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FR2969147B1 - Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification - Google Patents

Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification

Info

Publication number
FR2969147B1
FR2969147B1 FR1060911A FR1060911A FR2969147B1 FR 2969147 B1 FR2969147 B1 FR 2969147B1 FR 1060911 A FR1060911 A FR 1060911A FR 1060911 A FR1060911 A FR 1060911A FR 2969147 B1 FR2969147 B1 FR 2969147B1
Authority
FR
France
Prior art keywords
etherification
isobutanol
dehydration
production
acid catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1060911A
Other languages
English (en)
Other versions
FR2969147A1 (fr
Inventor
Delphine Minoux
Cindy Adam
Nikolai Nesterenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Marketing Services SA
Original Assignee
Total Raffinage Marketing SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Raffinage Marketing SA filed Critical Total Raffinage Marketing SA
Priority to FR1060911A priority Critical patent/FR2969147B1/fr
Priority to BR112013011269A priority patent/BR112013011269A2/pt
Priority to PCT/EP2011/073413 priority patent/WO2012084950A1/fr
Priority to CN2011800612267A priority patent/CN103261129A/zh
Priority to EP11811537.7A priority patent/EP2655300A1/fr
Priority to US13/878,016 priority patent/US20130261345A1/en
Publication of FR2969147A1 publication Critical patent/FR2969147A1/fr
Application granted granted Critical
Publication of FR2969147B1 publication Critical patent/FR2969147B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/08Alkenes with four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/08Alkenes with four carbon atoms
    • C07C11/09Isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/05Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2775Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/82Phosphates
    • C07C2529/84Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85Silicoaluminophosphates (SAPO compounds)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
FR1060911A 2010-12-21 2010-12-21 Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification Expired - Fee Related FR2969147B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1060911A FR2969147B1 (fr) 2010-12-21 2010-12-21 Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification
BR112013011269A BR112013011269A2 (pt) 2010-12-21 2011-12-20 produção de aditivos para combustível através da desidratação e isomerização estrutural simultâneas de isobutanol sobre catalisadores ácidos seguido pela eterificação
PCT/EP2011/073413 WO2012084950A1 (fr) 2010-12-21 2011-12-20 Production d'additifs pour carburant par déshydratation et isomérisation de squelette simultanées de l'isobutanol sur des catalyseurs acides suivies d'une éthérification
CN2011800612267A CN103261129A (zh) 2010-12-21 2011-12-20 通过异丁醇在酸性催化剂上同时脱水和骨架异构化然后醚化制备燃料添加剂
EP11811537.7A EP2655300A1 (fr) 2010-12-21 2011-12-20 Production d'additifs pour carburant par déshydratation et isomérisation de squelette simultanées de l'isobutanol sur des catalyseurs acides suivies d'une éthérification
US13/878,016 US20130261345A1 (en) 2010-12-21 2011-12-20 Production of fuel additives via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by etherification

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1060911A FR2969147B1 (fr) 2010-12-21 2010-12-21 Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification

Publications (2)

Publication Number Publication Date
FR2969147A1 FR2969147A1 (fr) 2012-06-22
FR2969147B1 true FR2969147B1 (fr) 2013-01-04

Family

ID=44260184

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1060911A Expired - Fee Related FR2969147B1 (fr) 2010-12-21 2010-12-21 Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification

Country Status (6)

Country Link
US (1) US20130261345A1 (fr)
EP (1) EP2655300A1 (fr)
CN (1) CN103261129A (fr)
BR (1) BR112013011269A2 (fr)
FR (1) FR2969147B1 (fr)
WO (1) WO2012084950A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106278788B (zh) * 2015-05-22 2018-11-02 中国石油化工股份有限公司 一种以混合醇生产甲基叔丁基醚和/或异丁烯的方法
EP3162763A1 (fr) * 2015-10-30 2017-05-03 Total Research & Technology Feluy SA Déshydratation simultanée et isomérisation squelettique d'isobutanol sur des catalyseurs de zéolite contenant du titane
CN107987898A (zh) * 2017-12-01 2018-05-04 山东滨州裕华化工厂有限公司 一种乙醇汽油及其制备方法
CN112898121A (zh) * 2021-01-23 2021-06-04 四川上氟科技有限公司 一种全氟烷基乙醇的制备方法
FR3135263A1 (fr) * 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés
FR3135264A1 (fr) * 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés
FR3135265A1 (fr) * 2022-05-06 2023-11-10 Totalenergies Onetech Procédé d’obtention d’hydrocarbures, et installation associée

