, saturated or unsaturated - The hydrogen atom, R24, R26 and R28, identical or different, are chosen from linear or branched, saturated or unsaturated C7-C21 hydrocarbon groups; r, s and t, which are identical or different, are integers from 2 to 6, where r1 and t1 are identical or different and are 0 or 1 with r2 + r1 = 2r and t1 + t2 = 2t ^ y is an integer from 1 to 10, ^ x and z, which may be identical or different, are integers ranging from 0 to 10, X "represents an anionic counterion, organic or inorganic, provided that the sum x + y + z is from 1 to 15 that when x is 0 then R23 is R27 and that when z is 0 then R25 is R29.The alkyl groups R22 may be linear or branched, and more preferably linear.R22 is preferably a methyl, ethyl, hydroxyethyl or dihydroxypropyl group. , and more particularly a methyl or ethyl group. Advantageously, the sum x + y + z is from 1 to 10. When R23 is a hydrocarbon R27 group, it may be long and have from 12 to 22 carbon atoms, or short and When R25 is a hydrocarbon R29 group, it preferably has 1 to 3 carbon atoms. with 3 carbon atoms R24 Advantageously, R24, R26 and R28, which may be identical or different, are chosen from linear or branched, saturated or unsaturated C11-C21 hydrocarbon groups, and more particularly from C11 alkyl and alkenyl groups. -C21, linear or branched, saturated or unsaturated.

Preferably, x and z, which are identical or different, are equal to 0 or 1. Advantageously, y is equal to 1. Preferably, r, s and t, identical or different, are equal to 2 or 3, and even more particularly are equal to 2 The anionic counterion X "is preferably a halide, such as chloride, bromide or iodide, a (C 1 -C 4) alkyl sulphate, a (C 1 -C 4) alkyl or (C 1 -C 4) alkyl aryl sulphonate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function. is even more particularly chloride, methylsulfate or ethylsulfate. In the composition according to the invention, the ammonium salts of formula (A7) are used more particularly in which: R 22 denotes a methyl or ethyl group, x and y are equal to 1, z is equal to or 1; r, s and t are equal to 2, - R23 is chosen from: O - the group R26 - the methyl, ethyl or C14-C22 hydrocarbon groups, - the hydrogen atom, - R25 is chosen from: O - the group R2 C - the hydrogen atom, - R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C13-C17 hydrocarbon groups, and preferably from alkyl groups and C13-C17 alkenyl, linear or branched, saturated or unsaturated. Advantageously, the hydrocarbon radicals are linear. Examples of compounds of formula (A7) include salts, especially diacyloxyethyldimethylammonium, diacyloxyethylhydroxyethylmethylammonium chloride, monoacyloxyethyldihydroxyethylmethylammonium chloride, triacyloxyethylmethylammonium chloride, monoacyloxyethylhydroxyethyldimethylammonium salt, and mixtures thereof. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different.

These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine optionally oxyalkylenated on fatty acids or mixtures of fatty acids of plant or animal origin, or by transesterification. of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide, preferably methyl or ethyl, a dialkyl sulphate, preferably methyl or ethyl sulphate. methyl methanesulfonate, methyl para-toluenesulfonate, glycol or glycerol chlorohydrin. Such compounds are, for example, sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWOWITCO. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180. The behenoylhydroxypropyltrimethylammonium chloride proposed by KAO can be used under the name Quatarmin BTC 131.

Preferably the ammonium salts containing at least one ester function contain two ester functions.

Among the cationic surfactants that may be present in the composition according to the invention, it is more particularly preferred to choose the salts of cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethylhydroxyethylmethylammonium, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, dipalmitoylethylhydroxyethylammonium methosulfate, and mixtures thereof. Examples of nonionic surfactants useful in the composition used according to the invention are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp. 116-178. They are chosen in particular from alcohols, alpha-diols and (C 1 -C 20) alkyl phenols, these compounds being polyethoxylated, polypropoxylated and / or polyglycerolated, and having at least one fatty chain comprising, for example, from 8 to 18 carbon atoms, the number of ethylene oxide groups and / or propylene oxide ranging in particular from 2 to 50 and the number of glycerol groups ranging in particular from 2 to 30. Mention may also be made of ethylene and propylene, esters of optionally oxyethylenated fatty and sorbitan acids, sucrose fatty acid esters, polyoxyalkylenated fatty acid esters, optionally oxyalkylenated alkylpolyglycosides, alkylglucoside esters, N -alkylglucamine and N-acyl-methylglucamine, aldobionamides and amine oxides. The nonionic surfactants are more particularly chosen from mono or polyoxyalkylenated, mono- or polyglycerolated nonionic surfactants. The oxyalkylenated units are more particularly oxyethylenated units, oxypropylene, or their combination, preferably oxyethylenated.

As examples of oxyalkylenated nonionic surfactants, mention may be made of: oxyalkylenated (C 8 -C 24) alkyl phenols; - C8-C30 alcohols, saturated or unsaturated, linear or branched, oxyalkylenated; - C8-C30 amides, saturated or unsaturated, linear or branched, oxyalkylenated; saturated or unsaturated linear or branched C 8 -C 30 acid esters of polyethylene glycols; saturated or unsaturated, linear or branched C 8 -C 30 acid esters of polyoxyethylenated sorbitol; vegetable oils oxyethylenated, saturated or not; condensates of ethylene oxide and / or propylene oxide, among others, alone or in mixtures. Oxyethylenated and / or oxypropylenated silicones. Surfactants having a number of moles of ethylene oxide and / or propylene of between 1 and 100, preferably between 2 and 50, preferably between 2 and 30. Advantageously, the nonionic surfactants do not comprise oxypropylene units.

According to a preferred embodiment of the invention, the oxyalkylenated nonionic surfactants are chosen from oxyethylenated C 8 -C 30 alcohols comprising from 1 to 100 moles of ethylene oxide; linear or branched, saturated or unsaturated C8-C30 acid esters, and polyoxyethylenated sorbitol esters comprising from 1 to 100 moles of ethylene oxide.

By way of example of mono- or poly-glycerolated nonionic surfactants, the C 8 -C 40 mono- or polyglycerolated alcohols are preferably used. In particular, mono- or polyglycerolated C 8 -C 40 alcohols correspond to the following formula (A 8): R 29 O- [CH 2 -CH (CH 2 OH) -O], nH (A 8) Formula (A 8) in which: R 29 represents a linear or branched C8-C40, preferably C8-C30, alkyl or alkenyl radical; and m represents a number ranging from 1 to 30 and preferably from 1 to 10. By way of example of compounds of formula (A8) which are suitable in the context of the invention, mention may be made of 4-lauryl alcohol. glycerol moles (INCI name: POLYGLYCERYL-4 LAURYL ETHER), lauric alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol to 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol to 2 moles of glycerol, cetearyl alcohol to 6 moles of glycerol, oleocetyl alcohol to 6 moles of glycerol, and octadecanol to 6 moles of glycerol. The alcohol of formula (A8) may represent a mixture of alcohols in the same way that the value of m represents a statistical value, which means that in a commercial product several species of polyglycerolated fatty alcohols may coexist in the form of a mixed. Among the mono- or poly-glycerolated alcohols, it is more particularly preferred to use the C 8 / C alcohol, one mole of glycerol, the C 10 / C 12 alcohol with 1 mole of glycerol and the alcohol with 12 to 1 , 5 moles of glycerol.

Preferably, the surfactant used in the process of the invention in the composition is a mono or polyoxyalkylene nonionic surfactant, especially mono or polyoxyethylenated, mono or polyoxypropylenated, or a combination thereof, more particularly mono or polyoxyethylenes.

Preferably, the surfactant or surfactants are chosen from nonionic surfactants or from anionic surfactants. More particularly, the surfactant (s) present in the composition are chosen from nonionic surfactants.

Even more preferentially, the nonionic surfactants are chosen from polyoxyethylenated sorbitol esters and polyoxyethylenated fatty alcohols, and mixtures thereof.

In the composition of the invention, the amount of the surfactant (s) in the composition preferably ranges from 0.1 to 50% by weight, more preferably from 0.5 to 20% by weight, relative to the total weight of the composition. c) Basis of oxidation:

The composition of the invention comprises c) one or more oxidation bases chosen in particular from heterocyclic bases, benzene bases and their addition salts. The benzene oxidation bases according to the invention are particularly chosen from paraphenylenediamines, bis-phenylalkylenediamines, para-aminophenols, ortho-aminophenols, and their addition salts. Among the paraphenylenediamines, there may be mentioned, for example, para-phenylenediamine, paratoluylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl-para-phenylenediamine, N, N-dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N, N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N- bis - ([3-hydroxyethyl) paraphenylenediamine, 4-N, N-bis (13-hydroxyethyl) amino-2-methylaniline, 4-N, N-bis- (13-hydroxyethyl) amino-2-chloroaniline, 2-13-hydroxyethyl paraphenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N- (13-hydroxypropyl) -paraphenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3-methyl-para-phenylenediamine, N, N- (ethyl, [3-hydroxyethyl) paraphenylenediamine, N - ([3, ydihydroxypropyl) paraphenylenediamine, N- (4'-aminophenyl) paraphenylenediamine, N-phenyl-para-phenylenediamine, 2-13-hydroxyethyloxy-para-phenylenediamine, 2-13-acetylaminoethyloxy-para-phenylenediamine, N- (13-methoxyethyl) para-phenylenediamine, 4-aminophenylpyrrolidine, 2-thienyl paraphenylenediamine, 2- (3-hydroxyethylamino) -amino toluene, 3-hydroxy-1- (4'-aminophenyl) pyrrolidine and their addition salts with an acid. Among the paraphenylenediamines mentioned above, paraphenylenediamine, paratoluylenediamine, 2-isopropyl paraphenylenediamine, 2-13-hydroxyethyl paraphenylenediamine, 2- [3-hydroxyethyloxy paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2, 6-diethyl paraphenylenediamine, 2,3-dimethyl paraphenylenediamine, N, N-bis- (13-hydroxyethyl) paraphenylenediamine, 2-chloro-para-phenylenediamine, 2- [3-acetylaminoethyloxy-para-phenylenediamine, and their addition salts with a acid are particularly preferred. Among the bis-phenylalkylenediamines, mention may be made, by way of example, of N, N'-bis- (13-hydroxyethyl) N, N'-bis- (4'-aminophenyl) 1,3-diamino propanol, N N, N'-bis ((3-hydroxyethyl) N, N'-bis- (4'-aminophenyl) ethylenediamine, N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis- (13-hydroxyethyl) N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (4-methylaminophenyl) tetramethylenediamine, N, N'-bis (ethyl) N, N Bis (4'-amino, 3'-methylphenyl) ethylenediamine, 1,8-bis (2,5-diamino phenoxy) -3,6-dioxaoctane, and their addition salts. Among para-aminophenols, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4- amino 3-hydroxymethyl phenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2 - ([ 3-hydroxyethylaminomethyl) phenol, 4-amino-2-fluoro phenol, and their addition salts with an acid. Among the ortho-aminophenols, mention may be made, for example, of 2-amino phenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and their addition salts.

The heterocyclic bases according to the invention are more particularly chosen from pyridine derivatives, pyrimidine derivatives and pyrazole derivatives and their addition salts.

Among the pyridine derivatives, mention may be made of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5-diamino pyridine, 2- (4-methoxyphenyl) amino-3-amino pyridine, 3,4-diamino pyridine, and their addition salts. Other pyridinic oxidation bases which are useful in the dyeing process according to the invention are the 3-amino pyrazolo [1,5-a] -pyridines oxidation bases or their addition salts, described for example in the application Patent FR 2801308. By way of example, mention may be made of pyrazolo [1,5-a] pyridin-3-ylamine; 2-acetylamino pyrazolo [1,5-a] pyridin-3-ylamine; 2-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 3-aminopyrazolo [1,5-a] pyridin-2-carboxylic acid; 2-methoxy-pyrazolo [1,5-a] pyridin-3-ylamino; (3-amino-pyrazolo [1,5-a] pyridin-7-yl) -methanol; 2- (3-Amino-pyrazolo [1,5-a] pyridin-5-yl) -ethanol; 2- (3-Amino-pyrazolo [1,5-a] pyridin-7-yl) -ethanol; (3-Amino-pyrazolo [1,5-a] pyridin-2-yl) -methanol; 3,6-diamino-pyrazolo [1,5-a] pyridine; 3,4-diaminopyrazolo [1,5-a] pyridine; pyrazolo [1,5-a] pyridine-3,7-diamine; 7-morpholin-4-ylpyrazolo [1,5-a] pyridin-3-ylamine; pyrazolo [1,5-a] pyridine-3,5-diamine; 5-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 2 - [(3-amino-pyrazolo [1,5-a] pyridin-5-yl) - (2-hydroxyethyl) amino] ethanol; 2 - [(3-amino-pyrazolo [1,5-a] pyridin-7-yl) - (2-hydroxyethyl) amino] ethanol; 3-amino-pyrazolo [1,5-a] pyridin-5-ol; 3-Amino-pyrazolo [1,5-a] pyridin-4-ol; 3-amino-pyrazolo [1,5-a] pyridin-6-ol; 3-aminopyrazolo [1,5-a] pyridin-7-ol; as well as their addition salts. Among the pyrimidine derivatives, mention may be made of the compounds described, for example, in DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy 2,5,6-triaminopyrimidine, 2-hydroxy 4,5,6-triaminopyrimidine, , 4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and tautomeric forms, when tautomeric equilibrium exists.

