FR2650827B1 - Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium - Google Patents
Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadiumInfo
- Publication number
- FR2650827B1 FR2650827B1 FR8910856A FR8910856A FR2650827B1 FR 2650827 B1 FR2650827 B1 FR 2650827B1 FR 8910856 A FR8910856 A FR 8910856A FR 8910856 A FR8910856 A FR 8910856A FR 2650827 B1 FR2650827 B1 FR 2650827B1
- Authority
- FR
- France
- Prior art keywords
- vanadium
- support
- mgcl2
- liquid hydrocarbon
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 title 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 2
- 150000003682 vanadium compounds Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000009826 distribution Methods 0.000 abstract 1
- 229920001198 elastomeric copolymer Polymers 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000012798 spherical particle Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Laminated Bodies (AREA)
- Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Steroid Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (22)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8910856A FR2650827B1 (fr) | 1989-08-08 | 1989-08-08 | Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium |
US07/561,786 US5070054A (en) | 1989-08-08 | 1990-08-02 | Process for preparing a vanadium-based catalyst suitable for olefin polymerization |
AT90308541T ATE113614T1 (de) | 1989-08-08 | 1990-08-02 | Verfahren zur herstellung eines katalysators vom ziegler-natta-typ für olefinpolymerisation. |
DE69013798T DE69013798T2 (de) | 1989-08-08 | 1990-08-02 | Verfahren zur Herstellung eines Katalysators vom Ziegler-Natta-Typ für Olefinpolymerisation. |
ES90308541T ES2063281T3 (es) | 1989-08-08 | 1990-08-02 | Proceso para preparar un catalizador basado en vanadio adecuado para polimerizacion de olefinas. |
EP90308541A EP0412729B1 (fr) | 1989-08-08 | 1990-08-02 | Procédé de préparation d'un catalyseur de type Ziegler-Natta à base de vanadium |
FI903887A FI903887A0 (fi) | 1989-08-08 | 1990-08-06 | Foerfarande foer framstaellning av en vanadinbaserad katalyt laempad foer polymerisation av olefiner. |
CA002022815A CA2022815C (fr) | 1989-08-08 | 1990-08-07 | Methode de preparation d'un catalyseur a base de vanadium, utile pour la polymerisation d'olefines |
MYPI90001314A MY108533A (en) | 1989-08-08 | 1990-08-07 | Process for preparing a vanadium-based catalyst suitable for olefin polymerisation. |
NO903462A NO175061B (no) | 1989-08-08 | 1990-08-07 | Fremgangsmåte for fremstilling av en vanadiumbasert katalysator egnet for olefinpolymerisasjon samt fremgangsmåte for fremstilling av (ko-)polymerer av olefiner |
HU904927A HUT59701A (en) | 1989-08-08 | 1990-08-07 | Process for producing catalyst of vanadium base and utilizing it for polymerizing olefines |
JP2208320A JPH0381303A (ja) | 1989-08-08 | 1990-08-08 | オレフィン重合に適したバナジウム―ベース触媒の製造方法 |
KR1019900012157A KR0172119B1 (ko) | 1989-08-08 | 1990-08-08 | 올레핀 중합용으로 적절한 바나듐-기재촉매의 제조방법 |
CN90107787A CN1025339C (zh) | 1989-08-08 | 1990-08-08 | 制备适用于烯烃聚合的钒基催化剂的方法 |
NZ234816A NZ234816A (en) | 1989-08-08 | 1990-08-08 | Process for preparing a vanadium-based ziegler-natta type catalyst for polymerising olefins, a process using the catalyst and elastomeric polymers |
AU60827/90A AU639248B2 (en) | 1989-08-08 | 1990-08-08 | Process for preparing a vanadium-based catalyst suitable for olefin polymerisation |
BR909003878A BR9003878A (pt) | 1989-08-08 | 1990-08-08 | Processo para a preparacao de um catalisador do tipo ziegler-natta e uso do mesmo |
