FR2940068A1 - Composition, useful for e.g. cleaning keratin materials, comprises anionic surfactants, carboxylic anionic surfactants, amphoteric and/or zwitterionic surfactants, alkyl(poly)glycoside nonionic surfactants, cationic polymers, and filters - Google Patents

Abstract

Detergent cosmetic composition (I) comprises: one or more anionic surfactants (A) having one or more sulfate, sulfonate and/or phosphate groups; one or more carboxylic anionic surfactants (B) different form the anionic surfactant (A); one or more amphoteric and/or zwitterionic surfactants (C); one or more alkyl (poly)glycoside nonionic surfactants (D); one or more cationic polymers (E); and one or more filters (F) having sulfonyl (2-hydroxy-4-methoxy-phenyl)-phenyl-methanone structure (a). Detergent cosmetic composition (I) comprises: one or more anionic surfactants (A) having one or more sulfate, sulfonate and/or phosphate groups; one or more carboxylic anionic surfactants (B) different form the anionic surfactant (A); one or more amphoteric and/or zwitterionic surfactants (C); one or more alkyl (poly)glycoside nonionic surfactants (D); one or more cationic polymers (E); and one or more filters (F) having sulfonyl (2-hydroxy-4-methoxy-phenyl)-phenyl-methanone structure of formula (a). X : H or monovalent cation comprising alkali metal ion such as sodium and potassium ions and ions from organic amine bases such as monoethanolamine, preferably H or Na +>. Independent claims are included for: (1) washing and conditioning keratin materials, preferably human keratin fibers such as hair, comprising applying the composition to the wet keratin materials; and rinsing with water after an optional time breaks; and (2) kit for coloring comprising a first compartment containing direct or oxidation hair coloring product in one or both sides, and a second compartment comprising the composition. [Image].

Description

B08-2703EN GD / ET OA 08 598

Company known as L'ORÉAL Cosmetic detergent composition comprising four surfactants, a cationic polymer and benzophenone-4, and uses.

Invention of: LALLEMAN Boris A detergent cosmetic composition comprising four surfactants, a cationic polymer and benzophenone-4, and uses The present invention relates to novel detergent cosmetic compositions of keratinous materials, in particular human keratinous fibers such as the hair, comprising a or a plurality of anionic sulfate and / or sulphonate and / or phosphate surfactants, one or more anionic carboxylic surfactants, one or more amphoteric and / or zwitterionic surfactants, one or more alkyl (poly) glucoside type nonionic surfactants, one or more polymers. cationic agents and one or more particular filters. The invention also relates to their various uses, in particular to protect the artificial color of keratin fibers from sunlight and / or repeated washing. It is well known that the hair is sensitized or weakened to varying degrees by the action of atmospheric agents including light, water and moisture and by repeated mechanical or chemical treatments such as brushing combing, washing, discoloration, perms, straightening and / or dyeing. Many publications disclose that natural light destroys certain amino acids in the hair. These aggression altering the hair fiber, they reduce the mechanical properties such as tensile strength, tensile strength and elasticity, or their resistance to swelling in an aqueous medium. The hair is dull, rough and brittle. The hair is difficult to disentangle and comb.

It is also known that in particular light and washing agents tend to attack the natural color of the hair as well as the artificial color of the dyed hair. The color of the hair weakens little by little or turns towards unsightly or undesirable shades.

For many years, the cosmetic industry has been seeking substances that protect hair from damage caused by atmospheric aggressions, such as light, heat, treatments, and especially hair washing. In particular, it seeks products improving the cosmetic properties (including detangling, softness, smoothing, shine, ...), products protecting the color of keratin fibers naturally colored or artificially dyed and preserving or enhancing the mechanical properties intrinsic keratin fibers (tensile strength, tensile strength and elasticity, or resistance to swelling in an aqueous medium). Furthermore, the skin can also be altered to varying degrees by the action of atmospheric agents and by the repeated action of detergent products. The skin tissues can be burned, the skin becomes dry and rough and loses its natural elasticity. An appearance of dandruff, an excess of seborrhea or conversely of an excess of drought can then be observed. We have already tried to protect the hair and the skin from the effects of light by applying UV filters, water-soluble or non-polymeric, polymeric or otherwise, nanoparticles, antioxidants, complexing agents of metals or chelants, anti-free radical agents . The compositions of the prior art make it possible to solve, to a certain extent, the problems mentioned, but their use is not satisfactory. Indeed, repeated applications of these compositions often have the effect of communicating an unpleasant touch to the hair, a loss of volume and nervousness of the hair, and sometimes a lack of shine. On the other hand, with such compositions, a persistent greasy feel is obtained on the skin. In the field of so-called rinsed cosmetic compositions, such as shampoos, shower gels, facial cleansers or shaving foams, there are known detergent compositions comprising filters for applying to the hair or the skin.

To obtain the desired beneficial effect, it is necessary to introduce a quantity of beneficial agent into the rinsed composition much greater than the amount necessary to obtain the effect. For rinsed detergent compositions, most of the beneficial agent is indeed removed during the rinsing of the composition, the effective portion of the agent contained in the composition is therefore very low. However, as of today, there are no rinsed detergent compositions to increase significantly the amount of filter deposited on the fibers after rinsing. Such compositions would allow to use much less filter to provide a very good level of protection. The Applicant has surprisingly discovered that by using a combination of four particular surfactants, one or more cationic polymers in combination with one or more particular filters, the disadvantages mentioned above could be overcome. In particular, it is possible to increase the deposition of said filter on the keratin materials and thereby increase the efficiency of said filter or reduce the amount of said filter used.

The subject of the invention is therefore a detergent cosmetic composition characterized in that it comprises one or more anionic surfactants (A) comprising at least one sulphate and / or sulphonate and / or phosphate group, one or more carboxylic anionic surfactants (B). ) different from the surfactants mentioned in (A), one or more amphoteric and / or zwitterionic surfactants (C), one or more alkyl (poly) glucoside surfactants (D), one or more cationic polymers (E), and one or more filters (F) corresponding to the following formula (I): OCH3 (I) SO3x with X denoting a hydrogen atom or a monovalent cation selected from alkali metal ions such as sodium and potassium, ammonium ions and ions from organic amine bases such as monoethanolamine. Without wishing to limit the present invention to any theory, it would appear to exist during rinsing, particular interactions and / or affinities between the filter, the combination of surfactants, the cationic polymer, used according to the invention, and the hair, which promote a regular, substantial and durable deposit of said filter and the cationic polymer on the surface of said hair, this qualitative and quantitative deposit being probably one of the causes of the improvement observed in the final properties, in particular the protection of the color dyed hair, in particular with respect to solar radiation, UV and / or repeated washing, as well as the ease of styling, disentangling, smoothing, softness and shine of the treated hair. All these discoveries are at the basis of the present invention. In addition, it has been observed that the compositions of the invention show very good use qualities (foam start, foaming power, rinsability). Another subject of the invention relates to the use of one or more anionic surfactants (A) comprising at least one sulphate and / or sulphonate and / or phosphate group, of one or more carboxylic anionic surfactants (B) different from surfactants. cited in (A), one or more amphoteric and / or zwitterionic surfactants (C), one or more alkyl (poly) glucoside surfactants (D), and one or more cationic polymers (E) in or for the manufacture of a cosmetic composition comprising one or more filters (F) of formula (I). The subject of the invention is also the use of one or more anionic surfactants (A) comprising at least one sulphate and / or sulphonate and / or phosphate group, of one or more carboxylic anionic surfactants (B) different from the surfactants mentioned. in (A), one or more amphoteric and / or zwitterionic surfactants (C), one or more alkyl (poly) glucoside surfactants (D), and one or more cationic polymers (E) in a cosmetic composition comprising one or more filters of formula (I) to increase the efficiency of the filter and its fixation on keratin materials. The invention also relates to the use of a composition according to the invention for cleaning and / or removing make-up and / or conditioning of keratin materials such as hair and skin and / or for the protection of color dyed hair, especially vis-à-vis solar radiation, UV and / or repeated washing. Other features, aspects, objects and advantages of the present invention will become more apparent upon reading the description and the examples which follow.

The different objects of the invention will now be detailed. All the meanings and definitions of the compounds used in the present invention given below are valid for all the objects of the invention. In the present application, an entity is described as being "anionic" when it possesses at least one permanent negative charge or when it can be ionized into a negatively charged entity, under the conditions of use of the compositions of the invention ( medium, pH for example) and not comprising a cationic charge.

Likewise, an entity is described as being "cationic" when it possesses at least one permanent positive charge or when it can be ionized into a positively charged entity, under the conditions of use of the compositions of the invention (medium, pH for example) and not comprising anionic charge.

An entity is described as being "nonionic" when it is neither cationic nor anionic within the meaning of the present application, in particular it does not include any cationic or anionic group within the meaning of the present application.

By cosmetically acceptable or physiologically acceptable, we mean that is compatible with the application on the body of a living being, in particular the human body, including the scalp and hair.

For simplification, the terms: "surfactant (A)" or "compound (A)" may be used to designate an anionic surfactant comprising in its structure one or more sulfate and / or sulphonate and / or phosphate groups, used according to US Pat. invention and as subsequently described; "surfactant (B)" or "compound (B)" for a carboxylic anionic surfactant different from the surfactant (A) used according to the invention and as described later; "surfactant (C)" or "compound (C)" for an amphoteric and / or zwitterionic surfactant used according to the invention and as described later; "surfactant (D)" or "compound (D)" for a nonionic surfactant of the alkyl (poly) glycoside type used according to the invention and as described later; "polymer (E)" or "compound (E)" for a cationic polymer used according to the invention and as described later; "filter (F)" or "compound (F)" for a UV filter (or ultraviolet radiation filtering system) corresponding to formula (I), used according to the invention and as described in the present application. Of course, the compounds (A), (B), (C), (D), (E) and (F) as defined in the different objects of the invention are each different from each other. In the absence of any indication to the contrary, each of the compounds, optional or otherwise, used or envisaged in the context of the present invention may be present alone or as a mixture.

Anionic surfactant (s) (A) having in their structure one or more • routers. sulphate and / or sulphonate and / or • hos. Preferably, the surfactant or surfactants (A) used according to the invention do not comprise in their structure carboxylic groups (COOH) or carboxylic groups in salt form (COO-).

Among the surfactants (A), it is preferred to use anionic surfactants comprising in their structure one or more sulfate and / or sulphonate groups. The surfactant (s) (A) may be oxyethylenated and / or oxypropylenated. The total average number of ethylene oxide (OE) and / or propylene oxide (PO) groups can then vary from 2 to 50 and especially from 2 to 10. The surfactant (s) that can be used according to the invention, alone. (S) or in admixture (s), can be chosen from alkyl sulphates, alkylamidosulfates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl ether sulphates, alkyl ether sulphosuccinates, acyl isethionates and methyl acyl taurates, and their salts; the alkyl or acyl group of all these different compounds preferably containing from 8 to 24 carbon atoms, and the aryl group preferably denoting a phenyl or benzyl group.