Among the pyrazole derivatives, mention may be made of the compounds described in DE 3843892, DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988 as the 4.5 1-methyl pyrazole, 4,5-diamino 1 - ([3-hydroxyethyl) pyrazole, 3,4-diamino pyrazole, 4,5-diamino 1- (4'-chlorobenzyl) pyrazole, 4, 5-diamino 1,3-dimethyl pyrazole, 4,5-diamino-3-methyl-1-phenylpyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl-5-hydrazino pyrazole, 1-benzyl 4,5-diamino-3-methyl pyrazole, 4,5-diamino-3-tert-butyl-1-methyl pyrazole, 4,5-diamino-1-tert-butyl-3-methyl pyrazole, 4 5-diamino 1 - ([3-hydroxyethyl) 3-methylpyrazole, 4,5-diamino-1-ethyl-3-methylpyrazole, 4,5-diamino-1-ethyl-3- (4'-methoxyphenyl) pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-methyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-isopropyl pyrazole, 4,5-diamino-3- mét 1-isopropyl pyrazole, 4-amino-5- (2'-aminoethyl) amino-1,3-dimethyl pyrazole, 3,4,5-triamino pyrazole, 1-methyl-3,4,5-triamino pyrazole, 3,5-diamino-1-methyl-4-methylamino pyrazole, 3,5-diamino 4 - ([3-hydroxyethyl) amino-1-methyl pyrazole, and their addition salts. It is also possible to use 4-5-diamino 1- (3-methoxyethyl) pyrazole. Preferably, a 4,5-diaminopyrazole and even more preferably 4,5-diamino-1 - ([3-hydroxyethyl) pyrazole and / or one of its salts will be used. As pyrazole derivatives, mention may also be made of diamino N, N-dihydropyrazolopyrazolones and in particular those described in application FR-A-2 886 136 such as the following compounds and their addition salts: 2,3-diamino-6 7-Dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] ] pyrazol-1-one, 2-amino-3-isopropylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3- (pyrrolidin-1) -yl) -6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 4,5-diamino-1,2-dimethyl-1,2-dihydro-pyrazol-3- one, 4,5-diamino-1,2-diethyl-1,2-dihydro-pyrazol-3-one, 4,5-diamino-1,2-di- (2-hydroxyethyl) -1,2-dihydro- pyrazol-3-one, 2-amino-3- (2-hydroxyethyl) amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3- dimethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2,3-diamino-5,6,7,8-tetrahydro-1H, 6H-pyridazino [ 1,2-a] pyrazol-1-one, 4-amino-1,2-diethyl-5- (pyrrolidin-1-yl) -1,2-dihydro-pyrazol-3-one, 4-amino-5- (3-dimethyl 1-amino-pyrrolidin-1-yl) -1,2-diethyl-1,2-dihydro-pyrazol-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H, 5H-pyrazolo [ 1,2-a] pyrazol-1-one. It will be preferred to use 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one and / or a salt thereof. As heterocyclic bases, 4,5-diamino-1 - ([3-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2] will preferably be used. a] pyrazol-1-one and / or a salt thereof.

The oxidation base (s) according to the invention are each advantageously from 0.0001 to 10% by weight relative to the total weight of the composition, and preferably from 0.005 to 5% by weight relative to the total weight of the composition. D) Couplers and 2-hydroxynaphthalene derivatives:

The cosmetic composition according to the invention comprises d) one or more 2-hydroxynaphthalene couplers By 2-hydroxynaphthalenic couplers is meant couplers with a 2-hydroxynaphthalenic unit whose hydroxyl group at the 2-position is free or blocked by a hydrolysable function. Among the 2-hydroxynaphthalenic couplers that may be mentioned those of formula (B4) as well as their salts, their optical isomers, geometrical, tautomers and their hydrates; Formula (B4) wherein: R2, R3, R4 and R5, the same or different, represent an atom or a group selected from: i) hydrogen; ii) halogen such as chlorine or bromine; iii) hydroxyl; iv) NRaRb with Ra and Rb, identical or different, represent a hydrogen atom or a (C 1 -C 8) alkyl group optionally substituted with a hydroxyl group or a (di) (C 1 -C 8) (alkyl) group amino; or Ra, Rb with the nitrogen atom together form a mono or polycyclic heterocycle, saturated or partially unsaturated, comprising from 3 to 10 members and from 1 to 5 heteroatoms selected from oxygen, nitrogen, sulfur, sulfoxide S (0) ) and S (O) 2 sulfone, the heterocycle may be substituted by a (C 1 -C 4) alkyl group or an oxo group, particularly the heterocycle is selected from morpholino, piperidino and piperazino; v) (C 1 -C 8) alkyl optionally substituted by one or more atoms or groups selected from halogen such as fluorine, hydroxyl, cyano, carboxy and amino NRaRb as defined above; vi) (C1-C8) alkoxy; vii) (C 1 -C 8) alkyl-S (O) p with p = 0, 1 or 2; viii) aryl such as phenyl; (B4) ix) mono or polycyclic heterocycle, saturated or partially unsaturated, comprising from 3 to 10 members and from 1 to 5 heteroatoms selected from oxygen, nitrogen, sulfur, sulfoxide S (O) and sulfone S (O) 2, heterocycle may be substituted by a (C 1 -C 4) alkyl group or an oxo group, particularly the heterocycle is selected from morpholinyl, piperidinyl and piperazinyl; x) aryloxy such as phenoxy; xi) cyano -CN; xii) carboxy -C (O) OM with M representing a hydrogen atom, a (C 1 -C 8) alkyl group or a cation derived from alkali metal, alkaline earth metal, or an organic cation such as ammonium; xiii) -S (O) (OM) 2 or -O-S (O) (OM) 2 with M as defined above; xiv) -C (O) NRaRb or -NRa-C (O) Rb with Ra and Rb, as previously defined; xv) -S (O) n-NRaRb or -NRa-S (O) n-Rb with n being 1 or 2 and Ra and Rb as defined above; or two contiguous radicals R2 and R3 and / or R 'and R5 and / or R4 and R5 together with the carbon atom to which each is attached, a (hetero) ring, or optionally substituted (hetero) aryl; preferentially together form a benzo group; R6 represents a hydrogen atom, a hydrolyzable protecting group of the hydroxyl group such as -C (X) -R7 with X denoting an oxygen or sulfur atom, particularly oxygen, and R7 denoting a hydrogen atom, or a (C 1 -C 8) alkyl group; preferentially R6 represents a hydrogen atom.

According to one particular embodiment of the invention, the 2-hydroxynaphthalenic coupler (s) of formula (B4) are such that R ', R2, R3, R4 and R5, which are identical or different, represent a hydrogen or halogen atom. such that bromine preferably in position 1 or 3, a hydroxyl group preferably in position 3 or 7, cyano preferentially in position 6, or (C 1 -C 8) alkoxy preferentially in position 3, 4, 6 or 7.

More particularly, the 2-hydroxynaphthalenic coupler (s) of formula (B4) are such that: R 'represents a (C 1 -C 6) alkyloxy group such as methoxy, preferably in position 6 or 7; and R2, R3, R4 and R5 represent a hydrogen atom; or else - R3 represents a (C 1 -C 6) alkyloxy group such as methoxy, preferably in position 3 or 4; and R2, R4 and R5 represent a hydrogen atom; or else - R3 represents a halogen atom such as brominated preferably in position 1 or 2; and R2, R4 and R5 represent a hydrogen atom; or else - R4 represents a cyano group preferably in position 4; and R2, R3 and R5 represent a hydrogen atom; or else - R2, R3, R4 and R5 represent a hydrogen atom.

Examples of 2-hydroxynaphthalene couplers according to the invention include the following compounds: ## STR5 ## 2-Naphtol (6): 2,3-dihydroxy-O: 6-methoxy-2-naphthol naphthalene (7): 2, 7-dihydroxynaphthalene (8): 3-bromo-2-naphthol (9): 1-bromo-2-naphthol NEC OH (10): 6-cyano-2-naphthol The 2-hydroxynaphthalene coupler (s), each advantageously represents 0.0001 to 10% by weight relative to the total weight of the composition, and preferably from 0.005 to 5% by weight relative to the total weight of the composition of the invention.