DD90343336A DD299652A5 (de) | 1989-08-08 | 1990-08-08 | Verfahren zur herstellung eines katalysators von ziegler - auf der basis von vanadin, der fuer die olefinpolymerisation geeignet ist |
SU904830915A RU2033257C1 (ru) | 1989-08-08 | 1990-08-08 | Способ получения катализатора |
US07/736,791 US5208303A (en) | 1989-08-08 | 1991-07-29 | Process for preparing a vanadium-based catalyst suitable for olefin polymerization |
AU37077/93A AU650814B2 (en) | 1989-08-08 | 1993-04-21 | Vanadium-containing copolymer |
NO934478A NO300926B1 (no) | 1989-08-08 | 1993-12-08 | Kopolymer av propylen med etylen |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8910856A FR2650827B1 (fr) | 1989-08-08 | 1989-08-08 | Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2650827A1 FR2650827A1 (fr) | 1991-02-15 |
FR2650827B1 true FR2650827B1 (fr) | 1993-03-05 |
Family
ID=9384684
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8910856A Expired - Fee Related FR2650827B1 (fr) | 1989-08-08 | 1989-08-08 | Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium |
Country Status (19)
Country | Link |
---|---|
US (1) | US5070054A (fr) |
EP (1) | EP0412729B1 (fr) |
JP (1) | JPH0381303A (fr) |
KR (1) | KR0172119B1 (fr) |
CN (1) | CN1025339C (fr) |
AT (1) | ATE113614T1 (fr) |
AU (2) | AU639248B2 (fr) |
BR (1) | BR9003878A (fr) |
CA (1) | CA2022815C (fr) |
DD (1) | DD299652A5 (fr) |
DE (1) | DE69013798T2 (fr) |
ES (1) | ES2063281T3 (fr) |
FI (1) | FI903887A0 (fr) |
FR (1) | FR2650827B1 (fr) |
HU (1) | HUT59701A (fr) |
MY (1) | MY108533A (fr) |
NO (2) | NO175061B (fr) |
NZ (1) | NZ234816A (fr) |
RU (1) | RU2033257C1 (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2656614B1 (fr) * | 1990-01-03 | 1993-05-07 | Bp Chemicals Snc | Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium, supporte sur un chlorure de magnesium. |
US5252688A (en) * | 1990-01-03 | 1993-10-12 | Bp Chemicals Limited | Process for preparing a Ziegler-Natta type catalyst |
IT1254474B (it) * | 1992-02-28 | 1995-09-25 | Montecatini Tecnologie Srl | Processo per la preparazione di copolimeri elastomerici dell'etilene |
US5585184A (en) * | 1994-09-29 | 1996-12-17 | Union Carbide Chemicals & Plastics Technology Corporation | Colorable non-sticky resin core-shell particles |
BR9505044A (pt) * | 1994-11-02 | 1997-10-21 | Union Caribe Chemical & Plasti | Processo para a polimerização de uma ou mais olefinas processo para a polimerização de uma EPR ou EPDM homogênea |
US6391816B1 (en) * | 1999-10-27 | 2002-05-21 | Phillips Petroleum | Organometal compound catalyst |
KR20010076328A (ko) * | 2000-01-19 | 2001-08-11 | 이정태 | 티씨피/아이피를 하드웨어적으로 처리하는 장치 및 그동작방법 |
CN100460423C (zh) * | 2005-06-30 | 2009-02-11 | 中国石油化工股份有限公司 | 原位合成的负载型钒系非茂聚烯烃催化剂及制备与应用 |
CN105732699B (zh) * | 2014-12-10 | 2018-07-13 | 中国石油天然气股份有限公司 | 烷氧基钒化合物及其制备方法和应用 |
RU2682163C1 (ru) * | 2018-10-31 | 2019-03-15 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Способ приготовления ванадиймагниевого катализатора полимеризации этилена и сополимеризации этилена с альфа-олефинами |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2529207A1 (fr) * | 1982-06-24 | 1983-12-30 | Bp Chimie Sa | Procede pour la preparation de supports de catalyseurs pour la polymerisation des alpha-olefines et supports obtenus |
FR2529209A1 (fr) * | 1982-06-24 | 1983-12-30 | Bp Chimie Sa | Catalyseurs pour la polymerisation et la copolymerisation du propylene et procedes de polymerisation utilisant ces catalyseurs |
