FR2476098B1 - - Google Patents
Info
- Publication number
- FR2476098B1 FR2476098B1 FR8101078A FR8101078A FR2476098B1 FR 2476098 B1 FR2476098 B1 FR 2476098B1 FR 8101078 A FR8101078 A FR 8101078A FR 8101078 A FR8101078 A FR 8101078A FR 2476098 B1 FR2476098 B1 FR 2476098B1
- Authority
- FR
- France
- Prior art keywords
- methacrylate
- dmaema
- gma
- ionic
- linking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 238000005349 anion exchange Methods 0.000 abstract 1
- 239000003125 aqueous solvent Substances 0.000 abstract 1
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- -1 methacrylate ester Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F20/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The reaction of glycidyl methacrylate (GMA) with an ionogenic methacrylate ester containing amine groups of the tertiary type such as dimethylaminoethyl methacrylate (DMAEMA) in the presence of an acidic water solution produces a new and novel water soluble, ionic, cross-linking, methacrylate bifunctional monomer which is useful in the manufacture of anion exchange polymers while employing an aqueous solvent system.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/084,337 US4275227A (en) | 1979-10-12 | 1979-10-12 | Synthesis of water soluble cross-linkers and their use in the manufacture of anionic polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2476098A1 FR2476098A1 (en) | 1981-08-21 |
FR2476098B1 true FR2476098B1 (en) | 1985-03-22 |
Family
ID=22184311
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8018314A Granted FR2467192A1 (en) | 1979-10-12 | 1980-08-21 | SYNTHESIS OF WATER-SOLUBLE CROSSLINKABLE PRODUCTS AND THEIR USE IN THE MANUFACTURE OF ANIONIC POLYMERS |
FR8101078A Granted FR2476098A1 (en) | 1979-10-12 | 1981-01-21 | CROSSLINKED POLYMERIC COMPOUND, ION EXCHANGERS, PREPARATION, ELECTROCHEMICAL CELL |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8018314A Granted FR2467192A1 (en) | 1979-10-12 | 1980-08-21 | SYNTHESIS OF WATER-SOLUBLE CROSSLINKABLE PRODUCTS AND THEIR USE IN THE MANUFACTURE OF ANIONIC POLYMERS |
Country Status (8)
Country | Link |
---|---|
US (1) | US4275227A (en) |
JP (1) | JPS5668647A (en) |
CA (1) | CA1151668A (en) |
DE (1) | DE3038051A1 (en) |
FR (2) | FR2467192A1 (en) |
GB (1) | GB2061273B (en) |
IT (1) | IT1128596B (en) |
NL (1) | NL8005119A (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5847022A (en) * | 1995-03-27 | 1998-12-08 | Dainippon Ink And Chemicals, Inc. | Radiation curable resin composition and method therefor |
US6410672B1 (en) * | 1999-07-28 | 2002-06-25 | Ionics, Incorporated | Ion exchange and electrochemical methods and devices employing one-step quaternized and polymerized anion selective polymers |
US7959780B2 (en) | 2004-07-26 | 2011-06-14 | Emporia Capital Funding Llc | Textured ion exchange membranes |
US7780833B2 (en) | 2005-07-26 | 2010-08-24 | John Hawkins | Electrochemical ion exchange with textured membranes and cartridge |
US8562803B2 (en) | 2005-10-06 | 2013-10-22 | Pionetics Corporation | Electrochemical ion exchange treatment of fluids |
GB201112389D0 (en) * | 2011-07-19 | 2011-08-31 | Fujifilm Mfg Europe Bv | Curable compositions and membranes |
JP6118282B2 (en) * | 2014-02-28 | 2017-04-19 | 富士フイルム株式会社 | Ion exchange membrane and method for producing the same |
US9757695B2 (en) | 2015-01-03 | 2017-09-12 | Pionetics Corporation | Anti-scale electrochemical apparatus with water-splitting ion exchange membrane |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2946758A (en) * | 1955-10-07 | 1960-07-26 | Ici Ltd | Anion exchange resins from esters of acrylic acids with polyhydroxy substituted quaternary ammonium salts |
US3397227A (en) * | 1967-11-09 | 1968-08-13 | Shell Oil Co | Ester production |
US3678098A (en) * | 1969-04-04 | 1972-07-18 | Rohm & Haas | Unsaturated quaternary monomers and polymers |
US3694393A (en) * | 1969-04-04 | 1972-09-26 | Rohm & Haas | Method of producing paper,and paper obtained |
US3868409A (en) * | 1969-09-24 | 1975-02-25 | Broadview Chem Corp | Acrylic acid esters |
US3720656A (en) * | 1971-05-10 | 1973-03-13 | Broadview Chem Corp | Anaerobic sealant compositions |
JPS53282A (en) * | 1976-06-24 | 1978-01-05 | Nippon Paint Co Ltd | Thermosetting resin, method of preparing same, and coating composition containing same as main component |
GB2009748B (en) * | 1977-12-03 | 1982-06-30 | Nippon Paint Co Ltd | Ampho-ionic compounds and their production |
-
1979
- 1979-10-12 US US06/084,337 patent/US4275227A/en not_active Expired - Lifetime
-
1980
- 1980-08-12 CA CA000358084A patent/CA1151668A/en not_active Expired
- 1980-08-21 FR FR8018314A patent/FR2467192A1/en active Granted
- 1980-09-11 NL NL8005119A patent/NL8005119A/en not_active Application Discontinuation
- 1980-10-08 DE DE19803038051 patent/DE3038051A1/en active Granted
- 1980-10-09 GB GB8032673A patent/GB2061273B/en not_active Expired
- 1980-10-09 IT IT49862/80A patent/IT1128596B/en active
- 1980-10-09 JP JP14065380A patent/JPS5668647A/en active Granted
-
1981
- 1981-01-21 FR FR8101078A patent/FR2476098A1/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5668647A (en) | 1981-06-09 |
GB2061273A (en) | 1981-05-13 |
DE3038051C2 (en) | 1989-07-13 |
FR2467192A1 (en) | 1981-04-17 |
IT1128596B (en) | 1986-05-28 |
IT8049862A0 (en) | 1980-10-09 |
CA1151668A (en) | 1983-08-09 |
NL8005119A (en) | 1981-04-14 |
FR2476098A1 (en) | 1981-08-21 |
FR2467192B1 (en) | 1983-03-18 |
JPS6340419B2 (en) | 1988-08-11 |
GB2061273B (en) | 1984-06-27 |
DE3038051A1 (en) | 1981-04-23 |
US4275227A (en) | 1981-06-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |