FR2655333B1 - Procede de preparation d'halogenoacetals a partir d'enamines. - Google Patents
Procede de preparation d'halogenoacetals a partir d'enamines.Info
- Publication number
- FR2655333B1 FR2655333B1 FR898915868A FR8915868A FR2655333B1 FR 2655333 B1 FR2655333 B1 FR 2655333B1 FR 898915868 A FR898915868 A FR 898915868A FR 8915868 A FR8915868 A FR 8915868A FR 2655333 B1 FR2655333 B1 FR 2655333B1
- Authority
- FR
- France
- Prior art keywords
- preparation
- halogenoacetals
- enamines
- haloacetals
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000002081 enamines Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- -1 halogen cation Chemical class 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 235000019155 vitamin A Nutrition 0.000 abstract 1
- 239000011719 vitamin A Substances 0.000 abstract 1
- 235000019165 vitamin E Nutrition 0.000 abstract 1
- 239000011709 vitamin E Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
- C07D295/067—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents attached to the same carbon chain, which is not interrupted by carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
- C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/30—Compounds having groups
- C07C43/313—Compounds having groups containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D317/16—Radicals substituted by halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR898915868A FR2655333B1 (fr) | 1989-12-01 | 1989-12-01 | Procede de preparation d'halogenoacetals a partir d'enamines. |
FR909004194A FR2655653B1 (fr) | 1989-12-01 | 1990-04-02 | Procede de preparation d'halogenoacetals a partir d'enamines. |
EP90403393A EP0430807A1 (fr) | 1989-12-01 | 1990-11-29 | Procédé de préparation d'halogénoacétals à partir d'énamines |
AT90403392T ATE106858T1 (de) | 1989-12-01 | 1990-11-29 | Verfahren zur herstellung von halogenacetalen aus enaminen. |
ES90403392T ES2055377T3 (es) | 1989-12-01 | 1990-11-29 | Procedimiento para la preparacion de halogenoacetales a partir de enaminas. |
DE69009698T DE69009698T2 (de) | 1989-12-01 | 1990-11-29 | Verfahren zur Herstellung von Halogenacetalen aus Enaminen. |
EP90403392A EP0430806B1 (fr) | 1989-12-01 | 1990-11-29 | Procédé de préparation d'halogénoacétals à partir d'énamines |
CA002031249A CA2031249A1 (fr) | 1989-12-01 | 1990-11-30 | Procede de preparation d'halogenoacetals a partir d'enamines |
JP2336847A JPH03209390A (ja) | 1989-12-01 | 1990-11-30 | エナミンからのハロアセタールの製造法 |
CA002031245A CA2031245A1 (fr) | 1989-12-01 | 1990-11-30 | Procede de preparation d'halogenoacetals a partir d'enamines |
JP2336846A JPH03220150A (ja) | 1989-12-01 | 1990-11-30 | エナミンからのハロアセタールの製造法 |
US07/620,610 US5145972A (en) | 1989-12-01 | 1990-12-03 | Process for preparing halo acetals from enamines |
US07/858,406 US5292897A (en) | 1989-12-01 | 1992-03-27 | Process for preparing halo acetals from enamines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR898915868A FR2655333B1 (fr) | 1989-12-01 | 1989-12-01 | Procede de preparation d'halogenoacetals a partir d'enamines. |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2655333A1 FR2655333A1 (fr) | 1991-06-07 |
FR2655333B1 true FR2655333B1 (fr) | 1992-02-21 |
Family
ID=9388026
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR898915868A Expired - Lifetime FR2655333B1 (fr) | 1989-12-01 | 1989-12-01 | Procede de preparation d'halogenoacetals a partir d'enamines. |
Country Status (8)
Country | Link |
---|---|
US (2) | US5145972A (fr) |
EP (1) | EP0430806B1 (fr) |
JP (1) | JPH03220150A (fr) |
AT (1) | ATE106858T1 (fr) |
CA (1) | CA2031249A1 (fr) |
DE (1) | DE69009698T2 (fr) |
ES (1) | ES2055377T3 (fr) |
FR (1) | FR2655333B1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5344995A (en) * | 1992-07-14 | 1994-09-06 | Basf Aktiengesellschaft | Preparation of cyclic acetals of 3-formyl-2-butenyltriphenylphosphonium chloride |
DE4426561A1 (de) * | 1994-07-27 | 1996-02-01 | Basf Ag | Verfahren zur Herstellung von Phosphonsäureestern |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3428633A (en) * | 1966-12-19 | 1969-02-18 | Monsanto Co | Salts of enaminoketones and processes for their preparation |
BE794872A (fr) * | 1972-02-02 | 1973-08-01 | Rhone Poulenc Sa | Nouvelles sulfones derivees de dimethyl-1,5 hexadiene-1,5 ylene |