Preferably, the surfactant or surfactants (A) are in the form of salts, and in particular of alkaline salts, in particular of sodium salts, of ammonium salts, of amine salts, of which the aminoalcohol salts, and / or of magnesium salts. In particular, among the anionic surfactants having in their structure one or more sulphate and / or sulphonate groups, it is even more preferred to use those chosen from the salts of alkyl sulphates and alkyl ether sulphates, in C 8 -C 14 and more particularly those in C 12. C14. These salts preferably comprise from 2 to 5 ethylene oxide groups. Alkyl (C12-C14) sulphates of sodium, triethanolamine, magnesium or ammonium, and / or sodium (C12-C14) alkyl ethersulfates are more preferably used alone or in mixtures. ammonium or magnesium, oxyethylenated, for example to 2.2 moles of ethylene oxide. More preferably, the surfactant or surfactants (A) are chosen from sodium, ammonium or magnesium (C 12 -C 14) alkyl ethersulfates, oxyethylenated with 2.2 moles of ethylene oxide, as sold under the name TEXAPON N702 by the company COGNIS. The at least one surfactant (A) is present in a proportion of from 1% to 50% by weight, in particular from 2% to 25% by weight, more preferably from 3% to 20% by weight, and more preferably 3% by weight. 5% to 8% by weight, based on the total weight of the composition.

Carboxylic anionic surfactant (s) (B) According to the invention, the anionic carboxylic surfactant (s) are anionic surfactants comprising in their structure at least one carboxylic function (-COOH), optionally in the form of a sodium salt. carboxylic acid (-COO-).

The anionic carboxylic surfactant (s) used according to the invention are different from the surfactants (A) and preferably do not comprise sulphate, sulphonate and / or phosphate groups. The surfactant (s) (B) used in the context of the present invention may be chosen, alone or in admixture (s), from: - (C 6 -C 24) alkyl-D-galactoside uronic acids and their salts, - acyl (C6-C24) sarcosinic acids and their salts, - acyl (C6-C4) lactylic acids and their salts, - acyl (C6-C4) glutamic acids and their salts. It is also possible to use the alkyl (poly) glycoside carboxylic acids, preferably in the form of salts, such as alkylglucoside acetates, alkylglucoside citrates and alkylpolyglycoside tartrates; the alkyl group of these alkyl (poly) glycoside carboxylic acids preferably having from 6 to 24 carbon atoms. Such products are sold in particular under the names EUCAROL APG / EC and EUCAROL APG / ET by the company LAMBERTI and PLANTAPON LGC SORB by the company COGNIS. The surfactant (s) (B) used in the context of the present invention may be oxyalkylenated with alkylene oxide groups, preferably oxyethylenated and / or oxypropylenated groups. The total average number of alkylene oxide groups then varies preferably from 2 to 50, in particular from 2 to 24, and more preferably from 2 to 15. When the surfactant (s) (B) are oxyalkylenated, they may preferably be chosen, alone or in admixture (s), from: - polyoxyalkylenated (C6-C24) alkylcarboxylic acids, - polyoxyalkylenated (C6-C24) aryl ether carboxylic acids, - (C6-C24) alkyl acids ) polyoxyalkylenated carboxylic amido ether, and their salts; and in particular those having from 2 to 50 alkylene oxide groups, preferably from 2 to 50 ethylene oxide (0E) groups, and more preferably from 2 to 15 ethylene oxide groups.

The salts are in particular chosen from alkali metal salts, especially sodium salts, ammonium salts, amine salts, including aminoalcohol salts such as triethanolamine or monoethanolamine salts, and magnesium salts. The following are preferably used alone or as mixtures: acyl (C6-C14) glutamic acids and their salts, (C6-C24) alkyl polyglycoside carboxylic acids and their salts, polyoxyalkylenated (C6-C24) alkyl carboxylic ether acids and their salts, in particular those containing from 2 to 24 alkylene oxide groups, preferably from 2 to 24 ethylene oxide groups, and more preferably from 2 to 15 ethylene oxide groups, - alkyl acids (C6 -C24) polyoxyalkylenated aryl ether carboxyls and their salts, in particular those containing from 2 to 24 alkylene oxide groups, preferably from 2 to 24 ethylene oxide groups, and better still from 2 to 15 ethylene oxide groups polyoxyalkylenated (C 6 -C 24) alkyl amido ether carboxylic acids and their salts, in particular those containing from 2 to 24 alkylene oxide groups, preferably from 2 to 24 ethylene oxide groups, and more preferably from 2 to 24 15 groups of ethyl oxides ene. More preferably, the polyethoxylated anionic carboxylic surfactants which correspond to the following formula (II): R1 (OC2H4) nOCH2000A (II)

wherein: R1 represents a linear or branched C8-C22 alkyl or alkenyl group or mixture, a (C8-C9) alkyl phenyl group, a R2CONH-CH2-CH2- group with R2 denoting an alkyl group; or linear or branched C11-C21 alkenyl, n is an integer or decimal number (average value) ranging from 2 to 24 and preferably from 2 to 10, A denotes H, NH 4, Na, K, Li, Mg or a monoethanolamine or triethanolamine residue. It is also possible to use mixtures of compounds of formula (II), in particular mixtures in which the groups R 1 are different. Preferably, R 1 denotes a group or a mixture of groups selected from C 12 -C 14 alkyl, cocoyl, oleyl, nonylphenyl, and octylphenyl; A denotes a hydrogen or sodium atom; and n ranges from 2 to 20, and preferably 2 to 10. More preferably, compounds of formula (II) in which R 1 is C 12 alkyl are used; 25 denotes a hydrogen or sodium atom; and n ranges from 2 to 10. Among the commercial products, it is preferable to use the products sold by CHEM Y under the names: AKYPO NP 70 (R1 = nonylphenyl, n = 7, A = H) AKYPO NP 40 ( R1 = nonylphenyl, n = 4, A = H) AKYPO OP 40 (R1 = octylphenyl, n = 4, A = H) AKYPO OP 80 (R1 = octylphenyl, n = 8, A = H) AKYPO OP 190 (R1 = octylphenyl, n = 19, A = H) AKYPO RLM 38 (R1 = C12-C14 alkyl, n = 4, A = H) AKYPO RLM 38 NV (R1 = C12-C14 alkyl, n = 4, A = Na) AKYPO RLM 45 (R1 = C12-C14 alkyl, n = 4.5, A = H) AKYPO RLM 45 NV (R1 = C12-C14 alkyl, n = 4.5, A = Na) AKYPO RLM (R1 = C12-C14 alkyl, n = 10, A = H) AKYPO RLM 100 NV (R1 = C12-C14 alkyl, n = 10, A = Na) AKYPO RLM 130 (R1 = C12-C14 alkyl) , n = 13, A = H) AKYPO RLM 160 NV (R1 = C12-C14 alkyl, n = 16, A = Na), or by SANDOZ under the names: SANDOPAN DTC-Acid (R1 = C13 alkyl , n = 6, A = H) SANDOPAN DTC (R1 = C13 alkyl, n = 6, A = Na) SANDOPAN LS 24 (R1 = C12-C14 alkyl, n = 12, A = Na) SANDOPAN JA 36 ( R1 = alkyl in C13, n = 18, A = H), and more particularly, the products sold under the following names: AKYPO RLM 45 (INCI: Laureth-5 carboxylic acid) AKYPO RLM 100 AKYPO RLM 38. The surfactant (s) (B) are preferably from 0.5% to 15% by weight, in particular from 1% to 10% by weight, more preferably from 1.5% to 8% by weight, and more preferably from 2% to 5% by weight, weight, relative to the total weight of the composition.

Amphoteric (s) and / or zwitterionic surfactant (s) (C)

The at least one amphoteric and / or zwitterionic surfactant may be in particular (non-limiting list) derivatives of aliphatic secondary or tertiary amines, in which the aliphatic substituent or substituents of the secondary or tertiary amine function are chosen from linear or branched chains comprising 8 to 22 carbon atoms and containing at least one water-soluble anionic group such as, for example, a carboxylate, sulphonate, sulphate, phosphate and / or phosphonate group; and / or betaines, such as those defined below. Among the amine derivatives that can be used in the context of the present invention, the products described in US Pat. following formula (III) or (IV):

formula (III): wherein R 2 -CO denotes a group or a mixture of groups chosen from C 6 -C 24 acyl groups, for example the C6-C24 acyl moiety corresponding to one of the fatty acids of the formula R2_000H present in the hydrolysed coconut oil, an octoyl group, a decoyl group, a dodecanoyl group, or a mixture of these groups, R3 denotes a beta-group; hydroxyethyl, R4 denotes a carboxymethyl group. formula (IV): R2, -CONHCH2CH2-N (B) (C) (IV)

in which: B represents -CH2CH2OX ', C represents - (CH2), -Y', with z = 1 or 2, X 'denotes the group -CH2CH2-COOH or a hydrogen atom, Y' denotes -COOH or the the group -CH 2 -CHOH-SO 3 H 2 -CO denotes a C 6 -C 24 acyl group, for example the C 6 -C 24 acyl part corresponding to one of the fatty acids of formula R 2_000H present in the hydrolysed coconut oil or the oil of lin, an octyl group, a decoy group, a dodecanoyl group, a stearoyl group, an isostearoyl group, an oleoyl group, or a mixture of these groups. These compounds are classified in the CTFA dictionary, under the names Disodium Cocoamphodiacetate, Disodium Lauroamphodiacetate, Disodium Caprylamphodiacetate, Disodium Capryloamphodiacetate, Disodium Cocoamphodipropionate, Disodium Lauroamphodipropionate, Disodium Caprylamphodipropionate, Disodium Capryloamphodipropionate, Lauroamphodipropionic Acid, Cocoamphodipropionic Acid. By way of example, mention may be made of the Disodium Cocoamphodiacetate marketed under the trade name MIRANOL C2M concentrated by the company Rhodia Chimie. Among the betaines that may be used in the context of the present invention, mention may be made of (C 8 -C 20) alkyl betaines, sulphobetaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines and (C 8 -C 20) alkylamidoalkyls. (C1-C6) sulfobetaines, optionally hydroxylated, alone or in mixtures. Preferably, the amphoteric and / or zwitterionic surfactant (s) employed in the present invention are selected from the above betaines and mixtures thereof. It is more particularly preferred to use the (C 8 -C 20) alkyl betaines, in particular the cocobetaine marketed by the company COGNIS under the name DEHYTON AB 30 in aqueous solution at 30% by weight of Active Matter (MA) relative to the total weight of the solution. ; the (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines, in particular cocamidopropylbetaine as sold under the name TEGOBETAINE F50 by the company GOLDSCHMIDT. Advantageously, the surfactant (s) (C) are chosen from betaines. The surfactant (s) (C) are present in amounts ranging preferably from 0.1% to 20% by weight, in particular from 1% to 15% by weight, more preferably from 2% to 10% by weight, and better still 3% to 7% by weight, relative to the total weight of the composition.