Additional couplers

The composition of the invention may comprise one or more couplers different from the 2-hydroxynaphthalene derivatives.

Among these non-2-hydroxynaphthalene couplers, there may be mentioned in particular meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene couplers other than 2-hydroxynaphthalene couplers, heterocyclic couplers and their addition salts. By way of example, mention may be made of 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene and 2,4-diamino-1- (13- hydroxyethyloxy) benzene, 2-amino 4- (13-hydroxyethylamino) 1-methoxybenzene, 1,3-diamino benzene, 1,3-bis (2,4-diaminophenoxy) propane, 3-ureido aniline, 3-ureido-dimethylamino benzene, sesamol, 1-13-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy N-methylindole, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine 3,5-diamino-2,6-dimethoxypyridine, 1-N- (R-hydroxyethyl) amino-3 , 4-methylene dioxybenzene, 2,6-bis- (13-hydroxyethylamino) toluene, 6-hydroxy indoline, 2,6-dihydroxy-4-methyl pyridine, 1-H 3 -methyl pyrazole 5-one, 1-phenyl-3-methyl pyrazole-5-one, 2,6-dimethyl pyrazolo [1,5-b] -1,2,4-triazole, 2,6-dimethyl [3,2-c] -1, 2,4-triazole, 6-methyl pyrazolo [1,5-a] benzimidazole, their addition salts with an acid, and mixtures thereof. The additional coupler (s) are each advantageously from 0.0001 to 10% by weight relative to the total weight of the composition, and preferably from 0.005 to 5% by weight relative to the total weight of the composition of the invention.

In general, the addition salts of the oxidation bases and couplers that can be used in the context of the invention are chosen especially from the addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.

Additional dyes

The composition of the invention may further comprise one or more direct dyes. The latter are more particularly chosen from ionic or nonionic species, preferably cationic or nonionic species. These direct dyes can be synthetic or of natural origin. As examples of suitable direct dyes, mention may be made of azo direct dyes; methinic; carbonyls; azinic; nitro (hetero) aryl; tri- (hetero) aryl methanes; porphyrins; phthalocyanines and natural direct dyes, alone or in mixtures. More particularly, the azo dyes comprise a function -N = N- whose two nitrogen atoms are not simultaneously engaged in a ring. However, it is not excluded that one of the two nitrogen atoms of the sequence -N = N- is engaged in a cycle. The dyes of the family of methines are more particularly compounds comprising at least one sequence chosen from> C = C <and -N = C <whose two atoms are not simultaneously engaged in a ring. It is however specified that one of the nitrogen or carbon atoms of the chains can be engaged in a cycle. More particularly, the dyes of this family are derived from methine, azomethine, mono- and di-arylmethane compounds, indoamines (or diphenylamines), indophenols, indoanilines, carbocyanines, azacabocyanines and their isomers, diazacarbocyanines and their isomers, tetraazacarbocyanines, hemicyanines. As regards the dyes of the carbonyl family, mention may be made, for example, of the dyes chosen from acridone, benzoquinone, anthraquinone, naphthoquinone, benzanthrone, anthranthrone, pyranthrone, pyrazolanthrone, pyrimidinoanthrone, flavanthrone, idanthrone, flavone, (iso) violanthrone, isoindolinone, benzimidazolone, isoquinolinone, anthrapyridone, pyrazoloquinazolone, perinone, quinacridone, quinophthalone, indigo, thioindigo, naphthalimide, anthrapyrimidine, diketopyrrolopyrrole, coumarin. As regards the dyes of the family of cyclic azines, there may be mentioned in particular azine, xanthene, thioxanthene, fluorindine, acridine, (di) oxazine, (di) thiazine, pyronine.

The nitro (hetero) aromatic dyes are more particularly nitrobenzene or nitro pyridinic direct dyes. With regard to porphyrin or phthalocyanine dyes, it is possible to use cationic or non-cationic compounds, optionally comprising one or more metals or metal ions, for example alkali and alkaline earth metals, zinc and silicon. By way of example of particularly suitable direct dyes, mention may be made of the nitro dyes of the benzene series; azo direct dyes; azomethines; methinic; azacarbocyanines such as tetraazacarbocyanines (tetraazapentamethines); quinone direct dyes and in particular anthraquinone, naphthoquinone or benzoquinone dyes; direct azine dyes; xanthenics; triarylmethanics; indoamines; indigoids; phthalocyanines, porphyrins and natural direct dyes, alone or in mixtures.

Among the natural direct dyes that may be used according to the invention, lawsone, juglone, alizarin, purpurine, carminic acid, kermesic acid, purpurogalline, protocatechaldehyde, indigo, isatin , curcumin, spinulosin, apigenidine, orceins. It is also possible to use the extracts or decoctions containing these natural dyes, and in particular poultices or extracts made from henna.

When present, the direct dye (s) more particularly represent from 0.0001 to 10% by weight of the total weight of the composition, and preferably from 0.005 to 5% by weight.

e) Alkalinizing Agents: The composition of the invention further comprises e) one or more basifying agents. The basifying agent (s) may be inorganic or organic or hybrid. The inorganic alkalinizing agent (s) is (are) preferably chosen from ammonia, alkali carbonates or bicarbonates, such as sodium or potassium carbonates or bicarbonates, sodium or potassium hydroxides, or mixtures thereof. The organic basifying agent (s) are preferably chosen from organic amines whose pKb at 25 ° C. is less than 12, and preferably less than 10, and even more advantageously less than 6. It should be noted that this is pKb corresponding to the highest basicity function. In addition, the organic amines do not comprise a fatty chain, alkyl or alkenyl, comprising more than ten carbon atoms. The organic basifying agent (s) are, for example, chosen from alkanolamines, ethylenediamines which are oxyethylenated and / or oxypropylenated, amino acids and compounds of the following formula (I): ## STR2 ## wherein W is a divalent C1-C6 alkylene radical optionally substituted by one or more hydroxyl groups or a C1-C6 alkyl radical, and / or optionally interrupted by one or more heteroatoms such as O, or NRu; RX, Ry, RZ, Rt, Ru and the same or different, represent a hydrogen atom, a C1-C6 alkyl or C1-C6 hydroxyalkyl, C1-C6 aminoalkyl radical. Examples of amines of formula (I) are 1,3-diaminopropane, 1,3-diaminopropanol, spermine and spermidine.

By alkanolamine is meant an organic amine comprising a primary, secondary or tertiary amine function, and one or more linear or branched C1-C8 alkyl groups carrying one or more hydroxyl radicals.

In particular, the organic amines chosen from alkanolamines, such as mono-, di- or trialkanolamines, comprising one to three identical or different C1-C4 hydroxyalkyl radicals, are suitable in particular for carrying out the invention. Among compounds of this type, mention may be made of monoethanolamine (MEA), diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N-dimethylaminoethanolamine, 2-amino-2-methyl-1-propanol and triisopropanolamine. 2-amino-2-methyl-1,3-propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-1,2-propanediol, tris-hydroxymethylamino-methane.

More particularly, the amino acids that can be used are of natural or synthetic origin, in their L, D, or racemic form, and comprise at least one acid function chosen more particularly from the carboxylic, sulphonic, phosphonic or phosphoric acid functions. Amino acids can be in neutral or ionic form.

As amino acids that may be used in the present invention, mention may in particular be made of aspartic acid, glutamic acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine and cysteine. , glutamine, glycine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine.

Advantageously, the amino acids are basic amino acids comprising an additional amine function optionally included in a ring or in a ureido function. Such basic amino acids are preferably chosen from those corresponding to the following formula (II): ## STR2 ## Formula (II) in which R represents a group chosen from: N NHJ; - (CH2) 3NH2, - (CH2) 2NH2; - (CH2) 2NHCONH2; and - (CH 2) 2 NH -NH 2 NH The compounds corresponding to formula (II) are histidine, lysine, arginine, ornithine, citrulline. The organic amine may also be selected from heterocyclic organic amines. In addition to the histidine already mentioned in the 30 amino acids, mention may be made especially of pyridine, piperidine, imidazole, triazole, tetrazole and benzimidazole.

The organic amine may also be selected from amino acid dipeptides. As amino acid dipeptides that can be used in the present invention, mention may be made in particular of carnosine, anserin and whale.

The organic amine may also be selected from compounds having a guanidine function. As amino amines of this type which can be used in the present invention, mention may in addition be made of arginine already mentioned as amino acid, creatine, creatinine, 1,1-dimethylguanidine, 1,1 diethylguanidine, glycocyamine, metformin, agmatine, n-amidinoalanine, 3-guanidino-propionic acid, 4-guanidinobutyric acid and 2 - ([amino (imino) methyl] amino acid) ethane-1-sulfonic acid. As hybrid compounds, mention may be made of the salts of the amines mentioned above with acids such as carbonic acid and hydrochloric acid. In particular, guanidine carbonate or monoethanolamine hydrochloride can be used.

Preferably, the alkalinizing agent (s) present in the composition of the invention are chosen from alkanolamines, amino acids in neutral or ionic form, in particular basic amino acids, and preferably corresponding to those of formula (II). Even more preferentially, the alkalinizing agent (s) are chosen from monoethanolamine (MEA) and basic amino acids, in neutral or ionic form.

Advantageously, the composition according to the invention has a content of alkalinizing agent (s) ranging from 0.01 to 30% by weight, preferably from 0.1 to 20% by weight relative to the weight of the composition According to a first particular embodiment, the composition does not contain ammonia or one of its salts or the process according to the invention does not use ammonia or a salt thereof, as an agent. alkalizing. According to another particular embodiment, if however the composition or the method used it, advantageously its content would not exceed 0.03% by weight (expressed in NH 3), preferably would not exceed 0.01% by weight, relative to weight of the composition of the invention. Preferably, if the composition comprises ammonia or a salt thereof, then the amount of alkalinizing agent (s) other than ammonia is greater than that of ammonia (expressed as NH 3). ) Chemical oxidizing agent

The composition of the invention may further comprise f) one or more chemical oxidizing agents. The term "chemical oxidizing agent" means an oxidizing agent different from the oxygen in the air. Preferably, the composition of the invention contains one or more chemical oxidizing agents. More particularly, the chemical oxidizing agent (s) is (are) chosen from hydrogen peroxide, urea peroxide, alkali metal bromates, peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors and percarbonates. This oxidizing agent is advantageously constituted by hydrogen peroxide and in particular in aqueous solution (hydrogen peroxide), the concentration of which may vary, more particularly from 0.1 to 50% by weight, and even more preferentially. from 0.5 to 20% by weight, better still from 1 to 15% by weight relative to the weight of the composition.

Preferably, the composition of the invention does not contain peroxygenated salts.

Solvent

The composition according to the invention may also comprise one or more organic solvents. Examples of organic solvents that may be mentioned include linear or branched C 2 -C 4 alkanols, such as ethanol and isopropanol; glycerol; polyols and polyol ethers such as 2-butoxyethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, diethylene glycol monoethyl ether and monomethyl ether, and aromatic alcohols or ethers such as benzyl alcohol or phenoxyethanol, and mixtures thereof . The solvent or solvents, if present, represent a content usually ranging from 1 to 40% by weight relative to the weight of the composition and preferably from 5 to 30% by weight. The composition according to the invention may also contain various adjuvants conventionally used in compositions for dyeing hair, such as anionic, cationic, nonionic, amphoteric or zwitterionic polymers, or mixtures thereof; mineral thickeners, and in particular fillers such as clays, talc; organic thickeners, in particular anionic, cationic, nonionic and amphoteric polymeric associative thickeners; antioxidants; penetrants; sequestering agents; perfumes ; dispersants; film-forming agents; ceramides; preservatives; opacifying agents. The adjuvants above are generally present in an amount for each of them between 0.01 and 20% by weight relative to the weight of the composition. The composition may especially comprise one or more inorganic thickening agents chosen from organophilic clays. fumed silicas, or mixtures thereof. The organophilic clay may be selected from montmorillonite, bentonite, hectorite, attapulgite, sepiolite, and mixtures thereof. The clay is preferably a bentonite or a hectorite. These clays can be modified with a chemical compound chosen from quaternary amines, tertiary amines, amino acetates, imidazolines, amine soaps, fatty sulphates, alkyl aryl sulphonates, amine oxides, and mixtures thereof. As organophilic clays, mention may be made of quaternium-18 bentonites such as those sold under the names Bentone 3, Bentone 38, Bentone 38V by Rheox, Tixogel VP by United catalyst, Claytone 34, Claytone 40, Claytone XL by Southern Clay Company; stearalkonium bentonites such as those sold under the names Bentone 27 by Rheox, Tixogel LG by United Catalyst, Claytone AF, Claytone APA by Southern Clay; quaternium-18 / benzalkonium bentonite such as those sold under the names Claytone HT, Claytone PS by Southern Clay. The fumed silicas can be obtained by high temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, producing a finely divided silica. This process makes it possible in particular to obtain hydrophilic silicas which have a large number of silanol groups on their surface. Such hydrophilic silicas are, for example, sold under the names "AEROSIL 130®", "AEROSIL 200®", "AEROSIL 255®", "AEROSIL 300®", "AEROSIL 380®" by the company Degussa, "CAB-O- SIL HS-5® "," CAB-O-SIL EH-5® "," CAB-O-SIL LM-130® "," CAB-O-SIL MS-55® "," CAB-O-SIL M -5® "by the company Cabot. It is possible to chemically modify the surface of the silica by chemical reaction in order to reduce the number of silanol groups. In particular, it is possible to substitute silanol groups with hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups may be: trimethylsiloxyl groups, which are especially obtained by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are referred to as "Silica silylate" according to the CTFA (2nd edition, 1995). They are for example marketed under the references "AEROSIL R812®" by the company Degussa, "CABO-SIL TS-530®" by Cabot. - Dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained in particular by treatment of fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are called "Silica dimethyl silylate" according to the CTFA (heme edition, 1995). They are for example sold under the references "AEROSIL R972®", "AEROSIL R974®" by the company Degussa, "CAB-O-SIL TS-610®", "CAB-O-SIL TS-720®" by the company Pooch.

