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FR2366299A1 - PREPARATION OF A COPPER ACETYLIDE COMPLEX AND ITS USE AS A CATALYST IN THE PREPARATION OF 1,4-BUTYNEDIOL - Google Patents

PREPARATION OF A COPPER ACETYLIDE COMPLEX AND ITS USE AS A CATALYST IN THE PREPARATION OF 1,4-BUTYNEDIOL

Info

Publication number
FR2366299A1
FR2366299A1 FR7800133A FR7800133A FR2366299A1 FR 2366299 A1 FR2366299 A1 FR 2366299A1 FR 7800133 A FR7800133 A FR 7800133A FR 7800133 A FR7800133 A FR 7800133A FR 2366299 A1 FR2366299 A1 FR 2366299A1
Authority
FR
France
Prior art keywords
preparation
butynediol
catalyst
copper acetylide
acetylide complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7800133A
Other languages
French (fr)
Other versions
FR2366299B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/803,261 external-priority patent/US4110249A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of FR2366299A1 publication Critical patent/FR2366299A1/en
Application granted granted Critical
Publication of FR2366299B1 publication Critical patent/FR2366299B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/08—Copper compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8437—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G29/00—Compounds of bismuth
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G3/00—Compounds of copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/04—Acyclic alcohols with carbon-to-carbon triple bonds
    • C07C33/042—Acyclic alcohols with carbon-to-carbon triple bonds with only one triple bond
    • C07C33/044—Alkynediols
    • C07C33/046—Butynediols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention se rapporte aux catalyseurs. Elle concerne un procédé de préparation d'un complexe d'acétyliure de cuivre, caractérisé en ce qu'on soumet des agglomérats sphéroïdaux de cristaux de carbonate de cuivre basique contenant de l'oxycarbonate de bismuth uniformément dispersé, sous forme d'une bouillie dans un milieu aqueux à l'action de formaldéhyde et d'acétylène. Utilisation dans la préparation de 1,4-butynediol.The invention relates to catalysts. It relates to a process for preparing a copper acetylide complex, characterized in that spheroidal agglomerates of basic copper carbonate crystals containing uniformly dispersed bismuth oxycarbonate are subjected in the form of a slurry in an aqueous medium with the action of formaldehyde and acetylene. Use in the preparation of 1,4-butynediol.

FR7800133A 1976-08-05 1978-01-04 PREPARATION OF A COPPER ACETYLIDE COMPLEX AND ITS USE AS A CATALYST IN THE PREPARATION OF 1,4-BUTYNEDIOL Granted FR2366299A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US71172476A 1976-08-05 1976-08-05
US05/803,261 US4110249A (en) 1976-08-05 1977-06-06 Preparation of bismuth modified spheroidal malachite

Publications (2)

Publication Number Publication Date
FR2366299A1 true FR2366299A1 (en) 1978-04-28
FR2366299B1 FR2366299B1 (en) 1984-10-05

Family

ID=27108686

Family Applications (2)

Application Number Title Priority Date Filing Date
FR7724022A Granted FR2366222A1 (en) 1976-08-05 1977-08-04 PREPARATION OF SPHEROIDAL MALACHITE MODIFIED BY BISMUTH
FR7800133A Granted FR2366299A1 (en) 1976-08-05 1978-01-04 PREPARATION OF A COPPER ACETYLIDE COMPLEX AND ITS USE AS A CATALYST IN THE PREPARATION OF 1,4-BUTYNEDIOL

Family Applications Before (1)

Application Number Title Priority Date Filing Date
FR7724022A Granted FR2366222A1 (en) 1976-08-05 1977-08-04 PREPARATION OF SPHEROIDAL MALACHITE MODIFIED BY BISMUTH

Country Status (7)

Country Link
JP (1) JPS5340700A (en)
CA (1) CA1096134A (en)
DE (1) DE2735465C2 (en)
FR (2) FR2366222A1 (en)
GB (1) GB1579039A (en)
IT (1) IT1085695B (en)
NL (1) NL7708642A (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57145523A (en) * 1981-03-04 1982-09-08 Kato Giichirou Lightning warning device utilizing transmission line
JPS6042680A (en) * 1983-08-17 1985-03-06 M Syst Giken:Kk Thunderbolt sensor
US4536491A (en) * 1984-06-04 1985-08-20 E. I. Dupont De Nemours And Company Agglomerates of malachite crystals and method for their preparation
RU2225360C1 (en) * 2003-02-25 2004-03-10 Соколов Валерий Васильевич Malachite and a method for preparation thereof
CN105642303B (en) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 Synthesize copper bismuth catalyst of 1,4 butynediols and preparation method thereof
CN105642301B (en) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 A kind of preparation method for being used to synthesize the copper bismuth catalyst of 1,4 butynediols
CN105709759B (en) * 2014-12-04 2018-04-10 中国石油化工股份有限公司 A kind of copper bismuth catalyst preparation method for being used to synthesize 1,4 butynediols
CN105709758B (en) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 A kind of copper bismuth catalyst and preparation method thereof
CN112023963B (en) * 2020-09-02 2023-07-07 河北瑞克新能源科技有限公司 Catalyst for synthesizing 1, 4-butynediol and application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3650985A (en) * 1967-10-23 1972-03-21 Du Pont Ethynylation catalyst catalyst preparation and process
BE825446A (en) * 1974-02-25 1975-08-12 PROCESS FOR CO-PRECIPITATION OF MALACHITE AND BISMUTH, PROCESS FOR PREPARATION OF A COPPERY ACETYLIDE COMPLEX FROM THE CO-PRECIPITE OBTAINED, AND COMPLEX THUS PRODUCED

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3294849A (en) * 1965-04-15 1966-12-27 Gen Aniline & Film Corp Production of alkynols and alkynediols using continuous phase silica gel carrier impregnated with 15 to 20 percent copper and 2 to 9 percent bismuth
US3560576A (en) * 1967-10-23 1971-02-02 Du Pont Ethynylation of formaldehyde

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3650985A (en) * 1967-10-23 1972-03-21 Du Pont Ethynylation catalyst catalyst preparation and process
BE825446A (en) * 1974-02-25 1975-08-12 PROCESS FOR CO-PRECIPITATION OF MALACHITE AND BISMUTH, PROCESS FOR PREPARATION OF A COPPERY ACETYLIDE COMPLEX FROM THE CO-PRECIPITE OBTAINED, AND COMPLEX THUS PRODUCED

Also Published As

Publication number Publication date
JPS5340700A (en) 1978-04-13
GB1579039A (en) 1980-11-12
FR2366222A1 (en) 1978-04-28
DE2735465C2 (en) 1986-05-07
FR2366299B1 (en) 1984-10-05
DE2735465A1 (en) 1978-02-09
CA1096134A (en) 1981-02-24
IT1085695B (en) 1985-05-28
JPS6125037B2 (en) 1986-06-13
NL7708642A (en) 1978-02-07
FR2366222B1 (en) 1984-06-08

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