Nonionic surfactant (s) alkyl (poly) glycoside (D) "Alkyl (poly) glycoside" means an alkylpolyglycoside or an alkylmonoglycoside also called alkylglycoside in the present application, which may be alkoxylated with one or more oxide groups Preferably, the alkyl (poly) glycoside nonionic surfactants used, alone or in admixture (s), according to the present invention may be represented by the following formula (V): R 10 - (R 2 O) t (G) - (V)

wherein: R1 represents a saturated or unsaturated, linear or branched alkyl group having from about 8 to 24 carbon atoms, an alkylphenyl group having a linear or branched alkyl group of from 8 to 24 carbon atoms, R2 represents an alkylene group; comprising about 2 to 4 carbon atoms, G represents a saccharide unit having 5 to 6 carbon atoms, t denotes a value ranging from 0 to 10, preferably 0 to 4, and v denotes a value ranging from 1 to 15 Preferably, the alkyl (poly) glycoside nonionic surfactant (s) corresponds to the formula (V) in which: R1 denotes a saturated or unsaturated, linear or branched alkyl group containing from 8 to 18 carbon atoms, G denotes the glucose, fructose or galactose, and preferably glucose, t denotes a value ranging from 0 to 3, and is preferably equal to 0, and R2 and v are as defined above. The degree of polymerization of the alkyl (poly) glycoside nonionic surfactant (s), as represented for example by the index v in formula (V), varies on average from 1 to 15, and preferably from 1 to 4. The degree of polymerization varies more particularly from 1 to 2, and more preferably from 1.1 to 1.5, on average. The glycosidic linkages between the saccharide units are in 1,6 or 1,4; and preferably 1.4.

The compounds of formula (V) that may be used in the present invention are especially represented by the products sold by the company Cognis under the names PLANTAREN (600 CS / U, 1200 and 2000) or PLANTACARE (818, 1200 and 2000). It is also possible to use the products sold by the company SEPPIC under the trade names TRITON CG 110 (or ORAMIX CG 110) and TRITON CG 312 (or ORAMIX NS 10), the products sold by B.A.S.F. under the name LUTENSOL GD 70 or those sold by CHEM Y under the name AG10 LK.

It is also possible to use the alkyl (C 8 -C 16) polyglucoside in 1,4, for example in aqueous solution at 53% by weight of the total weight of the solution, marketed by COGNIS under the reference PLANTACARE 818 UP. The surfactant (s) are present in amounts ranging preferably from 0.1% to 20% by weight, in particular from 1% to 15% by weight, more preferably from 2% to 10% by weight, and better still from 3% to 8% by weight, relative to the total weight of the composition. The minimum amount of anionic (s), amphoteric (s) and / or zwitterionic (s), and nonionic (s) surfactants is that sufficient to give the composition a satisfactory foaming and / or detergent power. Too large amounts of surfactants do not really bring additional benefits. Thus, according to the invention, the total amount of anionic (s), amphoteric (s) and / or zwitterionic (s), and nonionic (s) surfactants may represent from 4% to 50% by weight, preferably from 6% to % to 35% by weight, and more preferably from 8% to 25% by weight, of the total weight of the composition. The weight ratio of the amount of surfactant (s) (A) to the amount of surfactant (s) (B) is preferably from 0.1 to 10, in particular from 0.5 to 5. The weight ratio of the amount of surfactant (s) (A) relative to the amount of surfactant (s) (C) is preferably from 0.1 to 10, in particular from 0.5 to 5, and more preferably from 0.7 to 2.

The weight ratio of the amount of surfactant (s) (A) to the amount of surfactant (s) (D) is preferably from 0.1 to 10, in particular from 0.2 to 5, and more preferably from 0, 5 to 1.5. The weight ratio of the amount of surfactant (s) (B) to the amount of surfactant (s) (C) is preferably from 0.1 to 10, in particular from 0.2 to 5, and more preferably from 0, 3 to 2.

Cationic Polymer (s) (E) The cationic polymer (s) that may be used in accordance with the present invention may be chosen from all those already known per se as improving the cosmetic properties of the hair treated with detergent compositions, namely in particular those described in the patent application EP-A-0 337 354 and in the French patent applications FR-A-2 270 846, FR-A-2 383 660, FR-A-2 598 611, FR-A-2 470 596, FR The preferred cationic polymer (s) are chosen from those which contain in their structure units containing primary, secondary, tertiary and / or quaternary amine groups which may, for example, be part of of the polymer backbone, be carried by a side substituent directly connected thereto. Among the cationic polymers, there may be mentioned more particularly the polymers of the family of polyamines, polyaminoamides and polyammonium quaternaries. Among these polymers, mention may be made of: (1) Homopolymers or copolymers derived from acrylic or methacrylic esters or amides, crosslinked or otherwise, and comprising at least one of the units of formulas (VI), (VII), (VIII ) or (IX) R 3 R 3 R 3 O 1 NNR R 2 R 4 R 6 AOA (VI) (VII) R 3 NH 1 A (VIII) 5 in which R 1 and R 2, which are identical or different, each represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms and preferably methyl or ethyl; R3, which may be identical or different, each denote a hydrogen atom or a CH3 group; A, which may be identical or different, each represents a linear or branched alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, each represents an alkyl group having from 1 to 6 carbon atoms or a benzyl group and preferably an alkyl group having from 1 to 6 carbon atoms; X- denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide. The polymers of family (1) may also contain one or more unit (s) derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetones acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyls (C1 -C4), acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Thus, among these polymers of the family (1), mention may be made of: copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company HERCULES the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride described, for example, in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY, the copolymer of acrylamide and methosulphate of methacryloyloxyethyltrimethylammonium sold under the name RETEN by the company HERCULES, - vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers quaternized or otherwise, such as the products sold under the name "GAFQUAT" by the company ISP such as "GAFQUAT 734" or "GAFQUAT 755 "or the products referred to as" COPOLYMER 845, 958 and 937 ". These polymers are described in detail in French patents 2,077,143 and 2,393,573, dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, such as the product sold under the name GAFFIX VC 713 by the company ISP, vinylpyrrolidone copolymers. / methacrylamidopropyl dimethylamine sold in particular under the name STYLEZE CC 10 by ISP, quaternized vinylpyrrolidone / dimethylaminopropyl methacrylamide copolymers such as the product sold under the name "GAFQUAT HS 100" by the company ISP, - crosslinked polymers of methacryloyloxyalkyl salts ( C1-C4) trialkyl (C1-C4) ammonium such as polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized by methyl chloride, homo or copolymerization followed by a r by an olefinically unsaturated compound, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil.

This dispersion is marketed under the name "SALCARE SC 92" by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are marketed under the names "SALCARE SC 95" and "SALCARE SC 96" by the company CIBA. (2) cationic polysaccharides, in particular cationic celluloses and cationic galactomannan gums. Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives comprising quaternary ammonium groups as described, for example, in French Patent 1,492,597, cellulose copolymers or cellulose derivatives grafted with a water-soluble monomer. quaternary ammonium, as described in particular in US Pat. No. 4,131,576, and cationic galactomannan gums as described, for example, in US Pat. Nos. 3,589,578 and 4,031,307. (3) Polymers consisting of piperazinyl units and divalent alkylene or straight or branched chain hydroxyalkylene groups, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as the oxidation and / or quaternization products of these polymers. Such polymers are especially described in French Patents 2 162 025 and 2 280 361. (4) The cationic polyaminoamides soluble in water, prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide or else by an oligomer resulting from the reaction of a bifunctional compound which is reactive with a bis-halohydrin, a bis-azetidinium, a bishaloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or bis-unsaturated derivative; these polyaminoamides can be alkylated if they contain one or more tertiary amine functions and / or one or more quaternized functions. Such polymers are described in particular in French Patents 2,252,840 and 2,368,508. (5) The polyaminoamide derivatives resulting from the condensation of polyalkylene-polyamines with polycarboxylic acids, followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid / dialkylaminohydroxyalkyl-dialkylenetriamine polymers in which the alkyl group contains from 1 to 4 carbon atoms and preferably denotes a methyl, ethyl or propyl group, and the alkylene group contains from 1 to 4 atoms. carbon, and preferably denotes the ethylene group. Such polymers are in particular described in French Patent 1,583,363. Among these derivatives, mention may be made more particularly of adipic acid / dimethylaminohydroxypropyl-diethylenetriamine polymers. (6) Polymers obtained by reaction of a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group, with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. Such polymers are especially described in US Pat. Nos. 3,227,615 and 2,961,347. (7) cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to the formulas ( Xa) or (Xb): (CH2) k (aH2) ti CR12 C (R12) -CH2-1H2C + ~ CH2 N / \ Y R10 R11 (CH2) k - (CH2) CR12 C (R12) ùCH2-H2C \ H2 R10 (Xa) (Xb)

in which k and t are equal to 0 or 1, the sum k + t being equal to 1; R12 denotes a hydrogen atom or a methyl group; R10 and R11, independently of one another, denote an alkyl group having 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, an amidoalkyl group; lower (ie whose alkyl part is C 1 -C 4), or R 10 and R 11 may designate together with the nitrogen atom to which they are attached, a heterocyclic group, such as piperidinyl or morpholinyl; Y-is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are described in particular in French patent 2,080,759 and in its certificate of addition 2,190,406.