The fumed silica preferably has a particle size that may be nanometric to micrometric, for example ranging from about 5 to 200 nm. Preferably, the composition comprises a hectorite, an organomodified bentonite or an optionally modified pyrogenic silica. When present, the mineral thickening agent represents from 1 to 30% by weight relative to the weight of the composition. The composition may also include one or more organic thickeners. These thickening agents may be chosen from fatty acid amides (diethanol or coconut monoethanol amide, oxyethylenated alkyl ether carboxylic acid monoethanolamide), polymeric thickeners such as cellulosic thickeners (hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose), guar gum and its derivatives (hydroxypropylguar), gums of microbial origin (xanthan gum, scleroglucan gum), crosslinked homopolymers of acrylic acid or acrylamidopropanesulfonic acid and associative polymers (polymers comprising hydrophilic zones, and fatty-chain hydrophobic zones (alkyl, alkenyl comprising at least 10 carbon atoms) capable, in an aqueous medium, of reversibly associating with each other or with other molecules). According to one particular embodiment, the organic thickener is chosen from cellulose thickeners (hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose), guar gum and its derivatives (hydroxypropylguar), gums of microbial origin (xanthan gum, scleroglucan gum). ), the crosslinked homopolymers of acrylic acid or acrylamidopropanesulfonic acid, and preferably from cellulosic thickeners with in particular hydroxyethylcellulose.

The content of organic thickening agent (s), if present, usually ranges from 0.01% to 20% by weight, based on the weight of the composition, preferably from 0.1 to 5% by weight.

The composition of the invention may be in various forms, such as, for example, a solution, an emulsion (milk or cream) or a gel.

Methods of the invention

The composition according to the invention comprising the ingredients a) to f) as defined above is applied to dry or moist keratin fibers. It is left in place on the fibers for a duration, generally from 1 minute to 1 hour, preferably from 5 minutes to 30 minutes. The temperature during the dyeing process is typically between room temperature (between 15 and 25 ° C) and 80 ° C, preferably between room temperature and 60 ° C. At the end of the treatment, the human keratin fibers are optionally rinsed with water, optionally washed with a shampoo followed by rinsing with water, before being dried or allowed to dry. The composition according to the invention is generally prepared by mixing at least two compositions. In a first variant of the invention, the composition according to the invention comprising the ingredients a) to f) as defined above, is derived from the mixture of two compositions: a composition (A) comprising c) at least one base d oxidation as defined above; d) at least one 2-hydroxynaphthalene coupler as defined above and e) at least one basifying agent as defined above; and a composition (B) comprising f) at least one chemical oxidizing agent as defined above, it being understood that: at least one of the compositions (A) or (B) comprises a) at least one fatty substance as defined above and b) at least one surfactant as defined above, so that the fat content of the composition according to the invention resulting from the mixture of compositions (A) + (B) comprises at least 25% fat .

Preferably at least one of the compositions (A) or (B) is aqueous. Even more preferentially, the two compositions (A) and (B) are aqueous.

By "aqueous composition" is meant a composition comprising at least 5% water. Preferably, an aqueous composition comprises more than 10% by weight of water, and still more preferably more than 20% by weight of water. Preferably the composition (A) is aqueous. In this variant, the composition (A) comprises at least 50% of fatty substances and even more preferably at least 50% of fatty substances that are liquid at room temperature (25 ° C.).

Preferably the composition (A) is an emulsion, direct or inverse and preferably direct (O / W). In this variant the compositions (A) and (B) are preferably mixed in a weight ratio (A) / (B) of from 0.2 to 0.5 to 2.

In a second variant of the invention, the composition according to the invention comprising the ingredients a) to f) as defined above is derived from the mixture of three compositions, the three compositions being aqueous or at least one of them being anhydrous.

More particularly, the term "anhydrous cosmetic composition" in the meaning of the invention is intended to mean a cosmetic composition having a water content of less than 5% by weight, preferably less than 2% by weight and even more preferably less than 1% by weight. % by weight relative to the weight of said composition. It should be noted that the water present in the composition is more particularly "bound water", as the water of crystallization salts or traces of water absorbed by the raw materials used in the production of compositions according to the invention. 'invention. In this second variant, it will be preferred to use two aqueous compositions (B ') and (C') and an anhydrous composition (A '). The anhydrous composition (A ') then preferably comprises a) at least one fatty substance as defined above and more preferably at least one liquid fatty substance. The composition (B ') then preferably comprises c) at least one oxidation base as defined above and d) at least one 2-hydroxynaphthalene coupler as defined above. The composition (C ') then preferably comprises f) at least one chemical oxidizing agent as defined above. The alkalinizing agent (s) e) as defined above are included in the compositions (A ') and / or (EB') and preferably only in the composition (3 '). The surfactant (s) as defined above are included in at least one of the compositions (A '), (B') or (C '), these three compositions being such that the fat content of the composition according to invention resulting from the mixture of the three compositions (A ') + (B') + (C ') comprises at least 25% fat.

In this variant the compositions (A`), (B ') and (C') are preferably mixed in a weight ratio (A ') + (B') I (C ') ranging from 0.2 to 10, better from 0.5 to 2 and in a weight ratio (A ') 1 (B') ranging from 0.5 to 10, more preferably from 1 to 5.

Finally, the invention relates to a first multi-compartment device comprising a first compartment containing the composition (A) as described above and at least a second compartment containing the composition (B) as described above, the compositions of compartments being intended to be mixed before application, to give the formulation after mixing according to the invention, provided that the amount of fat in this formulation is at least 25% by weight relative to the weight of the formulation resulting from the mixture of ( A) + (B)

The invention also relates to a second multi-compartment device comprising a first compartment containing the composition (A ') as described above and a second compartment containing a cosmetic composition (') as described above and at least a third compartment comprising the composition (C ') as described above, the compositions of the compartments being intended to be mixed before application, to give the formulation after mixing according to the invention provided that the amount of fat in this formulation represents at least 25% by weight relative to the weight of the formulation resulting from the mixture of (A ') + (B') + (C ').

The following examples serve to illustrate the invention without being limiting in nature.

EXAMPLES

The following compositions are prepared in which the amounts are expressed in grams of active materials).

