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FR2317323A1 - CATION EXCHANGER MEMBRANE, ITS PREPARATION PROCESS AND ITS APPLICATIONS - Google Patents

CATION EXCHANGER MEMBRANE, ITS PREPARATION PROCESS AND ITS APPLICATIONS

Info

Publication number
FR2317323A1
FR2317323A1 FR7621093A FR7621093A FR2317323A1 FR 2317323 A1 FR2317323 A1 FR 2317323A1 FR 7621093 A FR7621093 A FR 7621093A FR 7621093 A FR7621093 A FR 7621093A FR 2317323 A1 FR2317323 A1 FR 2317323A1
Authority
FR
France
Prior art keywords
groups
ocf
membrane
brine
membranes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7621093A
Other languages
French (fr)
Other versions
FR2317323B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP50084111A external-priority patent/JPS5224176A/en
Priority claimed from JP50084112A external-priority patent/JPS5224177A/en
Priority claimed from JP3559376A external-priority patent/JPS52119486A/en
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Publication of FR2317323A1 publication Critical patent/FR2317323A1/en
Application granted granted Critical
Publication of FR2317323B1 publication Critical patent/FR2317323B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2287—After-treatment
    • C08J5/2293—After-treatment of fluorine-containing membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/08—Reinforcements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08J2300/102—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

1523047 Cation exchange membranes for brine electrolysis cells ASAHI KASEI KOGYO KK 2 July 1976 [9 July 1975(2) 31 March 1976] 27654/76 Heading C7B [Also in Divisions B5 and C3] Electrolytic cells, especially for brine, have the anode and cathode compartments separated by a cation exchange membrane comprising a fluorocarbon polymer containing pendant carboxylic groups of formula -OCF2COOM, where M is hydrogen, ammonium, quaternary ammonium or metal. The said groups are obtained by reduction of -OCF 2 CF 2 SO 3 X groups (see Division C3), and the membrane may contain residual groups of this type. Preferred membranes contain -OCF 2 COOM groups on one surface, which faces the cathode, and -OCF 2 CF 2 SO 3 M groups on the opposite surface. The membrane may be formed from a single film, or may be a composite of two polymeric films, and in either case it may further include a reinforcing layer, e.g. a fabric formed from PTFE fibres. The 27 specific examples describe a variety of such membranes and their application in the electrolysis of brine, the starting copolymers being of tetrafluoroethylene and perfluoro (3, 6-dioxa- 4-methyl-7-octene sulphonyl fluoride, in some cases with a further monomer which is hexafluoropropene, perfluoropropyl vinyl ether or perfluoro- 3, 6-dioxa-5-methyl-nonene-1.
FR7621093A 1975-07-09 1976-07-09 CATION EXCHANGER MEMBRANE, ITS PREPARATION PROCESS AND ITS APPLICATIONS Granted FR2317323A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP50084111A JPS5224176A (en) 1975-07-09 1975-07-09 Cathion exchange membrane
JP50084112A JPS5224177A (en) 1975-07-09 1975-07-09 Manufacturing method of fluorocarbon cathion exchange membrane
JP3559376A JPS52119486A (en) 1976-03-31 1976-03-31 Fluorocarbon composite membraneous product and production thereof

Publications (2)

Publication Number Publication Date
FR2317323A1 true FR2317323A1 (en) 1977-02-04
FR2317323B1 FR2317323B1 (en) 1981-02-06

Family

ID=27288811

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7621093A Granted FR2317323A1 (en) 1975-07-09 1976-07-09 CATION EXCHANGER MEMBRANE, ITS PREPARATION PROCESS AND ITS APPLICATIONS

Country Status (8)

Country Link
BR (1) BR7604438A (en)
CA (1) CA1219399A (en)
DE (1) DE2630584C3 (en)
FR (1) FR2317323A1 (en)
GB (1) GB1523047A (en)
IT (1) IT1061477B (en)
NL (1) NL161789C (en)
SE (2) SE436048B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2388831A1 (en) * 1977-04-25 1978-11-24 Tokuyama Soda Kk MANUFACTURING OF FLUOROUS POLYMERIC MATERIALS WITH CARBOXY GROUPS
FR2411899A1 (en) * 1977-12-19 1979-07-13 Asahi Chemical Ind PROCESS FOR THE ELECTROLYSIS OF SODIUM CHLORIDE USING A CATION EXCHANGE MEMBRANE
FR2457880A1 (en) * 1979-05-31 1980-12-26 Asahi Chemical Ind
FR2467247A1 (en) * 1979-10-06 1981-04-17 Toyo Soda Mfg Co Ltd PROCESS FOR ELECTROLYSIS OF ALKALI METAL HALIDES
FR2485024A1 (en) * 1977-04-20 1981-12-24 Du Pont FLUORINATED POLYMERS WITH SIDED CARBOXYLATED SIDE CHAINS, FILMS, MEMBRANES AND LAMINATED STRUCTURES EXCHANGED FROM FORMED IONS OF THESE POLYMERS AND THEIR USE IN CHLORINE-ALKALI ELECTROLYSIS CELLS