Preferably, R 10 and R 11 denote, independently of one another, an alkyl group having 1 to 4 carbon atoms. Among the polymers defined above, homopolymers of dialkyldiallylammonium chloride may be mentioned, more particularly the homopolymer of dimethyldiallyl ammonium chloride (INCI name: Polyquaternium-6) sold under the name "MERQUAT 100" by the company NALCO ( and its low weight average molecular weight counterparts) and copolymers of dialkyldiallylammonium chloride, more particularly the copolymer of dimethyldiallylammonium chloride and acrylamide sold under the name "MERQUAT 550". (8) The quaternary diammonium polymers containing repeating units corresponding to the formula (XI): ## STR5 ## in which: R 13, R 14, R 15 and R 16, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic groups containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic groups (ie whose alkyl part is C 1 -C 4), or R 13, R 14, R 15 and R 16, together or separately, together with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen, or R13, R14, R15 and R16 each represent a linear or branched C1-C6 alkyl group substituted with a nitrile group, ester, acyl, amide or -CO-O-R17-E or -CO-NH-R17-E where R17 is an alkylene group and E is a quaternary ammonium group; Al and B1 represent polymethylene groups containing from 2 to 20 carbon atoms, which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more atoms oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and X- denotes an anion derived from a mineral or organic acid; A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; in addition, if Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene group, B1 may also designate a group: - (CH2) n -CO-E'-OC- (CH2) n- in which n denotes a number integer from 0 to 7 and E 'denotes a) a glycol residue of formula -OZO-, where Z denotes a linear or branched hydrocarbon group, or a group corresponding to one of the following formulas: - (CH2-CH2-O ) X-CH 2 -CH 2 - - [CH 2 -CH (CH 3) -O] y -CH 2 -CH (CH 3) - where x and y each denote an integer of 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon group, or the divalent group -CH 2 -CH 2 -S-S-CH 2 -CH 2 -; d) a ureylene group of formula -NH-CO-NH-. Preferably, X- is an anion such as chloride or bromide. Polymers of this type are described in particular in French Patents 2,330,330, 2,270,846, 2,316,271, 2,336,434 and 2,413,907 and US Patents 2,273,780, 2,375,853, 2,388,614 and 2,454,547. , 3,206,462, 2,261,002, 2,271,378, 3,874,870, 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945 and 027 020. It is more particularly possible to use polymers which consist of repeating units corresponding to the formula (XII): (XII) in which R13, R14, R15 and R16, which may be identical or different, each denote an alkyl or hydroxyalkyl group having About 1 to about 4 carbon atoms, n and p are integers ranging from about 2 to about 20, and X- is an anion derived from a mineral or organic acid. Preferably, R13, R14, R15 and R16 each denote a methyl group. As an example of a usable polymer of formula (XII), mention may be made of hexadimethrine chloride, sold under the name MEXOMERE PO by the company CHIMEX. (9) Quaternary polyammonium polymers consisting of units of formula (XIII):

R13 R20 ùN (CH2) r NHùCO (CH2) qùCOùNH (CH₂) sùNNA X R19 X R21 (XIII)

in which: R18, R19, R20 and R21, which may be identical or different, each represent a hydrogen atom or a methyl, ethyl, propyl, beta-hydroxyethyl or beta-hydroxypropyl group or -CH2CH2 (OCH2CH2) pOH, where p is equal to at 0 or an integer from 1 to 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom, r and s, which may be identical or different, are integers ranging from 1 to 6 , q is 0 or an integer from 1 to 34, R 15 -r (CH 2) n (CH 2) p XR X- X- denotes an anion such as a halide, A denotes a group comprising two halogen atoms or is preferably CH2CH2OCH2-CH2. Such compounds are described in particular in patent application EP-A-122,324. For example, Mirapol A15, Mirapol AD1, Mirapol AZ1 and Mirapol 175 sold by Miranol can be mentioned among them. (10) Quaternary polymers of vinyllactam (such as vinylpyrrolidone or vinylcaprolactam) and vinylimidazole. (11) Cationic vinylamide homopolymers or copolymers and in particular partially hydrolysed vinylamide homopolymers such as poly (vinylamine / vinylamide). These polymers are formed from at least one vinylamide monomer corresponding to the following formula:

H2C = CR2NRC (0) R1

wherein R, R 1 and R 2 are each selected from hydrogen, C 1 -C 20 alkyl, aryl and alkylaryl wherein the alkyl portion comprises 1 to 20 carbon atoms. In particular, said monomer may be chosen from N-vinylformamide, N-methyl-N-vinylacetamide and N-vinylacetamide. Poly (vinylamine / N-vinylformamide) as marketed under the name CATIOFAST VMP by the company BASF in aqueous solution at 16% by weight of the total weight of the solution or under the name LUPAMIN 9030 by the company BASF is preferably used. These polymers may be formed, for example, by radical polymerization of a vinylamide monomer and then partial acidic or basic hydrolysis of the amide functions to quaternizable amine functions, as described in applications WO 2007/005577, US Pat. Nos. 5,374,334, 6,426,383 and 6,894,110.

Other cationic polymers which can be used in the context of the invention are cationic proteins or hydrolysates of cationic proteins, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives.

Among these polymers, it is preferred to use those of the families (1), (7), (8), (9), (10), and (11) and the polyethyleneimines, alone or in mixture (s).

More preferably, the cationic polymer (s) (E) that can be used according to the invention are chosen, alone or as a mixture, from among

homopolymers or crosslinked copolymers of methacryloyloxy (C 1 -C 4 alkyl) tri (C 1 -C 4 alkyl) ammonium salts,

cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium chosen from homopolymers of diallyldimethylammonium chloride and copolymers of diallyldimethylammonium chloride and acrylamide. the quaternary diammonium polymers containing recurring units corresponding to formula (XI): ## STR1 ##

R14 X R16 X (XI) wherein R13, R14, R15 and each an alkyl carbon group; Al represents a R16, identical or different, represent or hydroxyalkyl, having from 1 to 4 atoms of group (CH2) p, and B1 represents a group (CH2) p, with n and p integers ranging from 2 to about 20; and X- denotes an anion derived from a mineral or organic acid. quaternary polymers of vinylpyrrolidone and of vinylimidazole, copolymers of vinylamine / N-vinylformamide, and polyethyleneimines.

The composition according to the invention preferably comprises one or more cationic polymers whose cationic charge density is greater than or equal to 4 milliequivalents per gram (meq / g), preferably greater than or equal to 5 milliequivalents per gram (meq / g). more preferably from 5 to 20 meq / g, and more preferably from 5.5 to 10 meq / g. Among all the cationic polymers that may be used in the context of the present invention, it is preferred to use, alone or in admixture (s), one or more cationic polymers chosen from cationic cyclopolymers, in particular homopolymer of dimethylammonium chloride, sold under the name MERQUAT 100 by the company NALCO, the diammonium quaternary polymers, and the vinylamine / N-vinylformamide copolymers. The polymer or polymers (E) are present in amounts ranging preferably from 0.01% to 10% by weight, in particular from 0.05% to 10% by weight, and more preferably from 0.1% to 5% by weight, relative to the total weight of the composition.

Ultraviolet filter (s) (F) The composition of the invention contains, as indicated previously, one or more filters (F) corresponding to the following formula (I):

OCH3 S03x (I)

with X denoting a hydrogen atom or a monovalent cation chosen from alkali metal ions such as sodium and potassium, ammonium ions and ions derived from organic amine bases such as monoethanolamine. Preferably, X denotes a hydrogen atom or Na +. The corresponding compounds are designated under the names BENZOPHENONE-4 or BENZOPHENONE-5.

The filter or filters (F) of formula (I) as defined above are present in amounts ranging preferably from 0.1% to 10% by weight, in particular from 0.2% to 8% by weight, and better still from 0.5% to 6% by weight, relative to the total weight of the composition.

The composition of the invention may also contain one or more beneficial agents for keratin materials, different from the filters (F) of the invention, different from the surfactants (A), (B), (C), (D) and polymers (E) above-mentioned. The beneficial agent (s) may be chosen from: (1) Saccharides, oligosaccharides, polysaccharides, nonionic, hydrolysed or otherwise, modified or not, (2) amino acids, oligopeptides, peptides, proteins, hydrolysed or not, modified or unmodified, (3) Non-oxyalkylenated, branched or unbranched fatty acids and alcohols, (4) Animal, vegetable or mineral waxes, (5) Ceramides and pseudo-ceramides, (6) Organic acids (7) UV filters other than filters (F) as defined above, (8) Antioxidants and anti-free radical agents, (9) Chelating agents, (10) Anti-dandruff agents, (11) Regulating agents of Seborrhea, (12) Soothing agents, (13) Cationic surfactants, (14) Organomodified or non-volatile silicones, whether volatile or not, (15) Mineral, vegetable or animal oils, (16) Polyisobutenes and poly (alpha- olefins), (17) Fatty acid esters, (18) Polymers soluble or dispersed anionic agents in the composition, (19) nonionic polymers which are soluble or dispersed in the composition. The composition according to the invention may comprise one or more saccharides, oligosaccharides and / or polysaccharides, nonionic, hydrolysed or otherwise, modified or otherwise. In general, compounds of this type which can be used in the present invention are chosen from those described in particular in Encyclopedia of Chemical Technology, Kirk-Othmer, Third Edition, 1982, Volume 3, pp. 896-900, and volume 15, pp. 439-458, in Polymers in Nature, by E.A.MacGREGOR and C.T.GREENWOOD, Editions John Wiley & Sons, chapter 6, pp. 240-328, 1980 and in the Industrial Gums - Polysaccharides and their Derivatives, edited by Roy L. WHISTLER, Second Edition, Academic Press Publishing Inc., the contents of these three works being fully included in this application for reference. . As examples of saccharides, oligosaccharides and polysaccharides, nonionic, hydrolysed or otherwise, modified or otherwise, that can be used in the invention, there may be mentioned glucans, modified starches or not (such as those derived, for example, cereals such as wheat, corn or rice, vegetables such as sweet pea, tubers such as potatoes or cassava) and different from starch betainate as described above, amyloidosis, amylopectin, glycogen, dextrans, beta-glucans, celluloses and their derivatives (methylcellulloses, hydroxyalkylcelluloses, ethylhydroxyethylcellulose), fructans, inulin, levan, mannan, xylan, lignins, arabans, galactans , galacturonans, chitin, glucoronoxylans, arabinoxylans, xyloglucans, galactomannans, pectic acids and pectins, alginic acid and alginates, arabinogalactans, carrageenans, agars, glycosaminoglucans, gum arabic, tragacanth gum, ghatti gum, karaya gum, locust bean gum, guar gum and xanthan gum, and mixtures thereof. The composition according to the invention may comprise one or more amino acids, oligopeptides, peptides, proteins, hydrolysed or otherwise, modified or otherwise, different from the polymers (E). As amino acids, there may be mentioned, for example, cysteine, lysine, alanine, N-phenylalanine, arginine, glycine, leucine, and mixtures thereof. As oligopeptides, peptides, proteins, hydrolysed or otherwise, modified or otherwise, different from the polymers (E) that can be used in the composition according to the invention, mention may be made of hydrolysates of wool proteins or silk, modified or not, vegetable proteins such as wheat proteins. The composition according to the invention may comprise one or more branched or unbranched fatty acids and alcohols, not oxyalkylenated.

Among the fatty acids that are suitable in the present invention, mention may especially be made of C 8 -C 30 carboxylic acids, such as palmitic acid, oleic acid, linoleic acid, myristic acid, stearic acid, lactic acid and the like. lauric acid, and mixtures thereof. The fatty alcohols that may be used in the present invention include, for example, C 8 -C 30 alcohols, for example palmitic, oleyl, linoleyl, myristyl, stearyl and lauryl alcohols, and mixtures thereof. The composition according to the invention may comprise one or more animal, vegetable or mineral waxes.

A wax, within the meaning of the present invention, is a lipophilic compound, solid at room temperature (about 25 ° C.), with a reversible solid / liquid state change, having a melting temperature greater than about 40 ° C. and that can go up to 200 ° C, and having in the solid state an anisotropic crystalline organization. In general, the size of the crystals of the wax is such that the crystals diffract and / or diffuse the light, conferring on the composition which comprises them a more or less opaque cloudy appearance. By bringing the wax to its melting temperature, it is possible to render it miscible with oils and to form a homogeneous mixture microscopically, but by bringing the temperature of the mixture to room temperature, a recrystallization of the wax in the oils of the mixture, detectable microscopically and macroscopically (opalescence).