Composition Al: Ingredients Al Petrolatum oil (fats) 64,5 Octyl-2 dodecanol (fats) 11,5 Modified hectorite distearyl dimethyl ammonium 3 Propylene carbonate 1 Sorbitan mono-laurate oxyethylenated (40E) (surfactant) 11 Distearate of glycol 8 Oxyethylenated lauryl alcohol (20E) (surfactant) 1 10 Composition B1: Ingredients B1 Propylene glycol 6.2 Ethyl alcohol 8.25 Hexylene glycol (2 methyl -2,4 pentanediol) 3 Dipropylene glycol 3 Monoethanolamine (basifying agent) 14 Sodium metabisulfite 0.7 Vitamin C: L-ascorbic acid 0.25 Diethylene triamine pentaacetic acid, pentasodium salt in 40% aqueous solution Hydroxyethyl cellulose (Natrosol 250 HHR, Aqualon) 3.5 Oxidation base 2.10- 2 moles Coupler 2.10-2 moles Water Qsp100g 39 15 Composition Cl (chemical oxidant): Ingredients Cl Cetylstearyl alcohol (Nafol 1618F) (fats) 8 Glycerine 0.5 Vaseline oil (fatty substance) 20 Cetylstearyl alcohol oxyethylenated (33 0E) (surfactant) 3 Ammonia of rapeseed acids oxyethylenated (40E) (surfactant) 1.2 Tetrasodium pyrophosphate 0.03 Diethylene triamine pentaacetic acid, pentasodium salt in solution 0.15 aqueous 40% Phosphoric acid 0.1 Polycoondensate tetramethyl hexamethylenediamine / 1,3-dichloro-propylene dichloro (40% aqueous solution) Polydimethyl diallyl ammonium chloride (40% aqueous solution) 0.2 Hydrogen peroxide in 50% aqueous solution (chemical oxidizing agent 6) Sodium stannate 0.04 Vitamin E 0.1 Phosphoric acid Qs pH 2.2 water Qsp 100g At the time of use, mix (by weight): - 10 parts of the composition Al - 4 parts of the composition B1 - 16 parts of the composition Cl

The resulting mixture is then applied to 90% white hair. The mixing ratio "bath / wick" is 10/1 (g / g). The exposure time is 30 minutes at 27 ° C. At the end of this time, the locks are rinsed, then washed with shampoo and dried. The results obtained in the composition of the invention were compared with those obtained with a composition of the prior art (RECITAL®) containing in the mixture with oxidant the same dyes at the same concentrations.

Calculation of color variation (AELab * The rise in staining (AELab *) was evaluated in the CIE L * a * b * system.

In this system L * a * b *, L * represents the intensity of the color, a * indicates the axis of 40 green / red color and b * the blue / yellow color axis. The lower the value of L *, the darker or more intense the color. The value of AELab * was calculated from the values of L * a * b * according to the following equation (i): AELab * = 1I (L * - Lo *) 2 + (a * - ao *) 2 + (b * - bo *) 2 (i) The increase in staining (AELab *) was calculated on untreated locks of hair (Lo *, ao * and bo *) and on strands of colored hair (L * , a * and b *). The values of L *, a *, b * of untreated BN hair are as follows L * = 57.93, a * = 0.76, b * = 14.32. The higher the value of AELab *, the better the coverage of the treated fibers and thus the roots.

Calculation of the light-fastness AE, um- - apparatus: SUNTEST XLS + (Atlas company) equipped with an infrared quartz filter and a special UV filter, xenon arc lamp (2200 W) - principle: the strands are fixed on cardboard supports, a half wick being obscured by a cardboard. The sample holders are introduced into the apparatus on horizontal trays placed under the lamp for 18 hours.

The light fastness is evaluated from the determination of AE. The value AE, um- was calculated from the values of L * a * b * according to the following equation: AE, um * = AELab * non-irradiated wick - AELab * irradiated wick The lower the value of AE, um-, the better the light fastness. Comparative Support Coupler Support of the invention RECITAL O: (A1) + (B1) + (C1) L * a * b * AELab * L * a * b * AELab * 2,7- Para-22,98 3, 42 3.15 36.79 2006 4.73 3.19 3967 dihydroxyphenylene napthalene diamine 2-naphthol 4- (3-Amino-50,70 -17,03 18,49 19,65 382 -17,31 17, 2689 pyrazolo [1,5- 8a] in-2-yl) -1,1-dimethylpiperazin-1-ium chloride hydrochloride It is unexpectedly apparent that the composition according to the invention makes it possible to obtain a much greater coloring on ELAB * hair on 90% white hair and therefore a much better coverage of staining at the root than that obtained using a composition of the prior art. Light Toughness Coupler Base SUNTEST L * a * b * AELab * L \ E, um- (hours) (D65) (D65) (D65) 4- (3-Aminopyrazolo- 0 34,28 -3,87 0,09 27 , 98 4-methoxy-2- [1,5-a] pyrid-2-yl) - 18 34.83 -3 1,3 26,78 1,2 naphthol 1,1-dimethylpiperazin-1-ium chloride hydrochloride 4- (3-Aminopyrazolo- O 36,53 -17,54 17,55 28,34 6-methoxy-2- [1,5-a] pyrid-2-yl) - 18 38.09-18 , 18.87 27.34 1.0 naphthol 1,1-dimethyl-piperazin-1-ium chloride hydrochloride 4- (3-Aminopyrazolo-) 38.2 -17.31 17.08 26.89 2-naphthol [ 1,5-a] pyrid-2-yl) - 39,96 -18,6 -17,87 26,65 -0,24 1,1-dimethylpiperazin-1-ium chloride hydrochloride The colorations obtained with the compositions of the invention have a very good light fastness.

Claims (20)

