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FR2395778A1 - Catalyseur de polymerisation d'olefines - Google Patents

Catalyseur de polymerisation d'olefines

Info

Publication number
FR2395778A1
FR2395778A1 FR7819721A FR7819721A FR2395778A1 FR 2395778 A1 FR2395778 A1 FR 2395778A1 FR 7819721 A FR7819721 A FR 7819721A FR 7819721 A FR7819721 A FR 7819721A FR 2395778 A1 FR2395778 A1 FR 2395778A1
Authority
FR
France
Prior art keywords
iodine
catalyst
ether
reduction
catalytic activity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7819721A
Other languages
English (en)
Other versions
FR2395778B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of FR2395778A1 publication Critical patent/FR2395778A1/fr
Application granted granted Critical
Publication of FR2395778B1 publication Critical patent/FR2395778B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La présente invention concerne un procédé pour produire des catalyseurs ayant une grande activité catalytique dans la polymérisation d'oléfines et permettant d'obtenir des polyoléfine' de grande stéréorégularité et de densité volumique élevée. L'invention propose également un procédé de polymérisation qui utilise le catalyseur selon l'invention. Le catalyseur (triculorure de titane solide) est obtenu par réduction de tétrachlorure de titane avec un composé organoaluminique en présence d'un éther; lorsque la réduction est pratiquement terminée, on ajoute de l'iode au mélange réactionnel. Après traitement avec le mélange d'iode et d'éther (entre environ 30 et environ 150 degrés C), on précipite le trichlorure de titane solide et on le sépare. La présence d'iode permet d'obtenir des améliorations au point de vue activité catalytique, stéréorégularité et densité volumique des polyoléfines obtenues avec ce catalyseur.
FR7819721A 1977-06-30 1978-06-30 Catalyseur de polymerisation d'olefines Granted FR2395778A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7865577A JPS5411985A (en) 1977-06-30 1977-06-30 Preparation of olefin polymer

Publications (2)

Publication Number Publication Date
FR2395778A1 true FR2395778A1 (fr) 1979-01-26
FR2395778B1 FR2395778B1 (fr) 1982-01-22

Family

ID=13667864

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7819721A Granted FR2395778A1 (fr) 1977-06-30 1978-06-30 Catalyseur de polymerisation d'olefines

Country Status (16)

Country Link
US (2) US4246135A (fr)
JP (1) JPS5411985A (fr)
AR (1) AR221486A1 (fr)
BE (1) BE868565A (fr)
BR (1) BR7804066A (fr)
CA (1) CA1120022A (fr)
DE (1) DE2827999A1 (fr)
ES (1) ES472025A1 (fr)
FR (1) FR2395778A1 (fr)
GB (1) GB2000513A (fr)
GR (1) GR64977B (fr)
IT (1) IT1105048B (fr)
NL (1) NL7807022A (fr)
NO (1) NO782258L (fr)
PT (1) PT68242A (fr)
YU (1) YU154878A (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1152697A (fr) * 1978-12-28 1983-08-23 Kiyoshi Matsuyama Methode d'obtention de copolymere de propylene
US4382018A (en) * 1979-06-27 1983-05-03 Dart Industries, Inc. Method for making titanium trichloride catalysts
JPS5922913A (ja) * 1982-07-15 1984-02-06 Chisso Corp 高剛性成形品用ポリプロピレン樹脂
JPS59122506A (ja) * 1982-12-28 1984-07-16 Sumitomo Chem Co Ltd 軟質プロピレン重合体
EP0121011A1 (fr) * 1983-03-30 1984-10-10 Sumitomo Chemical Company, Limited Procédé de préparation d'un catalyseur solide à base de trichlorure de titane
JPH02500113A (ja) * 1987-07-10 1990-01-18 クウォンタム　ケミカル　コーポレイション プロピレン重合触媒及び方法
WO1998033823A1 (fr) * 1997-02-05 1998-08-06 The Penn State Research Foundation SYNTHESE A PARTIR DE METAUX CATALYSES D'ETHYLENE HYPERRAMIFIE ET/OU DE POLYMERES α-OLEFINE

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3129256A (en) * 1959-12-01 1964-04-14 Gulf Research Development Co Alkylation of benzene with propylene in the presence of a catalyst containing titanium tetrachloride, alkyl aluminum sesquichloride, and oxygen
US3409681A (en) * 1964-06-25 1968-11-05 Exxon Research Engineering Co Method of making novel bimetallic heterogeneous catalysts and their use in hydrocarbon conversions
US3414554A (en) * 1965-07-06 1968-12-03 Phillips Petroleum Co Polymerization process and catalyst
US3558271A (en) * 1969-06-25 1971-01-26 Benedetto Calcagno Method of preparing catalytically active ticl3
US3865749A (en) * 1973-08-30 1975-02-11 Exxon Research Engineering Co Butadiene polymerization catalyst
US4060593A (en) * 1974-07-31 1977-11-29 Mitsubishi Chemical Industries Preparation of titanium trichloride

Also Published As

Publication number Publication date
BE868565A (fr) 1978-10-16
IT7850068A0 (it) 1978-06-28
YU154878A (en) 1982-06-30
ES472025A1 (es) 1980-01-01
FR2395778B1 (fr) 1982-01-22
PT68242A (en) 1978-07-01
BR7804066A (pt) 1979-05-22
JPS5411985A (en) 1979-01-29
CA1120022A (fr) 1982-03-16
IT1105048B (it) 1985-10-28
GR64977B (en) 1980-06-11
NO782258L (no) 1979-01-03
GB2000513A (en) 1979-01-10
DE2827999A1 (de) 1979-01-18
AR221486A1 (es) 1981-02-13
NL7807022A (nl) 1979-01-03
US4246135A (en) 1981-01-20
US4304892A (en) 1981-12-08

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Legal Events

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