As waxes that can be used in the present invention, mention may be made of waxes of animal origin, such as beeswax, spermaceti, lanolin wax and lanolin derivatives; vegetable waxes such as Carnauba wax, Candelilla wax, Ouricury wax, Japan wax, cocoa butter or cork fiber or sugarcane waxes; mineral waxes, for example paraffin, petrolatum, lignite or microcrystalline waxes or ozokerites, and mixtures thereof. The composition according to the invention may comprise one or more ceramides and / or pseudo-ceramides. Mention may in particular be made of class I, II, III and V ceramides according to the DAWNING classification, and mixtures thereof, and more particularly N-o-lysedeshydrosphingosine. The composition according to the invention may comprise one or more hydroxylated organic acids chosen from those well known and used in the art. There may be mentioned citric acid, lactic acid, tartaric acid, malic acid and mixtures thereof. The composition according to the invention may comprise one or more UV-A and / or UV-B active sun filters well known to those skilled in the art, different from the previously defined filters (F).

Dibenzoylmethane derivatives such as 4-methyldibenzoylmethane, 4-isopropyldibenzoylmethane, 4-tertbutyldibenzoylmethane, 2,4-dimethyldibenzoylmethane, 4-tertbutyl-4'-diisopropyldibenzoylmethane and p-amino acid may be mentioned in particular. benzoic acid and its esters such as 2-ethylhexyl p-dimethylaminobenzoate and N-propoxylated ethyl p-aminobenzoate, salicylates such as triethanolamine salicylate, cinnamic acid esters such as 4-methoxycinnamate of 2-ethylhexyl, methyl diisopropylcinnamate, menthyl anthranilate, benzotriazole derivatives, triazine derivatives, (3, 3'-diphenylacrylate derivatives such as 2-cyano-3,3-diphenylacrylate, 2-ethylhexyl and ethyl 2-cyano-3,3-diphenylacrylate, 2-phenylbenzimidazole-5-sulfonic acid and its salts, benzylidenecamphor derivatives, silicone filters, and mixtures thereof.

As antioxidants and anti-free radical agents that can be used in the present invention, mention may be made, for example, of ascorbic acid, ascorbyl compounds such as ascorbyl dipalmitate, t-butylhydroquinone, polyphenols such as phloroglucinol, sodium sulfite, erythorbic acid, flavonoids, and mixtures thereof. The composition according to the invention may comprise one or more chelating agents chosen in particular from EDTA (ethylenediaminetetraacetic acid) and its salts such as disodium EDTA and dipotassium EDTA, phosphate compounds such as sodium metaphosphate, sodium hexametaphosphate, tetrapotassium pyrophosphate, phosphonic acids and their salts, such as salts of ethylenediaminetetramethylenephosphonic acid, and mixtures thereof. The composition according to the invention may comprise one or more anti-dandruff agents chosen, for example, from: benzethonium chloride, benzalkonium chloride, chlorhexidine, chloramine T, chloramine B, 1,3-dibromo-5 5-dimethylhydantoin, 1,3-dichloro-5,5-dimethylhydantoin, 3-bromo-1-chloro-5,5-dimethylhydantoin, N-chlorosuccinimide; derivatives of 1-hydroxy-2-pyridone such as, for example, 1-hydroxy-4-methyl-2-pyridone, 1-hydroxy-6-methyl-2-pyridone and 1-hydroxy-4, 6-dimethyl-2-pyridone; - trihalocarbamides; - triclosan; azole compounds such as climbazole, ketoconazole, clotrinazole, econazole, isoconazole and miconazole b; antifungal polymers such as amphotericin B or nystatin; - selenium sulphides; sulfur in its various forms, cadmium sulphide, allantoin, tars of coal or wood and their derivatives in particular, cade oil, undecylenic acid, fumaric acid, allylamines such as terbinafine; or a mixture of these anti-dandruff agents. They can also be used in the form of their physiologically acceptable acid addition salts, in particular in the form of salts of sulfuric, nitric, thiocyanic, hydrochloric, hydrobromic, hydroiodic, phosphoric, acetic, benzoic, glycolic, aceturic, succinic acids. , nicotinic, tartaric, maleic, palmitic, methane sufonic, propanoic, 2-oxopropanoic, propanedioic, 2-hydroxy-1,4-butanedioic, 3-phenyl-2-propenoic, ethanesulfonic, 2-hydroxyethanesulfonic, 4-methylbenzenesulfonic, 4- amino-2-hydroxybenzoic, 2-phenoxybenzoic, 2-acetyloxybenzoic, picric, lactic, citric, malic, oxalic and amino acids. The anti-dandruff agents mentioned above may also optionally be used in the form of their physiologically acceptable organic or inorganic base addition salts. Examples of organic bases include alkanolamines of low molecular weight such as ethanolamine, diethanolamine, N-ethylethanolamine, triethanolamine, diethylaminoethanol, 2-amino-2-methylpropanedione; non-volatile bases such as ethylenediamine, hexamethylenediamine, cyclohexylamine, benzylamine, N-methylpiperazine; quaternary ammonium hydroxides, for example, trimethylbenzyl hydroxide; guanidine and its derivatives, and particularly its alkyl derivatives. Examples of inorganic bases include alkali metal salts, such as sodium or potassium; ammonium salts, alkaline earth metal salts, such as magnesium, calcium; cationic, tri or tetravalent metal salts, such as zinc, aluminum and zirconium. Alkanolamines, ethylenediamine and inorganic bases such as alkali metal salts are preferred. The composition according to the invention may comprise one or more seborrhea regulating agents such as succinylchitosan and poly-beta-alanine, and mixtures thereof. The composition according to the invention may comprise one or more soothing agents such as azylene and glycyrrhetinic acid, and mixtures thereof. The composition according to the invention may comprise one or more cationic surfactants that are well known per se, such as primary, secondary or tertiary fatty amine salts, optionally polyoxyalkylenated; quaternary ammonium salts such as tetraalkylammonium, alkylamidoalkyltrialkylammonium, trialkylbenzylammonium, trialkylhydroxyalkylammonium or alkylpyridinium chlorides or bromides; imidazoline derivatives; or oxides of amines with a cationic character.

The silicones that may be used in accordance with the invention may be soluble or insoluble in the composition, and they may in particular be polyorganosiloxanes that are insoluble in the composition of the invention; they may be in the form of oils, waxes, resins or gums.

Organopolysiloxanes are further defined in the work of Walter Noll Chemistry and Technology of Silicones (1968) Academic Press. They can be volatile or nonvolatile. When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic silicones containing from 3 to 7 silicon atoms and preferably from 4 to 5 silicon atoms. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name VOLATILE SILICONE 7207 by UNION CARBIDE or SILBIONE 70045 V 2 by RHODIA, decamethylcyclopentasiloxane sold under the name VOLATILE SILICONE 7158 by UNION CARBIDE, SILBIONE 70045 V 5 by RHODIA, as well as their mixtures.

Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the VOLATILE SILICONE FZ 3109 marketed by UNION CARBIDE, of chemical structure:

## STR1 ## with D: Cyclic silicone mixtures with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50), and the mixture of octamethylcyclotetrasiloxane and oxy-1,1- (hexa-2,2,2 ', 2', 3,3'-trimethylsilyloxy) bis-neopentane; (ii) linear volatile silicones having 2 to 9 silicon atoms and having a viscosity of less than or equal to 5.10.6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name SH 200 by Toray Silicone. Silicones included in this class are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, p.27-32 - TODD & BYERS Volatile Silicone fluids for cosmetics.

Among the non-volatile silicones, there may be mentioned polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, gums and silicone resins, polyorganosiloxanes modified with organofunctional groups, and mixtures thereof. The organomodified silicones that may be used in accordance with the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group. Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally containing C 6 -C 24 alkyl groups, such as the products known as dimethicone-copolyol sold by the company Dow Corning under the name DC 1248 or SILWET oils L 722, L 7500, L 77, L 711 from UNION CARBIDE and the (C 12) -methicone-copolyol alkyl marketed by the company Dow Corning under the name Q 2 5200; substituted or unsubstituted amine groups, such as the products sold under the name GP 4 Silicone Fluid and GP 7100 by the company Genesee or the products sold under the names Q2 8220 and Dow Corning 929 or 939 by the company Dow Corning. The substituted amino groups are, in particular, C1-C4 aminoalkyl groups; thiol groups, such as the products sold under the names GP 72 A and GP 71 from GENESEE; alkoxylated groups, such as the product sold under the name SILICONE COPOLYMER F-755 by SWS SILICONES and ABIL WAX 2428, 2434 and 2440 by the company GOLDSCHMIDT; hydroxyl groups, such as the hydroxyalkyl-functional polyorganosiloxanes described in the French patent application FR-A-8 516 334; acyloxyalkyl groups such as, for example, the polyorganosiloxanes described in US Pat. No. 4,957,732; anionic groups of the carboxylic acid type, for example in the products described in patent EP 186 507 of the company Chisso Corporation, or of the alkylcarboxylic type, such as those present in the product X-22-3701E from the company Shin-Etsu ; 2-hydroxyalkylsulfonate; 2-hydroxyalkylthiosulphate such as the products marketed by GOLDSHMIDT under the names ABIL 5201 and ABIL S255; hydroxyacylamino groups, such as the polyorganosiloxanes described in patent application EP 342 834. Mention may be made, for example, of the product Q2-8413 from the company Dow Corning. The composition according to the invention may comprise one or more mineral, vegetable or animal oils. These include vegetable oils, sweet almond oil, avocado oil, castor oil, olive oil, oil of j oj oba, oil sunflower oil, wheat germ oil, sesame oil, peanut oil, grape seed oil, soybean oil, rapeseed oil, safflower oil, coconut oil, corn oil, hazelnut oil, shea butter, palm oil, apricot kernel oil, calophyllum oil; as an oil of animal origin, perhydrosqualene; as oils of mineral origin, paraffin oil and petrolatum oil; and their mixtures. The composition according to the invention may comprise one or more polyisobutenes and poly (alpha-olefins), chosen from those well known in the art. The composition according to the invention may comprise one or more esters. Examples that may be mentioned include esters of fatty acids such as isopropyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, purcellin oil (stearyl octanoate), isononyl isononanoate or isostearyl, isopropyl lanolate, and mixtures thereof. Mention may also be made of esters of fatty alcohols. The composition according to the invention may comprise one or more anionic polymers which are soluble or dispersed in the composition and preferably in water, and which are well known per se. The anionic polymers generally used in the present invention are polymers containing groups derived from carboxylic, sulfonic or phosphoric acids, and having a weight-average molecular mass ranging from 500 to 5,000,000. In particular, these polymers are different from surfactants. (A) and (B) above. The carboxylic groups are provided by unsaturated mono- or di-carboxylic acid monomers, such as those corresponding to formula (XIV): ## STR2 ##