EP0099772B2 (fr) * | 1982-06-24 | 1991-11-13 | BP Chimie Société Anonyme | Catalyseurs pour la polymérisation et la copolymérisation de l'éthylène et procédés de polymérisation utilisant ces catalyseurs |
FR2529206A1 (fr) * | 1982-06-24 | 1983-12-30 | Bp Chimie Sa | Procede de preparation de supports a base de chlorure de magnesium pour la preparation de catalyseurs de polymerisation des alpha-olefines et supports obtenus |
FR2560200B1 (fr) * | 1984-02-23 | 1986-06-27 | Bp Chimie Sa | Procede de preparation de catalyseurs supportes a base de composes de vanadium pour la polymerisation et la copolymerisation de l'ethylene |
FR2649708B1 (fr) * | 1989-07-17 | 1991-10-25 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite |
FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
-
1989
- 1989-08-08 FR FR8910856A patent/FR2650827B1/fr not_active Expired - Fee Related
-
1990
- 1990-08-02 AT AT90308541T patent/ATE113614T1/de not_active IP Right Cessation
- 1990-08-02 ES ES90308541T patent/ES2063281T3/es not_active Expired - Lifetime
- 1990-08-02 DE DE69013798T patent/DE69013798T2/de not_active Expired - Fee Related
- 1990-08-02 US US07/561,786 patent/US5070054A/en not_active Expired - Lifetime
- 1990-08-02 EP EP90308541A patent/EP0412729B1/fr not_active Expired - Lifetime
- 1990-08-06 FI FI903887A patent/FI903887A0/fi not_active Application Discontinuation
- 1990-08-07 HU HU904927A patent/HUT59701A/hu unknown
- 1990-08-07 MY MYPI90001314A patent/MY108533A/en unknown
- 1990-08-07 NO NO903462A patent/NO175061B/no unknown
- 1990-08-07 CA CA002022815A patent/CA2022815C/fr not_active Expired - Fee Related
- 1990-08-08 RU SU904830915A patent/RU2033257C1/ru active
- 1990-08-08 NZ NZ234816A patent/NZ234816A/en unknown
- 1990-08-08 BR BR909003878A patent/BR9003878A/pt unknown
- 1990-08-08 AU AU60827/90A patent/AU639248B2/en not_active Ceased
- 1990-08-08 JP JP2208320A patent/JPH0381303A/ja active Pending
- 1990-08-08 KR KR1019900012157A patent/KR0172119B1/ko not_active IP Right Cessation
- 1990-08-08 DD DD90343336A patent/DD299652A5/de not_active IP Right Cessation
- 1990-08-08 CN CN90107787A patent/CN1025339C/zh not_active Expired - Fee Related
-
1993
- 1993-04-21 AU AU37077/93A patent/AU650814B2/en not_active Ceased
- 1993-12-08 NO NO934478A patent/NO300926B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
FR2650827A1 (fr) | 1991-02-15 |
CA2022815A1 (fr) | 1991-02-09 |
CN1049850A (zh) | 1991-03-13 |
AU6082790A (en) | 1991-02-14 |
AU639248B2 (en) | 1993-07-22 |
JPH0381303A (ja) | 1991-04-05 |
FI903887A0 (fi) | 1990-08-06 |
NO175061C (fr) | 1994-08-24 |
DD299652A5 (de) | 1992-04-30 |
HU904927D0 (en) | 1991-01-28 |
KR910004677A (ko) | 1991-03-29 |
NO175061B (no) | 1994-05-16 |
ATE113614T1 (de) | 1994-11-15 |
AU3707793A (en) | 1993-07-15 |
EP0412729A1 (fr) | 1991-02-13 |
US5070054A (en) | 1991-12-03 |
RU2033257C1 (ru) | 1995-04-20 |
MY108533A (en) | 1996-10-31 |
NO903462D0 (no) | 1990-08-07 |
EP0412729B1 (fr) | 1994-11-02 |
CA2022815C (fr) | 2000-12-12 |
BR9003878A (pt) | 1991-09-03 |
NO903462L (no) | 1991-02-11 |
DE69013798D1 (de) | 1994-12-08 |
NO934478L (no) | 1991-02-11 |
ES2063281T3 (es) | 1995-01-01 |
CN1025339C (zh) | 1994-07-06 |
NO934478D0 (no) | 1993-12-08 |
NO300926B1 (no) | 1997-08-18 |
NZ234816A (en) | 1991-09-25 |
AU650814B2 (en) | 1994-06-30 |
KR0172119B1 (ko) | 1999-03-30 |
DE69013798T2 (de) | 1995-03-16 |
HUT59701A (en) | 1992-06-29 |
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FR2650827B1 (fr) | Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium | |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |