FR2969147B1 - Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification - Google Patents
Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherificationInfo
- Publication number
- FR2969147B1 FR2969147B1 FR1060911A FR1060911A FR2969147B1 FR 2969147 B1 FR2969147 B1 FR 2969147B1 FR 1060911 A FR1060911 A FR 1060911A FR 1060911 A FR1060911 A FR 1060911A FR 2969147 B1 FR2969147 B1 FR 2969147B1
- Authority
- FR
- France
- Prior art keywords
- etherification
- isobutanol
- dehydration
- production
- acid catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 title 2
- 239000003377 acid catalyst Substances 0.000 title 1
- 230000018044 dehydration Effects 0.000 title 1
- 238000006297 dehydration reaction Methods 0.000 title 1
- 238000006266 etherification reaction Methods 0.000 title 1
- 239000002816 fuel additive Substances 0.000 title 1
- 238000006317 isomerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
- C07C11/09—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1060911A FR2969147B1 (fr) | 2010-12-21 | 2010-12-21 | Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification |
BR112013011269A BR112013011269A2 (pt) | 2010-12-21 | 2011-12-20 | produção de aditivos para combustível através da desidratação e isomerização estrutural simultâneas de isobutanol sobre catalisadores ácidos seguido pela eterificação |
PCT/EP2011/073413 WO2012084950A1 (fr) | 2010-12-21 | 2011-12-20 | Production d'additifs pour carburant par déshydratation et isomérisation de squelette simultanées de l'isobutanol sur des catalyseurs acides suivies d'une éthérification |
CN2011800612267A CN103261129A (zh) | 2010-12-21 | 2011-12-20 | 通过异丁醇在酸性催化剂上同时脱水和骨架异构化然后醚化制备燃料添加剂 |
EP11811537.7A EP2655300A1 (fr) | 2010-12-21 | 2011-12-20 | Production d'additifs pour carburant par déshydratation et isomérisation de squelette simultanées de l'isobutanol sur des catalyseurs acides suivies d'une éthérification |
US13/878,016 US20130261345A1 (en) | 2010-12-21 | 2011-12-20 | Production of fuel additives via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by etherification |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1060911A FR2969147B1 (fr) | 2010-12-21 | 2010-12-21 | Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2969147A1 FR2969147A1 (fr) | 2012-06-22 |
FR2969147B1 true FR2969147B1 (fr) | 2013-01-04 |
Family
ID=44260184
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1060911A Expired - Fee Related FR2969147B1 (fr) | 2010-12-21 | 2010-12-21 | Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification |
Country Status (6)
Country | Link |
---|---|
US (1) | US20130261345A1 (fr) |
EP (1) | EP2655300A1 (fr) |
CN (1) | CN103261129A (fr) |
BR (1) | BR112013011269A2 (fr) |
FR (1) | FR2969147B1 (fr) |
WO (1) | WO2012084950A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106278788B (zh) * | 2015-05-22 | 2018-11-02 | 中国石油化工股份有限公司 | 一种以混合醇生产甲基叔丁基醚和/或异丁烯的方法 |
EP3162763A1 (fr) * | 2015-10-30 | 2017-05-03 | Total Research & Technology Feluy SA | Déshydratation simultanée et isomérisation squelettique d'isobutanol sur des catalyseurs de zéolite contenant du titane |
CN107987898A (zh) * | 2017-12-01 | 2018-05-04 | 山东滨州裕华化工厂有限公司 | 一种乙醇汽油及其制备方法 |
CN112898121A (zh) * | 2021-01-23 | 2021-06-04 | 四川上氟科技有限公司 | 一种全氟烷基乙醇的制备方法 |
FR3135263A1 (fr) * | 2022-05-06 | 2023-11-10 | Totalenergies Onetech | Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés |
FR3135264A1 (fr) * | 2022-05-06 | 2023-11-10 | Totalenergies Onetech | Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés |
FR3135265A1 (fr) * | 2022-05-06 | 2023-11-10 | Totalenergies Onetech | Procédé d’obtention d’hydrocarbures, et installation associée |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1012686B (it) | 1974-05-21 | 1977-03-10 | Snam Progetti | Procedimento per la preparazione di eteri ter alchilici |
US4071567A (en) | 1974-05-21 | 1978-01-31 | Snamprogetti S.P.A. | Process for the production of methyl tert-butyl ether |
DE2629769C3 (de) | 1976-07-02 | 1989-03-16 | Hüls AG, 4370 Marl | Verfahren zur Herstellung von reinem Methyl-tertiär-butyläther |
DE2706465C3 (de) | 1977-02-16 | 1980-10-02 | Deutsche Texaco Ag, 2000 Hamburg | Verfahren zur Gewinnung von Butadien bzw. n-Butenen aus diese enthaltenden Kohlenwasserstoffgemischen unter Abtrennung von Isobuten |
NL7803135A (nl) | 1978-03-23 | 1979-09-25 | Shell Int Research | Werkwijze ter bereiding van tertiaire alkyl- ethers. |
EP0008860B2 (fr) | 1978-07-27 | 1991-12-04 | CHEMICAL RESEARCH & LICENSING COMPANY | Système catalytique |
US4469911A (en) | 1980-10-23 | 1984-09-04 | Petro Tex Chemical Corporation | Isobutene removal from C4 streams |
DE4013711A1 (de) | 1990-04-28 | 1991-10-31 | Erdoelchemie Gmbh | Verfahren zur herstellung von hochoktanigen, olefinarmen kraftstoffen und kraftstoffkomponenten |
ZA966107B (en) * | 1995-07-21 | 1997-02-03 | Shell Int Research | Dehydration of primary alcohols. |
US5895830A (en) | 1995-12-15 | 1999-04-20 | Uop Llc | Process for oligomer production and saturation |
US5877372A (en) | 1997-11-21 | 1999-03-02 | Arco Chemical Technology, L.P. | Isobutylene oligomerization using isooctane diluent |
US6689927B1 (en) | 2001-05-07 | 2004-02-10 | Uop Lcc | Process for oligomer production and saturation |
US6768035B2 (en) * | 2002-01-31 | 2004-07-27 | Chevron U.S.A. Inc. | Manufacture of high octane alkylate |
DE10302457B3 (de) | 2003-01-23 | 2004-10-07 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen |
US6977318B2 (en) | 2004-05-04 | 2005-12-20 | Equistar Chemicals, Lp | Propylene production |
US20080132741A1 (en) * | 2006-06-16 | 2008-06-05 | D Amore Michael B | Process for making butenes from dry isobutanol |
US20090030239A1 (en) | 2006-06-16 | 2009-01-29 | D Amore Michael B | Process for making butenes from aqueous isobutanol |
US8975047B2 (en) | 2006-06-16 | 2015-03-10 | E I Du Pont De Nemours And Company | Process for making isooctenes from dry 1-butanol |
EP2543721A1 (fr) | 2007-04-18 | 2013-01-09 | Butamax (TM) Advanced Biofuels LLC | Production fermentative d'isobutanol utilisant des enzymes cétol-acide réductoisomérase hautement actives |
CN101952398B (zh) * | 2007-12-03 | 2014-05-21 | 格沃股份有限公司 | 可再生组合物 |
US20100216958A1 (en) * | 2009-02-24 | 2010-08-26 | Peters Matthew W | Methods of Preparing Renewable Butadiene and Renewable Isoprene |
-
2010
- 2010-12-21 FR FR1060911A patent/FR2969147B1/fr not_active Expired - Fee Related
-
2011
- 2011-12-20 US US13/878,016 patent/US20130261345A1/en not_active Abandoned
- 2011-12-20 BR BR112013011269A patent/BR112013011269A2/pt not_active IP Right Cessation
- 2011-12-20 WO PCT/EP2011/073413 patent/WO2012084950A1/fr active Application Filing
- 2011-12-20 CN CN2011800612267A patent/CN103261129A/zh active Pending
- 2011-12-20 EP EP11811537.7A patent/EP2655300A1/fr not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
CN103261129A (zh) | 2013-08-21 |
WO2012084950A1 (fr) | 2012-06-28 |
EP2655300A1 (fr) | 2013-10-30 |
US20130261345A1 (en) | 2013-10-03 |
BR112013011269A2 (pt) | 2016-11-01 |
FR2969147A1 (fr) | 2012-06-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |
Effective date: 20140829 |