in which n is an integer ranging from 0 to 10, A denotes a methylene group, optionally linked to the carbon atom of the unsaturated group or to the neighboring methylene group when n is greater than 1, via a heteroatom such as oxygen or sulfur, R1 denotes a hydrogen atom, a phenyl or benzyl group, R2 denotes a hydrogen atom, a lower alkyl or carboxyl group, R3 denotes a hydrogen atom, a lower alkyl group, a group -CH 2 -COOH, phenyl or benzyl. In the formula (XIV) above, a lower alkyl group preferably contains from 1 to 4 carbon atoms and denotes in particular the methyl and ethyl groups. The anionic polymers with carboxylic groups that are preferred according to the invention are: a) homo- or copolymers of acrylic or methacrylic acid or their salts, and in particular the products sold under the names VERSICOL E or K by the company ALLIED COLLOID, ULTRAHOLD by BASF. Copolymers of acrylic acid and acrylamide sold in the form of their sodium salt under the names RETEN 421, 423 or 425 by the company HERCULES, the sodium salts of polyhydroxycarboxylic acids. b) copolymers of acrylic or methacrylic acids with a monoethylenic monomer such as ethylene, styrene, vinyl esters, esters of acrylic or methacrylic acid, optionally grafted onto a polyalkylene glycol such as polyethylene glycol, and optionally crosslinked. Such polymers are described in particular in French Patent 1,222,944 and German Application No. 2,330,956, copolymers of this type comprising in their chain an acrylamide unit optionally N-alkylated and / or hydroxyalkylated as described in particular in US Pat. Luxembourg patent applications 75370 and 75371 or proposed under the name QUADRAMER by AMERICAN CYANAMID. Mention may also be made of copolymers of acrylic acid and of C 1 -C 4 alkyl methacrylate and the copolymer of methacrylic acid and of ethyl acrylate sold under the name Luvimer MAEX by the company BASF. c) copolymers derived from crotonic acid, such as those comprising in their chain vinyl acetate or propionate units, and optionally other monomers such as the allyl or methallyl ester, vinyl ether or vinyl ester of a saturated carboxylic acid, linear or branched, long hydrocarbon chain, such as those comprising at least 5 carbon atoms, these polymers may optionally be grafted and crosslinked, or a vinyl ester, allyl or methallylique of an alpha or beta-cyclic carboxylic acid. Such polymers are described, inter alia, in French patents Nos. 1,222,944, 1,580,545, 2,265,782, 2,265,781, 1,564,110 and 2,439,798. Commercial products in this class are resins 28-29. 30, 26-13-14 and 28-13-10 sold by NATIONAL STARCH. d) Polymers derived from maleic, fumaric, itaconic acids or anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters; these polymers can be esterified. Such polymers are described in particular in US Pat. Nos. 2,047,398, 2,723,248, 2,102,113 and GB 839,805, and in particular those sold under the names GANTREZ AN or ES by the company ISP. Polymers also falling into this class are copolymers of maleic anhydride, citraconic anhydride, itaconic anhydride and an allyl or methallyl ester optionally containing an acrylamide, methacrylamide, an alpha-olefin, acrylic or methacrylic esters, acrylic or methacrylic acid group. or vinylpyrrolidone in their chain, the anhydrous functions are monoesterified or monoamidified. These polymers are for example described in French patents 2,350,384 and 2,357,241 of the applicant. e) polyacrylamides containing carboxylate groups. The polymers comprising the sulphonic groups are polymers comprising vinylsulphonic, styrenesulphonic, naphatalenesulphonic or acrylamidoalkylsulphonic units.

These polymers may especially be chosen from: polyvinylsulfonic acid salts having a molecular weight ranging from about 1,000 to 100,000, as well as copolymers with an unsaturated comonomer such as acrylic or methacrylic acids, and their esters, and acrylamide or its derivatives, vinyl ethers and vinylpyrrolidone; the salts of polystyrenesulphonic acid, the sodium salts, having a molecular mass ranging from about 500,000 to about 100,000 sold respectively under the names Flexan 500 and Flexan 130 by National Starch. These compounds are described in patent FR 2 198 719; polyacrylamidesulfonic acid salts such as those mentioned in US Pat. No. 4,128,631, and more particularly the polyacrylamidoethylpropanesulphonic acid sold under the name COSMEDIA POLYMER HSP 1180 by Henkel.

According to the invention, the anionic polymers are preferably chosen from acrylic acid copolymers such as the acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymer sold under the name ULTRAHOLD STRONG by the company BASF, the copolymers derived from crotonic acid such as vinyl acetate terpolymers / vinyl tert-butylbenzoate / crotonic acid and crotonic acid / vinyl acetate / vinyl neododecanoate terpolymers sold under the name Resin 28-29-30 by National Starch, the polymers derived therefrom of maleic, fumaric, itaconic acids or anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters, such as the methyl vinyl ether / monoesterified maleic anhydride copolymer sold under the name Gantrez ES 425 by ISP, copolymers of methacrylic acid and methacr methyl ylate sold under the name EUDRAGIT L by the company ROHM PHARMA, the copolymer of methacrylic acid and ethyl acrylate sold under the name LUVIMER MAEX by the company BASF, the vinyl acetate / crotonic acid copolymer sold under the name LUVISET CA 66 denomination by BASF and vinyl acetate / crotonic acid / polyethylene glycol terpolymer under the name ARISTOFLEX A by BASF. The most particularly preferred anionic polymers are chosen from the monoesterified methyl vinyl ether / maleic anhydride copolymer sold under the name Gantrez ES 425 by the company ISP, the copolymers of methacrylic acid and of methyl methacrylate sold under the name EUDRAGIT L by the company ROHM. PHARMA, the copolymer of methacrylic acid and ethyl acrylate sold under the name LUVIMER MAEX by the company BASF, the terpolymer of vinylpyrrolidone / acrylic acid / lauryl methacrylate sold under the name ACRYLIDONE LM by the company ISP.

According to the invention, it is also possible to use anionic polymers in the form of latex or pseudolatex, ie in the form of an aqueous dispersion of insoluble polymer particles. The composition according to the invention may also comprise one or more nonionic polymers which are soluble or dispersed in the composition and preferably in water. In particular, these polymers are different from the surfactants (D) mentioned above. As nonionic polymers that may be used according to the present invention, mention may be made in particular of: homopolymers of vinylpyrrolidone; copolymers of vinylpyrrolidone and of vinyl acetate; polyalkyloxazolines such as the polyethyloxazolines proposed by Dow Chemical under the names PEOX 50 000, PEOX 200 000 and PEOX 500 000; homopolymers of vinyl acetate, such as the product sold under the name APPRETAN EM by Hoechst or the product sold under the name RHODOPAS A 012 by the company RHONE POULENC; copolymers of vinyl acetate and of acrylic ester, such as the product sold under the name RHODOPAS AD 310 from RHONE POULENC; copolymers of vinyl acetate and of ethylene, such as the product sold under the name Appretan TV by the company Hoechst; copolymers of vinyl acetate and of maleic ester, for example of dibutyl maleate, such as the product sold under the name APPRETAN MB EXTRA by the company Hoechst; copolymers of polyethylene and maleic anhydride; homopolymers of alkyl acrylates and homopolymers of alkyl methacrylates such as the product sold under the name MICROPEARL RQ 750 by the company MATSUMOTO or the product sold under the name LUHYDRAN A 848 S by the company BASF; copolymers of acrylic esters such as, for example, copolymers of alkyl acrylates and of alkyl methacrylates, such as the products offered by the company Rohm & Haas under the names PRIMAL AC-261 K and EUDRAGIT NE 30 D , by the company BASF under the names ACRONAL 601, LUHYDRAN LR 8833 or 8845, by HOECHST under the names APPRETAN N 9213 or N 9212; the copolymers of acylonitrile and of a nonionic monomer chosen, for example, from butadiene and alkyl (meth) acrylates, mention may be made of the products sold under the names Nipol LX 531 8 by the company Nippon ZEON or those proposed under the name CJ 0601 8 by the company Rohm &Haas; polyurethanes such as the products sold under the names ACRYSOL RM 1020 or ACRYSOL RM 2020 by the company ROHM & HAAS, the URAFLEX XP 401 UZ products, URAFLEX XP 402 UZ by the company DSM RESINS; copolymers of alkyl acetate and urethane such as the product 8538-33 by the company National Starch; polyamides, such as the product ESTAPOR LO 11 proposed by RHONE POULENC; When the beneficial agent or agents different from the filters (F), surfactants (A), (B), (C), (D) and cationic polymers (E) used according to the invention, are present in the composition of the the invention are each present in amounts of preferably from 0.001% to 20% by weight, in particular from 0.005% to 15% by weight, more preferably from 0.01 to 12% by weight, and more preferably from 0 to , 1% to 5% by weight, relative to the total weight of the composition. The composition according to the invention preferably has a pH ranging from 3 to 8. Preferably, this pH ranges from 4 to 7.5. Adjusting the pH to the desired value can be done conventionally by adding a base (organic or inorganic) in the composition, for example sodium hydroxide, ammonia or a primary, secondary or tertiary (poly) amine such as monoethanolamine, diethanolamine, triethanolamine, isopropanolamine or 1,3-propanediamine, or by adding a mineral or organic acid, preferably citric acid or hydrochloric acid. The composition according to the invention preferably comprises a cosmetically acceptable medium. The cosmetically acceptable medium may be an aqueous medium consisting solely of water or of a mixture of water and one or more cosmetically acceptable solvents, such as a lower C 1 -C 4 alcohol, such as ethanol, lemon isopropanol, t-butanol, n-butanol; alkylene glycols such as propylene glycol, hexylene glycol; glycerol; or their mixtures. The composition according to the invention preferably comprises at least 30% by weight of water, in particular from 50% to 90% by weight and more preferably from 70% to 85% by weight, relative to the total weight of the composition. The composition according to the invention may further comprise compounds (A), (B), (C), (D), (E) and (F) as defined above, one or more viscosity-regulating agents such as thickening agents such as natural or synthetic polymeric thickeners, anionic, amphoteric, zwitterionic, nonionic or cationic, associative or not, nonpolymeric thickeners such as acids or electrolytes, and especially nonionic and / or anionic thickeners. Mention may in particular be made of scleroglucans, xanthan gums, alkanolamides of alkyl ether carboxylic acids, optionally ethoxylated with up to 5 moles of ethylene oxide, such as the product sold under the name AMINOL A15 by CHEM Y. crosslinked polyacrylic acids and acrylic acid / crosslinked C10-C30 alkyl acrylate copolymers. These viscosity-regulating agents are used in the composition according to the invention in proportions of up to 10% by weight relative to the total weight of the composition. The composition in accordance with the invention may also contain up to 5% by weight of pearlescent or opacifying agents well known in the state of the art, such as, for example, fatty alcohols, sodium or magnesium palmitates, stearates and sodium or magnesium hydroxystearates, fatty alcohols, fatty-chain acyl derivatives such as ethylene glycol or polyethylene glycol distearates, fatty-chain ethers such as, for example, distearyl ether or 1- (hexadecyloxy) - 2-octadecanol. The composition according to the invention may also contain additives such as foam synergists (such as C10-C18 1,2-alkanediols or C10-C18 fatty alkanolamides derived from mono or diethanolamine), perfumes, dyes , inorganic or organic particles, preservatives, pH stabilizers. By "additive" is meant a compound different from the compounds (A), (B), (C), (D), (E) and (F) used according to the invention and added in a composition of the invention. Those skilled in the art will take care to choose the optional additive (s) and their amounts so that they do not adversely affect the properties of the compositions of the present invention. This or these additives are each generally present in the composition according to the invention in an amount ranging from 0% to 20% by weight, relative to the total weight of the composition. Of course, those skilled in the art will take care to choose this or these optional additional compounds and / or their amounts so that the cosmetic properties intrinsically attached to the composition according to the invention are not, or not substantially, altered by the addition or additions envisaged. The foaming power of the composition according to the invention, characterized by a height of foam, is generally greater than 75 mm; preferably greater than 100 mm measured according to the modified ROSS-MILES method (NF T 73-404 / ISO 696). The modifications of the method are the following: the measurement is made at the temperature of 22 ° C with osmosis water. The concentration of the solution is 2 grams per liter. The height of the fall is 1 meter. The amount of composition that falls is 200 milliliters. These 200 ml of composition fall into a test tube having a diameter of 50 mm and containing 50 ml of the test composition. The measurement is made 5 minutes after stopping the flow of the composition.