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1012686B (it) 1974-05-21 1977-03-10 Snam Progetti Procedimento per la preparazione di eteri ter alchilici
US4071567A (en) 1974-05-21 1978-01-31 Snamprogetti S.P.A. Process for the production of methyl tert-butyl ether
DE2629769C3 (de) 1976-07-02 1989-03-16 Hüls AG, 4370 Marl Verfahren zur Herstellung von reinem Methyl-tertiär-butyläther
DE2706465C3 (de) 1977-02-16 1980-10-02 Deutsche Texaco Ag, 2000 Hamburg Verfahren zur Gewinnung von Butadien bzw. n-Butenen aus diese enthaltenden Kohlenwasserstoffgemischen unter Abtrennung von Isobuten
NL7803135A (nl) 1978-03-23 1979-09-25 Shell Int Research Werkwijze ter bereiding van tertiaire alkyl- ethers.
EP0008860B2 (fr) 1978-07-27 1991-12-04 CHEMICAL RESEARCH & LICENSING COMPANY Système catalytique
US4469911A (en) 1980-10-23 1984-09-04 Petro Tex Chemical Corporation Isobutene removal from C4 streams
DE4013711A1 (de) 1990-04-28 1991-10-31 Erdoelchemie Gmbh Verfahren zur herstellung von hochoktanigen, olefinarmen kraftstoffen und kraftstoffkomponenten
ZA966107B (en) * 1995-07-21 1997-02-03 Shell Int Research Dehydration of primary alcohols.
US5895830A (en) 1995-12-15 1999-04-20 Uop Llc Process for oligomer production and saturation
US5877372A (en) 1997-11-21 1999-03-02 Arco Chemical Technology, L.P. Isobutylene oligomerization using isooctane diluent
US6689927B1 (en) 2001-05-07 2004-02-10 Uop Lcc Process for oligomer production and saturation
US6768035B2 (en) * 2002-01-31 2004-07-27 Chevron U.S.A. Inc. Manufacture of high octane alkylate
DE10302457B3 (de) 2003-01-23 2004-10-07 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen
US6977318B2 (en) 2004-05-04 2005-12-20 Equistar Chemicals, Lp Propylene production
US20080132741A1 (en) * 2006-06-16 2008-06-05 D Amore Michael B Process for making butenes from dry isobutanol
US20090030239A1 (en) 2006-06-16 2009-01-29 D Amore Michael B Process for making butenes from aqueous isobutanol
US8975047B2 (en) 2006-06-16 2015-03-10 E I Du Pont De Nemours And Company Process for making isooctenes from dry 1-butanol
EP2543721A1 (fr) 2007-04-18 2013-01-09 Butamax (TM) Advanced Biofuels LLC Production fermentative d'isobutanol utilisant des enzymes cétol-acide réductoisomérase hautement actives
CN101952398B (zh) * 2007-12-03 2014-05-21 格沃股份有限公司 可再生组合物
US20100216958A1 (en) * 2009-02-24 2010-08-26 Peters Matthew W Methods of Preparing Renewable Butadiene and Renewable Isoprene

Also Published As

Publication number Publication date
CN103261129A (zh) 2013-08-21
WO2012084950A1 (fr) 2012-06-28
EP2655300A1 (fr) 2013-10-30
US20130261345A1 (en) 2013-10-03
BR112013011269A2 (pt) 2016-11-01
FR2969147A1 (fr) 2012-06-22

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Effective date: 20140829