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53149881A (en) * 1977-06-03 1978-12-27 Asahi Glass Co Ltd Strengthened cation exchange resin membrane and production thereof
JPS55160028A (en) 1979-05-31 1980-12-12 Asahi Chem Ind Co Ltd Improved fluorinated cation exchange membrane and production thereof
DE3050931C2 (en) * 1979-05-31 1994-06-09 Asahi Chemical Ind Fluorinated carboxylic acid derivatives and process for their preparation
JPS5638329A (en) * 1979-09-06 1981-04-13 Asahi Chem Ind Co Ltd Fluorinated copolymer membrane and its preparation
JPS5672190A (en) * 1979-11-20 1981-06-16 Toyo Soda Mfg Co Ltd Cation exchange membrane for electrolysis of alkali metal halogenide
DE3036066A1 (en) * 1980-09-25 1982-05-06 Hoechst Ag, 6000 Frankfurt Bonding electrode to fluorine contg. copolymer electrolysis membrane - by applying electrode powder to membrane and pressing opt. with heating
JP5211418B2 (en) 2005-07-08 2013-06-12 トヨタ自動車株式会社 Manufacturing method of electrolyte membrane
US9139669B2 (en) 2009-03-24 2015-09-22 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expandable functional products obtained therefrom and reaction of the expanded products
US8658707B2 (en) 2009-03-24 2014-02-25 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expanded functional products obtained therefrom and reaction of the expanded products
US20100280200A1 (en) * 2009-03-24 2010-11-04 Poddar Tarun K Water Permeable Fluoropolymer Articles

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3017338A (en) * 1958-03-03 1962-01-16 Diamond Alkali Co Electrolytic process and apparatus
US3135673A (en) * 1961-05-05 1964-06-02 Ionics Process and apparatus for electrolyzing salt solutions
US3366610A (en) * 1965-05-14 1968-01-30 Du Pont Perhalogenated epoxy olefin monomers and polymers
GB1145445A (en) * 1966-02-16 1969-03-12 Du Pont Fluorinated perfluorovinylethers, their preparation and copolymers thereof
US3496077A (en) * 1967-12-18 1970-02-17 Hal B H Cooper Electrolyzing of salt solutions
DE1941847A1 (en) * 1968-12-31 1970-07-23 Bitterfeld Chemie Cation exchange diaphragm for electrolysis - cells
BE790369A (en) * 1971-10-21 1973-04-20 Diamond Shamrock Corp METHOD AND APPARATUS FOR THE PREPARATION OF HYDROXIDES FROM HIGH PURE ALKALINE METALS IN AN ELECTROLYTIC TANK.
BE795460A (en) * 1972-02-16 1973-08-16 Diamond Shamrock Corp PERFECTIONS RELATING TO ELECTROLYTIC TANKS
US3773634A (en) * 1972-03-09 1973-11-20 Diamond Shamrock Corp Control of an olyte-catholyte concentrations in membrane cells
JPS551351B2 (en) * 1974-03-07 1980-01-12
FR2388014A1 (en) * 1977-04-20 1978-11-17 Du Pont Fluoro-polymer ion exchangers contg. carboxylic gps. - esp. for chlorine-alkali electrolysis cells giving high current yields
FR2388013B1 (en) * 1977-04-20 1985-08-02 Du Pont FLUORINATED ION EXCHANGE POLYMERS CONTAINING CARBOXYLIC GROUPS, THEIR PREPARATION AND THEIR USE IN CHLORINE-ALKALI ELECTROLYSIS CELLS
US4200711A (en) * 1977-04-25 1980-04-29 Tokuyama Soda Kabushiki Kaisha Process for preparing fluorine-containing polymers having carboxyl groups

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2485024A1 (en) * 1977-04-20 1981-12-24 Du Pont FLUORINATED POLYMERS WITH SIDED CARBOXYLATED SIDE CHAINS, FILMS, MEMBRANES AND LAMINATED STRUCTURES EXCHANGED FROM FORMED IONS OF THESE POLYMERS AND THEIR USE IN CHLORINE-ALKALI ELECTROLYSIS CELLS
FR2388831A1 (en) * 1977-04-25 1978-11-24 Tokuyama Soda Kk MANUFACTURING OF FLUOROUS POLYMERIC MATERIALS WITH CARBOXY GROUPS
FR2411899A1 (en) * 1977-12-19 1979-07-13 Asahi Chemical Ind PROCESS FOR THE ELECTROLYSIS OF SODIUM CHLORIDE USING A CATION EXCHANGE MEMBRANE
FR2457880A1 (en) * 1979-05-31 1980-12-26 Asahi Chemical Ind
FR2467247A1 (en) * 1979-10-06 1981-04-17 Toyo Soda Mfg Co Ltd PROCESS FOR ELECTROLYSIS OF ALKALI METAL HALIDES

Also Published As

Publication number Publication date
FR2317323B1 (en) 1981-02-06
DE2630584B2 (en) 1979-01-18
GB1523047A (en) 1978-08-31
DE2630584C3 (en) 1988-02-11
BR7604438A (en) 1978-01-31
SE7607832L (en) 1977-01-10
SE7907834L (en) 1979-09-21
IT1061477B (en) 1983-02-28
NL161789B (en) 1979-10-15
SE446199B (en) 1986-08-18
SE436048B (en) 1984-11-05
CA1219399A (en) 1987-03-17
NL161789C (en) 1983-04-18
NL7607628A (en) 1977-01-11
DE2630584A1 (en) 1977-01-13

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Legal Events

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ST Notification of lapse