The composition of the invention may be in the form of a more or less thickened liquid, cream or gel, foam, wax, water-in-oil emulsion (W / O), oil-in-water (O / W) or multiple emulsion and is mainly suitable for washing and caring for keratin materials, in particular hair and skin, and more particularly hair. Another subject of the invention is a process for washing and conditioning keratinous substances, in particular human keratinous fibers such as the hair, consisting in applying to said wetted keratinous materials an effective quantity of a composition according to the invention, then rinse with water after a possible pause time. The composition according to the invention is preferably used as a shampoo for washing and conditioning hair which is applied to wet hair in an amount effective to wash, the foam generated by massage or friction with the hands is then removed after a possible pause time, by rinsing with water, the operation being repeatable one or more times. The pause time can vary from 0.5 to 5 minutes.

The composition according to the invention can also be used as a shower gel for washing and conditioning the hair and / or the skin, which is applied to the skin and / or wet hair and then rinsed with water after application. Finally, the subject of the invention is also a dyeing kit comprising a first compartment containing a direct hair dyeing or oxidation product in one or two parts, and a second compartment comprising a composition according to the invention.

The following examples are given by way of illustration of the present invention, and can not limit the scope thereof.

EXAMPLES Staining step:

The following colored locks are prepared.

At the time of use, the coloring composition A below is mixed with hydrogen peroxide (20 volumes) weight for weight. Coloring composition A% by weight of the dye composition A propylene glycol 8 Butoxydiglycol 9 Oleyl alcohol 6 Oleic acid 3 2-polyglyceryl-oleyl ether 6-polyglyceryl-oleyl ether 7.7 Diethylaminopropyl 5,5 cocoaspartamide of sodium at 55% by weight in 1 water PEG-2-oleamine 7 alkyl monoethanolamide (C13 / C15, 70/30, 50% linear) carboxylic ether with 2 moles of ethylene oxide Pentasodium pentetate at 40% by 2.4 wt. water Ammonium acetate 0.8 96 Denatured ethyl alcohol 7 Erythorbic acid 0.31 Phenyl methyl pyrazolone 0.15 Sodium metabisulfite 0.46 p-Phenylenediamine 0.06 2,4-Diaminophenoxyethanol HCl 0.11 Ammonia at 20 5% by weight of NH 3 in water Demineralized water qs The mixture is then applied to strands of hair with 90% white hair permed at a rate of about 10 grams of dye mixture per gram of locks of hair. After a pause time of 15 minutes, the staining is then stopped by rinsing with water and then the locks are washed with a commercial DOP shampoo and are dried for 30 minutes with the helmet at 60 ° C.

EXAMPLE 1 Step of shampoos:

The following shampoo compositions were made. The amounts are indicated in percent by weight of active ingredient (MA) relative to the total weight of the composition. Shampoos ABC Coco glucoside [1] 5.0 5.0 5.0 Coco betaine [2] 5.4 5.4 5.4 Lauryl ether carboxylate (50E) sodium 3.0 3.0 3.0 [3] ] Sodium lauryl ether sulfate (2.2 0E) 4.0 4.0 4.0 [4] Hexadimethrin chloride [5] 1.0 - - Polyquaternium-6 [6] - 1.0 - Poly (vinylamine / N-vinylformamide) [7] - - 1.0 Benzophenone-4 [8] 5.0 5.0 5.0 Preservative qs qs q.s.10 Perfume q.s. qs qs Buffer q.s. pH = 5 q.s. pH = 5 qs pH = 5 Water q.s. 100 q.s. 100 q.s. 100 [1] PLANTACARE 818 UP marketed by COGNIS [2] DEHYTON AB 30 marketed by COGNIS [3] AKYPO RLM 45 CA marketed by KAO [4] TEXAPON N 702 marketed by COGNIS [5] MEXOMERE PO marketed by CHIMEX [6] MERQUAT 100 marketed by NALCO [7] CATIOFAST VMP marketed by BASF [8] UVINUL MS 40 marketed by BASF 0.4 gram of each of these shampoos is applied to locks of hair of 1 gram permed stained by the coloring composition A. The wicks are mixed for 15 seconds, left for 5 minutes and then rinsed for 10 seconds with water at 30 ° C and finally combed. The wet locks are then dried in the helmet 30 minutes at 60 ° C. Shampoos made according to the invention show very good qualities of use with a good start of foam, a good rinsability of the product and a good quality of the touch (softness) after rinsing.

Evaluation of the deposit of benzophenone-4: For each of the locks of hair washed with shampoo A, B or C, the amount of benzophenone-4 brought to the hair by the shampoo is then measured by assaying benzophenone-4 by HPLC chromatography. / UV after extraction of locks of hair treated with methanol shampoo. The amount of benzophenone-4 provided to the hair by the shampoo is defined by the absorbance measured on one of the filter absorption characteristic bands (322 5 nm). These measurements are performed after 1 or 5 washes with shampoo on the hair according to the protocol above. The results are collated in the following table and graph: Quantity of After 1 wash After 5 washes benzophenone-4 shampoo shampoo given to the hair in micrograms Shampoo A 1455 1924 Shampoo B 1186 2249 Shampoo C 706 963 Quantity of UV filter deposited ( in pg per g of hair) D After 1 wash after 5 washes ABC

We observe that despite rinsing with water after each application of the shampoo on the hair, significant amounts of UV filters are found on the hair treated with the shampoos A 10 to c of the invention. The shampoos A, B and C of the invention therefore allow a deposit of the UV filter benzophenone-4 important. EXAMPLE 2 - Protection of the color of dyed hair Step of shampoos:

The following shampoo compositions were made. Quantities are indicated as percent by weight of active ingredient (MA) based on the total weight of the composition. D Coco glucoside shampoo [1] 5.0 Coco betaine [2] 7.2 Sodium lauryl ether carboxylate (5OE) [3] 2.0 Sodium lauryl ether sulphate (2.2 0E) [4] 4.0 Poly (vinylamine / N-vinylformamide) [5] 0.24 Benzophenone-4 [6] 5.0 Preservative qs Perfume q.s. Potassium chloride q.s. Buffer q.s. pH = 5 Water q.s. 100 [1] PLANTACARE 818 UP marketed by COGNIS 10 [2] DEHYTON AB 30 marketed by COGNIS [3] AKYPO RLM 45 CA marketed by KAO [4] TEXAPON N 702 marketed by COGNIS [5] CATIOFAST VMP marketed by BASF [8] UVINUL MS 40 sold by BASF The application protocol is the same as for example 1. The application of shampoo D is repeated 5 times. The procedure is carried out with a commercial shampoo without filter.

Evaluation of color protection against UV / visible radiation: The colored and shampooed wicks are then exposed to UV / visible radiation for half of their length for a period of 18 hours by a solar simulator. Xenon lamp reproducing a reproducible light spectrum and close to that of the sun (Suntest XLS marketed by Atlas). The other half of the wick is obscured by card stock. The degradation of the color after exposure to UV / visible radiation is evaluated visually between the areas of masked and unmasked wicks. The photo-protective contribution of the various treatments is evaluated with respect to an untreated colored wick. Spectro-colorimetric monitoring accompanies these assessments. Measurements are made using the MINOLTA CM2022 spectrocolorimeter, before and after exposure to UV / visible radiation. The degradation caused by the UV / visible radiation is expressed in AE: AE (exposed area - unexposed area) = \ (AL * 2 + Aa * 2 + Ab e), 20 AL *, Aa * and Ab * respectively representing the variation in the intensity of hair color before and after exposure to UV / visible light, variation in chromaticity on the green / red color axis before and after exposure to UV / visible light and variation in chromaticity on the blue / yellow color axis before and after exposure to UV / visible light. Results:

We observe, after exposure to UV / visible radiation, that the locks which have been washed by the shampoo D remain much more faithful to their original color than the locks washed by the commercial control shampoo.

These results are confirmed by the colorimetric measurements which indicate a significant increase in AE of the shampoo of the invention D compared to the wicks washed by the control shampoo. The shampoo D according to the invention thus makes it possible to bring about a significant improvement in the holding of the artificial color of the hair. UV / visible degradation AE (exposed area to unexposed area) Protection Gain in AE compared to untreated locks After 5 applications of shampoo Shampoo 7.3 control Shampoo 5.2 D yes

Claims (21)

REVENDICATIONS1. Detergent cosmetic composition, characterized in that it comprises: one or more anionic surfactants (A) comprising in their structure one or more sulfate and / or sulphonate and / or phosphate groups; one or more carboxylic anionic surfactants (B) other than anionic surfactants mentioned in (A), one or more amphoteric and / or zwitterionic surfactants (C), one or more alkyl (poly) glycoside nonionic surfactants (D), one or more cationic polymers (E), and one or more filters (F) corresponding to the following formula (I): OCH 3 with X denoting a hydrogen atom or a monovalent cation chosen from alkali metal ions such as sodium and potassium, ammonium ions and ions from organic amine bases such as monoethanolamine. 2. Composition according to the preceding claim, characterized in that the total amount of anionic (s), amphoteric (s) and / or zwitterionic (s), and nonionic (s), varies from 4 to 50% by weight, preferably from 6% to 35% by weight, and more preferably from 3% to 25% by weight, based on the total weight of the composition. 3. Composition according to any one of claims 1 or 2, characterized in that the surfactant (s) (A) is (are) present (s) in concentrations ranging from 1% to 50% by weight, preferably from 2% to 25% by weight, relative to the total weight of the composition. 4. Composition according to any one of the preceding claims, characterized in that the surfactant (s) (B) is (are) present in concentrations ranging from 0.5% to 15% by weight, of preferably from 1% to 10% by weight, more preferably from 1.5% to 8% by weight, relative to the total weight of the composition. 5. Composition according to any one of the preceding claims, characterized in that the surfactant (s) (C) is (are) present in concentrations ranging from 0.1% to 20% by weight, of preferably from 1% to 15% by weight, more preferably from 2% to 10% by weight, relative to the total weight of the composition. 6. Composition according to any one of the preceding claims, characterized in that the surfactant (s) (D) is (are) present in concentrations ranging from 0.1% to 20% by weight, of preferably from 1% to 15% by weight, relative to the total weight of the composition. 7. Composition according to any one of the preceding claims, characterized in that at least one of the weight ratios, and preferably all the weight ratios of the amount of surfactant (s) (A) to the amount of surfactant (s) (B) or the amount of surfactant (s) (A) to the amount of surfactant (s) (C), or the amount of surfactant (s) (A) to the amount of surfactant (s) (D) , or the amount of surfactant (s) (B) on the amount of surfactant (s) (C) is from 0.1 to 10. 8. Composition according to any one of the preceding claims, characterized in that the surfactant (s) (A) is (are) chosen (s), alone or in admixture (s), from alkyl sulphates, alkylamidosulfates, alkyl ether sulphates, alkylamidoether sulphates, alkylaryl ether sulphates, alkyl ether sulphosuccinates, acyl isethionates, methyl acyl taurates, and their salts, in particular the alkaline salts, the ammonium salts, the amine salts, including the amino alcohols salts, and / or magnesium salts; the alkyl or acyl group of all these different compounds preferably comprising from 8 to 24 carbon atoms, and the aryl group preferably denoting a phenyl or benzyl group; said surfactants can be oxyethylenated and / or oxypropylenated. 9. Composition according to any one of the preceding claims, characterized in that the surfactant (s) (B) is (are) chosen (s), alone (s) or in mixture (s), from the following compounds and their salts: - (C6-C24) alkyl-D-galactoside uronic acids, acyl (C6-C24) sarcosinic acids, - acyl (C6-C4) lactylic acids, - acyl (C6-C4) acids glutamics, - (C6-C24) alkyl (poly) glycoside carboxylic acids, such as alkylglucoside acetates, alkylglucoside citrates and alkylpolyglycoside tartrates, - polyoxyalkylenated (C6-C24) alkylcarboxylic acids, in particular, those containing from 2 to 50 alkylene oxide groups, and preferably from 2 to 50 ethylene oxide groups, - polyoxyalkylenated (C6-C24) alkylarycarboxylic acids, in particular those containing from 2 to 50 alkylene oxide groups, and preferably from 2 to 50 ethylene oxide groups, - (C6-C24) alkyl acids polyoxyalkylenated carboxylic ether, in particular those containing from 2 to 50 alkylene oxide groups, and preferably from 2 to 50 ethylene oxide groups. 10. Composition according to any one of the preceding claims, characterized in that the surfactant (s) (C) is (are) chosen (s), alone (s) or in mixture (s), among the derivatives of aliphatic secondary or tertiary compounds, in which the aliphatic substituent (s) of the secondary or tertiary amine function are chosen from linear or branched chains containing 8 to 22 carbon atoms and containing at least one water-soluble anionic group such as a carboxylate group, sulphonate, sulphate, phosphate and / or phosphonate; and / or betaines selected from (C8-C20) alkyl betaines, sulfobetaines, (C8-C20) alkylamido (C1-C6) alkylbetaines and (C8-C20) alkylamido (C1-C6) alkyl sulfobetaines, optionally hydroxylated. 11. Composition according to any one of the preceding claims, characterized in that the surfactant or surfactants (D) are chosen, alone or in admixture (s), from the compounds corresponding to the following formula (V): R1O Wherein R 1 represents a linear or branched, saturated or unsaturated alkyl group having from about 8 to 24 carbon atoms, an alkylphenyl group whose linear or branched alkyl group comprises 8 to 24 carbon atoms, R2 is an alkylene group having about 2 to 4 carbon atoms, G is a saccharide unit having 5 to 6 carbon atoms, t is a value of 0 to 10, preferably 0 to 4, and v denotes a value ranging from 1 to 15. 12. Composition according to any one of the preceding claims, characterized in that the filter (s) (F) meets (ent) the formula (I) wherein X = H or Na +. 13. Composition according to any one of the preceding claims, characterized in that the filter (s) (F) is (are) present in concentrations ranging from 0.1% to 10% by weight, preferably from 0.2% to 8% by weight, and in particular from 0.5% to 6% by weight, relative to the total weight of the composition. 14. Composition according to any one of the preceding claims, characterized in that it further comprises one or more beneficial agent (s) different (s) of the filter (F), surfactants (A), ( B), (C), (D) and the polymer (E) as defined in any one of the preceding claims. 15. Composition according to any one of the preceding claims, characterized in that the cationic polymer (s) (E) is (are) chosen (s), alone or in admixture (s), from: 1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides, crosslinked or otherwise, and comprising at least one of the following units of formulas (VI), (VII), (VIII) or (IX): R3 R3 Wherein R1 and R2, which may be identical or different, each represents a hydrogen atom or a hydrogen atom, or alkyl group having 1 to 6 carbon atoms and preferably methyl or ethyl; R3, which may be identical or different, each denote a hydrogen atom or a CH3 group; A, which may be identical or different, each represents a linear or branched alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, each represents an alkyl group having from 1 to 6 carbon atoms or a benzyl group and preferably an alkyl group having from 1 to 6 carbon atoms; X- denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide. (2) cationic polysaccharides. (3) Polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent groups optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. (4) water-soluble cationic polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide or else by an oligomer resulting from the reaction of a bifunctional compound which is reactive with a bis-halohydrin, a bis-azetidinium, a bishaloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or bis-unsaturated derivative; these polyaminoamides may be alkylated if they contain one or more tertiary amine functions and / or one or more quaternized amine functional groups (5) The polyamino amide derivatives resulting from the condensation of polyalkylene-polyamines with polycarboxylic acids, followed by an alkylation by bifunctional agents. (6) Polymers obtained by reaction of a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group, with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. (7) cyclopolymers of alkyldiallylamine or dialkyldiallylammonium. (8) Quaternary diammonium polymers containing repeating units corresponding to formula (XI): ## STR5 ## in which: R 13, R 14, R 15 and R 16, which may be identical or different, represent groups aliphatic, alicyclic or arylaliphatic containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic groups (C1-C4), or R13, R14, R15 and R16, together or separately, together with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen, or R13, R14, R15 and R16 each represent a linear or branched C1-C6 alkyl group substituted with a nitrile, ester, acyl, amide or -CO group -O-R17-E or -CO-NHR17-E where R17 is an alkylene group and E a quaternary ammonium group; Al and B1 represent polymethylene groups containing from 2 to 20 carbon atoms, which may be linear or branched, saturated or unsaturated, and which may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, ammonium groups quaternary, ureido, amide or ester, and X- denotes an anion derived from a mineral or organic acid; A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; B1 which may denote the following group when Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene group: - (CH2) n -CO-E'-OC- (CH2) n- in which n denotes an integer of 0 to And E 'denotes a) a glycol residue of formula -OZO-, where Z denotes a linear or branched hydrocarbon group, or a group corresponding to one of the following formulas: - (CH2-CH2-O) x-CH2 -CH2- [CH2-CH (CH3) -O] y -CH2-CH (CH3) - where x and y each denote an integer of 1 to 4, representing a defined and unique degree of polymerization or any number of 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon group, or the divalent group -CH 2 -CH 2 -S-S-CH 2 -CH 2 -; d) a ureylene group of formula -NH-CO-NH-. (9) Quaternary polyammonium polymers consisting of units of formula (XIII): ## STR2 ## in which: R18, R19, R20 and R21 , identical or different, each represent a hydrogen atom or a methyl, ethyl, propyl, beta-hydroxyethyl, beta-hydroxypropyl or -CH 2 CH 2 (OCH 2 CH 2) pOH group, where p is 0 or an integer ranging from 1 at 6, provided that R18, R19, R20 and R21 are not simultaneously hydrogen, r and s, which may be identical or different, are integers from 1 to 6, q is 0 or a number integer from 1 to 34, X- denotes an anion such as a halide, A denotes a group having two halogen atoms or is preferably CH2CH2OCH2-CH2. (10) Vinylpyrrolidone and vinylimidazole quaternary polymers, (11) Cationic vinylamide homopolymers or copolymers and in particular partially hydrolysed vinylamide homopolymers such as poly (vinylamine / vinylamide), and cationic proteinins or cationic protein hydrolysates polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives. 16. Composition according to the preceding claim, characterized in that the cationic polymer (s) (E) is (are) chosen (s), alone (s) or in mixture (s), among: - the cross-linked homopolymers or copolymers of methacryloyloxy (C1-C4 alkyl) tri (C1-C4) alkylammonium salts, cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium chosen from homopolymers of diallyldimethylammonium chloride and copolymers of diallyldimethylammonium chloride and acrylamide, - quaternary diammonium polymers containing repeating units corresponding to the formula (XI): in which: R13, R14, R15 and R16, identical or different, represent an alkyl or hydroxyalkyl group, having from 1 to 4 atoms; about 15 carbon; Al represents a group (CH2) p, and B1 represents a group (CH2) p, with n and p integers ranging from 2 to about 20; and X- denotes an anion derived from a mineral or organic acid, quaternary vinylpyrrolidone and vinylimidazole polymers, vinylamine / N-vinylformamide copolymers, and polyethyleneimines. 17. Composition according to any one of the preceding claims, characterized in that the cationic polymer (s) 25 (E) is (are) present in concentrations ranging from 0.01% to 10%. % by weight, preferably from 0.05% to 10% by weight, and more preferably from 0.1% to 5% by weight, relative to the total weight of the composition. 18. Use of a composition as defined in any one of the preceding claims, for cleaning and / or removing make-up and / or conditioning of keratin materials. 19. Use of a composition as defined in any one of the preceding claims, for protecting the color of dyed hair, especially with respect to solar radiation, UV and / or repeated washings. 20. A process for washing and conditioning keratin materials, in particular human keratinous fibers such as the hair, comprising applying to said wetted keratinous materials an effective amount of a cosmetic composition as defined in any one of claims 1. to 17, then rinse with water after a possible pause time. 21. Staining kit comprising a first compartment containing a direct or oxidation capillary dyeing product in one or two parts, and a second compartment comprising a composition as defined in any one of Claims 1 to 17.