REVENDICATIONS1. Composition for dyeing keratinous fibers comprising: a) at least one fatty substance; b) at least one surfactant; c) at least one oxidation base; d) at least one coupler 2-hydroxynaphthalenic; e) at least one basifying agent; f) optionally at least one chemical oxidizing agent; and the fat content representing in total at least 25% by weight relative to the total weight of formulation 2. Composition according to the preceding claim, characterized in that a) the fatty substance (s) are chosen from C 6 -alkanes. C16, non-silicone oils of mineral, vegetable, animal or synthetic origin, fatty alcohols, fatty acid esters, fatty alcohol esters, non-silicone waxes and silicones. 3. Composition according to any one of the preceding claims, characterized in that a) the fat or fats are liquid at room temperature and at atmospheric pressure are particularly chosen from Vaseline oil, C6-C16 alkanes, polydecenes, esters of fatty acids or fatty alcohols, liquids, or mixtures thereof. 4. Composition according to any one of the preceding claims, characterized in that a) the concentration of fatty substance ranges from 25 to 80% by weight, preferably from 30 to 70% by weight, still more advantageously from 30 to 60% by weight. by weight relative to the total weight of the composition. 5. Composition according to any one of the preceding claims, characterized in that it comprises b) one or more surfactants chosen from nonionic surfactants, in particular mono- or polyoxyalkylenated and mono- or polyglycerolated nonionic surfactants. 6. Composition according to any one of the preceding claims, characterized in that it comprises c) one or more benzene oxidation bases, preferably chosen from para-phenylenediamines, bis-phenylalkylenediamines, para-aminophenols and ortho-aminophenols. , and their addition salts. 44 7. Composition according to any one of the preceding claims, characterized in that it comprises d) one or more 2-hydroxynaphthalene couplers chosen from those of formula (B4) as well as their salts, their optical isomers, geometric, tautomers and their hydrates; Formula (B4) wherein: R1, R2, R3, R4 and R5, the same or different, represent an atom or a group selected from: i) hydrogen; ii) halogen such as chlorine or bromine; iii) hydroxyl; iv) NRaRb with Ra and Rb, identical or different, represent a hydrogen atom or a (C 1 -C 8) alkyl group optionally substituted by a hydroxyl group or a (di) (C 1 -C 8) (alkyl) group amino; or Ra, Rb together with the nitrogen atom together form a mono or polycyclic heterocycle, saturated or partially unsaturated, comprising from 3 to 10 members and from 1 to 5 heteroatoms selected from oxygen, nitrogen, sulfur, sulfoxide S (0 ) and S (O) 2 sulfone, the heterocycle may be substituted by a (C 1 -C 4) alkyl group or an oxo group, particularly the heterocycle is selected from morpholino, piperidino and piperazino; v) (C 1 -C 8) alkyl optionally substituted with one or more atoms or groups selected from halogen such as fluorine, hydroxyl, cyano, carboxy and amino NRaRb as defined above; vi) (C1-C8) alkoxy; vii) (C 1 -C 8) alkyl-S (O) p with p = 0, 1 or 2; viii) aryl such as phenyl; ix) mono or polycyclic heterocycle, saturated or partially unsaturated, comprising from 3 to 10 members and from 1 to 5 heteroatoms selected from oxygen, nitrogen, sulfur, sulfoxide S (O) and sulfone S (O) 2, heterocycle ( B4) may be substituted with a (C 1 -C 4) alkyl group or an oxo group, particularly the heterocycle is selected from morpholinyl, piperidinyl and piperazinyl; x) aryloxy such as phenoxy; xi) cyano -CN; xii) carboxy -C (O) OM with M representing a hydrogen atom, a (C 1 -C 8) alkyl group or a cation derived from alkali metal, alkaline earth metal, or an organic cation such as ammonium; xiii) -S (O) (OM) 2 or -O-S (O) (OM) 2 with M as defined above; xiv) -C (O) NRaRb or -NRa-C (O) Rb with Ra and Rb, as previously defined; xv) -S (O) n-NRaRb or -NRa-S (O) n-Rb with n being 1 or 2 and Ra and Rb as defined above; or two contiguous radicals R2 and R3 and / or R 'and R5 and / or R4 and R5 together with the carbon atom to which each is attached, a (hetero) ring, or optionally substituted (hetero) aryl; preferentially together form a benzo group; R6 represents a hydrogen atom, a hydrolyzable protecting group of the hydroxyl group such as -C (X) -R7 with X denoting an oxygen or sulfur atom, particularly oxygen, and R7 denoting a hydrogen atom, or a (C 1 -C 8) alkyl group; preferentially R6 represents a hydrogen atom. 8. Composition according to the preceding claim, characterized in that it comprises d) one or more 2-hydroxynaphthalenic couplers chosen from those of formula (B4) in which R2, R3, R4 and R5, identical or different, represent an atom of hydrogen, halogen, hydroxyl, cyano, or (C 1 -C 8) alkoxy. 9. Composition according to any one of the preceding claims, characterized in that it comprises one or more 2-hydroxynaphthalenic couplers chosen from the following compounds: ## STR2 ## OH-OH (1): 2-naphthol (2): 3-methoxy -2- (3): 4-methoxy-2-naphthol naphthol (4): 6-methoxy-2-naphthol (5): 7-methoxy-2-naphthol (6): 2,3-dihydroxy 1-bromo-2-naphthol dihydroxynaphthalene nec (OH): 6-cyano-2-bromo-2-naphthol Naphthalenesulfonamide br (7): 2,7- (8): 3-bromo-2-naphthol (9) naphthol 10. Composition according to any one of the preceding claims, characterized in that it comprises one or more additional couplers chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalenic couplers other than 2-hydroxynaphthalenic couplers. , and heterocyclic couplers. 11. Composition according to any one of the preceding claims, characterized in that e) the alkalinizing agent (s) are mineral, organic or hybrid and preferably chosen from ammonia, alkali carbonates or bicarbonates such as carbonates or bicarbonates of sodium or potassium hydroxides, sodium or potassium hydroxides, organic amines chosen from alkanolamines, oxyethylenated and / or oxypropylenated ethylenediamines, amino acids and compounds of formula (I) or mixtures thereof: RX / RZ NWN Ry Rt (I) formula (I) wherein W is a divalent C1-C6 alkylene radical optionally substituted by one or more hydroxyl groups or a C1-C6 alkyl radical, and / or optionally interrupted by one or more heteroatoms such as O , or NRu; RX, Ry, RZ, Rt, Ru and the same or different, represent a hydrogen atom, a C1-C6 alkyl or C1-C6 hydroxyalkyl, C1-C6 aminoalkyl radical. 12. Composition according to the preceding claim, wherein e) the alkalinizing agent (s) are chosen from alkanolamines, particularly monoethanolamine, and amino acids in neutral or ionic form. 13. Composition according to any one of the preceding claims, characterized in that it comprises f) one or more chemical oxidizing agents, preferably hydrogen peroxide. 14. A process for dyeing keratinous fibers, in particular human keratinous fibers such as the hair, comprising applying to said fibers the composition according to any one of the preceding claims in the presence of at least one chemical oxidizing agent as defined. in the preceding claim. 15. Method according to the preceding claim, wherein the composition as described in any one of claims 1 to 13 is obtained by mixing at least two compositions, preferably two or three compositions. 16. Method according to the preceding claim, wherein the composition is derived from the mixture of two compositions: a composition (A) comprising: at least one oxidation base as defined in claims 1 or 6; at least one 2-hydroxynaphthalene coupler as defined in any one of claims 1, 7 to 9; at least one basifying agent as defined in any one of claims 1, 11 or 12; and a composition (B) comprising: - at least one chemical oxidizing agent as defined in claim 13; at least one of compositions (A) and (B) comprising: at least one fatty substance as defined in any one of claims 1 to 4, and at least one surfactant as defined in claims 1 or 5, so that the fat content of the composition according to the invention resulting from the mixture of compositions (A) + (B) comprises at least 25% fat. 17. The method of claim 15, wherein the composition is derived from the mixture of three compositions, the three compositions being aqueous or at least one of them being anhydrous. 18. The method of claim 17, wherein using two aqueous compositions (B ') and (C') and an anhydrous composition (A '), - the anhydrous composition (A') comprising at least one fatty substance as defined in any one of claims 1 to 4 and preferentially the one or more fatty substances are liquid, the composition (') comprising o at least one oxidation base as defined in claims 1 or 6; and o at least one 2-hydroxynaphthalene coupler as defined in any one of claims 1, 7 to 9; the composition (C ') comprising: at least one chemical oxidizing agent as defined in claim 13; it being understood that: at least one basifying agent as defined in any one of claims 1, 11 or 12 is included in the compositions (A ') and / or (B') and preferably only in the composition (B ') ); at least one surfactant as defined in claims 1 or 5, is included in at least one of the compositions (A '), (B') or (C '); these three compositions being such that the fat content of the composition resulting from the mixture of the three compositions (A ') + (B') + (C ') comprises at least 25% fat. 19. Multi-compartment device comprising a first compartment containing the composition (A) as defined in claim 16 and at least a second compartment containing the composition (B) as defined in claim 16, the compartment compositions being intended for to be mixed before application, to give a composition after mixing of (A) + (B) whose quantity in fats constitutes at least 25% by weight relative to the weight of the composition resulting from the mixture of (A) + (B) . 20. Multi-compartment device comprising a first compartment containing the composition (A ') as defined in claim 18; and a second compartment containing a cosmetic composition (B ') as described in claim 18 and at least one third compartment containing the composition (C') as described in claim 18; the compositions of the compartments being intended to be mixed before application, to give a composition after mixing of (A ') + (B') + (C ') whose quantity in fats constitutes at least 25% by weight relative to the weight of the composition resulting from the mixture of (A ') + (B') + (C ')