NL176165C (nl) * | 1976-02-25 | 1985-03-01 | Rhone Poulenc Ind | Werkwijze voor het bereiden van halogeenacetalen van alkenisch onverzadigde aldehyden. |
NL175906C (nl) * | 1976-02-25 | 1985-01-16 | Rhone Poulenc Ind | Werkwijze voor het bereiden van halogeenacetalen van alkenisch onverzadigde aldehyden. |
US4087405A (en) * | 1977-08-26 | 1978-05-02 | Eastman Kodak Company | Polyhydrazides as stabilizers for polyolefins |
FR2655342A1 (fr) * | 1989-12-01 | 1991-06-07 | Rhone Poulenc Sante | Nouveaux intermediaires, leur procede de preparation et leur utilisation pour la synthese des vitamines a et e. |
-
1989
- 1989-12-01 FR FR898915868A patent/FR2655333B1/fr not_active Expired - Lifetime
-
1990
- 1990-11-29 EP EP90403392A patent/EP0430806B1/fr not_active Expired - Lifetime
- 1990-11-29 DE DE69009698T patent/DE69009698T2/de not_active Expired - Fee Related
- 1990-11-29 AT AT90403392T patent/ATE106858T1/de not_active IP Right Cessation
- 1990-11-29 ES ES90403392T patent/ES2055377T3/es not_active Expired - Lifetime
- 1990-11-30 CA CA002031249A patent/CA2031249A1/fr not_active Abandoned
- 1990-11-30 JP JP2336846A patent/JPH03220150A/ja active Pending
- 1990-12-03 US US07/620,610 patent/US5145972A/en not_active Expired - Fee Related
-
1992
- 1992-03-27 US US07/858,406 patent/US5292897A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ATE106858T1 (de) | 1994-06-15 |
US5145972A (en) | 1992-09-08 |
ES2055377T3 (es) | 1994-08-16 |
DE69009698T2 (de) | 1994-11-03 |
DE69009698D1 (de) | 1994-07-14 |
CA2031249A1 (fr) | 1991-06-02 |
JPH03220150A (ja) | 1991-09-27 |
EP0430806A1 (fr) | 1991-06-05 |
FR2655333A1 (fr) | 1991-06-07 |
EP0430806B1 (fr) | 1994-06-08 |
US5292897A (en) | 1994-03-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES555147A0 (es) | Un procedimiento para la produccion de un compuesto de tiazolidindiona hipoglicemico | |
FR2507183B1 (fr) | Procede de preparation d'acides 6,8-difluoro-1,4-dihydro-4-oxo-quinoleine-3-carboxyliques | |
SE8902264L (sv) | 2-(5-fluoronikotinoyl)-aettiksyraderivat och foerfarande foer framstaellning av detta | |
FI833918A (fi) | -karboliner, foerfarande foer deras framstaellning och dessa innehaollande farmaceutiska preparat | |
NO894410D0 (no) | Fremgangsmaate for fremstilling av 3,5-dimetyl-4-metoksypyridinderivater samt nye mellomprodukter for dette formaal. | |
AU566685B2 (en) | 2-(3,4-dihydroxyphenyl)-3,4-dihydro-24-1-benzopyran- 3,5,7-triol | |
MA21122A1 (fr) | Procede de preparation de derives d'acides aminocarboxyliques bicycliques . | |
FR2655333B1 (fr) | Procede de preparation d'halogenoacetals a partir d'enamines. | |
FI951378A0 (fi) | N-asetyyli-neuramiinihapon johdannaisten synteesi | |
EP0240431A3 (en) | Process for the preparation of ethylenic carbonyl compounds | |
BG44203A3 (en) | Method for preparing of 2- oxyindol- 1- carboxamides | |
FR2552761B1 (fr) | Procede de transformation directe d'un aldehyde en un ester ethylenique, nouvelles molecules synthetisees | |
MX9404783A (es) | Procedimiento para la preparacion de erdosteina. | |
FR2655645B1 (fr) | Procede de preparation d'acides hexenediouiques-1,6 a partir du butenediol. | |
FR2786772B1 (fr) | Procede de preparation d'un aldose ou derive d'aldose par decarboxylation | |
IL100916A0 (en) | Manufacture of alpha,beta unsaturated aldehydes and ketones | |
DE3560017D1 (en) | Tetraene, its preparation and its use | |
IT8221219A0 (it) | Procedimento per la produzione di alfa-aminoderivati ciclici di 1(3',4'-metilendiossifenil)etanolo . | |
SU825518A1 (ru) | Способ получения мононадфталевой кислоты 1 | |
FR2624511B1 (fr) | Procede enantioselectif pour preparer des derives de l'aldehyde hemicaronique de structure trans ou cis | |
FR2661408B1 (fr) | Procede de preparation de citral. | |
ATE120463T1 (de) | Dienoxysilane, verfahren zu ihrer herstellung und alpha-ethylenische alpha-halogenierte aldehyde davon erreichbar. | |
ES2070517T3 (es) | Productos intermedios en la preparacion del acido 4,5-difluoroantranilico. | |
FR2655644B1 (fr) | Procede de preparation d'acides hexenediouiques-1,6. | |
FR2675502B1 (fr) | Procede de purification de la pseudo-ionone. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |